CN103131298B - A kind of Flame Retardant Powder Coatings containing hydration zinc borate - Google Patents
A kind of Flame Retardant Powder Coatings containing hydration zinc borate Download PDFInfo
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- CN103131298B CN103131298B CN201310040640.0A CN201310040640A CN103131298B CN 103131298 B CN103131298 B CN 103131298B CN 201310040640 A CN201310040640 A CN 201310040640A CN 103131298 B CN103131298 B CN 103131298B
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- Prior art keywords
- zinc borate
- hydration zinc
- flame retardant
- nano
- coatings containing
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- 239000000843 powder Substances 0.000 title claims abstract description 24
- 238000000576 coating method Methods 0.000 title claims abstract description 21
- 230000036571 hydration Effects 0.000 title claims abstract description 18
- 238000006703 hydration reaction Methods 0.000 title claims abstract description 18
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000003063 flame retardant Substances 0.000 title claims abstract description 16
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000012764 mineral filler Substances 0.000 claims abstract description 7
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- XGQJGMGAMHFMAO-UHFFFAOYSA-N 1,3,4,6-tetrakis(methoxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound COCN1C(=O)N(COC)C2C1N(COC)C(=O)N2COC XGQJGMGAMHFMAO-UHFFFAOYSA-N 0.000 claims abstract description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims abstract description 4
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 4
- 239000002956 ash Substances 0.000 claims abstract description 4
- 239000003822 epoxy resin Substances 0.000 claims abstract description 4
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 4
- FIBARIGPBPUBHC-UHFFFAOYSA-N octyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCCC1OC1CCCCCCCC FIBARIGPBPUBHC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 4
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims description 12
- 239000002893 slag Substances 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims description 3
- 235000021388 linseed oil Nutrition 0.000 claims description 3
- 239000000944 linseed oil Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- XUIMIQQOPSSXEZ-NJFSPNSNSA-N silicon-30 atom Chemical compound [30Si] XUIMIQQOPSSXEZ-NJFSPNSNSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of Flame Retardant Powder Coatings containing hydration zinc borate, obtained by the raw material of following weight parts: bisphenol A type epoxy resin 90-95, vibrin 20-30, 138 Gum Rosin 7-8, nitrocellulose 3-5, mineral filler 80-90, nano titanium oxide 3-5, silicone antifoam agent 1-2, st-yrax 0.5-1.5, stalk ashes 2.4-2.8, hydration zinc borate 0.3-0.5, aluminium hydroxide 1-2, ethylene bis stearamide 3-4, titanium dioxide 55-60, methyl acrylate 1-2, octyl epoxy stearate 1-2, antioxidant 1010: 0.3-0.4, antioxidant 264: 0.5-0.7, tetramethoxymethylglycoluril 4-7.Environmental protection of the present invention, physical strength is high; Both easy to use, nontoxic again, fire-retardant, weathering resistance is strong.
Description
Technical field
The present invention relates to paint field, is exactly a kind of Flame Retardant Powder Coatings containing hydration zinc borate.
Background technology
Powder coating is a kind of novel not containing solvent 100% solid powdery coating.There is solvent-free, pollution-free, recyclable, environmental protection, the saving energy and resource, reduce labor intensity and film physical strength high.Powder coating is form diverse with general coating, and it exists with the state of fines.Owing to not using solvent, so be called powder coating.The principal feature of powder coating has: have nuisanceless, high-level efficiency, saving resource feature.
Summary of the invention
The object of the present invention is to provide a kind of Flame Retardant Powder Coatings containing hydration zinc borate.
Above-mentioned purpose is realized by following scheme:
A kind of Flame Retardant Powder Coatings containing hydration zinc borate, it is characterized in that, obtained by the raw material of following weight parts: bisphenol A type epoxy resin 90-95, vibrin 20-30, 138 Gum Rosin 7-8, nitrocellulose 3-5, mineral filler 80-90, nano titanium oxide 3-5, silicone antifoam agent 1-2, st-yrax 0.5-1.5, stalk ashes 2.4-2.8, hydration zinc borate 0.3-0.5, aluminium hydroxide 1-2, ethylene bis stearamide 3-4, titanium dioxide 55-60, methyl acrylate 1-2, octyl epoxy stearate 1-2, antioxidant 1010 0.3-0.4, antioxidant 264 0.5-0.7, tetramethoxymethylglycoluril 4-7, .
Described a kind of powder coating fire-retardant containing hydration zinc borate, it is characterized in that: described mineral filler is made up of the raw material of following weight parts: nano silicon 20-30, nano kaoline 10-12, nano-aluminium oxide 20-30, mica powder 10-15, modified Nano Iron-ore Slag 10-15;
The preparation method of described modified Nano Iron-ore Slag is: Iron-ore Slag is calcined 4-6 hour at 700-800 DEG C, after cooling, broken, cross 100-200 mesh sieve, then after soaking 5-7 hour in the acetic acid solution of 8-10%, take out, deionized water wash is to neutral, add the epoxidized linseed oil being equivalent to Iron-ore Slag weight 1-2%, the dioctyl maleate of 1-2%, after mixing, dries, grind to form nanometer powder, to obtain final product.
