CN103232773A - Waterborne luminescent paint with anion releasing function - Google Patents
Waterborne luminescent paint with anion releasing function Download PDFInfo
- Publication number
- CN103232773A CN103232773A CN2013101412733A CN201310141273A CN103232773A CN 103232773 A CN103232773 A CN 103232773A CN 2013101412733 A CN2013101412733 A CN 2013101412733A CN 201310141273 A CN201310141273 A CN 201310141273A CN 103232773 A CN103232773 A CN 103232773A
- Authority
- CN
- China
- Prior art keywords
- paint
- releasing function
- negative ion
- fluorescent coating
- aqueous fluorescent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000001450 anions Chemical class 0.000 title abstract description 6
- 239000005101 luminescent paint Substances 0.000 title abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- 229940070527 tourmaline Drugs 0.000 claims abstract description 7
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 7
- 239000011032 tourmaline Substances 0.000 claims abstract description 7
- 239000013530 defoamer Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 27
- 239000011248 coating agent Substances 0.000 claims description 25
- 150000002500 ions Chemical class 0.000 claims description 19
- 230000008719 thickening Effects 0.000 claims description 10
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical group [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- -1 propylene soda Chemical compound 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 230000008961 swelling Effects 0.000 claims description 5
- ORRQAJNPUXDISB-UHFFFAOYSA-N manganese silicic acid zinc Chemical group [Mn].[Zn].[Si](O)(O)(O)O ORRQAJNPUXDISB-UHFFFAOYSA-N 0.000 claims description 4
- 239000005083 Zinc sulfide Substances 0.000 claims description 3
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 3
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 4
- 241000894006 Bacteria Species 0.000 abstract description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 230000036541 health Effects 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- 230000001900 immune effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention belongs to the field of paint and discloses a waterborne luminescent paint with an anion releasing function. The paint is characterized by comprising the following raw materials in percentage by weight: 0.5-1% of ethylene glycol, 20-60% of acrylic resin emulsion, 1.5-5% of tourmaline powder, 2-5% of diatomite, 0.5-1% of titanium dioxide, 1-2% of calcium sulfate whisker, 5-20% of long afterglow phosphor, 0.5-2% of dispersant, 0.6-2% of thickening agent, 0.15-0.5% of defoamer and the balance of water. The paint disclosed by the invention takes water as solvent, is safe, free from environment pollution, wide in application range, and suitable for various occasions needing the luminescent paint. The luminescent paint disclosed by the invention has an anion releasing function and can effectively block the volatilization of harmful substances in a base material, such as formaldehyde, benzene, and dimethylbenzene; the anions released by the paint can actively combine with fine grains such as dust particles, bacteria and the like in air to play a role in purifying environment and killing bacteria; and in addition, the paint has fluorescence and can effectively prevent lots of hidden dangers.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of aqueous fluorescent coating with negative ion-releasing function.
Background technology
Along with rapid economic development, people more and more pay attention to the health of self, have a health environment and be the primary prerequisite that keeps self health.At present, most of coating is solvent based coating, contains 50% the organic solvent of having an appointment in the solvent based coating, can discharge a large amount of VOC gas behind these paint spay-coatings, and not only serious harm healthy to the end user also can pollute atmosphere, damages ecotope.
According to statistics, the VOC that human life and activity in production are discharged in the atmosphere accounts for 15% of global atmosphere contamination level, and coating processing and produce the VOC amount that discharges and account for 20% ~ 30% of its total emission volumn, is only second to emission of automobile wastes and occupies second of contamination level.Therefore, the discharging of control coating VOC more and more is subject to people's attention.Water-borne coatings is as the ideal substitute of solvent based coating, with its advantage such as safe, nontoxic, pollution-free, enjoys the research and development scholar's of all circles concern.
Many public places will produce great potential safety hazard when losing light source, as underpass, stair corridor etc.At this time, just need badly in these places and scribble fluorescent coating, reduce potential safety hazard.Elsewhere as hazard indexs such as various safe emergency starting signs, high voltage electric, also needs this coating.
