CN103113823B - Functional paint and preparation method thereof - Google Patents
Functional paint and preparation method thereof Download PDFInfo
- Publication number
- CN103113823B CN103113823B CN201210388618.0A CN201210388618A CN103113823B CN 103113823 B CN103113823 B CN 103113823B CN 201210388618 A CN201210388618 A CN 201210388618A CN 103113823 B CN103113823 B CN 103113823B
- Authority
- CN
- China
- Prior art keywords
- catalyzer
- coating
- powdered carbon
- preparation
- silicone composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims description 76
- 239000003973 paint Substances 0.000 title abstract description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 108
- 239000000203 mixture Substances 0.000 claims abstract description 99
- 238000006243 chemical reaction Methods 0.000 claims abstract description 41
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000000576 coating method Methods 0.000 claims description 165
- 239000011248 coating agent Substances 0.000 claims description 163
- 229910052799 carbon Inorganic materials 0.000 claims description 103
- 229920001296 polysiloxane Polymers 0.000 claims description 60
- 238000002156 mixing Methods 0.000 claims description 58
- 238000003756 stirring Methods 0.000 claims description 48
- 239000003002 pH adjusting agent Substances 0.000 claims description 47
- 239000002994 raw material Substances 0.000 claims description 35
- 229920002050 silicone resin Polymers 0.000 claims description 35
- 239000002253 acid Substances 0.000 claims description 34
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 claims description 25
- 238000001354 calcination Methods 0.000 claims description 24
- 238000007599 discharging Methods 0.000 claims description 24
- 239000011259 mixed solution Substances 0.000 claims description 24
- 244000018633 Prunus armeniaca Species 0.000 claims description 13
- 235000009827 Prunus armeniaca Nutrition 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 230000035484 reaction time Effects 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 abstract description 23
- 239000003054 catalyst Substances 0.000 abstract description 16
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 abstract 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- MTEZSDOQASFMDI-UHFFFAOYSA-N 1-trimethoxysilylpropan-1-ol Chemical compound CCC(O)[Si](OC)(OC)OC MTEZSDOQASFMDI-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- OYKSFZKYLDITBW-UHFFFAOYSA-N dimethoxy-phenoxy-phenylsilane Chemical class C=1C=CC=CC=1[Si](OC)(OC)OC1=CC=CC=C1 OYKSFZKYLDITBW-UHFFFAOYSA-N 0.000 abstract 1
- ORRNVHHOEJMPDQ-UHFFFAOYSA-N ethoxy-hydroxy-dimethoxysilane Chemical compound CCO[Si](O)(OC)OC ORRNVHHOEJMPDQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 33
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 239000002131 composite material Substances 0.000 description 18
- 238000010438 heat treatment Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 230000000274 adsorptive effect Effects 0.000 description 12
- 238000009434 installation Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 230000008569 process Effects 0.000 description 11
- 230000007613 environmental effect Effects 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 229910001018 Cast iron Inorganic materials 0.000 description 9
- 230000036541 health Effects 0.000 description 9
- 239000000049 pigment Substances 0.000 description 9
- 230000001681 protective effect Effects 0.000 description 9
- 238000005096 rolling process Methods 0.000 description 9
- 239000010410 layer Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- -1 Diphenyl dimethoxy siloxanes Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004523 agglutinating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to a functional paint, particularly an anticorrosion paint for cutters, which comprises a basic paint and an organic silicon resin in a volume ratio of 1:(0.5-4), wherein the basic paint comprises the following components in percentage by volume: 5-25% of pH regulator, 0.001-0.7% of functional catalyst and the balance of siloxane composition. The functional catalyst is a catalyst containing carbon powder; and the functional catalyst comprises the following components in percentage by volume: 20-60% of zirconate, 1-15% of acetylacetone and the balance of isopropanol. The siloxane composition comprises the following components in percentage by volume: 7-25% of diphenyldimethoxysiloxane, 7-15% of methyltrimethoxysiloxane, 1-5% of gamma-glycidol ether oxypropyltrimethoxysilane, 7-10% of phenyltrimethoxysiloxane and the balance of propylene glycol monomethyl ether. The zirconate, acetylacetone and isopropanol form a space cross-linked structure, thereby being beneficial to controlling the performance of the mild reaction. Compared with the technique of using the single zirconate catalyst, the invention can better control the reaction rate.
