CN103276313B - High-speed steel roll collar and heat treatment method - Google Patents
High-speed steel roll collar and heat treatment method Download PDFInfo
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Abstract
本发明涉及一种高速钢辊环及热处理方法,各元素成分按重量百分比为:C:1.3-1.9,B:0.4-0.8,Cr:3.0-5.0,Si:0.5-0.9,Mn:0.6-1.3,V:2.0-10.0,Ni:0.5-1.5,Mo:1.0-4.0,Nb:0.1-2.0,Co:4.5-5.0, Al:0.3-0.4,Ti:0.02-0.04,Zr:0.05-0.2, S<0.04,P<0.04,其余为Fe。本发明大幅提高了合金耐磨性、耐热性、抗热冲击性,减少轧辊在使用过程中出现的热疲劳裂纹现象及由此产生的掉肉、崩裂,体现出良好的安全性与耐磨性。本发明应用于高速线材轧机。The invention relates to a high-speed steel roll ring and a heat treatment method. The elements are composed by weight percentage: C: 1.3-1.9, B: 0.4-0.8, Cr: 3.0-5.0, Si: 0.5-0.9, Mn: 0.6-1.3 , V: 2.0-10.0, Ni: 0.5-1.5, Mo: 1.0-4.0, Nb: 0.1-2.0, Co: 4.5-5.0, Al: 0.3-0.4, Ti: 0.02-0.04, Zr: 0.05-0.2, S <0.04, P<0.04, the rest is Fe. The invention greatly improves the wear resistance, heat resistance, and thermal shock resistance of the alloy, reduces the phenomenon of thermal fatigue cracks and the resulting meat loss and cracking of the roll during use, and reflects good safety and wear resistance sex. The invention is applied to a high-speed wire rod rolling mill.
Description
技术领域 technical field
本发明涉及轧钢机械领域,尤其涉及一种高速钢辊环及热处理方法。 The present invention relates to the field of steel rolling machinery, in particular to a high-speed steel roll ring and a heat treatment method.
背景技术 Background technique
我国自1986年从国外引进首条高速线材轧机生产线以来,发展极其迅速,目前我国已建成高速线材轧机生产线100多条,高线产品的总产量已接近线材总产量的50%。随着轧机速度的提高,对轧辊质量要求越来越高,特别是轧辊表面硬度要求越来越高。常用的轧辊材质是高铬铸铁和高镍铬无限冷硬铸铁,但在高速线材轧机生产线的预精轧段和精轧段,由于轧辊辊径小且旋转速度高,通常采用辊环和辊轴机械组合而成的组合轧辊,且辊环由硬质合金通过粉末冶金方法加工而成,成本高且脆性大,使用中易出现爆辊和剥落等现象,影响轧钢生产。因此,解决辊环的材质问题是有效的提高轧钢作业效率和钢材质量,降低消耗,减轻工人劳动强度,减少事故的有效措施。辊环使用环境恶劣,对其性能要求苛刻,辊环材料要有优良的机械性能,目前我国仅辊环所耗资金超过30亿元,研制出合适的辊环材料以及制备方法,应用于轧钢设备上,必将推动轧钢行业的快速发展并节约很多资源。 Since my country introduced the first high-speed wire rod mill production line from abroad in 1986, it has developed extremely rapidly. At present, more than 100 high-speed wire rod mill production lines have been built in my country, and the total output of high-speed wire products is close to 50% of the total wire rod output. As the speed of the rolling mill increases, the requirements for the quality of the rolls are getting higher and higher, especially the requirements for the surface hardness of the rolls are getting higher and higher. Commonly used roll materials are high-chromium cast iron and high-nickel-chromium infinitely chilled cast iron, but in the pre-finishing section and finishing section of the high-speed wire rod mill production line, due to the small roll diameter and high rotation speed, roll rings and roll shafts are usually used. The combined rolls are mechanically combined, and the roll ring is made of cemented carbide through powder metallurgy. The cost is high and the brittleness is high. During use, roll bursting and peeling are prone to occur, which affects rolling production. Therefore, solving the material problem of the roll ring is an effective measure to improve the efficiency of steel rolling operations and steel quality, reduce consumption, reduce labor intensity of workers, and reduce accidents. The use environment of the roller ring is harsh, and its performance is demanding. The material of the roller ring must have excellent mechanical properties. At present, only the roller ring in my country has spent more than 3 billion yuan in funds to develop suitable materials and preparation methods for the roller ring and apply it to rolling equipment. On the one hand, it will definitely promote the rapid development of the steel rolling industry and save a lot of resources.
