CN103217503A - Aqueous color-variable treatment agent - Google Patents
Aqueous color-variable treatment agent Download PDFInfo
- Publication number
- CN103217503A CN103217503A CN 201210015342 CN201210015342A CN103217503A CN 103217503 A CN103217503 A CN 103217503A CN 201210015342 CN201210015342 CN 201210015342 CN 201210015342 A CN201210015342 A CN 201210015342A CN 103217503 A CN103217503 A CN 103217503A
- Authority
- CN
- China
- Prior art keywords
- resin
- variable color
- water
- treatment agent
- treating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims abstract description 15
- UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012948 isocyanate Substances 0.000 claims abstract description 10
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 10
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 239000003208 petroleum Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- 229920001971 elastomer Polymers 0.000 claims abstract description 7
- 239000005060 rubber Substances 0.000 claims abstract description 7
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims abstract description 6
- FRPHFZCDPYBUAU-UHFFFAOYSA-N Bromocresolgreen Chemical compound CC1=C(Br)C(O)=C(Br)C=C1C1(C=2C(=C(Br)C(O)=C(Br)C=2)C)C2=CC=CC=C2S(=O)(=O)O1 FRPHFZCDPYBUAU-UHFFFAOYSA-N 0.000 claims abstract description 3
- ATJXMQHAMYVHRX-CPCISQLKSA-N Ellagic acid Natural products OC1=C(O)[C@H]2OC(=O)c3cc(O)c(O)c4OC(=O)C(=C1)[C@H]2c34 ATJXMQHAMYVHRX-CPCISQLKSA-N 0.000 claims abstract description 3
- LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 claims abstract description 3
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 claims abstract description 3
- 229940012189 methyl orange Drugs 0.000 claims abstract description 3
- CEQFOVLGLXCDCX-WUKNDPDISA-N methyl red Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-WUKNDPDISA-N 0.000 claims abstract description 3
- ZHFPEICFUVWJIS-UHFFFAOYSA-M sodium 2-hydroxy-5-[(3-nitrophenyl)diazenyl]benzoate Chemical compound [Na+].Oc1ccc(cc1C([O-])=O)N=Nc1cccc(c1)[N+]([O-])=O ZHFPEICFUVWJIS-UHFFFAOYSA-M 0.000 claims abstract description 3
- PRZSXZWFJHEZBJ-UHFFFAOYSA-N thymol blue Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C PRZSXZWFJHEZBJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- -1 acryl Chemical group 0.000 claims description 8
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 3
- KVYRCBOUKXJXDK-UHFFFAOYSA-N 3,4-dimethylphenazine-1,2-diamine hydrochloride Chemical compound Cl.C1=CC=CC2=NC3=C(C)C(C)=C(N)C(N)=C3N=C21 KVYRCBOUKXJXDK-UHFFFAOYSA-N 0.000 claims description 2
- 241000282941 Rangifer tarandus Species 0.000 claims description 2
- 238000006277 sulfonation reaction Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 230000035945 sensitivity Effects 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- PGSADBUBUOPOJS-UHFFFAOYSA-N neutral red Chemical compound Cl.C1=C(C)C(N)=CC2=NC3=CC(N(C)C)=CC=C3N=C21 PGSADBUBUOPOJS-UHFFFAOYSA-N 0.000 abstract 1
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 239000004645 polyester resin Substances 0.000 abstract 1
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000002696 acid base indicator Substances 0.000 description 5
- 210000002700 urine Anatomy 0.000 description 4
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 208000026935 allergic disease Diseases 0.000 description 2
- 230000009610 hypersensitivity Effects 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
Abstract
The invention discloses an aqueous color-variable treatment agent. The aqueous color-variable treatment agent comprises rubber, acrylic resin, polyurethane resin or polyester resin, and also comprises vinyl ether, one or more indicators and a fixing agent. The one or more indicators are selected from methyl orange, methyl red, bromophenol blue, phenolphthalein, purple litmus reagent, bromocresol green, neutral red, thymolsulfonphthalein, thymolphthalein and alizarin yellow. The one or more indicators are sensitive to a pH value. The ether, the petroleum resin, isocyanate, the epoxy resin and the fixing agent anchor the indicator and provide a color change environment. The product treated by the aqueous color-variable treatment agent has high pH sensitivity and can change its color in an acid/base environment. The aqueous color-variable treatment agent has good adhesion to a plurality of cloths and porous materials, produces small influence on the materials, does not contain any organic solvent, does not damage a human body and can be widely used for the daily life.