Description
[technical field]
The present invention relates to technical field of coatings, specifically, is a kind of functional coating and preparation method thereof.
[background technology]
In coating, the granularity of pigment and the dispersiveness in base-material will affect gloss of film.Pigment fineness is thinner, and the dispersing uniformity in base-material is better, contributes to the paint film forming flat smooth.Resin-pigment ratio in coating has an impact to gloss of film.Cause gloss to reduce because granules of pigments in paint film weakens specular reflection, and decline gradually along with the increase gloss of pigment volume concentration (PVC) (P.V.C).Resin-pigment ratio one timing, the oil number of pigment is larger, and gloss is lower.The absorption of various pigments to light is different with degree of reflection, absorb completely, and white paint reflects completely to light due to pitch-dark to light, so black paint shows high gloss than white paint.The solvent species selected in paint directly affects the speed of its evaporation rate, and the too fast or excessively slow smooth degree that all can affect paint film, reduce gloss of film.
The filmogen of anticorrosive coating has chemical stability in corrosive medium, and its standard is relevant with chemical structure with the composition of filmogen.Mainly see it under dry film condition whether easily and corrosive medium react or resolve into small molecules in media as well.No matter consider from cathodic protection or from simple buffer action, the shielding effect of anticorrosive coating is all very important,
[summary of the invention]
The object of the invention is to overcome the deficiencies in the prior art, a kind of functional coating and preparation method thereof is provided.
The object of the invention is to be achieved through the following technical solutions:
Technical scheme one: a kind of anticorrosive coating for cutter
For an anticorrosive coating for cutter, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5 ~ 4, is preferably 1: 3.
For a preparation method for the anticorrosive coating of cutter, after basic coating and silicone resin mixing, obtain the anticorrosive coating for cutter.
Described basic coating, its component volume percent is:
PH adjusting agent 5 ~ 25%
Function catalyzer 0.001 ~ 0.7%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of anticorrosive coating is 1 ~ 4;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5 ~ 15, is preferably 1: 13; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 2: 1, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 85nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 20 ~ 60%
Methyl ethyl diketone 1 ~ 15%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For an anticorrosive coating for cutter, coating can be sprayed directly on cutter.
Technical scheme two: a kind of protective system for cast iron kitchen range
For a protective system for cast iron kitchen range, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5 ~ 2.5, is preferably 1: 1.5.
For a preparation method for the protective system of cast iron kitchen range, after basic coating and silicone resin mixing, obtain the protective system for cast iron kitchen range.
Described basic coating, its component volume percent is:
PH adjusting agent 1 ~ 25%
Function catalyzer 0.002 ~ 0.7%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of protective system is 1 ~ 4;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5 ~ 15; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 1: 2, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 75nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 15 ~ 60%
Methyl ethyl diketone 1 ~ 15%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For a protective system for cast iron kitchen range, coating can be sprayed directly on cast iron kitchen range.
Technical scheme three: a kind of high-performance coating for screw
For a high-performance coating for screw, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5 ~ 1.5, is preferably 1:1.3.
For a preparation method for the high-performance coating of screw, after basic coating and silicone resin mixing, obtain the high-performance coating for screw.
Described basic coating, its component volume percent is:
PH adjusting agent 1 ~ 25%
Function catalyzer 0.003 ~ 0.7%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of high-performance coating is 1 ~ 4;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5 ~ 15, is preferably 1: 7; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 2: 2, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 80nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 15 ~ 60%
Methyl ethyl diketone 1 ~ 15%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For a high-performance coating for screw, coating can be sprayed directly on screw.
