CN103058780B - Herbicide vermifuge fertilizer with benzyl. propyl and production method thereof - Google Patents
Herbicide vermifuge fertilizer with benzyl. propyl and production method thereof Download PDFInfo
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- CN103058780B CN103058780B CN201310038556.5A CN201310038556A CN103058780B CN 103058780 B CN103058780 B CN 103058780B CN 201310038556 A CN201310038556 A CN 201310038556A CN 103058780 B CN103058780 B CN 103058780B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 106
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 41
- 239000004009 herbicide Substances 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 title claims abstract description 14
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 title abstract description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 70
- 235000009566 rice Nutrition 0.000 claims abstract description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000009333 weeding Methods 0.000 claims abstract description 15
- 238000005507 spraying Methods 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 230000004720 fertilization Effects 0.000 claims abstract description 4
- 239000003814 drug Substances 0.000 claims description 90
- 150000001412 amines Chemical class 0.000 claims description 48
- 239000008187 granular material Substances 0.000 claims description 25
- 239000000575 pesticide Substances 0.000 claims description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 16
- 239000003905 agrochemical Substances 0.000 claims description 15
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 238000013268 sustained release Methods 0.000 claims description 12
- 239000012730 sustained-release form Substances 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 11
- 239000004202 carbamide Substances 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 239000000945 filler Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 239000012467 final product Substances 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 9
- 239000010452 phosphate Substances 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 claims description 8
- -1 nicotinoids Substances 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- NRFQZTCQAYEXEE-UHFFFAOYSA-N Fenclorim Chemical compound ClC1=CC(Cl)=NC(C=2C=CC=CC=2)=N1 NRFQZTCQAYEXEE-UHFFFAOYSA-N 0.000 claims description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims description 7
- 239000003125 aqueous solvent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 230000002265 prevention Effects 0.000 claims description 7
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 6
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 239000003053 toxin Substances 0.000 claims description 6
- 231100000765 toxin Toxicity 0.000 claims description 6
- 241001498622 Cixius wagneri Species 0.000 claims description 5
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- 244000215068 Acacia senegal Species 0.000 claims description 4
- 235000006491 Acacia senegal Nutrition 0.000 claims description 4
- 229920000858 Cyclodextrin Polymers 0.000 claims description 4
- 239000001116 FEMA 4028 Substances 0.000 claims description 4
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 4
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 4
- 229960004853 betadex Drugs 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 238000010008 shearing Methods 0.000 claims description 3
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims description 2
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 claims description 2
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 claims description 2
- 239000005875 Acetamiprid Substances 0.000 claims description 2
- 239000005888 Clothianidin Substances 0.000 claims description 2
- 239000005696 Diammonium phosphate Substances 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 2
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 claims description 2
- 235000013877 carbamide Nutrition 0.000 claims description 2
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 2
- 239000006012 monoammonium phosphate Substances 0.000 claims description 2
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 2
- 239000004323 potassium nitrate Substances 0.000 claims description 2
- 235000010333 potassium nitrate Nutrition 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- 229960004249 sodium acetate Drugs 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 claims description 2
- 241000209094 Oryza Species 0.000 claims 3
- 238000003825 pressing Methods 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 abstract description 67
- 238000000034 method Methods 0.000 abstract description 20
- 239000002917 insecticide Substances 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 4