Negative ion is described as the air VITAMIN, has environmental protection, health, sterilization three big functions, can not only purify air, and can also strengthen people's resistibility, enhances metabolism, and existing medical research shows that the anion number of keeping health of people is 1000-2000/cm
3, and the anion number of dwelling house, office has only 40-50/cm now
3, far less than keeping healthy standard-required, be the problem that paint field is needed solution badly so develop a kind of aqueous fluorescent coating with negative ion-releasing function.
Summary of the invention
Purpose of the present invention just provides a kind of aqueous fluorescent coating with negative ion-releasing function.
The technical solution used in the present invention is as follows:
A kind of aqueous fluorescent coating with negative ion-releasing function, its raw material and weight percent thereof are ethylene glycol 0.5 ~ 1%, Emulsion acrylic resin 30% ~ 60%, tourmaline powder 1.5 ~ 5%, diatomite 2 ~ 5%, titanium dioxide 0.5 ~ 1%, calcium sulfate crystal whiskers 1 ~ 2%, luminescent powder 5 ~ 20%, dispersion agent 0.5 ~ 2%, thickening material 0.6 ~ 2%, defoamer 0.15 ~ 0.5%, and all the other are water.
Described luminescent powder is silicic acid zinc-manganese or zinc sulphide.
Described dispersion agent is Tetramethylammonium hydroxide or palmityl trimethyl ammonium chloride.
Described thickening material is propylene soda acid swelling type thickening material.
Described defoamer is nonionic surface active agent.
Preparation process of the present invention is: (1) is added to the water ethylene glycol, Emulsion acrylic resin, dispersion agent, thickening material, defoamer at normal temperatures and stirs; (2) tourmaline powder, diatomite, titanium dioxide, calcium sulfate crystal whiskers, luminescent powder are stirred in the normal temperature high speed dispersor after, grind to form fine powder; (3) product that step (1) and step (2) are drawn is poured under 0 ℃ in the stirred pot by a certain percentage, slowly stirs and is warming up to room temperature, obtains described aqueous fluorescent coating with negative ion-releasing function.
The mechanism of action of the present invention: the aqueous fluorescent coating that (1) has negative ion-releasing function is coated on the base material, forms the required epipolic pattern that has on its surface, can effectively reduce the time potential safety hazard that produces that the public place loses light source; (2) the aqueous fluorescent coating with negative ion-releasing function forms a kind of protective membrane at substrate surface; blocked the volatilization of objectionable impuritiess such as formaldehyde, benzene, dimethylbenzene in the base material; and the negative ion of its release can initiatively be combined with particulates such as koniology particle, bacteriums, plays the effect of environment purification, sterilization.
The present invention has the following advantages: (1) product of the present invention is solvent with water, product safety, environmentally safe; (2) product of the present invention has negative ion-releasing function, meets the basic demand of health of people, under this environment, has strengthened immunological competence and the antibacterial ability of human body greatly; (3) product of the present invention has fluorescence, can effectively avoid many potential safety hazards; (4) application range of products of the present invention is wider, can be used for the various places that need fluorescent coating.
Specific embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment 1
A kind of aqueous fluorescent coating with negative ion-releasing function, content comprises following component by mass percentage: ethylene glycol 1%, Emulsion acrylic resin 30%, tourmaline powder 1.5%, diatomite 3.5%, titanium dioxide 1%, calcium sulfate crystal whiskers 2%, silicic acid zinc-manganese 20%, Tetramethylammonium hydroxide 2%, propylene soda acid swelling type thickening 1.6%, nonionic surface active agent 0.25%, water 37.15%.
Embodiment 2
A kind of aqueous fluorescent coating with negative ion-releasing function, content comprises following component by mass percentage: ethylene glycol 0.5%, Emulsion acrylic resin 60%, tourmaline powder 5%, diatomite 2%, titanium dioxide 0.5%, calcium sulfate crystal whiskers 1%, zinc sulphide 5%, palmityl trimethyl ammonium chloride 0.5%, propylene soda acid swelling type thickening material 0.6%, nonionic surface active agent 0.15%, water 24.75%.
