CN103214929A - Anticorrosion technology of metal structure - Google Patents
Anticorrosion technology of metal structure Download PDFInfo
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- CN103214929A CN103214929A CN2012105477465A CN201210547746A CN103214929A CN 103214929 A CN103214929 A CN 103214929A CN 2012105477465 A CN2012105477465 A CN 2012105477465A CN 201210547746 A CN201210547746 A CN 201210547746A CN 103214929 A CN103214929 A CN 103214929A
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- Prior art keywords
- coating method
- protective system
- described protective
- coating
- substrate surface
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 12
- 239000002184 metal Substances 0.000 title claims abstract description 12
- 238000005516 engineering process Methods 0.000 title abstract description 6
- 239000000758 substrate Substances 0.000 claims abstract description 17
- 230000008021 deposition Effects 0.000 claims abstract description 7
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 239000004642 Polyimide Substances 0.000 claims abstract description 6
- 239000004917 carbon fiber Substances 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 229920001721 polyimide Polymers 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 14
- 230000001681 protective effect Effects 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 230000035800 maturation Effects 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- BAAAEEDPKUHLID-UHFFFAOYSA-N decyl(triethoxy)silane Chemical compound CCCCCCCCCC[Si](OCC)(OCC)OCC BAAAEEDPKUHLID-UHFFFAOYSA-N 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- MZSAMHOCTRNOIZ-UHFFFAOYSA-N 3-[4-(aminomethyl)-6-(trifluoromethyl)pyridin-2-yl]oxy-N-phenylaniline Chemical compound NCC1=CC(=NC(=C1)C(F)(F)F)OC=1C=C(NC2=CC=CC=C2)C=CC=1 MZSAMHOCTRNOIZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000001680 brushing effect Effects 0.000 claims description 2
- 238000005137 deposition process Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- -1 rare earth compound Chemical class 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000011247 coating layer Substances 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007739 conversion coating Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
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- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an anticorrosion technology of a metal structure. According to the anticorrosion technology, siloxane, a solvent, silica particles, a rare earth compound, deionized water, a catalyst, carbon fibers, polyimide and other components are mixed, then are subjected to an aging treatment; the aged mixture is filtered, and then is sprayed, brushed or dipped on the surface of a substrate; and a coating layer is formed on the surface of the substrate after deposition so as to achieve a surface anticorrosion treatment.
Description
Technical field
The present invention relates to a kind of aseptic technic of metal construction, relate in particular to a kind of metal structure surface that is applicable to, have the coating method of the environmental protection coating material of excellent gloss and mechanical and physical performance and aromatic free solvent.
Background technology
In modern industry and daily life, corrosion of metal is seen everywhere, and especially the destruction of the forms such as crevice corrosion, stress corrosion and corrosion fatigue that take place in the storage vessel of a fuel oil dangerization product is caused great potential safety hazard for people's lives.
The metal protection method that adopts can roughly be divided three classes at present: a class is to carry out anodic oxidation treatment, promptly form the anode oxide film of one deck tens micron thickness in the metallic surface, but because the anode oxidation process power consumption is big, and electrolyte solution is seriously polluted, be difficult to handle, use its application to be restricted; Second class is a chemical conversion film, being about to metal parts is immersed in the solution of definite composition, rely on chemical reaction to form one deck chemical conversion film at a certain temperature, now most widely used is the oxidation of chromic salt chemistry, but chromic salt is a kind of carcinogenic toxicant, and the world environments protective tissue has proposed restriction and used chromic salt and other to contain chromate compound; The 3rd class is an organic coating, promptly applies one deck organic coating in the metallic surface, with outward appearance and the physical and chemical performance that improves metal.People begin rare earth element is used in the aseptic technic of metallic surface in recent years.
The rare-earth conversion coatings film technique develops into today, and people have carried out a large amount of improvement to various film-forming process, and the performance of film also is improved.At present the rare-earth conversion coatings technology mainly is an immersion treatment, and this technological operation is simple, be easy to safeguard; But its drawback is that the long period of soaking process treatment time is oversize, and formed rete is thin and relatively poor with the sticking power of base material.Discover through long-term exploration, add strong oxidizer in the soaking solution, as H
2O
2, KMnO
4, (NH
4)
2S
2O
8Etc. strong oxide compound, rate of film build is improved greatly, the treatment time shortens dramatically, and the treatment soln temperature is not high yet simultaneously, can at room temperature use.But because the existence of strong oxidizer makes the less stable of treatment process.
In order to solve the problem that the rare-earth conversion coatings treatment process exists, the present invention proposes a kind of improved protective system coating method.This method anticorrosion with low cost, remarkable in economical benefits can be carried out normal temperature and be spread, and coating processes is simple, and solution is environment friendly and pollution-free.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art part, provide a kind of aseptic technic of metal construction, in order to solve the protection against corrosion difficult problem of steel, surfaces externally and internally applications such as aluminium, especially aluminium alloy, and coating aromatic free solvent, do not contain strong oxidizer, do not have poisonous pigment, be fit to various constructional methods, application is not subject to seasonal restrictions, and construction technology is simple and convenient, and technical costs is cheap, good environmental protection.
The present invention is achieved by the following technical solutions:
(1) prepare following component (mass parts):
A decyl triethoxyl silane 11-20;
B ethanol 61-80;
C SiO
2Particle 6-10;
The oxide compound 1-5 of d cerium;
E deionized water 26-50;
F acetate 1-3;
G carbon fiber 8-10;
H polyimide 4-6;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in substrate surface then, the deposition back forms coating at substrate surface, realizes the surface anticorrosion processing.