- 239000005472 Bensulfuron methyl Substances 0.000 abstract description 3
- YLPGTOIOYRQOHV-UHFFFAOYSA-N Pretilachlor Chemical compound CCCOCCN(C(=O)CCl)C1=C(CC)C=CC=C1CC YLPGTOIOYRQOHV-UHFFFAOYSA-N 0.000 abstract description 3
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 abstract description 3
- 235000013339 cereals Nutrition 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000002775 capsule Substances 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 40
- 230000000694 effects Effects 0.000 description 29
- 230000003449 preventive effect Effects 0.000 description 16
- 241000426497 Chilo suppressalis Species 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 13
- 244000025254 Cannabis sativa Species 0.000 description 11
- 230000012010 growth Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 241000192043 Echinochloa Species 0.000 description 8
- 238000011160 research Methods 0.000 description 8
- 241000098289 Cnaphalocrocis medinalis Species 0.000 description 7
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 7
- 241001249129 Scirpophaga incertulas Species 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 210000000582 semen Anatomy 0.000 description 7
- 241000169139 Monochoria Species 0.000 description 6
- 235000003990 Monochoria hastata Nutrition 0.000 description 6
- 238000009331 sowing Methods 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
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- 230000007774 longterm Effects 0.000 description 2
- STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
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- 241000254158 Lampyridae Species 0.000 description 1
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- XUYPXLNMDZIRQH-LURJTMIESA-N N-acetyl-L-methionine Chemical compound CSCC[C@@H](C(O)=O)NC(C)=O XUYPXLNMDZIRQH-LURJTMIESA-N 0.000 description 1
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- 240000009132 Sagittaria sagittifolia Species 0.000 description 1
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- 241001074085 Scophthalmus aquosus Species 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a herbicide vermifuge fertilizer with benzyl. propyl. The herbicide vermifuge fertilizer is prepared by combining herbicide bensulfuron methyl, pretilachlor, vermifuge and a fertilizer carrier, wherein the bensulfuron methyl is 0.01-0.3% of the total weight of the herbicide vermifuge fertilizer, and the pretilachlor is 0.05-5.0% of the total weight of the herbicide vermifuge fertilizer. The invention further discloses a production method of the herbicide vermifuge fertilizer; water is used as the solvent, and herbicide vermifuge fertilizer grains are prepared by using a spraying capsule method. The herbicide vermifuge fertilizer is short in process procedure, stable in quality and small in environmental pollution; the obtained herbicide fertilizer grains are suitable for being applied in rice fields, has multi-functions of fertilization, weeding and insecticide, and the purposes of labor saving and time saving are achieved.
Description
Technical field
The invention belongs to agricultural chemicals product innovation field, relate in particular to a kind of herbicide pesticide medicine fertilizer and production method thereof containing benzyl third, this product innovation is a kind of rice terrace agriculture production medicine fertilizer that simultaneously contains weedicide, sterilant and fertilizer nutrition.
Background technology
Grain-production is the infrastructural industries of national economy, paddy rice is the important food crop of China, rice yield accounts for 45% of total output of grain, its sown area accounts for 1/3 of food crop sown area, the long-term sown area of China exceedes 4.2 hundred million mu at present, becomes one of country that world's Monitoring of Paddy Rice Plant Area and output are maximum.
But, the growth of paddy rice be subject to impact and the restriction, particularly insect pest of disease pest and weed and crop smothering particularly serious.Between paddy rice and weeds, between different sorts weeds, competition is very fierce naturally, and they constantly fight for moisture and the nutrition in space, air and soil around, to maintain the needs that grow separately.It is reported, when Weedy Rice density is 1 strain/m
2, can cause Rice Yield Loss Caused 9.15%; When Weedy Rice density reaches 7 strains/m
2time, can cause Rice Yield Loss Caused more than 50%; Weedy Rice density reaches 12 strains/m
2time, Rice Yield Loss Caused can be up to 72.29%.Planthopper, striped rice borer, yellow rice borer, Cnaphalocrocis medinali(rice leaf roller) are the primary pests of hazard rice, and they all can cause very serious impact to the fertility growth of paddy rice, as anti-smelting not in time even can cause paddy rice total crop failure.