Description
Technical field
The present invention relates to chemical field, relate in particular to acid base indicator, particularly a kind of water-based variable color treating agent.
Background technology:
Acid base indicator is widely used in the laboratory.But because use inconvenience, so seldom be applied in the daily life.For example: baby' diaper has very strong water absorptivity, only is difficult to find whether contain urine in the baby' diaper with naked eyes.Drip acid base indicator on baby' diaper, can judge whether to contain urine according to change color, still, the inconvenient acid base indicator that utilizes at any time detects just in use baby' diaper in the daily life.
Summary of the invention:
Technical matters to be solved by this invention provides a kind of water-based variable color treating agent, and described this water-based variable color treating agent will solve the technical matters that acid base indicator in the prior art is difficult to be applied to daily life.
This water-based variable color treating agent of the present invention contains rubber or acryl resin or urethane resin or vibrin, also contains vinyl ether, indicator and fixing agent, and the weight portion of above-mentioned substance is as follows,
100 parts in rubber or acryl resin or urethane resin or vibrin,
45.0～55.0 parts of vinyl ether,
1.0～5.0 parts of indicator,
0.01～0.03 part of fixing agent.
Further, also contain petroleum resin, the weight portion of described petroleum resin is 1～10.0 part.
Further, also contain isocyanates, the weight portion of described isocyanates is 1～10.0 part.
Further, also contain epoxy resin, the weight portion of described epoxy resin is 1～10.0 part.
Further, described indicator is selected from one or more in methyl orange, methyl red, bromophenol blue, phenolphthalein, purple reindeer moss, bromcresol green, dimethyl diaminophenazine chloride, thymol blue, thymolphthalein, the alizarin yellow.
Further, described fixing agent can adopt G4502 type material of the prior art.
Further, described fixing agent is the sulfonation isocyanates.
Principle of work of the present invention is: indicator is to the soda acid sensitivity, and ethers, petroleum resin, isocyanates, epoxy resin and fixing agent carry out anchoring to indicator, and is indicator creation changeable colour environment.The product that utilizes the present invention to handle has hypersensitivity to soda acid, has obvious change color in acid or alkali environment.
The present invention compares with prior art, and its effect is actively with tangible.Water-based variable color treating agent of the present invention has hypersensitivity to soda acid, and the product of handling has obvious change color in soda acid.The present invention has good tack in multiple cloth and porosint, minimum to the performance impact of material own, does not contain any organic solvent, and human body is not had injury, can be widely used in the daily life.
Embodiment:
Embodiment 1
Vibrin: 100 (weight portions)
Vinyl ether: 45.0 (weight portions)
Bromophenol blue: 5.0 (weight portions)
Fixing agent: the 0.01(weight portion).
Concrete production technology is: the polymethyl vinyl ether that Henkel KGaA vibrin, Tokyo are changed into mixes in proportion, while stir the mixed liquor that dropwise splashes into bromophenol blue and fixing agent, adds the back stirring and promptly obtains water-based variable color treating agent in 3 hours.
Embodiment 2
Acryl resin: 100 (weight portions)
Vinyl ether: 45.0 (weight portions)
Bromophenol blue: 3.0 (weight portions)
Fixing agent: the 0.03(weight portion).
Concrete production technology is: the polymethyl vinyl ether that Henkel KGaA acryl resin, Tokyo are changed into mixes in proportion, while stir the mixed liquor that dropwise splashes into bromophenol blue and fixing agent, adds the back stirring and promptly obtains water-based variable color treating agent in 3 hours.
Embodiment 3
Urethane resin: 100 (weight portions)
Vinyl ether: 55.0 (weight portions)
Bromophenol blue: 1.0 (weight portions)
Fixing agent: the 0.03(weight portion).
Concrete production technology is with embodiment 1.
Concrete production technology is: the polymethyl vinyl ether that Henkel KGaA vibrin A109 emulsion, Tokyo are changed into mixes in proportion, while stirring the mixed liquor that dropwise splashes into bromophenol blue and fixing agent, add the back stirring and promptly obtained water-based variable color treating agent in 3 hours.
Embodiment 4
Rubber: the 100(weight portion)
Vinyl ether: 5.0 (weight portions)
Bromophenol blue: 1.0 (weight portions)
Fixing agent: the 0.03(weight portion).
Concrete production technology is: the polymethyl vinyl ether that the auspicious father-in-law's rubber of Japan, Tokyo are changed into mixes in proportion, while stir the mixed liquor that dropwise splashes into bromophenol blue and fixing agent, adds the back stirring and promptly obtains water-based variable color treating agent in 3 hours.