发明内容 Contents of the invention
本发明的目的是提供一种能保证辊环有优良的机械性能,降低生产成本,提高生产的钢材质量的高速钢辊环及热处理方法。 The purpose of the present invention is to provide a high-speed steel roller ring and a heat treatment method that can ensure excellent mechanical properties of the roller ring, reduce production costs, and improve the quality of the produced steel.
本发明是这样实现的:一种高速钢辊环,其特征在于:各元素成分按重量百分比为:C:1.3-1.9,B:0.4-0.8,Cr:3.0-5.0,Si:0.5-0.9,Mn:0.6-1.3,V:2.0-10.0,Ni:0.5-1.5,Mo:1.0-4.0,Nb:0.1-2.0,Co :4.5-5.0, Al:0.3-0.4, Ti:0.02-0.04, Zr:0.05-0.2, S<0.04,P<0.04,其余为Fe。 The present invention is achieved in the following way: a high-speed steel roll ring, characterized in that: the components of each element are: C: 1.3-1.9, B: 0.4-0.8, Cr: 3.0-5.0, Si: 0.5-0.9, Mn:0.6-1.3, V:2.0-10.0, Ni:0.5-1.5, Mo:1.0-4.0, Nb:0.1-2.0, Co:4.5-5.0, Al:0.3-0.4, Ti:0.02-0.04, Zr: 0.05-0.2, S<0.04, P<0.04, the rest is Fe.
本发明包括以下步骤:退火,淬火和2-3次回火,退火时辊环随炉加热至800-860℃,炉冷至小于500℃后炉冷或空冷;淬火时辊环随炉加热至1020-1150℃,随后风冷或空冷;回火时辊环随炉加热至500-550℃,随后炉冷或空冷,相同工艺下回火2-3次。 The present invention includes the following steps: annealing, quenching and tempering for 2-3 times. During annealing, the roller ring is heated to 800-860°C with the furnace, and after the furnace is cooled to less than 500°C, it is furnace cooled or air-cooled; during quenching, the roller ring is heated to 1020°C with the furnace. -1150°C, then air-cooled or air-cooled; during tempering, the roller ring is heated to 500-550°C with the furnace, then furnace-cooled or air-cooled, tempered 2-3 times under the same process.
本发明大幅提高了合金耐磨性、耐热性、抗热冲击性,减少轧辊在使用过程中出现的热疲劳裂纹现象及由此产生的掉肉、崩裂,体现出良好的安全性与耐磨性。 The invention greatly improves the wear resistance, heat resistance, and thermal shock resistance of the alloy, reduces the phenomenon of thermal fatigue cracks and the resulting meat loss and cracking of the roll during use, and reflects good safety and wear resistance sex.