Along with the acceleration of China's urbanization, Development of Urbanization; people in the countryside, rural laborer shift to city in a large number; agriculture production will be to intensive, mass-producing, high efficiency future development, and the mode of production and the technical measures of raising labour efficiency, improve resource utilization will more and more be subject to people's attention.Weed removal medicinal fertilizer is scientifically integrated pesticide herbicide and carrier fertilizer organic combination, become a kind of polyfunctional " medicine fertilizer " product, it has the usefulness of fertilizer and agricultural chemicals concurrently, applied once can complete two or more operations simultaneously, reach dual or multi-efficiency, realized saving of work and time labour-saving object.Scientific progress is exactly complicated thing will be simplified, saving of work and time is laborsaving is exactly to liberate the productive forces, numerous working people are freed from loaded down with trivial details agriculture business, go to create more social benefit, meet the reason of " lazyboot's science ", so the generation of medicine fertilizer is representing scientific progress, be the needs of modern agriculture with high efficiency development.
The research of Weed removal medicinal fertilizer is on the books in phase early 1960s, once the weedicide more than 300 that proposition can be mixed with fertilizer is planted, but there is the key technical problems such as quality uniformity, stability and application security in the fertile production process of medicine, so it is few to realize the product of industrialization, but also exist many jejune aspects, need scientific worker to remove research and probe.For the research of Weed removal medicinal fertilizer, China is scarcely out of swaddling-clothes, and applicant has has researched and developed successfully multiple Weed removal medicinal fertilizer for paddy rice and accomplished scale production.Through retrieval, about patent or the patent application of Weed removal medicinal fertilizer mainly contain:
| Patent (application) number | Invention and created name | Open day |
| 200610067294.5 | Weed removal medicinal fertilizer for paddy rice and manufacture method thereof | On October 11st, 2006 |
| 200710135666.8 | Weed removal medicinal fertilizer for paddy rice and manufacture method thereof | On October 10th, 2007 |
| 200910310314.0 | A kind of herbicide fertilizer granules and production method | On 06 02nd, 2010 |
| 200810112401.0 | A kind of herbicide-fertilizer composite granule for paddy rice and preparation thereof, using method | On October 22nd, 2008 |
| 200810134482.4 | A kind of farmland fertilizer with herbicide and its preparation method and application | On December 17th, 2008 |
| 95111890.0 | Agent used as herbicide pesticide for sturdying rice seedlings and preparation technology thereof | On 01 29th, 1997 |
| 99114015.X | Multiple-effect rice seed dressing agent series composition | On 09 15th, 1999 |
But, how pesticide herbicide, sterilant and fertilizer carrier are integrated, and the fertile current research of medicine that is applied to field crop herbicide pesticide have not been reported, be also in current agricultural sciences, to need the technical barrier that solves.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of security is good, good stability, effect are good, pollute herbicide pesticide medicine fertilizer and the production method thereof containing the benzyl third that reduce.
For solving the problems of the technologies described above, the present invention takes following technical scheme: containing the herbicide pesticide medicine fertilizer of benzyl third, mainly press row weight percent by weedicide, sterilant, carrier fertilizer and auxiliary agent and make:
Weedicide: benbbensulfuronmethyl 0.01%-0.3%, the third careless amine 0.05%-5.0%,
Sterilant: 0.05%-5.0%,
Carrier fertilizer: 78.7%-99.04%,
Auxiliary agent: aqueous solvent 0.2%-3.0%, stablizer 0.1%-1.0%, diffusant 0.2%-2.0%, sustained release dosage 0.3%-3.0%, safener 0.05%-2.0%.
Weedicide accounts for the 0.1%-1.0% of the fertile gross weight of medicine, and wherein benbbensulfuronmethyl and the third careless amine weight ratio are 1:5-11.
Sterilant is the one in silkworm-killing toxin class, nicotinoids, acetamiprid, ethiprole, Rynaxypyr; Silkworm-killing toxin class is disosultap, desinsection list or cartap, and nicotinoids is Provado, Diacloden, clothianidin or MTI-446.