Technical scheme four: a kind of high-performance coating for electric iron
For a high-performance coating for electric iron, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.2 ~ 1.2, is preferably 1: 1.
For a preparation method for the high-performance coating of electric iron, after basic coating and silicone resin mixing, obtain the high-performance coating for electric iron.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1 ~ 25%
Function catalyzer 0.004 ~ 0.7%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of high-performance coating is 1 ~ 4;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 4 ~ 15, is preferably 1: 10; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 2: 3, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 95nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1 ~ 60%
Methyl ethyl diketone 1 ~ 20%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For a high-performance coating for electric iron, coating can be sprayed directly on electric iron.
Technical scheme five: a kind of efficient coating for lighting housing
For an efficient coating for lighting housing, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.4 ~ 1.4, is preferably 1: 0.7.
For a preparation method for the efficient coating of lighting housing, after basic coating and silicone resin mixing, obtain the efficient coating for lighting housing.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1 ~ 22%
Function catalyzer 0.005 ~ 0.7%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of efficient coating is 1 ~ 4;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 7 ~ 15, is preferably 1: 9; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 2: 4, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 80nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1 ~ 55%
Methyl ethyl diketone 1 ~ 18%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For an efficient coating for lighting housing, coating can be sprayed directly on lighting housing.
Technical scheme six: a kind of health paint for life small household appliances sandwich layer
For a health paint for life small household appliances sandwich layer, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.6 ~ 1.6, is preferably 1: 1.4.The interlayer coatings of life small household appliances such as soybean milk maker or the undercoat of thermos cup.
For a preparation method for the health paint of life small household appliances sandwich layer, after basic coating and silicone resin mixing, obtain the health paint for life small household appliances sandwich layer.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1 ~ 23%
Function catalyzer 0.006 ~ 0.7%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of health paint is 1 ~ 5;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 8 ~ 15, is preferably 1: 13; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 2: 6, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 75nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1 ~ 52%
Methyl ethyl diketone 1 ~ 17%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For a health paint for life small household appliances sandwich layer, coating can be sprayed directly on small household appliances sandwich layer.
Technical scheme seven: a kind of environmental protection coating material for cosmetology fixture
For an environmental protection coating material for cosmetology fixture, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.7 ~ 1.7, is preferably 1: 1.1.
For a preparation method for the environmental protection coating material of cosmetology fixture, after basic coating and silicone resin mixing, obtain the environmental protection coating material for cosmetology fixture.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1 ~ 19%
Function catalyzer 0.007 ~ 0.5%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of environmental protection coating material is 1 ~ 4.1;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 8 ~ 15, is preferably 1: 10; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 3: 1, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 60nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1 ~ 48%
Methyl ethyl diketone 1 ~ 14%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For an environmental protection coating material for cosmetology fixture, coating can be sprayed directly on cosmetology fixture.
Technical scheme eight: a kind of Multifunctional composite coating for heating installation
For a Multifunctional composite coating for heating installation, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.8 ~ 1.8, is preferably 1: 1.4.Heating installation be radiator and other, or the instrument such as heating tube.
For a preparation method for the Multifunctional composite coating of heating installation, after basic coating and silicone resin mixing, obtain the Multifunctional composite coating for heating installation.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1 ~ 22%
Function catalyzer 0.008 ~ 0.6%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of Multifunctional composite coating is 1 ~ 4.2;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5 ~ 15; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 3: 2, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 65nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1 ~ 51%
Methyl ethyl diketone 1 ~ 16%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For a Multifunctional composite coating for heating installation, coating can be sprayed directly on heating installation.
Technical scheme nine: a kind of anticorrosion composite coating for isolator
For an anticorrosion composite coating for isolator, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.9 ~ 1.9, is preferably 1: 1.7.Heating installation be radiator and other, or the instrument such as heating tube.Isolator is such as graphite flake.
