CN103266027B - Allantoin skin-care washing-up liquid - Google Patents
Allantoin skin-care washing-up liquid Download PDFInfo
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- CN103266027B CN103266027B CN201310205038.8A CN201310205038A CN103266027B CN 103266027 B CN103266027 B CN 103266027B CN 201310205038 A CN201310205038 A CN 201310205038A CN 103266027 B CN103266027 B CN 103266027B
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Abstract
The invention discloses an allantoin skin-care washing-up liquid prepared from the following raw materials in parts by weight: 4-6 parts of disodium stearoamphodiacetate, 4-6 parts of behenamidopropyl betaine, 2-4 parts of cocamidopropylamine oxide, 5-7 parts of decyl polyglucoside, 0.05-0.15 part of allantoin and 80 parts of water. A nonionic surfactant and an ampholytic surfactant are compounded and the traditional anionic surfactant is abandoned, so a good decontamination washing effect is guaranteed and the pungency to the surfaces of hands is greatly reduced; and allantoin is compounded, so when the allantoin skin-care washing-up liquid is used for cleaning tableware, xerodermia, psoriasis and skin ulcer are remitted effectively and the skin can be protected effectively.
Description
Technical field:
The present invention relates to a kind of liquid detergent, particularly a kind of wallantoin skin-care detergent.
Background technology:
Liquid washing agent is a large class in synthetic detergent, and in synthetic detergent, output maximum is washing powder, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities compared with solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid washing agent is the articles for washing using water or other organic solvents as base-material, and it has the characteristic of surfactant soln.Generally the liquid product with cleaning function is called to liquid washing agent.Be divided into liquid detergent, fabric liquid detergent, shampoo and skin cleaner and hard surface cleaner according to purposes or function.
Liquid detergent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be for washing water fruit, vegetables and the heavy clothing of greasy dirt.It is the indispensable washing product of catering industry and family.
Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent is on the market a feast for the eyes, have detersive power superpower, have concentrated type and strong sterilizing power etc.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be take environment-friendly and green type as main flow.Except having the function of strong detersive power, harmless, sterilization and disinfection, gentle high bubble, also should easily degrade, free from environmental pollution.The effective constituent of dish washing detergent is mainly tensio-active agent, and traditional dish washing detergent is mainly take synthetic surfactant (as LAS, AS, AES, SAS etc.) as raw material.But being difficult for degraded mostly, they maybe cannot degrade, to environment.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially, in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, particularly functional liquid detergent is just fewer.
Summary of the invention:
For prior art above shortcomings, technical problem to be solved by this invention is to provide a kind of wallantoin skin-care detergent.
Technical problem of the present invention, is solved by following technical proposals:
A kind of wallantoin skin-care detergent, is made up of the raw material of following weight part: stearyl both sexes base oxalic acid disodium 4-6 part, mountain Yu amido propyl betaine 4-6 part, cocamidopropyl propyl amide amine oxide 2-4 part, Dodecyl Polyglucosides 5-7 part, wallantoin 0.05-0.15 part, 80 parts, water.
Stearyl both sexes base oxalic acid disodium, mountain Yu amido propyl betaine, cocamidopropyl propyl amide amine oxide, Dodecyl Polyglucosides and wallantoin are added to the water, are heated to 40-60 ℃, mix, can make this wallantoin skin-care detergent.
Raw material involved in the present invention is made to simple introduction below:
Stearyl both sexes base oxalic acid disodium, DISODIUM STEAROAMPHODIACETATE, No. CAS: 69868-14-0.
Mountain Yu amido propyl betaine, BEHENAMIDOPROPYL BETAINE, No. CAS: 84082-44-0.
Cocamidopropyl propyl amide amine oxide, Cocamidopropylamine oxide, 68155-09-9.
Dodecyl Polyglucosides, CAS accession number: 110615-47-9.
Wallantoin, Chinese another name: Allantoin, Allantoin, Allantion, Allantoin, English name: Allantoin, English another name: Alantan, Allegron, Alphosyl, Alyonyldiurened, Cordianine, Egopsoryl, Sebical, CAS accession number: 97-59-6.
Wallantoin skin-care detergent of the present invention; adopt nonionogenic tenside and amphoterics composite; abandon traditional anion surfactant; in guaranteeing good decontamination washing effect; greatly reduce the pungency to watch face; composite wallantoin simultaneously, uses the present invention can effectively alleviate xeroderma, scales of skin that peel off skin illness and skin ulcer in clean tableware, thereby effectively protects skin.
Embodiment:
Embodiment further illustrates of the present invention below, rather than limits the scope of the invention.In the present invention, if no special instructions, each raw material is all take working substance content as 100%.
Embodiment 1
0.1 kilogram of 5 kilograms of stearyl both sexes base oxalic acid disodiums, 5 kilograms of mountain Yu amido propyl betaines, 3 kilograms of cocamidopropyl propyl amide amine oxides, 6 kilograms of Dodecyl Polyglucosides and wallantoin is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative example 1
0.1 kilogram of 13 kilograms of stearyl both sexes base oxalic acid disodiums, 6 kilograms of Dodecyl Polyglucosides and wallantoin is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative example 2
0.1 kilogram of 13 kilograms of mountain Yu amido propyl betaines, 6 kilograms of Dodecyl Polyglucosides and wallantoin is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative example 3
0.1 kilogram of 13 kilograms of cocamidopropyl propyl amide amine oxides, 6 kilograms of Dodecyl Polyglucosides and wallantoin is added in the deionized water of 80 kilograms, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Test case 1:
Detergency test:
1) preparation of artificial dirt
Mixing oil formula: take butter, lard, vegetables oil mass ratio as 0.5:0.5:1 preparation, and add the glyceryl monostearate of its total mass 5%, this is artificial dirt.
Artificial dirt is put on electric furnace and is heated to 180 ℃, stir and keep this temperature 10min, beaker is moved to magnetic stirrer and stir, naturally cool to temperature required for subsequent use.The temperature of defiling is recommended reference: in the time that room temperature is 20 ℃, need 80 ℃ of oil temperatures; When room temperature is 25 ℃, need 45 ℃ of oil temperatures; When room temperature is lower than 17 ℃ or during higher than 27 ℃, test should not be carried out, and need to carry out at air conditioning room.Should use if desired the Terg-O-Tometer of attached freezing plant.
2) preparation of dirty sheet
Edge on slide glass is drawn to 10mm line, be limited in this below line to show to defile; Edge under slide glass is drawn to 5mm line, to show that the unnecessary greasy dirt of wiping is limited in this below line.
3) newly purchasing slide glass need to boil after 15min in detergent solution, and clear water washing is put in acid wash liquid again and soaked after 1h to not hanging the globule, and clear water rinsing and distilled water flushing are put loft drier for subsequent use after dry.
4) preparation of standard dish washing detergent
Take 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts, urea, adds water to 100 parts, mixes, with hydrochloric acid or sodium hydroxide adjusting pH to 7-8, for subsequent use.
5) defile
Clean slide glass is put and weighed on frame take four as one group, accurately weigh (accurately to 1mg) for m0 with analytical balance, the slide glass after weighing is sandwiched on film airing stand one by one, more than clip should be clipped in slide glass ascender line, film airing stand is put to ward off in dish and prepare to defile.
In the time that greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, slide glass is immersed (1-2) s, slowly taking-up to 10mm ascender line in greasy dirt by hand-held clip, after the lower speed of greasy dirt is slack-off, hangs back and on original film airing stand, prepare successively dirty sheet.After greasy dirt solidifies, by dirty sheet take off with filter paper or absorbent cotton by under dirty sheet along base in 5mm and the unnecessary greasy dirt in both sides wipe, then speckle with the absorbent cotton wiped clean of sherwood oil with tweezers folder.Under room temperature, hanging after 4h, is m1 weighing on frame with analytical balance accurate weighing.Now on every group of dirty sheet, dirty amount should guarantee (0.5 ± 0.05) g.
6) testing sequence
The slide glass of the known amount of defiling is inserted in corresponding wash stand and prepares to wash.
Spotter is switched on power, and wash temperature is set to 30 ℃, and velocity of rotation is set to 160r/min, and washing time is set to 3min.
Take 5.00g sample to be tested in 2500mL hard water, after shaking up, measure respectively 800mL test solution in three washing becks of Terg-O-Tometer, in the time that test solution temperature rises to 30 ℃, rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand, after putting into washing beck, last wash stand starts to count soak time, rapidly agitator is installed simultaneously, while soaking 1min, start spotter, start washing, when 3min, machine auto stop, rapidly agitator is taken off, take out wash stand, press from both sides one by one and hang on original film airing stand washing rear dirty sheet, extension dries in the air and dirty sheet is put to corresponding weighing frame after 3h and weighed as m2.
(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)
In formula: m0---slide glass quality before defiling, g; M1---slide glass quality after defiling, g; M2---the quality of dirty sheet after washing, g.
The rate of deoiling test chart
| ? | The rate of deoiling ω, % |
| Embodiment 1 | 45.2 |
| Standard dish washing detergent | 38.2 |
| Comparative example 1 | 38.3 |
| Comparative example 2 | 39.6 |
| Comparative example 3 | 37.0 |
Wallantoin skin-care detergent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandon traditional anion surfactant, and amphoterics stearyl both sexes base oxalic acid disodium, mountain Yu amido propyl betaine and cocamidopropyl propyl amide amine oxide and nonionogenic tenside Dodecyl Polyglucosides composite (embodiment 1) synergy as can be seen from the above table, compare with nonionogenic tenside Dodecyl Polyglucosides composite (comparative example 1-3) with single amphoterics, detersive power obviously improves.