Carrier fertilizer is by n-p-k element fertilizer and media assemblage, carrier Nitrogen constituent content accounts for the 15-25% of the fertile gross weight of medicine, phosphorus potassium element can be adjusted or need not according to actual, nitrogen element is from one or more in urea, ammonium chloride, ammonium sulfate, phosphoric is from one or more in monoammonium phosphate, diammonium phosphate, fused(calcium magnesium)phosphate, and potassium element is from one or more in Repone K, potassium sulfate, saltpetre.
Filler is one or more in kaolin powder, clay powder, diatomite.
Stablizer is the mixture of potassium primary phosphate and 2,6 ditertiary butyl p cresol or sodium-acetate and 2,6 ditertiary butyl p cresol; Diffusant is one or more in methyl sodiosul foaliphatate, Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether; Sustained release dosage is one or more in polyoxyethylene glycol, beta-cyclodextrin, polyacrylic ester, sodium polystyrene sulfonate, gelatin, Sudan Gum-arabic; Safener is allyl dichloride amine, how to pacify, in fenclorim any two kinds.
The production method of the above-mentioned herbicide pesticide medicine fertilizer containing benzyl third, comprises the following steps:
<1> prepares agricultural-chemical suspension mixture taking water as solvent, former benbbensulfuronmethyl medicine, the former medicine of the third careless amine, preparing protodrug, stablizer, diffusant, sustained release dosage, safener and water are added in sand mill, reach below 5 microns to material particular diameter through shearing sand milling, to obtain final product;
<2> prepares carrier fertiliser granulates n-p-k element fertilizer and filler compatibility is mixed, and through drum granulating, Drying and cooling, screening, to obtain final product;
<3> prepares agricultural chemicals herbicide pesticide fertilizer granules and adopts spraying coating method, the agricultural-chemical suspension mixture of step <1> is sprayed to coating on the carrier fertiliser granulates of step <2>, mix, to obtain final product.
The application of the above-mentioned herbicide pesticide medicine fertilizer containing benzyl third, is used so that fertilization of rice is shortly turned green at rice terrace, weeding and prevention rice borer, planthopper early stage.
Can realize and synchronize the problem of carrying out, contriver have obtained sure conclusion through long-term and arduous research in the face of fertilization of rice, weeding and desinsection.5-15 days after rice transplanting (rice transplanting), has following feature: 1) rice shoot is turned green a seedling stage just, requires to supplement the fertilizer nutrition such as nitrogen on plant strain growth physiology, needs nitrogen fertilizer application could promote paddy rice early growth and quick tiller; 2) peak period that paddy field weed is sprouted is just also the best moment of weeding; 3) sprouting initial stage of rice insect pest just, dispenser early can be controlled planthopper, striped rice borer, yellow rice borer, the harm of Cnaphalocrocis medinali(rice leaf roller) to paddy rice effectively.According to the principle of " putting prevention first and combining prevention with control ", in paddy rice this period in early stage, exist fertilising, weeding and synchronize the binding site carrying out with desinsection.
Based on this, contriver optimizes the combinations of herbicides that is applicable to medicine fertilizer: benbbensulfuronmethyl and the third careless amine.
Benbbensulfuronmethyl (having another name called Nongdeshi, English popular name bensulfuron-methyl) is efficient sulfonylurea herbicide, has selectivity inner sucting conduction type performance.Effective constituent can spread rapidly in water, for weeds root and blade absorb and transfer to the each portion of weeds, hinder the amino acid whose biosynthesizing such as Methionin, Isoleucine, stop division and the growth of cell, susceptible weeds GF is obstructed, tender tissue turns to be yellow too early and suppresses the growth of leaf portion, hinders root growth and necrosis.It is harmless inertia chemicals that effective constituent enters rapid metabolism in paddy rice body, to rice safety.Use benbbensulfuronmethyl at rice terrace, can effectively prevent and kill off annual and perennial broadleaf weeds and sedge weed, but invalid to gramineous weeds.Benbbensulfuronmethyl is that rice terrace uses at most and the safest weedicide.