具体实施方式 Detailed ways
一种高速钢辊环,其特征在于:各元素成分按重量百分比为:C:1.3-1.9,B:0.4-0.8,Cr:3.0-5.0,Si:0.5-0.9,Mn:0.6-1.3,V:2.0-10.0,Ni:0.5-1.5,Mo:1.0-4.0,Nb:0.1-2.0,Co :4.5-5.0, Al:0.3-0.4, Ti:0.02-0.04, Zr:0.05-0.2, S<0.04,P<0.04,其余为Fe。高速钢辊环的热处理方法,包括以下步骤:退火,淬火和2-3次回火,退火时辊环随炉加热至800-860℃,炉冷至小于500℃后炉冷或空冷;淬火时辊环随炉加热至1020-1150℃,随后风冷或空冷;回火时辊环随炉加热至500-550℃,随后炉冷或空冷,相同工艺下回火2-3次。具体实施时,本发明是在含钼高速钢中,通过提高碳、钒含量,得到高硬度的MC型碳化物,在此基础上,加入较多的钴元素,以增加高速钢的二次硬化能力、红硬性和高温硬度,从而改善辊环的高温耐磨性。还加入适量铝,以进一步提高轧辊红硬性,并改善高温耐磨性,加入铝还可改善碳化物形态,促使碳化物由连续网状分布变成断网状和孤立状分布。加入适量铌,可减轻辊环离心铸造过程中钒的偏析,使辊环的组织和性能均匀,加入少量稀土、钛、锆等元素,目的是为了细化组织,改善碳化物分布的均匀性,提高辊环综合性能,确保辊环的安全使用,并实现高速钢辊环的规模化生产和工业化应用。由于碳、钒、钴、钼等元素含量高,因此热处理后硬度高,辊面硬度均匀性好,耐磨性好,其中硬度达到69~71HRC,辊面硬度差小于1.5HRC。由于钴、钼、铝等元素的加入,使辊环具有优异的红硬性,625℃的红硬性达到59~62HRC,使辊环在高温下具有优良的耐磨性,它不仅可应用于高速线材轧机预精轧机架,也可应用于高速线材轧机精轧机架上。其中稀土、钛、锆、铝等元素经冶炼后,组织细小,碳化物分布均匀,因此具有较高的抗弯强度,达到1850~1960Mpa,冲击韧性大于10J/cm2。不含密度高的钨元素,且铌的加入可消除钒元素的偏析,因此辊环元素偏析轻,辊环辊径方向组织和性能均匀,辊身径向35mm内硬度落差小于2HRC。 A high-speed steel roll ring, characterized in that: the composition of each element by weight percentage is: C: 1.3-1.9, B: 0.4-0.8, Cr: 3.0-5.0, Si: 0.5-0.9, Mn: 0.6-1.3, V :2.0-10.0, Ni:0.5-1.5, Mo:1.0-4.0, Nb:0.1-2.0, Co:4.5-5.0, Al:0.3-0.4, Ti:0.02-0.04, Zr:0.05-0.2, S<0.04 , P<0.04, the rest is Fe. The heat treatment method of high-speed steel roller rings includes the following steps: annealing, quenching and 2-3 times of tempering. During annealing, the roller rings are heated to 800-860°C with the furnace, cooled to less than 500°C in the furnace, and then furnace-cooled or air-cooled; The ring is heated to 1020-1150°C with the furnace, then air-cooled or air-cooled; when tempering, the roller ring is heated to 500-550°C with the furnace, then furnace-cooled or air-cooled, and tempered 2-3 times in the same process. During specific implementation, the present invention obtains high-hardness MC-type carbides by increasing the content of carbon and vanadium in the molybdenum-containing high-speed steel. On this basis, more cobalt elements are added to increase the secondary hardening of the high-speed steel. ability, red hardness and high temperature hardness, thereby improving the high temperature wear resistance of the roller ring. An appropriate amount of aluminum is also added to further increase the red hardness of the roll and improve the high temperature wear resistance. The addition of aluminum can also improve the shape of carbides and promote the distribution of carbides from continuous network to broken network and isolated distribution. Adding an appropriate amount of niobium can reduce the segregation of vanadium in the centrifugal casting process of the roller ring, and make the structure and performance of the roller ring uniform. Adding a small amount of rare earth, titanium, zirconium and other elements aims to refine the structure and improve the uniformity of carbide distribution. Improve the comprehensive performance of the roller ring, ensure the safe use of the roller ring, and realize the large-scale production and industrial application of the high-speed steel roller ring. Due to the high content of carbon, vanadium, cobalt, molybdenum and other elements, the hardness after heat treatment is high, the hardness uniformity of the roller surface is good, and the wear resistance is good. The hardness reaches 69-71HRC, and the hardness difference of the roller surface is less than 1.5HRC. Due to the addition of cobalt, molybdenum, aluminum and other elements, the roller ring has excellent red hardness, and the red hardness at 625 °C reaches 59-62HRC, which makes the roller ring have excellent wear resistance at high temperatures. It can not only be used for high-speed wire rods The pre-finishing stand of the rolling mill can also be applied to the finishing stand of the high-speed wire rod mill. Among them, rare earth, titanium, zirconium, aluminum and other elements after smelting have fine structure and uniform distribution of carbides, so they have high bending strength, reaching 1850-1960Mpa, and impact toughness greater than 10J/cm 2 . It does not contain high-density tungsten elements, and the addition of niobium can eliminate the segregation of vanadium elements, so the element segregation of the roll ring is light, the structure and performance of the roll ring diameter are uniform, and the hardness drop within 35mm in the radial direction of the roll body is less than 2HRC.
