CN103215129B - Additive for increasing stability of essences and application of additive - Google Patents
Additive for increasing stability of essences and application of additive Download PDFInfo
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- CN103215129B CN103215129B CN201310164319.3A CN201310164319A CN103215129B CN 103215129 B CN103215129 B CN 103215129B CN 201310164319 A CN201310164319 A CN 201310164319A CN 103215129 B CN103215129 B CN 103215129B
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- 239000000654 additive Substances 0.000 title claims abstract description 25
- 230000000996 additive effect Effects 0.000 title claims abstract description 23
- 239000000686 essence Substances 0.000 title abstract description 15
- 239000000796 flavoring agent Substances 0.000 claims abstract description 22
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims abstract description 9
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims abstract description 8
- 229960001679 octinoxate Drugs 0.000 claims abstract description 8
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 235000013355 food flavoring agent Nutrition 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 1
- 235000019634 flavors Nutrition 0.000 abstract description 20
- TYYHDKOVFSVWON-UHFFFAOYSA-N 2-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)(CCCC)C(=O)C1=CC=CC=C1 TYYHDKOVFSVWON-UHFFFAOYSA-N 0.000 abstract description 7
- 229960005193 avobenzone Drugs 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 5
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003205 fragrance Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical group CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- HYMLWHLQFGRFIY-UHFFFAOYSA-N Maltol Natural products CC1OC=CC(=O)C1=O HYMLWHLQFGRFIY-UHFFFAOYSA-N 0.000 description 1
- 239000002262 Schiff base Substances 0.000 description 1
- 150000004753 Schiff bases Chemical class 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000005882 aldol condensation reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- -1 ethyl malt Phenols Chemical class 0.000 description 1
- 229940073505 ethyl vanillin Drugs 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940043353 maltol Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
技术领域 technical field
本发明涉及一种香精的添加剂,具体地说,是涉及一种增加香精香料稳定性的添加剂,属于日化香精技术领域。 The present invention relates to an additive of essence, in particular to an additive for increasing the stability of essence and fragrance, which belongs to the technical field of daily chemical essence.
背景技术 Background technique
香精是由多种香原料调配出来的,其中含有许多天然或者合成的香原料,香原料的主要成分为醛类,酯类,酚类等,由于其特殊的化学结构,稳定性较差,容易受到外界的影响如遇光、热、氧等发生化学变化,失去原有的气味而产生不愉快的气味。香精的变化势必引起终端加香产品的品质变化如颜色改变,气味改变,必将影响终端产品的销售及使用。影响香精不稳定的因素可归纳为如下几个方面:1.香精中某些香料分子之间发生化学反应,如酯交换、酯化,酚醛缩合、醇醛缩合等反应;2.香精中某些分子,如醇、醛、不饱和键等分子和空气之间发生氧化反应;3、香精中某些分子,如醛,酮、含氮化合物等遇光照后发生物理化学变化。为了测试该UV吸收剂和抗氧化剂组合对大部分的不稳定香原料是否有效,被测试配方中具体含有的不稳定香原料如下:香兰素,乙基香兰素,麦芽酚,乙基麦芽酚、希夫碱、吲哚等。 Essence is formulated from a variety of fragrance materials, including many natural or synthetic fragrance materials. The main components of fragrance materials are aldehydes, esters, phenols, etc. Due to their special chemical structure, the stability is poor and easy to Affected by the outside world, such as light, heat, oxygen, etc., undergo chemical changes, lose their original smell and produce unpleasant smell. Changes in flavors will inevitably cause quality changes in terminal flavoring products such as color changes and odor changes, which will definitely affect the sales and use of terminal products. Factors that affect the instability of flavors can be summarized as follows: 1. Chemical reactions occur between certain fragrance molecules in flavors, such as transesterification, esterification, phenolic condensation, aldol condensation, etc.; 2. Some flavors in flavors Molecules, such as alcohols, aldehydes, unsaturated bonds, and other molecules undergo oxidation reactions with air; 3. Some molecules in essences, such as aldehydes, ketones, and nitrogen-containing compounds, undergo physical and chemical changes when exposed to light. In order to test whether the combination of UV absorber and antioxidant is effective for most of the unstable aroma raw materials, the specific unstable aroma raw materials contained in the tested formula are as follows: vanillin, ethyl vanillin, maltol, ethyl malt Phenols, Schiff bases, indole, etc.
发明内容 Contents of the invention
针对上述问题,本发明提供一种可以有效增加香精香料UV吸收性,抗氧化性和稳定性的添加剂。 In view of the above problems, the present invention provides an additive that can effectively increase the UV absorption, oxidation resistance and stability of flavors and fragrances.