The third careless amine (English popular name pretilachlor) is amides selectivity preemergence herbicide, can pass through plant hypocotyl, mesocotyl and coleoptile absorbs, root slightly absorbs, direct interference weeds body internal protein is synthetic, and photosynthetic and respiration is had to remote effect, the weeds seedling distortion of being injured, primary leaf difficulty is stretched out, leaf look deepens green, and growth stops, until dead.The third careless amine can be used for paddy field and nonirrigated farmland prevents there is good preventive effect divided by the gramineous weeds of seed germination, annual nutgrass flatsedge and some annual broadleaf weeds (as barnyard grass, Semen Euphorbiae, Herba Cyperi Difformis, cyperus iria, Herba Eleocharitis acicularis) etc., Sheathed Monochoria, Herba Clinopodii Polycephali, cusp flower and firefly Lin etc. are had to better prophylactic effect, to water Rhizoma Sparganii, the perennial weeds such as stalk bit of a bridle grass, Sagittaria trifolia L. Var. Angusti-folia(Sieb.) Kitag.(Sagittaria sagittifolia L.) is without obvious preventive effect partially.Paddy rice has stronger capacity of decomposition to the third careless amine, thereby has certain selectivity.The third careless amine is that rice terrace uses maximum and safer weedicide.
According to the difference of herbicide spectrum and site of action, benbbensulfuronmethyl and two kinds of highly selective weedicides of the third careless amine are carried out to compatibility, can expand herbicide spectrum, improve weeding activity.
In the selection of sterilant, contriver, according to China's agriculture chemical registration kind and agriculture chemical registration relevant regulations, in conjunction with using of medicine fertilizer, by changing application method and period, thereby realizes " old medicine is newly used ", has obtained excellent results.Silkworm-killing toxin class is used at paddy rice period of seedling establishment in early stage, and the brill such as striped rice borer, yellow rice borer insect in property is had to fabulous effect, and the anti-paddy rice Cnaphalocrocis medinali(rice leaf roller) harm of holding concurrently, and nicotinoids has good preventing iron-smelting effect to rice hoppers, rice leafhopper.
Contriver, on the basis of traditional Weed removal medicinal fertilizer, has made great innovation of the present invention through further investigation, compared with prior art, is mainly reflected in following several respects:
(1) realized first the combination of sciences of pesticide herbicide, sterilant and carrier fertilizer, successfully developed a kind of brand-new multifunctional medical fertilizer granular formulation, product is stable, effect stack, realizes the multiple action of fertilizing and weeding desinsection, and effect is good.
(2) probing into the stoichiometric(al) that obtains effective ingredient pesticide herbicide benbbensulfuronmethyl and the third careless amine is 1:5-11, and its co-toxicity to barnyard grass and nutgrass flatsedge has improved 140%, shows significant synergism.
(3) carrier fertilizer is had to great discovery, tiller early stage at rice striking root, according to paddy growth physiological characteristic, mainly absorb high nitrogen nutrition element this period, to promote rice striking root to tiller, reach the effect of early growth and quick tiller; Research finds that the reasonable coordination effect of urea and ammonium chloride is comparatively desirable, especially in cold spell in later spring (or cold dew wind) low temperature period, can effectively manifest fertility effect (turning green for 3 days), promote paddy growth to improve cold tolerance, research is found, in the rice striking root early tillering stage, using urea and the fiting effect of ammonium chloride, to use NpK complex fertilizer effect than isodose good.
(4) research finds that there is agricultural chemical insecticide silkworm-killing toxin class, nicotinoids etc. that paddy rice insect in early stage is had good preventive effect, good interior absorption energy and can be coexisted with fertilizer.
(5) application herbicide pesticide pesticide-fertilizer product of the present invention, can use early stage at rice terrace, weeding is clean, rice shoot is turned green soon (within 3 days, turning green), tillered, can reach the effect of early growth and quick tiller, integrated control effect to weeds reaches 90%, prevention effect to planthopper, rice borer reaches 91%, fertilizer efficiency effect increasing production of rice 13%.