For a preparation method for the anticorrosion composite coating of isolator, after basic coating and silicone resin mixing, obtain the anticorrosion composite coating for isolator.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1 ~ 20%
Function catalyzer 0.009 ~ 0.4%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of anticorrosion composite coating is 1 ~ 4.3;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5 ~ 15; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 3: 3, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 70nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1 ~ 47%
Methyl ethyl diketone 1 ~ 13%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For an anticorrosion composite coating for isolator, coating can be sprayed directly on isolator head.
Technical scheme ten: a kind of high-performance coating for rolling screen door
For a high-performance coating for rolling screen door, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 1 ~ 5, is preferably 1: 3.Heating installation be radiator and other, or the instrument such as heating tube.
For a preparation method for the high-performance coating of rolling screen door, after basic coating and silicone resin mixing, obtain the high-performance coating for rolling screen door.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1 ~ 21%
Function catalyzer 0.0065 ~ 0.1%
Silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of high-performance coating is 1 ~ 4.6;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5 ~ 15, is preferably 1: 13; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 4: 1, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals, is preferably 80nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1 ~ 46%
Methyl ethyl diketone 1 ~ 15%
Virahol surplus
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is:
For a high-performance coating for rolling screen door, coating can be sprayed directly in rolling screen door.
Compared with prior art, positively effect of the present invention is:
Diphenyl dimethoxy siloxanes of the present invention is first as one of the component of the siloxanes in coating, and its effect had is improve the gloss of coating, makes the coating of preparation have very high gloss; Main effect if it were not for playing conventional siloxanes; The orientation property of raising system, increases the heat-resisting oxidation-resistance performance of system, enhances the repulsion performance to water, improves thermo-elasticity, improves and the consistency of organic resin, the mutual solubility with pigment.And it is good to the agglutinating value(of coal) of various material, stability in storage.
The present invention is by zirconate, and methyl ethyl diketone and Virahol form a space crosslinking structure, and the gentleness being conducive to controlling reaction is carried out, and more can control speed of reaction than only adopting the catalyzer of zirconate.Can with in ground and coating reactive group generation crosslinking reaction, formed crane span structure, molecular weight is increased.And coating and ground finally make its sticking power improve by crane span structure effect, can also water tolerance be improved, solvent resistance and boiling fastness simultaneously, improve the rate of drying of paint film, surface luster.
The present invention contains coffee carbon, and product tool has the following advantages: coffee carbon raw materials for production are from the coffee grounds reclaimed, and environmental protection recycling, does not increase the burden of the earth, thus reaches the object of carbon reduction; When health or environment has a peculiar smell at one's side time, also by Van der Waals force effect, peculiar smell can be absorbed; Coffee carbon structural void is large, and surface irregularity is high to the assimilated efficiency of heat, and speed is fast, has the function that heats up instantaneously.
The present invention contains the fruit shell carbon of apricot shell and nut-shell formation, there is pore texture prosperity, specific surface area be large, high adsorption capacity, physical strength are high, bed resistance is little, good, the easy regeneration of chemical stability, the advantage such as durable in use, and there is the granularity of all size; Decompose obnoxious flavour and the various peculiar smell such as formaldehyde, ammonia, benzene, cigarette, oil smoke in air, especially carcinogenic aromatic substance, activated carbon has extremely strong adsorptive power.
Low-temperature carbonization and the charing of middle temperature are taked in powdered carbon preparation of the present invention, and obtain powdered carbon, it reduces costs, and its particle diameter meets again the requirement of application of paints simultaneously.
The present invention, using the carrier of powdered carbon as catalyzer, plays the effect controlling speed of reaction and play powdered carbon self.
[embodiment]
The embodiment of a kind of functional coating of the present invention and preparation method thereof is below provided.
