Utilize granite powder to be generative foaming material of raw material and preparation method thereof
Technical field
The present invention relates to a kind of granite powder waste material that utilizes and be generative foaming material of raw material and preparation method thereof.
Background technology
Grouan is the volcanic rock that a kind of magma condenses below the earth's surface and forms, and main component is feldspar and quartz.Because grouan is plutonite, often can form physically well develop, mineral grain that naked eyes can be distinguished, thereby gain the name.Grouan is easy-weathering not, and color is attractive in appearance, and appearance luster can keep more than a century, because its hardness is high, wear-resistant, and except being used as senior building decorative engineering, ground, hall, or the material of the first-selection of open-air engraving.The natural formation of grouan need to be passed through upper a century even more than one thousand years, because human constantly exploitation, the reserves of natural granite constantly reduce, and in the course of processing of grouan, can produce waste material and the granite powder of many grouan, the words that these waste materials and granite powder are not used, will produce severe contamination, welding, restriction expanding economy.The method of traditional digestion granite powder adopts low temperature, mixed sticking technique to make twice-laid stuff, and the density of its product is large, reaches 2.5 tons/m
3, conduct heat fast, and in making processes, need to add chemical adhesive.
Also have a kind of application number to be 200710142893.3 to be called the Chinese invention patent application of " utilize granite powder waste material artificial compound board prepared " to disclose a kind of novel artificial composite plank, made by granite waste material.Prescription comprises resin, solidifying agent, promotor, granite powder, gravel particle etc.This artificial composite plank, pattern is many, and length can accomplish enough large, thereby can be applied to various places.But owing to having used inflammable or poisonous chemicals in the prescription of described artificial composite plank, people's cognition is damaged, and density is large, heavy weight, transportation and installation are all inconvenient, again difficult insulation, nor can reuse.Therefore, the structure of this composition board also need be further improved.
Summary of the invention
First technical problem to be solved by this invention is to provide a kind of insulation, fire prevention, the granite powder that utilizes lightweight and environmental protection to be the generative foaming material of raw material for above-mentioned prior art present situation.
The present invention solves the technical scheme that first technical problem adopts: this utilizes granite powder to be the generative foaming material of raw material, it is characterized in that: the prescription of this generative foaming material consists of: granite powder is that 40~69 parts, 2~8 parts in flyash, the filler of fluxing are 6~25 parts, pore creating agent is 1~5 part, the polymerization material is 1~5 part, and above-mentioned is weight part.
As improvement, the described filler of fluxing may be selected to be the combined composition of any two and Feldspar Powder in talcum powder, silicon powder, wollastonite material, mica powder, the dry powder.
As improvement, the component ratio of described composition can be preferably: A: B: C=5: 1.5: 1.5, wherein A represents Feldspar Powder, B is a kind of in talcum powder, silicon powder, wollastonite material, mica powder, the dry powder, C is a kind of in talcum powder, silicon powder, wollastonite material, mica powder, the dry powder, and B is two kinds of not identical materials with C.
As improvement, described pore creating agent can be preferably diatomite, titanium dioxide, silicon carbide, calcium carbonate, any two composition in the barium carbonate.
Improve, the component ratio of described composition may be selected to be 1: 1 again.
As improvement, described polymerization material may be selected to be the composition of clay, wilkinite, borax.
Improve, the component ratio of described composition can be preferably clay: wilkinite: borax=1: 1: 1 again.
Technical problem to be solved by this invention is to provide for above-mentioned prior art present situation that a kind of technique is simple, easy to prepare, the granite powder that utilizes of environmental protection is the making method of the generative foaming material of raw material.
The present invention solves the technical scheme that second technical problem adopt: the present invention produces the described granite powder that utilizes according to above-mentioned prescription and is the making method of the generative foaming material of raw material: it is characterized in that: may further comprise the steps successively:
One, the powder particle fineness with granite powder, flyash, the filler of fluxing, pore creating agent, polymerization material is controlled to be more than 100 orders;
Two, according to above-mentioned prescription above-mentioned materials is mixed into compound, again with the compound mold pressing or be rolled into required granulate material;
Three, the die body of granulate material being put into desired shape is stacked moulding;
Four, it is that the High Temperature Furnaces Heating Apparatuss of 1100~1400 degree were heated 50~70 minutes that the material that then will stack moulding is put into temperature together with die body; From die body, take out after the cooling, be the generative foaming finished material.
As improvement, be cooled to naturally cooling in the described step 4.
Compared with prior art, the invention has the advantages that: generative foaming material of the present invention has following product performance:
(1) all raw materials are inorganic materials, without chemical pollution.
(2) high temperature burns till, more than high temperature resistant 1100 degree, and fire-resistant A level.
(3) cellular unicellular structure is airtight, and is waterproof, and heat conduction is slow.Waterproof, sound insulation, insulation.
(4) 0.3 ton/m of density range
3~1.2 tons/m
3, pressure-proof and snap-resistent, physical property is good.
(5) can reuse, still can burn till after dead meal is prepared burden again.