Embodiment 3
A kind of aqueous fluorescent coating with negative ion-releasing function, content comprises following component by mass percentage: ethylene glycol 0.7%, Emulsion acrylic resin 45%, tourmaline powder 3.5%, diatomite 5%, titanium dioxide 0.75%, calcium sulfate crystal whiskers 1.5%, silicic acid zinc-manganese 15%, Tetramethylammonium hydroxide 1%, propylene soda acid swelling type thickening material 2%, nonionic surface active agent 0.5%, water 25.05%.
Above-described embodiment only is the explanation to product of the present invention; be not that the present invention is made any pro forma restriction; do not breaking away within the technical scheme scope of the present invention, any technology contents that utilizes above-mentioned announcement is made the equivalent of simple transformation, all belongs to protection scope of the present invention.
Claims (5)
1. aqueous fluorescent coating with negative ion-releasing function, it is characterized in that its raw material and weight percent thereof are ethylene glycol 0.5 ~ 1%, Emulsion acrylic resin 20% ~ 60%, tourmaline powder 1.5 ~ 5%, diatomite 2 ~ 5%, titanium dioxide 0.5 ~ 1%, calcium sulfate crystal whiskers 1 ~ 2%, luminescent powder 5 ~ 20%, dispersion agent 0.5 ~ 2%, thickening material 0.6 ~ 2%, defoamer 0.15 ~ 0.5%, all the other are water.
2. the aqueous fluorescent coating with negative ion-releasing function according to claim 1 is characterized in that described luminescent powder is silicic acid zinc-manganese or zinc sulphide.
3. the aqueous fluorescent coating with negative ion-releasing function according to claim 1 is characterized in that described dispersion agent is Tetramethylammonium hydroxide or palmityl trimethyl ammonium chloride.
4. the aqueous fluorescent coating with negative ion-releasing function according to claim 1 is characterized in that described thickening material is propylene soda acid swelling type thickening material.
5. the aqueous fluorescent coating with negative ion-releasing function according to claim 1 is characterized in that described defoamer is nonionic surface active agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101412733A CN103232773A (en) | 2013-04-23 | 2013-04-23 | Waterborne luminescent paint with anion releasing function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101412733A CN103232773A (en) | 2013-04-23 | 2013-04-23 | Waterborne luminescent paint with anion releasing function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103232773A true CN103232773A (en) | 2013-08-07 |
Family
ID=48880846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013101412733A Withdrawn CN103232773A (en) | 2013-04-23 | 2013-04-23 | Waterborne luminescent paint with anion releasing function |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103232773A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103468072A (en) * | 2013-09-03 | 2013-12-25 | 吴江市冰心文教用品有限公司 | Inorganic fluorescent paint |
| CN103496917A (en) * | 2013-09-18 | 2014-01-08 | 武汉理工大学 | Ecologically functional interior and exterior wall inorganic coating and application method thereof |
| CN104263153A (en) * | 2014-09-19 | 2015-01-07 | 句容亿格纳米材料厂 | Energy storage type self-luminous nano coating material |
| CN104449306A (en) * | 2013-09-24 | 2015-03-25 | 丹阳恒安化学科技研究所有限公司 | Technique for processing latex paint |
| CN105113293A (en) * | 2015-08-20 | 2015-12-02 | 浙江百德纺织有限公司 | Fluorescent textile dye |
| CN105273544A (en) * | 2015-11-18 | 2016-01-27 | 广州聚注专利研发有限公司 | Water-based fluorescent paint and preparation method thereof |
| CN104263153B (en) * | 2014-09-19 | 2017-01-04 | 句容亿格纳米材料厂 | A kind of accumulating type self-luminous nano paint |