本发明生产的辊环在高速线材轧机上具有良好的使用效果。 The roll ring produced by the present invention has a good effect on high-speed wire rolling mills.
实施例1 Example 1
在高线预精轧机架上使用,效果如下:轧普线钢:5500~6000t/单槽,修磨量0.5~0.7mm/单边;轧硬线钢:3500~4000t/单槽,修磨量0.6~0.8mm/单边。 Used on the high-line pre-finishing mill stand, the effect is as follows: rolling ordinary steel: 5500-6000t/single groove, grinding amount 0.5-0.7mm/side; rolling hard wire steel: 3500-4000t/single groove, grinding Amount of 0.6 ~ 0.8mm / single side.
实施例2 Example 2
在高线精轧机架上使用,效果如下:轧普线钢:1200~1500t/单槽,修磨量0.5~0.7mm/单边;轧硬线钢:750~900t/单槽,修磨量0.6~0.8mm/单边。 It is used on the high-speed finish rolling stand, and the effect is as follows: rolling ordinary steel: 1200~1500t/single groove, grinding amount 0.5~0.7mm/side; rolling hard wire steel: 750~900t/single groove, grinding amount 0.6~0.8mm/one side.
本发明辊环的轧钢量和修磨量,无论是应用于高线预精轧机架,还是应用于精轧机架上,均达到了硬质合金辊环的水平,但生产成本比硬质合金辊环降低40~50%,且克服了硬质合金辊环易爆辊和剥落的不足,降低了轧材生产成本,具有显著的经济和社会效益。 The amount of rolled steel and the amount of grinding of the roll ring of the present invention, no matter it is applied to the high-line pre-finishing stand or the finishing stand, has reached the level of the hard alloy roll ring, but the production cost is lower than that of the hard alloy roll The ring is reduced by 40-50%, and the disadvantages of the hard alloy roll ring being explosive and peeling off are overcome, the production cost of the rolled material is reduced, and significant economic and social benefits are obtained.
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CN103602925B (en) * | 2013-11-29 | 2015-08-12 | 内蒙古包钢钢联股份有限公司 | A kind of containing the heating of Ni steel and the method removing iron scale |
CN103757556B (en) * | 2014-01-24 | 2015-11-11 | 东北大学 | A kind of Roller of High material for powder ore and roll surface preparation method |
CN105755379B (en) * | 2016-03-09 | 2017-10-31 | 安徽环渤湾高速钢轧辊有限公司 | Wear-resistant high speed steel collars for kocks milling trains and preparation method thereof |
CN105935776A (en) * | 2016-06-24 | 2016-09-14 | 中国航空工业集团公司西安飞机设计研究所 | Composite manufacturing method for titanium alloy lug |
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CN100575528C (en) * | 2005-05-10 | 2009-12-30 | 酒泉钢铁(集团)有限责任公司 | Cobalt-free multi-element high-speed tool steel and manufacturing method thereof |
CN101240402B (en) * | 2008-02-04 | 2010-04-07 | 娄底市三泰轧辊有限公司 | Cast high-boron high-speed steel for composite ring roller and heat treatment method thereof |
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