According to above-mentioned feature, the advantage of product of the present invention is, can fully digest the granite powder waste material, can solve the long-standing severe environmental pollution problem in grouan processing base, meet the requirement of environmental protection.This product stable physical property, lightweight, insulation, resistance to compression, anti-folding can be used for construction wall or decoration of exterior wall, reaches building loss of weight and energy-conservation target.Also have this product also to have the performance of fire prevention, waterproof, sound insulation, can be used for fire-retardant material, the body of wall barrier material.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail, following indication is weight part;
Embodiment one, and the granite powder that utilizes of the present embodiment consists of 69 parts of granite powders for the prescription of the generative foaming material of raw material, 8 parts in flyash, 22 parts of the fillers of fluxing, 3 parts of pore creating agents, 5 parts in polymerization material.The described filler of fluxing is the feldspar powder, talcum powder, and the silicon powder composition, its ratio is 5: 1.5: 1.5, described pore creating agent is diatomite, the silicon carbide composition, and its ratio is 1: 1, described polymerization material is clay, wilkinite, the borax composition, its ratio is 1: 1: 1.
According to above-mentioned prescription, the making method of generative foaming material may further comprise the steps successively:
One, is controlled to be more than 100 orders through the particle fineness of pulverizing, screen granite powder, flyash, the filler of fluxing, pore creating agent, polymerization material powder;
Two, granite powder, flyash, the filler of fluxing, pore creating agent, polymerization material powder are mixed and make compound, again compound is made required granulate material by mold pressing or roll extrusion;
Three, granulate material is put into the die body of desired shape, stacked moulding;
Four, the material that then will stack moulding is put into together High Temperature Furnaces Heating Apparatus with die body and is slowly heated, until the temperature of High Temperature Furnaces Heating Apparatus reaches 1100~1400 degree, and temperature be 1100~1400 the degree High Temperature Furnaces Heating Apparatuss in heated 50~70 minutes, be preferably 60 minutes, heat and from High Temperature Furnaces Heating Apparatus, take out after finishing, naturally cooling took out from die body after 11~13 hours, was the generative foaming finished material.
Embodiment two, and the granite powder that utilizes of the present embodiment for the prescription of the generative foaming material of raw material is: 50 parts of granite powders, 5 parts in flyash, 18 parts of the fillers of fluxing, 3 parts of pore creating agents, 3 parts in polymerization material.The described filler of fluxing is the feldspar powder, the wollastonite material, and the mica powder composition, its ratio is 5: 1.5: 1.5, described pore creating agent is diatomite, the barium carbonate composition, and its ratio is 1: 1, described polymerization material is clay, wilkinite, the borax composition, its ratio is 1: 1: 1.
According to above-mentioned prescription, the making method of generative foaming material may further comprise the steps successively:
One, is controlled to be more than 100 orders through the particle fineness of pulverizing, screen granite powder, flyash, the filler of fluxing, pore creating agent, polymerization material powder;
Two, granite powder, flyash, the filler of fluxing, pore creating agent, polymerization material powder are mixed and make compound, again compound is made required granulate material by mold pressing or roll extrusion;
Three, granulate material is put into the die body of desired shape, stacked moulding;
Four, the material that then will stack moulding is put into together High Temperature Furnaces Heating Apparatus with die body and is slowly heated, until the temperature of High Temperature Furnaces Heating Apparatus reaches 1100~1400 degree, and temperature be 1100~1400 the degree High Temperature Furnaces Heating Apparatuss in heated 50~70 minutes, be preferably 60 minutes, heat and from High Temperature Furnaces Heating Apparatus, take out after finishing, naturally cooling took out from die body after 11~13 hours, was the generative foaming finished material.
Embodiment three, and the granite powder that utilizes of the present embodiment for the prescription of the generative foaming material of raw material is: 40 parts of granite powders, 2 parts in flyash, 15 parts of the fillers of fluxing, 4 parts of pore creating agents, 6 parts in polymerization material.The described filler of fluxing is the feldspar powder, mica powder, and the dry powder composition, its ratio is followed successively by 5: 1.5: 1.5, described pore creating agent is titanium dioxide, the silicon carbide composition, and its ratio is 1: 1, described polymerization material is clay, wilkinite, the borax composition, its ratio is 1: 1: 1.
According to above-mentioned prescription, the making method of generative foaming material may further comprise the steps successively:
One, is controlled to be more than 100 orders through the particle fineness of pulverizing, screen granite powder, flyash, the filler of fluxing, pore creating agent, polymerization material powder;
Two, granite powder, flyash, the filler of fluxing, pore creating agent, polymerization material powder are mixed and make compound, again compound is made required granulate material by mold pressing or roll extrusion;
Three, granulate material is put into the die body of desired shape, stacked moulding;
Four, the material that then will stack moulding is put into together High Temperature Furnaces Heating Apparatus with die body and is slowly heated, until the temperature of High Temperature Furnaces Heating Apparatus reaches 1100~1400 degree, and temperature be 1100~1400 the degree High Temperature Furnaces Heating Apparatuss in heated 50~70 minutes, be preferably 60 minutes, heat and from High Temperature Furnaces Heating Apparatus, take out after finishing, naturally cooling took out from die body after 11~13 hours, was the generative foaming finished material.