| CN108325804A (en) * | 2018-03-13 | 2018-07-27 | 济南启程雄宇绿色建材有限公司 | A kind of acrylic emulsion based on nano-negative ion and CdSe quantum dot |
| CN109423131A (en) * | 2017-06-29 | 2019-03-05 | 上海前引科技有限公司 | A kind of hotel guest room antimildew and antibacterial anion Upholstering design construction method |
| CN110643232A (en) * | 2019-10-22 | 2020-01-03 | 嘉兴凤翼特种材料科技有限公司 | Energy-storage luminous anion water-based interior wall coating and preparation method thereof |
| CN111040559A (en) * | 2019-12-25 | 2020-04-21 | 湖南航天三丰科工有限公司 | Water-based fluorescent paint and preparation method thereof |
Citations (5)
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| KR100732936B1 (en) * | 2006-01-26 | 2007-06-27 | 이상준 | Functional Water-Based Paint Composition |
| CN102329544A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Environmentally-friendly photocatalyst air freshening inner wall coating and preparation method thereof |
| CN102391733A (en) * | 2011-12-20 | 2012-03-28 | 袁文君 | Multifunctional green environment-friendly interior wall emulsion paint |
| CN102850837A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Additive for fluorescent pavement paint |
| CN102898880A (en) * | 2012-08-14 | 2013-01-30 | 成钢 | Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint |
-
2013
- 2013-04-23 CN CN2013101412733A patent/CN103232773A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100732936B1 (en) * | 2006-01-26 | 2007-06-27 | 이상준 | Functional Water-Based Paint Composition |
| CN102329544A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Environmentally-friendly photocatalyst air freshening inner wall coating and preparation method thereof |
| CN102391733A (en) * | 2011-12-20 | 2012-03-28 | 袁文君 | Multifunctional green environment-friendly interior wall emulsion paint |
| CN102898880A (en) * | 2012-08-14 | 2013-01-30 | 成钢 | Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint |
| CN102850837A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Additive for fluorescent pavement paint |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103468072A (en) * | 2013-09-03 | 2013-12-25 | 吴江市冰心文教用品有限公司 | Inorganic fluorescent paint |
| CN103496917A (en) * | 2013-09-18 | 2014-01-08 | 武汉理工大学 | Ecologically functional interior and exterior wall inorganic coating and application method thereof |
| CN104449306A (en) * | 2013-09-24 | 2015-03-25 | 丹阳恒安化学科技研究所有限公司 | Technique for processing latex paint |
| CN104263153A (en) * | 2014-09-19 | 2015-01-07 | 句容亿格纳米材料厂 | Energy storage type self-luminous nano coating material |
| CN104263153B (en) * | 2014-09-19 | 2017-01-04 | 句容亿格纳米材料厂 | A kind of accumulating type self-luminous nano paint |
| CN105113293A (en) * | 2015-08-20 | 2015-12-02 | 浙江百德纺织有限公司 | Fluorescent textile dye |
| CN105273544A (en) * | 2015-11-18 | 2016-01-27 | 广州聚注专利研发有限公司 | Water-based fluorescent paint and preparation method thereof |
| CN109423131A (en) * | 2017-06-29 | 2019-03-05 | 上海前引科技有限公司 | A kind of hotel guest room antimildew and antibacterial anion Upholstering design construction method |
| CN108325804A (en) * | 2018-03-13 | 2018-07-27 | 济南启程雄宇绿色建材有限公司 | A kind of acrylic emulsion based on nano-negative ion and CdSe quantum dot |
| CN110643232A (en) * | 2019-10-22 | 2020-01-03 | 嘉兴凤翼特种材料科技有限公司 | Energy-storage luminous anion water-based interior wall coating and preparation method thereof |
| CN111040559A (en) * | 2019-12-25 | 2020-04-21 | 湖南航天三丰科工有限公司 | Water-based fluorescent paint and preparation method thereof |
| CN111040559B (en) * | 2019-12-25 | 2021-09-03 | 湖南航天三丰科工有限公司 | Water-based fluorescent paint and preparation method thereof |
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Application publication date: 20130807 |