(6) the safe production process environmental protection taking water as solvent, be beneficial to production operation; Adopt spraying coating to prepare herbicide fertilizer granules and farthest reduced the environmental pollution that in the fertile production of medicine, the drift of weedicide powder causes.
Embodiment
In order to understand better essence of the present invention, contriver has carried out the application test in rice seedling throwing field at rice in Guangxi province growing area, be summarized as follows:
1. test with medicament:
The careless amine disosultap fertilizer granules of test medicine A-2.2% benbbensulfuronmethyl third, forms according to following examples 3.
Contrast medicament B-0.2% benbbensulfuronmethyl the third careless amine fertilizer granules, being equal to weedicide and being equal to fertilizer compatibility in forming according to following examples 3 prepared.
Contrast medicament C-disosultap 3.6% granule
Contrast medicament D-benbbensulfuronmethyl 10% wettable powder
Careless amine 30% missible oil of contrast medicament E-the third
Blank test CK: not dispenser.
2. controlling object:
(1) Semen Euphorbiae [Leptochloa chinensis (L.) Nees]
(2) barnyard grass [Echinochloa crusgalli (L.) Beauv.]
(3) Herba Cyperi Difformis [Cyperus difformisL.]
(4) purslane [Portulaca oleraceaL.]
(5) rice-stem borer [Chilo suppressalis (Walker)]
3. test is processed:
(1), the fertile GR of the careless amine disosultap medicine of test medicine A-2.2% benbbensulfuronmethyl third, 10kg/ mu (commodity amount).
(2), contrast the fertile GR of medicament B-0.2% benbbensulfuronmethyl the third careless amine medicine, 10 ㎏/mus (commodity amount).
(3), contrast medicament C-disosultap 3.6%GR, 6000g/ mu (commodity amount).
(4), contrast medicament D-benbbensulfuronmethyl 10% wettable powder, 20g/ mu (commodity amount).
(5), contrast medicament E-the third careless amine 30% missible oil, 100g/ mu (commodity amount).
(6), blank-CK.
The test medicine 2.2% benzyl fertile GR of phonetic the third careless amine disosultap medicine and the fertile GR of the careless amine medicine of 0.2% benbbensulfuronmethyl third, 7-10 days after rice seedling throwing, directly spreads fertilizer over the fields by the consumption of test design; Disosultap, benbbensulfuronmethyl, the third careless amine in contrast medicament, adopt pesticide-clay mixture method, and medicament and equivalent fertilizer are mixed all and spread fertilizer over the fields afterwards, and the fertilizer (from urea) of equivalent, not spraying herbicide are directly spread fertilizer over the fields in blank test; When dispenser agent, the field thin water layer water conservation 7 days of 3cm of having an appointment is undertaken by normal field management later, and each community water and fertilizer management is consistent, within after medicine 25 days, 45 days, carries out preventive effect investigation, and test-results sees the following form 1, table 2, table 3, table 4.
Table 1 is each processes after medicine 25 days to paddy field weed strain preventive effect
Table 2 is each processes after medicine 45 days to paddy field weed strain preventive effect
Table 3 is each processes after medicine 45 days to paddy field weed fresh weight preventive effect
Table 4 is each to be processed after medicine rice-stem borer prevention effect
After paddy field weed is prevented and kill off in the each processing of table 5, paddy is surveyed product result
Test-results shows:
1) the prepared fertile GR of the careless amine disosultap of 2.2% benbbensulfuronmethyl third medicine of the present invention can prevent and kill off paddy field weed effectively, after medicine 25 days, comprehensive strain preventive effect to weeds reaches 97.81%, after medicine 45 days, comprehensive fresh preventive effect to weeds and strain preventive effect reach respectively more than 99.57% and 95.21%, compare with contrasting the fertile GR of the careless amine medicine of medicament 0.2% benbbensulfuronmethyl third, strain preventive effect and fresh preventive effect all increase, but difference is not remarkable; With contrast medicament D, E weeding single dose is compared, the comprehensive strain preventive effect of weeds and fresh preventive effect have significantly and to improve, difference reaches unusual effect.