Embodiment 1
For an anticorrosive coating for cutter, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5.
For a preparation method for the anticorrosive coating of cutter, after basic coating and silicone resin mixing, obtain the anticorrosive coating for cutter.
Described basic coating, its component volume percent is: pH adjusting agent is 5%, and function catalyzer is 0.001%, and silicone composition is 94.999%;
The preparation method of described basic coating, its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing is about 5min until mix;
Two, by the H in pH adjusting agent
2o and mixing acid mix in the container of other cleanings, after slowly drop in the silicone composition mixed in reactor while stirring; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to adjust ph, the pH value of anticorrosive coating is 1 ~ 4;
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5; Powdered carbon due to its space more, its adsorptive catalyst, be conducive to react slow gentleness carry out, be conducive to control and regulate reaction progress.
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality ratio of three is 1: 2: 1, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is: zirconate is 20%, methyl ethyl diketone is 1%, Virahol is 79%, the preparation method of described catalyzer is: temperature in reactor controlled at 40 DEG C, first add Virahol, add zirconate while stirring, low rate mixing about 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging.
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h;
Described silicone composition, its component volume percent is: diphenyl dimethoxy siloxanes is 7%, and methyl trimethoxy oxygen radical siloxane is 7%, γ-glycidyl ether oxygen propyl trimethoxy silicane is 1%, phenyl trimethoxy siloxane is 7%, and propylene glycol monomethyl ether is 78%
For an anticorrosive coating for cutter, coating can be sprayed directly on cutter.
Table 1-1 mono-kind detects data for the embodiment 1 of the anticorrosive coating of cutter:
Embodiment 2-5
For an anticorrosive coating for cutter, concrete preparation method refers to technological line one, and the proportioning of its Raw is for shown in table 2.
Table 1 is a kind of proportioning raw materials situation of the anticorrosive coating for cutter
Embodiment 6-10
For a protective system for cast iron kitchen range, concrete preparation method refers to technological line two, and the proportioning of its Raw is for shown in table 2.
Table 2 is a kind of proportioning raw materials situation of the protective system for cast iron kitchen range
Test data is: table 2-2 mono-kind is for embodiment 6 test data of the protective system of cast iron kitchen range
Embodiment 11-15
For a high-performance coating for screw, concrete preparation method refers to technological line three, and the proportioning of its Raw is for shown in table 3.
Table 3 is a kind of proportioning raw materials situation of the high-performance coating for screw
Detect data: table 3-3 mono-kind is for the test data of the embodiment 11 of the high-performance coating of screw
Embodiment 16-20
For a high-performance coating for electric iron, concrete preparation method refers to technological line four, and the proportioning of its Raw is for shown in table 4.
Table 4 is a kind of proportioning raw materials situation of the high-performance coating for electric iron
Detect data: table 4-4 mono-kind is for the test data of the embodiment 16 of the high-performance coating of electric iron
Embodiment 21-25
For an efficient coating for lighting housing, concrete preparation method refers to technological line five, and the proportioning of its Raw is for shown in table 5.
Table 5 is a kind of proportioning raw materials situation of the efficient coating for lighting housing
Test data: table 5-5 is a kind of embodiment 21 test data of the efficient coating for lighting housing
Embodiment 26-30
For a health paint for life small household appliances sandwich layer, concrete preparation method refers to technological line six, and the proportioning of its Raw is for shown in table 6.
The proportioning raw materials situation that table 6 is a kind of health paint for life small household appliances sandwich layer
Table 6-6 mono-kind is for the test data of the embodiment 26 of the high-performance coating of electric iron
Embodiment 31-35
For an environmental protection coating material for cosmetology fixture, concrete preparation method refers to technological line seven, and the proportioning of its Raw is for shown in table 7.