Described a kind of Flame Retardant Powder Coatings containing hydration zinc borate, is characterized in that:
Preparation method comprises the following steps:
(1), by each raw material of described weight part accurate weighing, under 500-600 rev/min, be uniformly mixed 3-4 minute, under 2800-3000 rev/min, be uniformly mixed 8-10 minute, after under 400-500 rev/min, be uniformly mixed 1-2 minute, stop stir, obtain mixture;
(2), by mixture forcing machine extrude at the temperature of 100-115 DEG C, obtain extruded stock;
(3), extruded stock crosses 100-200 mesh sieve after pulverizing, and to obtain final product.
Described a kind of Flame Retardant Powder Coatings containing hydration zinc borate, is characterized in that:
Described silicone antifoam agent solid content is 34%.
Described a kind of Flame Retardant Powder Coatings containing hydration zinc borate, is characterized in that: described vibrin is oh type polyester, acid number 30-40mkKOH/g, viscosity 5000-7000mPa.S, solidification value 180-200 DEG C.
Beneficial effect of the present invention is: environmental protection of the present invention, and physical strength is high; Both easy to use, nontoxic fire-retardant again, weathering resistance is strong.
Embodiment
A kind of Flame Retardant Powder Coatings containing hydration zinc borate, it is obtained by the raw material of following weight parts (kg): bisphenol A type epoxy resin 95, vibrin 30,138 Gum Rosins 8, nitrocellulose 5, mineral filler 90, nano titanium oxide 5, silicone antifoam agent 2, st-yrax 0.7, stalk ashes 2.6, hydration zinc borate 0.5, aluminium hydroxide 2, ethylene bis stearamide 4, titanium dioxide 60, methyl acrylate 2, octyl epoxy stearate 1.7, antioxidant 1010 0.4, antioxidant 264 0.7, tetramethoxymethylglycoluril 6.
Described mineral filler is made up of the raw material of following weight parts (kg): nano silicon 30, nano kaoline 12, nano-aluminium oxide 30, mica powder 15, modified Nano Iron-ore Slag 15;
The preparation method of described modified Nano Iron-ore Slag is: calcined 4 hours at 780 DEG C by Iron-ore Slag, after cooling, broken, cross 200 mesh sieves, then soak in the acetic acid solution of 10% after 5 hours, take out, deionized water wash is to neutral, add the epoxidized linseed oil being equivalent to Iron-ore Slag weight 1%, the dioctyl maleate of 2%, after mixing, dries, grind to form nanometer powder, to obtain final product.
Described a kind of Flame Retardant Powder Coatings containing hydration zinc borate,
Preparation method comprises the following steps:
(1), by each raw material of described weight part accurate weighing, be uniformly mixed 4 minutes under prior to 560 revs/min, under 2800 revs/min, be uniformly mixed 10 minutes, after under 450 revs/min, be uniformly mixed 1 minute, stop stir, obtain mixture;
(2), by mixture forcing machine extrude at the temperature of 115 DEG C, obtain extruded stock;
(3), extruded stock pulverize after cross 140 mesh sieves, to obtain final product.
Described silicone antifoam agent solid content is 34%.
Described vibrin is oh type polyester, acid number 30-40mkKOH/g, viscosity 5000-7000mPa.S, solidification value 180-200 DEG C.
Adopt high pressure electrostatic painting on foundry goods the present embodiment gained coating, voltage is 60KV, and average film thickness is 70-100 micron, and condition of cure is 180 DEG C of bakings 20 minutes;
Performance index are as follows:
According to GB/T1732 test, shock resistance >=50kg.cm;
According to GB/T6739 test, pencil hardness >=H level;
480hQUV-B accelerated light ageing experimental test obtains, and protects light rate and reaches 88%.
Gained coatingsurface is smooth, bubble-free, particle, shrinkage cavity, pin hole.
Claims (1)
1. the Flame Retardant Powder Coatings containing hydration zinc borate, it is characterized in that, obtained by the raw material of following weight parts: bisphenol A type epoxy resin 90-95, vibrin 20-30, 138 Gum Rosin 7-8, nitrocellulose 3-5, mineral filler 80-90, nano titanium oxide 3-5, silicone antifoam agent 1-2, st-yrax 0.5-1.5, stalk ashes 2.4-2.8, hydration zinc borate 0.3-0.5, aluminium hydroxide 1-2, ethylene bis stearamide 3-4, titanium dioxide 55-60, methyl acrylate 1-2, octyl epoxy stearate 1-2, antioxidant 1010 0.3-0.4, antioxidant 264 0.5-0.7, tetramethoxymethylglycoluril 4-7,
Described mineral filler is made up of the raw material of following weight parts: nano silicon 20-30, nano kaoline 10-12, nano-aluminium oxide 20-30, mica powder 10-15, modified Nano Iron-ore Slag 10-15; The preparation method of described modified Nano Iron-ore Slag is: Iron-ore Slag is calcined 4-6 hour at 700-800 DEG C, after cooling, broken, cross 100-200 mesh sieve, then after soaking 5-7 hour in the acetic acid solution of 8-10%, take out, deionized water wash is to neutral, add the epoxidized linseed oil being equivalent to Iron-ore Slag weight 1-2%, the dioctyl maleate of 1-2%, after mixing, dries, grind to form nanometer powder, to obtain final product;
Described silicone antifoam agent solid content is 34%; Described vibrin is oh type polyester, acid number 30-40mgKOH/g, viscosity 5000-7000mPas
, solidification value 180-200 DEG C;
The preparation method of described a kind of Flame Retardant Powder Coatings containing hydration zinc borate, comprises the following steps:
(1), by each raw material of described weight part accurate weighing, under 500-600 rev/min, be uniformly mixed 3-4 minute, under 2800-3000 rev/min, be uniformly mixed 8-10 minute, after under 400-500 rev/min, be uniformly mixed 1-2 minute, stop stir, obtain mixture;
(2), by mixture forcing machine extrude at the temperature of 100-115 DEG C, obtain extruded stock;
(3), extruded stock crosses 100-200 mesh sieve after pulverizing, and to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310040640.0A CN103131298B (en) | 2013-02-03 | 2013-02-03 | A kind of Flame Retardant Powder Coatings containing hydration zinc borate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310040640.0A CN103131298B (en) | 2013-02-03 | 2013-02-03 | A kind of Flame Retardant Powder Coatings containing hydration zinc borate |
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| Publication Number | Publication Date |
|---|---|
| CN103131298A CN103131298A (en) | 2013-06-05 |
| CN103131298B true CN103131298B (en) | 2016-03-02 |
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| CN201310040640.0A Expired - Fee Related CN103131298B (en) | 2013-02-03 | 2013-02-03 | A kind of Flame Retardant Powder Coatings containing hydration zinc borate |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103450710B (en) * | 2013-08-19 | 2016-05-18 | 铜陵瑞莱科技有限公司 | A kind of coated fire-retardant iron oxide blue |
| CN103483952B (en) * | 2013-09-03 | 2016-06-22 | 安徽精一机械设备有限公司 | A kind of Acrylic transparent powder paint |
| CN103834250A (en) * | 2014-03-21 | 2014-06-04 | 武汉大学 | Method for preparing heat-preserving coating by using straw ash |
| CN103965737A (en) * | 2014-05-09 | 2014-08-06 | 福建万安实业有限公司 | Flame retardant powder coating |
| CN104387926A (en) * | 2014-12-07 | 2015-03-04 | 李永志 | Scratching-resistant automobile powder coating with high adhesive force |
| CN104629578A (en) * | 2015-01-20 | 2015-05-20 | 安徽斯瑞尔阀门有限公司 | Electrostatic spraying powder and application method thereof in sealing copper gate valve |
| CN104805708A (en) * | 2015-05-05 | 2015-07-29 | 湖州圣航纺织有限公司 | Novel woven fabric pigment |
| CN105153838A (en) * | 2015-07-11 | 2015-12-16 | 安徽欧尚建材有限公司 | Aqueous environmentally-friendly coating |
| CN105505133A (en) * | 2015-12-23 | 2016-04-20 | 铜陵市经纬流体科技有限公司 | Fire retardant valve powder coating and preparing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH05320537A (en) * | 1992-05-25 | 1993-12-03 | Nippon Kayaku Co Ltd | Powder coating compound for aluminum electrolyzing condenser and condenser |
| CN1380370A (en) * | 2002-03-25 | 2002-11-20 | 葛明槽 | Fire-resistant powder coating material and its production process |
| CN101085897A (en) * | 2006-06-09 | 2007-12-12 | 徐州正菱涂装有限公司 | Steel structure fireproof powder coating and preparing method thereof |
| CN101205425B (en) * | 2006-12-22 | 2011-10-12 | 徐州正菱涂装有限公司 | Foaming powder coating |
| CN102391764A (en) * | 2011-09-30 | 2012-03-28 | 广州擎天实业有限公司 | Low-temperature curing flame-retardant finishing powder paint and preparation method thereof |
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Effective date of registration: 20161219 Address after: Meilin Village Dalingshan Town Kuang Wu Road 523820 Guangdong city of Dongguan Province, No. 15 Patentee after: Dongguan tide fire retardant material Co., Ltd. Address before: The new town of Anhui province Wuhu City fan 241200 Fanchang County Economic Development Office Patentee before: Ni Jinpei |
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