Embodiment
The present invention relates to a kind of aseptic technic of metal construction, after the various components of protective system are mixed, carry out maturation process, again the mixture after the slaking is filtered, spray, brush or be immersed in substrate surface then, the deposition back forms coating at substrate surface, realizes the surface anticorrosion processing.
Described SiO
2Particle grain size is the 50-100 nanometer.
Described maturation process is to leave standstill at normal temperatures 50-60 hour.
Described base material is steel or aluminium, preferred aluminium alloy.
Heat in the deposition process after spraying, brushing or dipping, Heating temperature is to heat 1 minute to 1 hour under 50 ℃ to the 150 ℃ temperature.
The thickness of described coating is 1 micron to 10 microns, preferred 1 micron to 5 microns.The preferred method that adopts spraying or brush forms coating at substrate surface.
Protective system coating method disclosed by the invention is simple, convenient, quick, reliable, and raw material is cheap, this method can be simply in conjunction with enter the existing pre-treatment that comprises coating and after in the conventional production line of other postprocessing working procedures of substrate material, substantially need not to carry out other adjustment on the equipment, is the Eco-power production technique of a kind of height.
Below the present invention is elaborated with embodiment, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
(1) prepare following component (mass parts):
A decyl triethoxyl silane 11;
B ethanol 61;
C SiO
2Particle 6;
The oxide compound 5 of d cerium;
E deionized water 26;
F acetate 1;
G carbon fiber 8;
H polyimide 6;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in substrate surface then, the deposition back forms coating at substrate surface, realizes the surface anticorrosion processing.
Embodiment 2
(1) prepare following component (mass parts):
A decyl triethoxyl silane 20;
B ethanol 80;
C SiO
2Particle 10;
The oxide compound 1 of d cerium;
E deionized water 50;
F acetate 2;
G carbon fiber 10;
H polyimide 5;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in substrate surface then, the deposition back forms coating at substrate surface, realizes the surface anticorrosion processing.
Embodiment 3
(1) prepare following component (mass parts):
A decyl triethoxyl silane 15;
B ethanol 70;
C SiO
2Particle 8;
The oxide compound 3 of d cerium;
E deionized water 38;
F acetate 3;
G carbon fiber 9;
H polyimide 4;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in substrate surface then, the deposition back forms coating at substrate surface, realizes the surface anticorrosion processing.
Claims (9)
1. the aseptic technic of a metal construction comprises:
(1) prepare following component (mass parts):
A decyl triethoxyl silane 11-20;
B ethanol 61-80;
C SiO
2Particle 6-10;
The oxide compound 1-5 of d cerium;
E deionized water 26-50;
F acetate 1-3;
G carbon fiber 8-10;
H polyimide 4-6;
(2) with carrying out maturation process after the said components mixing, spray, brush or be immersed in substrate surface then, the deposition back forms coating at substrate surface, realizes the surface anticorrosion processing.
2. according to the coating method of the described protective system of claim 1, it is characterized in that described SiO
2Particle grain size is the 50-100 nanometer.
3. according to the coating method of the described protective system of claim 1, it is characterized in that described maturation process is to leave standstill at normal temperatures 50-60 hour.
4. according to the coating method of the described protective system of claim 1, it is characterized in that described base material is steel or aluminium.
5. according to the coating method of the described protective system of claim 1, it is characterized in that described base material is an aluminium alloy.
6. according to the coating method of the described protective system of claim 1, it is characterized in that, in described deposition process, heat that Heating temperature is 50 ℃ to 150 ℃, 1 minute to 1 hour heat-up time.
7. according to the coating method of the described protective system of claim 1, it is characterized in that described coat-thickness is 1 micron to 10 microns.
8. according to the coating method of the described protective system of claim 7, it is characterized in that described coat-thickness is 1 micron to 5 microns.
9. according to the coating method of the described protective system of claim 1, it is characterized in that, adopt the method for spraying or brushing to form coating in the described step (2) at substrate surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105477465A CN103214929A (en) | 2012-12-17 | 2012-12-17 | Anticorrosion technology of metal structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105477465A CN103214929A (en) | 2012-12-17 | 2012-12-17 | Anticorrosion technology of metal structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103214929A true CN103214929A (en) | 2013-07-24 |
Family
ID=48813113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105477465A Pending CN103214929A (en) | 2012-12-17 | 2012-12-17 | Anticorrosion technology of metal structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103214929A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01215871A (en) * | 1988-02-23 | 1989-08-29 | Takano:Kk | Coating material containing far infrared radiating material |
| CN101035630A (en) * | 2004-08-03 | 2007-09-12 | 坎梅陶尔股份有限公司 | Process for coating metallic surfaces with an anti-corrosive coating |
| WO2008136866A2 (en) * | 2006-11-27 | 2008-11-13 | Micropyretics Heaters International, Inc. | Antimicrobal materials and coatings |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for hot forming and process for the production thereof |
-
2012
- 2012-12-17 CN CN2012105477465A patent/CN103214929A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01215871A (en) * | 1988-02-23 | 1989-08-29 | Takano:Kk | Coating material containing far infrared radiating material |
| CN101035630A (en) * | 2004-08-03 | 2007-09-12 | 坎梅陶尔股份有限公司 | Process for coating metallic surfaces with an anti-corrosive coating |
| WO2008136866A2 (en) * | 2006-11-27 | 2008-11-13 | Micropyretics Heaters International, Inc. | Antimicrobal materials and coatings |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for hot forming and process for the production thereof |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130724 |