Table 7 is a kind of proportioning raw materials situation of the environmental protection coating material for cosmetology fixture
Table 7-7 is a kind of embodiment 31 test data of the environmental protection coating material for cosmetology fixture
Embodiment 36-40
For a Multifunctional composite coating for heating installation, concrete preparation method refers to technological line eight, and the proportioning of its Raw is for shown in table 8.
Table 8 is a kind of proportioning raw materials situation of the Multifunctional composite coating for heating installation
Test data is: table 8-8 mono-kind is for embodiment 36 test data of the Multifunctional composite coating of heating installation
Embodiment 41-45
For an anticorrosion composite coating for isolator, concrete preparation method refers to technological line nine, and the proportioning of its Raw is that table 9 shows.
One kind, table 9 is for the proportioning raw materials situation of the anticorrosion composite coating of isolator
Test data: table 9-9 mono-kind is for the test data of the embodiment 41 of the anticorrosion composite coating of isolator
Embodiment 46-50
For a high-performance coating for rolling screen door, concrete preparation method refers to technological line ten, and the proportioning of its Raw is table 10.
One kind, table 10 is for the proportioning raw materials situation of the high-performance coating of rolling screen door
Test data: table 10-10 mono-kind is for the test data of the embodiment 46 of the high-performance coating of rolling screen door
Claims (2)
1. a functional coating, is characterized in that, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1:0.5 ~ 4;
Described basic coating, its component volume percent is:
PH adjusting agent 5 ~ 25%
Function catalyzer 0.001 ~ 0.7%
Silicone composition surplus
Described function catalyzer is the catalyzer containing powdered carbon, and wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1:5 ~ 15;
Described catalyzer, its component volume percent is:
Zirconate 20 ~ 60%
Methyl ethyl diketone 1 ~ 15%
Virahol surplus
Described silicone composition, its component volume percent is:
Described powdered carbon preparation method, its concrete steps are:
(1) carbonize: apricot shell, nut-shell and coffee grounds are raw material, the raw materials quality of three is than being 1:2:1, first through the drying treatment 1 ~ 2 hour of 150 ~ 180 DEG C, afterwards temperature is risen to 300 ~ 400 DEG C of calcinings 1 ~ 2 hour, and then be warming up to 600 ~ 700 DEG C of calcinings 1 ~ 2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grinds to form the powdered carbon of 30 ~ 200 nano-scale multifunctionals;
The preparation method of described catalyzer is: temperature in reactor controlled, at 40 DEG C, first to add Virahol, add zirconate while stirring, and low rate mixing 5 minutes is until mix; Slowly drip in the above-mentioned mixed solution mixed in methyl ethyl diketone to reactor under whipped state, react 1 hour at 40 DEG C after dropwising, cooling discharging;
The preparation method of described function catalyzer is: powdered carbon is added people in catalyzer, constantly stir, and the reaction times is 1 ~ 3h.