Embodiment 5
100 parts of acryl resins
50 parts of vinyl ether
4 parts of indicator
0.01 part of fixing agent.
3 parts of petroleum resin.
3 parts of isocyanates.
3 parts of epoxy resin.
Concrete production technology is: acryl resin, vinyl ether, petroleum resin, isocyanates, epoxy resin are mixed in proportion, while stir the mixed liquor that dropwise splashes into bromophenol blue and fixing agent, add the back stirring and promptly obtained water-based variable color treating agent in 3 hours.
Embodiment 6
The diaper material therefor was put into above-mentioned water-based variable color treating agent dipping 1 hour, and taking-up is dried.
With the above-mentioned material baby' diaper of handling well, go up infant urine, obvious variable color promptly appears in material.After using water-based variable color treating agent of the present invention that the material of baby' diaper is handled, infant urine makes the material variable color, can find by naked eyes.
Claims (6)
1. water-based variable color treating agent, it is characterized in that: contain rubber or acryl resin or urethane resin or vibrin, also contain vinyl ether, indicator and fixing agent, the weight portion of above-mentioned substance is as follows,
100 parts in rubber or acryl resin or urethane resin or vibrin,
45.0～55.0 parts of vinyl ether,
1.0～5.0 parts of indicator,
0.01～0.03 part of fixing agent.
2. water-based variable color treating agent as claimed in claim 1 is characterized in that: also contain petroleum resin, the weight portion of described petroleum resin is 1～10.0 part.
3. water-based variable color treating agent as claimed in claim 1 is characterized in that: also contain isocyanates, the weight portion of described isocyanates is 1～10.0 part.
4. water-based variable color treating agent as claimed in claim 1 is characterized in that: also contain epoxy resin, the weight portion of described epoxy resin is 1～10.0 part.
5. water-based variable color treating agent as claimed in claim 1 is characterized in that: described indicator is selected from one or more in methyl orange, methyl red, bromophenol blue, phenolphthalein, purple reindeer moss, bromcresol green, dimethyl diaminophenazine chloride, thymol blue, thymolphthalein, the alizarin yellow.
6. water-based variable color treating agent as claimed in claim 1 is characterized in that: described fixing agent is the sulfonation isocyanates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210015342 CN103217503A (en) | 2012-01-18 | 2012-01-18 | Aqueous color-variable treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210015342 CN103217503A (en) | 2012-01-18 | 2012-01-18 | Aqueous color-variable treatment agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103217503A true CN103217503A (en) | 2013-07-24 |
Family
ID=48815481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210015342 Pending CN103217503A (en) | 2012-01-18 | 2012-01-18 | Aqueous color-variable treatment agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103217503A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10288590B2 (en) | 2013-10-08 | 2019-05-14 | Smith & Nephew Plc | PH indicator device and formulation |
| US10520446B2 (en) | 2014-07-10 | 2019-12-31 | Smith & Nephew Plc | Polymer materials |
| US11162840B1 (en) | 2021-04-20 | 2021-11-02 | Giftedness And Creativity Company | Method and kit for detecting technetium-99m radioisotopes |
| US11471076B2 (en) | 2016-01-14 | 2022-10-18 | Smith & Nephew Plc | Device and kit for indicating a pH at a locus |
| US11504033B2 (en) | 2016-01-14 | 2022-11-22 | Smith & Nephew Plc | Polymer materials |
-
2012
- 2012-01-18 CN CN 201210015342 patent/CN103217503A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10288590B2 (en) | 2013-10-08 | 2019-05-14 | Smith & Nephew Plc | PH indicator device and formulation |
| US10520446B2 (en) | 2014-07-10 | 2019-12-31 | Smith & Nephew Plc | Polymer materials |
| US10782238B2 (en) | 2014-07-10 | 2020-09-22 | Smith & Nephew Plc | Device including a polymeric material for detecting species and stimulus and method of using thereof |
| US11471076B2 (en) | 2016-01-14 | 2022-10-18 | Smith & Nephew Plc | Device and kit for indicating a pH at a locus |
| US11504033B2 (en) | 2016-01-14 | 2022-11-22 | Smith & Nephew Plc | Polymer materials |
| US11162840B1 (en) | 2021-04-20 | 2021-11-02 | Giftedness And Creativity Company | Method and kit for detecting technetium-99m radioisotopes |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C05 | Deemed withdrawal (patent law before 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130724 |