Test case 2:
Pungency test
Simulation irritant experiment carries out in laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 ℃ of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.After marking according to the standard of following table for the pungency of wrist-watch skin, average again, mark higher, pungency is less.
Pungency test data table
| ? | Scoring |
| Embodiment 1 | 100 |
| Standard dish washing detergent | 50 |
| Comparative example 1 | 95 |
| Comparative example 2 | 90 |
| Comparative example 3 | 95 |
Embodiment 2
For extending the quality guaranteed period of the present invention, contriver has made following research pioneeringly.
In the prepared liquid detergent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, formed by weight by following component: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and tennecetins (CAS:7681-93-8).
; this wallantoin skin-care detergent is made up of the raw material of following weight part: 5 kilograms of stearyl both sexes base oxalic acid disodiums; 5 kilograms of mountain Yu amido propyl betaines; 3 kilograms of cocamidopropyl propyl amide amine oxides; 6 kilograms of Dodecyl Polyglucosides; 0.1 kilogram of wallantoin, 80 kilograms, water, 0.05 kilogram of composite environmental-friendly sanitas.
By adding the sanitas of specific proportioning on the basis at embodiment 1, greatly extend the quality guaranteed period of this wallantoin skin-care detergent.By 10 days 1 quality guaranteed perioves of embodiment, extend to 18 months.In addition, contrast, by the general single sanitas 1 of the industry for the composite environmental-friendly sanitas in embodiment 2,3-dihydroxymethyl-5,5-T10 is replaced, and add-on is constant, and its quality guaranteed period is only December.
Claims (1)
1. a wallantoin skin-care detergent, it is characterized in that, raw material by following weight part forms: stearyl both sexes base oxalic acid disodium 4-6 part, mountain Yu amido propyl betaine 4-6 part, cocamidopropyl propyl amide amine oxide 2-4 part, Dodecyl Polyglucosides 5-7 part, wallantoin 0.05-0.15 part, 80 parts, water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310205038.8A CN103266027B (en) | 2013-05-28 | 2013-05-28 | Allantoin skin-care washing-up liquid |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310205038.8A CN103266027B (en) | 2013-05-28 | 2013-05-28 | Allantoin skin-care washing-up liquid |
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| CN103266027A CN103266027A (en) | 2013-08-28 |
| CN103266027B true CN103266027B (en) | 2014-06-18 |
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| CN103275820B (en) * | 2013-05-28 | 2015-01-21 | 安徽省林锦记食品工业有限公司 | Mango seed oil skin-protecting detergent |
| CN103725445A (en) * | 2013-12-10 | 2014-04-16 | 芜湖华海生物工程有限公司 | Allantoin-containing non-residue traditional Chinese medicine washing-up liquid |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE19918267A1 (en) * | 1999-04-22 | 2000-10-26 | Henkel Kgaa | Surfactant-containing material, e.g., a washing-up liquid, which includes microcapsules in which incompatible or sensitive components are enclosed |
| DE10003567A1 (en) * | 2000-01-27 | 2001-08-09 | Henkel Kgaa | Combination of surfactants |
| WO2007065575A1 (en) * | 2005-12-09 | 2007-06-14 | Dsm Ip Assets B.V. | Stabilizing composition |
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Effective date of registration: 20190920 Address after: 233010 Incubation Workshop, 414 Changle Road, Yuhui District, Bengbu City, Anhui Province Patentee after: Bengbu Xingshi Intellectual Property Operations Co., Ltd. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Patentee before: Shanghai Yanzi Chemical Technology Co., Ltd. |
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Effective date of registration: 20210325 Address after: 241000 No.1 xiajiahu Road, economic development zone, Sanshan District, Wuhu City, Anhui Province Patentee after: WUHU HUAHAI BIOTECH Co.,Ltd. Address before: 233010 1st floor, incubation workshop, Industrial Automation Research Institute, 414 Changle Road, Yuhui District, Bengbu City, Anhui Province Patentee before: Bengbu Xingshi Intellectual Property Operations Co.,Ltd. |
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Denomination of invention: Allantoin skin care detergent Effective date of registration: 20220601 Granted publication date: 20140618 Pledgee: Wuhu Sanshan sub branch of Huishang Bank Co.,Ltd. Pledgor: WUHU HUAHAI BIOTECH CO.,LTD. Registration number: Y2022980006831 |
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