为解决上述技术问题,本发明提供的技术方案是这样的:该增加香精稳定性的添加剂,包括下述质量百分数的组分:丁基甲氧基二苯甲酰基甲烷6-9%,甲氧基肉桂酸辛酯10-15%,2,6-二叔丁基-4-甲基苯酚3-7%,肉豆蔻酸异丙酯70-80%,上述各个组分质量百分比之和为100%。 In order to solve the above-mentioned technical problems, the technical scheme provided by the present invention is as follows: the additive for increasing the stability of essence includes the following components in mass percentage: 6-9% of butylmethoxydibenzoylmethane, methoxycinnamon Octyl acid 10-15%, 2,6-di-tert-butyl-4-methylphenol 3-7%, isopropyl myristate 70-80%, the sum of the mass percentages of the above components is 100%.
上述的增加香精稳定性的添加剂,包括下述质量百分数的组分:丁基甲氧基二苯甲酰基甲烷7.5%,甲氧基肉桂酸辛酯12.5%,2,6-二叔丁基-4-甲基苯酚5%,肉豆蔻酸异丙酯75%。 The above-mentioned additives for increasing the stability of flavors include the following components in mass percent: 7.5% butylmethoxydibenzoylmethane, 12.5% octyl methoxycinnamate, 2,6-di-tert-butyl-4-methoxy Base phenol 5%, isopropyl myristate 75%.
本发明还提供该增加香精稳定性的添加剂作为香精香料稳定剂的用途。 The invention also provides the use of the additive for increasing the stability of flavor as a stabilizer of flavor and fragrance.
本发明还提供该增加香精稳定性的添加剂作为加香产品中香精香料稳定剂的用途。 The invention also provides the use of the additive for increasing the stability of flavor as a stabilizer of flavor and fragrance in perfuming products.
与现有配方技术相比,本发明具有以下优点:利用UV吸收剂和抗氧化剂的同时作用,能够有效的避免或减缓香精香料的变色变味问题,增强香精香料在最终产品中的稳定性,也从而延长加香产品的保质期。以防止由于变色变味问题,出现产品下架,报废等问题。 Compared with the existing formulation technology, the present invention has the following advantages: the simultaneous action of the UV absorber and the antioxidant can effectively avoid or slow down the problem of discoloration and odor of flavors and fragrances, enhance the stability of flavors and fragrances in the final product, and also Thereby prolonging the shelf life of flavored products. In order to prevent problems such as product removal from shelves and scrapping due to discoloration and odor.
具体实施方案 specific implementation plan
下面结合具体实施方式,对本发明的权利要求作进一步的详细说明,但不构成对本发明的任何限制,任何在本发明权利要求范围内所做的有限次的修改,仍在本发明的权利要求保护范围之内。 Below in conjunction with specific embodiment, the claims of the present invention are described in further detail, but do not constitute any restriction to the present invention, any limited number of modifications done within the scope of the claims of the present invention are still protected by the claims of the present invention within range.
实施例1 Example 1
本发明的一种增加香精稳定性的添加剂,包括下述组分:丁基甲氧基二苯甲酰基甲烷8g,甲氧基肉桂酸辛酯12g,2,6-二叔丁基-4-甲基苯酚6g,肉豆蔻酸异丙酯74g。 An additive for increasing the stability of essence of the present invention comprises the following components: 8 g of butyl methoxy dibenzoyl methane, 12 g of octyl methoxy cinnamate, 2,6-di-tert-butyl-4-methylphenol 6g, 74g of isopropyl myristate.
实施例2 Example 2
本发明的另一种增加香精稳定性的添加剂,包括下述组分:丁基甲氧基二苯甲酰基甲烷9g,甲氧基肉桂酸辛酯14g,2,6-二叔丁基-4-甲基苯酚7g,肉豆蔻酸异丙酯70g。 Another additive for increasing the stability of essence of the present invention includes the following components: 9 g of butyl methoxy dibenzoyl methane, 14 g of octyl methoxy cinnamate, 2,6-di-tert-butyl-4-methyl Phenol 7g, isopropyl myristate 70g.
实施例3 Example 3
本发明的另一种增加香精稳定性的添加剂,包括下述组分:丁基甲氧基二苯甲酰基甲烷6g,甲氧基肉桂酸辛酯11g,2,6-二叔丁基-4-甲基苯酚3g,肉豆蔻酸异丙酯80g。 Another additive for increasing the stability of essence of the present invention includes the following components: 6 g of butyl methoxy dibenzoyl methane, 11 g of octyl methoxy cinnamate, 2,6-di-tert-butyl-4-methyl Phenol 3g, isopropyl myristate 80g.