2. a kind of functional coating as claimed in claim 1, is characterized in that, the preparation method of described basic coating, and its concrete steps are:
One, control at 40 DEG C by temperature in reactor, limit is stirred and is added silicone composition according to quantity successively, and stir speed (S.S.) is 300r/min, and low rate mixing 5min is until mix;
Two, by the H in pH adjusting agent
2after O and mixing acid mix in the container of other cleanings, slowly drop to while stirring in the silicone composition mixed in reactor; Time for adding is 15 ~ 20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, function catalyzer is joined in mixed solution;
Four, after function catalyzer adds reaction 1h, after being cooled to room temperature, discharging is detected.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210388618.0A CN103113823B (en) | 2012-10-12 | 2012-10-12 | Functional paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210388618.0A CN103113823B (en) | 2012-10-12 | 2012-10-12 | Functional paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103113823A CN103113823A (en) | 2013-05-22 |
| CN103113823B true CN103113823B (en) | 2015-04-08 |
Family
ID=48412245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210388618.0A Expired - Fee Related CN103113823B (en) | 2012-10-12 | 2012-10-12 | Functional paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103113823B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087157B (en) * | 2014-06-25 | 2016-02-17 | 上海宜瓷龙新材料股份有限公司 | A kind of ceramic coating for public arena decorative wall |
| CN104403457A (en) * | 2014-12-13 | 2015-03-11 | 常熟市磊王合金工具有限公司 | Wear-resisting double-edge diamond cutter |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
| CN101857772A (en) * | 2010-06-22 | 2010-10-13 | 北京红狮漆业有限公司 | Scratch resistance nanometre water-based inorganic-organic polymer paint and application thereof |
-
2012
- 2012-10-12 CN CN201210388618.0A patent/CN103113823B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
| CN101857772A (en) * | 2010-06-22 | 2010-10-13 | 北京红狮漆业有限公司 | Scratch resistance nanometre water-based inorganic-organic polymer paint and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103113823A (en) | 2013-05-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102964972B (en) | Composite intensified heat dissipation coating containing graphene or graphene oxide and preparation method of coating | |
| CN105729597B (en) | A kind of color and luster sootiness treatment process of timber modification face layer | |
| CN102071267B (en) | Method for coproducing xylose, white carbon black and active carbon from rice hulls | |
| CN108610817A (en) | Nana intelligent health powdery paints | |
| CN102653628A (en) | Preparation method and application of nano sol modified waterborne polyurethane emulsion | |
| CN105017831A (en) | Composition for water-based electric heating nano paint, water-based electric heating nano paint as well as preparation method and application of water-based electric heating nano paint | |
| CN102146257B (en) | Formaldehyde-resistant odor-removing full-effect environment-friendly water-based woodware white paint and preparation method thereof | |
| CN108128774A (en) | A kind of preparation method of high-purity porous charcoal | |
| CN107118648A (en) | A kind of new type environment friendly coating and preparation method thereof | |
| CN102911537A (en) | Ceramic coating material with 3D effect and coating method of ceramic coating material | |
| CN108384390A (en) | Anti-slip heat-preservation sound-insulation environment-friendly floor coating and preparation method thereof | |
| CN108977064A (en) | A kind of environment-friendly water-based high-temperature resistant coating of silicone resin and its preparation and application | |
| CN103113823B (en) | Functional paint and preparation method thereof | |
| Shawabkeh et al. | Absorption of phenol and methylene blue by activated carbon from pecan shells | |
| CN102329524A (en) | Method for preparing attapulgite supported high weather resistance composite pigment | |
| CN107090200A (en) | A kind of preparation method of ultraviolet light screener | |
| CN101983929B (en) | Preparation method of low-valence titanium oxide powder | |
| CN102925053B (en) | Organic-inorganic composite paint, and preparation method and application thereof | |
| CN105944670A (en) | Preparation method of graphene purifying material | |
| CN106554719B (en) | A kind of oil colour | |
| CN101157451A (en) | A kind of preparation method of resin-based spherical carbon | |
| CN102277030A (en) | Efficient environment-friendly flame retardant for flame retardance of coating and preparation method thereof | |
| CN102898944B (en) | Anti-corrosion and high-gloss paint and preparation method and use thereof | |
| CN103849312B (en) | Improve lac and the method for modifying thereof of varnish thermotolerance | |
| CN107226675A (en) | Preparation method of novel energy-saving flame-retardant building material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 201108, No. 2, 3679 lane, 8 Jin Du Road, Shanghai, Minhang District Applicant after: SHANGHAI EXCILON NEW MATERIALS CO., LTD. Address before: 201108, No. 2, 3679 lane, 8 Jin Du Road, Shanghai, Minhang District Applicant before: Shanghai Excilon New Material Technology Co., Ltd. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: SHANGHAI EXCILON NEW MATERIAL TECHNOLOGY CO., LTD. TO: SHANGHAI EXCILON NEW MATERIALS CO., LTD. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150408 Termination date: 20181012 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |