CN103130267A - Preparation method for visible-light response black titanium dioxide photocatalyst - Google Patents
Preparation method for visible-light response black titanium dioxide photocatalyst Download PDFInfo
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- CN103130267A CN103130267A CN2013100529839A CN201310052983A CN103130267A CN 103130267 A CN103130267 A CN 103130267A CN 2013100529839 A CN2013100529839 A CN 2013100529839A CN 201310052983 A CN201310052983 A CN 201310052983A CN 103130267 A CN103130267 A CN 103130267A
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- titanium dioxide
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- glacial acetic
- acetic acid
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 183
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 66
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 106
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 79
- 239000010936 titanium Substances 0.000 claims abstract description 79
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 79
- 229960000583 acetic acid Drugs 0.000 claims abstract description 53
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 53
- 239000002608 ionic liquid Substances 0.000 claims abstract description 40
- 150000001408 amides Chemical class 0.000 claims abstract description 19
- 239000000975 dye Substances 0.000 claims abstract description 13
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims abstract description 13
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 230000000593 degrading effect Effects 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 84
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 76
- 238000010438 heat treatment Methods 0.000 claims description 44
- IAQLJCYTGRMXMA-UHFFFAOYSA-M lithium;acetate;dihydrate Chemical compound [Li+].O.O.CC([O-])=O IAQLJCYTGRMXMA-UHFFFAOYSA-M 0.000 claims description 44
- 239000008367 deionised water Substances 0.000 claims description 38
- 229910021641 deionized water Inorganic materials 0.000 claims description 38
- 238000003756 stirring Methods 0.000 claims description 38
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 38
- 238000001291 vacuum drying Methods 0.000 claims description 38
- -1 methane amide Chemical class 0.000 claims description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 10
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 claims description 8
- 230000003287 optical effect Effects 0.000 claims description 8
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 claims description 6
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 6
- 238000006731 degradation reaction Methods 0.000 claims description 6
- 230000015556 catabolic process Effects 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 4
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000012046 mixed solvent Substances 0.000 claims description 3
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 claims description 3
- LINPIYWFGCPVIE-UHFFFAOYSA-N 2,4,6-trichlorophenol Chemical compound OC1=C(Cl)C=C(Cl)C=C1Cl LINPIYWFGCPVIE-UHFFFAOYSA-N 0.000 claims description 2
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 claims description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 claims description 2
- 239000010919 dye waste Substances 0.000 claims description 2
- 229960000907 methylthioninium chloride Drugs 0.000 claims description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 2
- 229940043267 rhodamine b Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- 239000002351 wastewater Substances 0.000 abstract description 5
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 229910003002 lithium salt Inorganic materials 0.000 abstract description 2
- 159000000002 lithium salts Chemical class 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 230000004298 light response Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 22
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- HFZWRUODUSTPEG-UHFFFAOYSA-N 2,4-dichlorophenol Chemical compound OC1=CC=C(Cl)C=C1Cl HFZWRUODUSTPEG-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000015843 photosynthesis, light reaction Effects 0.000 description 1
- 238000006862 quantum yield reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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Abstract
本发明公开了一种可见光响应黑色二氧化钛光催化剂的制备方法，采用冰乙酸和酰胺为溶剂，金属锂盐为助剂，并使用钛片为钛源，加入离子液体作为结构导向剂，利用溶剂热法一步合成，所制得的产品粒径在100nm左右，相比于其他的二氧化钛其颜色是黑色的。其在可见光下显示出良好的降解有机染料的性能。本发明具有以下优点及突出效果：本发明所使用的化学试剂均为常用试剂、廉价易得，方法工艺简单，并将锐钛矿相二氧化钛拓展到可见光响应范围。同时，该光催化剂在可见光能降解低浓度染料废水，并在低浓度染料废水和酚类物质混合的体系中同样显示出高活性。
The invention discloses a preparation method of a visible light-responsive black titanium dioxide photocatalyst, which uses glacial acetic acid and amide as solvents, metal lithium salts as auxiliary agents, uses titanium sheets as titanium sources, adds ionic liquids as structure-directing agents, and utilizes solvothermal One-step synthesis, the particle size of the obtained product is about 100nm, and its color is black compared to other titanium dioxide. It shows good performance in degrading organic dyes under visible light. The invention has the following advantages and outstanding effects: the chemical reagents used in the invention are common reagents, cheap and easy to obtain, the method and process are simple, and the anatase phase titanium dioxide is extended to the visible light response range. At the same time, the photocatalyst can degrade low-concentration dye wastewater under visible light, and also shows high activity in a system where low-concentration dye wastewater and phenolic substances are mixed.
Description
Technical field
The invention discloses a kind of preparation method of visible-light-responsive photocatalyst, be specially a kind of preparation method of visible light-responded black titanium dioxide photocatalyst.Synthesize and utilize one step of solvent-thermal method to make, the gained catalyzer has the premium properties of efficient degradation lower concentration organic dye, and degraded has better effects to phenols sewage.
Background technology
Along with the growth of demographic and economic, environment and energy problem become two large factors of restriction human development.Semiconductor light-catalyst has unique advantage in dye wastewater treatment using and photolysis water hydrogen.Compare with the conventional process waster water process, photochemical catalysis has the advantages such as reaction conditions gentleness, energy consumption be low, pollution-free, has very important application prospect aspect environment and the energy.More and more to the research of semiconductor light-catalyst, well-known in recent years, TiO
2Due to cheapness, nontoxic, the advantage such as stable is used photocatalyst widely.But Anatase TiO
2Energy gap is 3.2eV, and it only can absorb UV-light (account for sunlight 4%), and quantum yield is low, can not be used for the actual production dye wastewater treatment.But TiO
2Because himself color is white, do not possess visible light-responded ability, the utilising efficiency in natural light is lower.Exploitation visible-light response type TiO
2Become improve light utilization efficiency solve environmental pollution in the urgent need to.
Summary of the invention
The object of the invention is to for the existing defective of prior art and satisfying the market needs, provide a kind of titanium dioxide optical catalyst of black Detitanium-ore-type simple, the expensive low novel preparation method of productive rate.
Black octahedrite type titanium dioxide photocatalyst provided by the present invention, adopting glacial acetic acid and acid amides is solvent, the metal lithium salts is auxiliary agent, and use the titanium sheet to be the titanium source, add ionic liquid as structure directing agent, utilize the solvent-thermal method one-step synthesis, prepared product cut size is in about 100nm, is black than other its color of titanium dioxide.It demonstrates the performance of good degradating organic dye under visible light.
The gained catalyzer has the premium properties of efficient degradation lower concentration organic dye, and degraded has better effects to phenols sewage.
A kind of preparation method of visible light-responded black titanium dioxide photocatalyst comprises the steps:
1) be transferred in 50mL tetrafluoroethylene water heating kettle after adding a certain amount of Lithium acetate dihydrate to stir to clarify in 30mL glacial acetic acid and amide solvent, add the titanium sheet as the titanium source, and add the 1-methyl of 2mL-3-tetrafluoroborate ionic liquid;
2) water heating kettle is reacted 8-48h under 150-220 ℃ of condition, after deionized water and ethanol respectively wash three times, obtain the titanium dioxide optical catalyst of the Detitanium-ore-type of black at 80 ℃ of lower vacuum-drying 12h.
In step 1), in 30mL glacial acetic acid and acid amides mixed solvent, the volume of each component is: 1-2:2-1.Preferred ratio has: glacial acetic acid 10mL, acid amides 20mL; Glacial acetic acid 12mL, acid amides 18mL; Glacial acetic acid 15mL, acid amides 15mL; Glacial acetic acid 18mL, acid amides 12mL; Glacial acetic acid 20mL, acid amides 10mL.
Described acid amides is a kind of in methane amide, ethanamide, DMF, N,N-dimethylacetamide and benzamide.
In step 1), described Lithium acetate dihydrate quality is 0.2-1.0g, and preferred Lithium acetate dihydrate quality is 0.2g, 0.4g, 0.6g and 1.0g, and more preferred Lithium acetate dihydrate quality is 0.6g.
Step 2) in, the Heating temperature of preferred water heating kettle is 150 ℃, 180 ℃, 200 ℃, 220 ℃, and the reaction times is 8h, 12h, 24h, 48h.The more preferred reaction times is 24h.
The titanium dioxide optical catalyst that the present invention makes is applied to degradation of dye waste water, and described dyestuff comprises tropeolin-D, methylene blue, rhodamine B, fluorescent yellow, Congo red.
The titanium dioxide optical catalyst that the present invention makes is applied to the degrading phenol material, described aldehydes matter comprises phenol, 4-chlorophenol (4CP), 2-chlorophenol (2CP), 4-chloro-3-methylphenol (4C3MP), 2,4-chlorophenesic acid (2,4-DCP), 2,4, the 6-Trichlorophenol (2,4,6-TCP) and pentachlorophenol (PCP).
The product of the present invention's preparation carries out structural characterization by following means: adopt the X-ray diffraction of measuring on Rigaku Rigaku D/Max-RB type X-ray diffractometer to carry out the structural analysis of sample; The stereoscan photograph that adopts Japanese JEOL JSM-6380LV type scanning electron microscope to obtain, the transmission electron microscope photo that adopts Japanese JEOL JEM-2100 type transmission electron microscope to obtain.
The present invention compared with prior art, have the following advantages and outstanding effect: chemical reagent used in the present invention is common agents, cheap and easy to get, method technique is simple, and anatase phase titanium dioxide is extended to visible light-responded scope.Simultaneously, this photocatalyst is at visible luminous energy degraded lower concentration waste water from dyestuff, and demonstrates equally high reactivity in the system that lower concentration waste water from dyestuff and aldehydes matter mix.
Description of drawings
Fig. 1 is the XRD figure spectrum of the photocatalyst sample of prepared black anatase titania;
Fig. 2 is the high resolution scanning Electronic Speculum figure of prepared black anatase titania photocatalyst sample;
Fig. 3 is transmission electron microscope picture and the single crystal diffraction figure of prepared black anatase titania photocatalyst sample;
Fig. 4 is that the black anatase titania photocatalyst sample that makes is to waste water from dyestuff degradation process figure.
Embodiment
Be doing further in detail, illustrating clearly and completely of how realizing below in conjunction with specific embodiment to the present invention, listed embodiment only is further described the present invention, and is not thereby limiting the invention:
Embodiment 1
Add in 12mL glacial acetic acid and 18mL methane amide and be transferred in 50mL tetrafluoroethylene reactor after the 0.2g Lithium acetate dihydrate stirs to clarify, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 3
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 24h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 4
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 48h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 5
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 6
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 7
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 8
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 24h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 9
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 220 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 10
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 48h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 11
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 220 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 12
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL methane amide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 13
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL N,N-dimethylacetamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 14
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL N,N-dimethylacetamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 15
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL N,N-dimethylacetamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 24h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 16
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 48h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 17
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL N,N-dimethylacetamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 18
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 19
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 24h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 21
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 220 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 22
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 48h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 23
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 220 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 24
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL ethanamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 25
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 26
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 27
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.2g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 24h under 180 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 28
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 48h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 29
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.4g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 31
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 32
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle was reacted 24 hours under 200 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 33
Be transferred in 50mL tetrafluoroethylene reactor after adding the 0.6g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 220 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 34
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 12mL glacial acetic acid and 18mL DMF, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 48h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
Embodiment 35
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 18mL glacial acetic acid and 12mL benzamide, add the titanium sheet as the titanium source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 8h under 220 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the titanium dioxide optical catalyst of the Detitanium-ore-type of black at 80 ℃ of lower vacuum-drying 12h.
Embodiment 36
Be transferred in 50mL tetrafluoroethylene reactor after adding the 1.0g Lithium acetate dihydrate to stir to clarify in 10mL glacial acetic acid and 20mL benzamide, add the titanium sheet as the source, and add 2mL1-methyl-3-tetrafluoroborate ionic liquid.Water heating kettle is reacted 12h under 150 ℃ of conditions; After deionized water and ethanol respectively wash three times, obtain the black octahedrite type titanium dioxide photocatalyst at 80 ℃ of lower vacuum-drying 12h.
What this method was synthetic as can be drawn from Figure 1 is the titanium dioxide of Detitanium-ore-type.
As can be seen from Figure 2 Electronic Speculum figure be cluster together.
Can obtain this kind material from Fig. 3 is monocrystalline.
Black titanium dioxide has good activity at degradation of contaminant as can be seen from Figure 4.
Claims (11)
1. the preparation method of a visible light-responded black titanium dioxide photocatalyst, is characterized in that: comprise the steps:
1) be transferred in 50mL tetrafluoroethylene water heating kettle after adding a certain amount of Lithium acetate dihydrate to stir to clarify in 30mL glacial acetic acid and amide solvent, add the titanium sheet as the titanium source, and add the 1-methyl of 2mL-3-tetrafluoroborate ionic liquid;
2) water heating kettle was reacted 8-48 hour under 150-220 ℃ of condition; After deionized water and ethanol respectively wash three times, obtain the titanium dioxide optical catalyst of the Detitanium-ore-type of black at 80 ℃ of lower vacuum-drying 12h.
2. the preparation method of a kind of visible light-responded black titanium dioxide photocatalyst according to claim 1, it is characterized in that: in step 1), in 30mL glacial acetic acid and acid amides mixed solvent, the volume of each component is: 1-2:2-1.
3. the preparation method of a kind of visible light-responded black titanium dioxide photocatalyst according to claim 2, it is characterized in that: in step 1), in 30mL glacial acetic acid and acid amides mixed solvent, the volume of each component is: glacial acetic acid 10mL, acid amides 20mL; Glacial acetic acid 12mL, acid amides 18mL; Glacial acetic acid 15mL, acid amides 15mL; Glacial acetic acid 18mL, acid amides 12mL; Glacial acetic acid 20mL, acid amides 10mL.
4. the preparation method of a kind of visible light-responded black titanium dioxide photocatalyst according to claim 1, it is characterized in that: described acid amides is methane amide, ethanamide, N, a kind of in dinethylformamide, N,N-dimethylacetamide and benzamide.
5. the preparation method of a kind of visible light-responded black titanium dioxide photocatalyst according to claim 1, it is characterized in that: in step 1), described Lithium acetate dihydrate quality is 0.2-1.0g.
6. the preparation method of a kind of visible light-responded black titanium dioxide photocatalyst according to claim 5, it is characterized in that: described Lithium acetate dihydrate quality is 0.2g, 0.4g, 0.6g and 1.0g.
7. want the preparation method of 6 described a kind of visible light-responded black titanium dioxide photocatalysts according to right, it is characterized in that: described Lithium acetate dihydrate quality is 0.6g.
8. want the preparation method of 1 described a kind of visible light-responded black titanium dioxide photocatalyst according to right, it is characterized in that: step 2) in, the Heating temperature of described water heating kettle is 150 ℃, 180 ℃, 200 ℃, 220 ℃, and the reaction times is 8h, 12h, 24h, 48h.
9. want the preparation method of 8 described a kind of visible light-responded black titanium dioxide photocatalysts according to right, it is characterized in that: the described reaction times is 24h.
10. want the preparation method of 1 described a kind of visible light-responded black titanium dioxide photocatalyst according to right, it is characterized in that: the titanium dioxide optical catalyst that makes is applied to degradation of dye waste water, and described dyestuff comprises tropeolin-D, methylene blue, rhodamine B, fluorescent yellow and Congo red.
11. want the preparation method of 1 described a kind of visible light-responded black titanium dioxide photocatalyst according to right, it is characterized in that the titanium dioxide optical catalyst that makes is applied to the degrading phenol material, described aldehydes matter comprises phenol, 4-chlorophenol, 2-chlorophenol, 4-chloro-3-methylphenol, 2,4-chlorophenesic acid and 2,4,6-Trichlorophenol and pentachlorophenol.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833075A (en) * | 2014-03-31 | 2014-06-04 | 中国科学院新疆理化技术研究所 | Preparation method for controllable micropore or mesoporous anatase titanium dioxide |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1613554A (en) * | 2004-09-29 | 2005-05-11 | 上海交通大学 | Preparation of visual responsing titania light catalyst |
| EP2123605A1 (en) * | 2008-05-15 | 2009-11-25 | Kyungpook National University Industry-Academic Cooperation Foundation | Production method of titanium dioxide (TIO2) photocatalyst and TIO2 photocatalyst produced by the same |
-
2013
- 2013-02-19 CN CN2013100529839A patent/CN103130267A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1613554A (en) * | 2004-09-29 | 2005-05-11 | 上海交通大学 | Preparation of visual responsing titania light catalyst |
| EP2123605A1 (en) * | 2008-05-15 | 2009-11-25 | Kyungpook National University Industry-Academic Cooperation Foundation | Production method of titanium dioxide (TIO2) photocatalyst and TIO2 photocatalyst produced by the same |
Non-Patent Citations (2)
| Title |
|---|
| HAO BIN WU ET AL: "Direct synthesis of anatase TiO2 nanowires with enhanced photocatalytic activity", 《ADVANCED MATERIALS》 * |
| JIAGUO YU ET AL.: "Ionic-Liquid-Assisted Synthesis of Uniform Fluorinated B/C-Codoped TiO2Nanocrystals and Their Enhanced Visible-Light Photocatalytic Activity", 《CHEMISTRY-A EUROPEAN JOURNAL》 * |
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