实施例4 Example 4
本发明的另一种增加香精稳定性的添加剂,包括下述组分:丁基甲氧基二苯甲酰基甲烷7.5g,甲氧基肉桂酸辛酯12.5g,2,6-二叔丁基-4-甲基苯酚5g,肉豆蔻酸异丙酯75g。 Another additive for increasing the stability of essence of the present invention includes the following components: 7.5 g of butyl methoxy dibenzoyl methane, 12.5 g of octyl methoxy cinnamate, 2,6-di-tert-butyl-4- 5 g of methyl phenol, 75 g of isopropyl myristate.
实施例1至4中的任一一组作为增加香精稳定性的添加剂的用途,其具体应用方法是,取按实施例1至4中的任一一组数据称取各个组分,该添加剂与其它常用香精按照10:90质量比混合,并搅拌至完全混匀,取样化验合格后入库即可制备稳定性优良的香精。 The purposes of any one group in embodiment 1 to 4 as the additive that increases flavor stability, its specific application method is, get and weigh each component by any one group of data in embodiment 1 to 4, this additive and Other commonly used flavors are mixed according to the mass ratio of 10:90, and stirred until completely mixed, and the flavors with excellent stability can be prepared after sampling and testing pass the warehouse.
实施例1至4中的任一一组作为增加加香产品中香精香料稳定剂的用途,其具体应用方法是,按实施例1至4中的任一一组数据称取各个组分,该添加剂与其它常用香精按照质量比10:90的比例混合,在按照香精常规添加量添加至香水膏霜护肤品,空气清新剂杀虫剂,洗手液洗衣液洁厕灵,耐高温橡胶塑料,香水膏霜护肤品,洗发水沐浴露,香皂洗衣粉洗洁精等需要加香的产品中。 Any one of the groups in Examples 1 to 4 is used as an increase of the flavor and fragrance stabilizer in the perfuming product, and its specific application method is to weigh each component according to any one of the data in Examples 1 to 4, the Additives and other commonly used flavors are mixed in a mass ratio of 10:90, and added to perfume, cream, skin care products, air fresheners, insecticides, hand sanitizers, laundry detergents, high temperature resistant rubber and plastics, and perfumes according to the mass ratio of 10:90. Cream skin care products, shampoo and shower gel, soap, washing powder, detergent and other products that need to be scented.
Claims (4)
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6355264B1 (en) * | 1998-03-20 | 2002-03-12 | Avon Products, Inc. | Insect repellent composition |
CN101406434A (en) * | 2007-05-21 | 2009-04-15 | 莱雅公司 | Fragrance composition comprising the combination of one filter a hydroxyaminobenzophenone, one filter b cinnamate and of one compound c piperidinole, benzotriazole or dibenzoylmethane |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10003786A1 (en) * | 2000-01-28 | 2001-08-02 | Merck Patent Gmbh | Galenic formulation |
WO2007065575A1 (en) * | 2005-12-09 | 2007-06-14 | Dsm Ip Assets B.V. | Stabilizing composition |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6355264B1 (en) * | 1998-03-20 | 2002-03-12 | Avon Products, Inc. | Insect repellent composition |
CN101406434A (en) * | 2007-05-21 | 2009-04-15 | 莱雅公司 | Fragrance composition comprising the combination of one filter a hydroxyaminobenzophenone, one filter b cinnamate and of one compound c piperidinole, benzotriazole or dibenzoylmethane |
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Address after: No. 66, Hongjing Road, East District, Guangzhou Economic and Technological Development Zone, Guangzhou, Guangdong 510000 Patentee after: Chi Hua ton flavor and fragrance (Guangzhou) Co.,Ltd. Address before: No. 66, Hongjing Road, East District, Guangzhou Economic and Technological Development Zone, Guangzhou, Guangdong 510000 Patentee before: DROM FRAGRANCES (GUANGZHOU) Co.,Ltd. |
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Effective date of registration: 20241014 Address after: 5 perfume Avenue, Vinaire, Switzerland Patentee after: GIVAUDAN S.A. Country or region after: Switzerland Address before: No. 66, Hongjing Road, East District, Guangzhou Economic and Technological Development Zone, Guangzhou, Guangdong 510000 Patentee before: Chi Hua ton flavor and fragrance (Guangzhou) Co.,Ltd. Country or region before: China |