2) the prepared fertile GR energy of the careless amine disosultap of the 2.2% benbbensulfuronmethyl third medicine effectively preventing rice-stem borer of the present invention, after medicine 7 days, 14 days, 21 days, prevention effect to rice-stem borer is investigated, preventive effect all reaches more than 90%, with contrast medicament C and compare, preventive effect increases, and shows that the fertile stack of medicine does not affect insecticidal effect.
3) rice yield of the fertile GR of the prepared careless amine disosultap of 2.2% benbbensulfuronmethyl third medicine of the present invention is higher is 355.69kg/ mu, with contrast CK and compare, stimulation ratio reaches 18.34%, the fertile GR of the careless amine medicine of 0.2% benbbensulfuronmethyl third takes second place for 346.25kg/ mu, stimulation ratio is 15.20%, and the two rice yield is all significantly higher than blank and other single dose processing.
Above-mentioned test-results shows: under identical water and fertilizer condition, fertile GR is variant with the fertilizer efficiency that contrasts medicament B, C, D, E for the prepared careless amine disosultap of 2.2% benbbensulfuronmethyl third medicine of the present invention, show that medicament-fertilizer mixture of the present invention produces the fertile synergistic effect of medicine, when transmitting fertility, improve herbicidal effect, the nutrient competition that has reduced weeds and paddy rice, has improved fertilizer efficiency, and this medicine fertilizer has insecticidal action, can effectively prevent and treat the drill string insects such as rice-stem borer, have good volume increase usefulness; Compare with contrasting medicament B, under the weeding pesticide condition of equivalent, no matter Weed removal medicinal fertilizer of the present invention is that herbicidal effect or fertilizer efficiency all increase, and manifests superiority of the present invention.
Below in conjunction with embodiment, the invention will be further described, and in embodiment, each proportioning raw materials is weight percentage.
Embodiment 1
Agent for removing grass in paddy field insecticide fertilizer---the careless amine cartap of 0.65% benbbensulfuronmethyl third fertilizer granules, mainly press row weight percent by weedicide, sterilant, carrier fertilizer and auxiliary agent and make:
Weedicide: account for 0.15% of the fertile gross weight of medicine, be mixed with by weight 1:11 by benbbensulfuronmethyl and the third careless amine;
Sterilant: account for 0.5% of the fertile gross weight of medicine, be mixed with by agricultural chemicals cartap;
Carrier fertilizer: account for 97.95% of the fertile gross weight of medicine, be made up of urea, ammonium sulfate and filler kaolin powder, wherein total nitrogen (N) accounts for 15%.
Auxiliary agent: account for 1.4% of the fertile gross weight of medicine, wherein
Aqueous solvent: 0.4%;
Stablizer: 0.2%, by potassium primary phosphate and the tertiary propyl group p-cresol of 2,6-bis-1:3 compatibility by weight;
Diffusant: 0.4%, by methyl sodiosul foaliphatate and Sodium dodecylbenzene sulfonate 1:1 compatibility by weight;
Sustained release dosage: 0.3%, by polyoxyethylene glycol and Sudan Gum-arabic 1:2 compatibility by weight;
Safener: 0.1%, by fenclorim and allyl dichloride amine 1:3 compatibility by weight;
Produce according to the following steps the agent for removing grass in paddy field insecticide fertilizer granule containing the careless amine cartap of 0.65% benbbensulfuronmethyl third:
<1> prepares agricultural-chemical suspension mixture taking water as solvent, by processing requirement, former benbbensulfuronmethyl medicine, the former medicine of the third careless amine, preparing protodrug, stablizer, diffusant, sustained release dosage, safener and water are added in sand mill, reach to material particular diameter below 5 microns through shearing sand milling, mix, to obtain final product;
<2> prepares carrier fertiliser granulates urea, ammonium sulfate and filler compatibility is mixed, and through drum granulating, Drying and cooling, screening, to obtain final product;
<3> prepares agricultural chemicals herbicide pesticide fertilizer granules and adopts spraying coating method, the agricultural-chemical suspension mixture of step <1> is sprayed to coating on the carrier fertiliser granulates of step <2>, mix, to obtain final product.
Using method and effect: after paddy rice throws cultivation, use in 5-10 days fields, sowing amount 20-30kg/ mu, after executing, maintain water in field 3-5 centimetre of water layer 5-7 days, can effectively control the harm of the weeds harm such as the Semen Euphorbiae, barnyard grass, Herba Cyperi Difformis, Sheathed Monochoria of rice terrace and rice hoppers, striped rice borer, yellow rice borer and Cnaphalocrocis medinali(rice leaf roller), realize fertilizing and weeding desinsection synchronous effect.
Embodiment 2
Agent for removing grass in paddy field insecticide fertilizer---the careless amine cartap of 0.8% benbbensulfuronmethyl third fertilizer granules, mainly press row weight percent by weedicide, sterilant, carrier fertilizer and auxiliary agent and make:
Weedicide: account for 0.20% of the fertile gross weight of medicine, be mixed with by weight 1:9 by benbbensulfuronmethyl and the third careless amine;
Sterilant: account for 0.6% of the fertile gross weight of medicine, be mixed with by agricultural chemicals cartap;
Carrier fertilizer: account for 98.0% of the fertile gross weight of medicine, be made up of urea, ammonium sulfate and filler kaolin powder, wherein total nitrogen (N) accounts for 16%.
Auxiliary agent: account for 1.2% of the fertile gross weight of medicine, wherein
Aqueous solvent: 0.3%;
Stablizer: 0.2%, by potassium primary phosphate and 2,6 ditertiary butyl p cresol 1:3 compatibility by weight;
Diffusant: 0.3%, by methyl sodiosul foaliphatate and fatty alcohol-polyoxyethylene ether 1:2 compatibility by weight;
Sustained release dosage: 0.3%, by polyoxyethylene glycol and polyacrylic ester 1:3 compatibility by weight;
Safener: 0.1%, by fenclorim with how pacify by weight 1:1 compatibility;
With reference to the method for embodiment 1, produce the agent for removing grass in paddy field insecticide fertilizer granule containing the careless amine cartap of 0.8% benbbensulfuronmethyl third.
Using method and effect: after paddy rice throws cultivation, use in 5-10 days fields, sowing amount 15-20kg/ mu, after executing, maintain water in field 3-5 centimetre of water layer 5-7 days, can effectively control the harm of the weeds harm such as the Semen Euphorbiae, barnyard grass, Herba Cyperi Difformis, Sheathed Monochoria of rice terrace and rice hoppers, striped rice borer, yellow rice borer and Cnaphalocrocis medinali(rice leaf roller), realize weeding fertilising synchronous effect, reach the laborsaving object of saving of work and time.
Embodiment 3
Agent for removing grass in paddy field insecticide fertilizer---the careless amine disosultap of 2.2% benbbensulfuronmethyl third fertilizer granules, mainly press row weight percent by weedicide, sterilant, carrier fertilizer and auxiliary agent and make:
Weedicide: account for 0.2% of the fertile gross weight of medicine, be mixed with by weight 1:9 by benbbensulfuronmethyl and the third careless amine;
Sterilant: account for 2.0% of the fertile gross weight of medicine, be mixed with by agricultural insecticide is two;
Carrier fertilizer: account for 96.5% of the fertile gross weight of medicine, be made up of urea, ammonium chloride and filler kaolin powder, wherein total nitrogen (N) accounts for 20%.
Auxiliary agent: account for 1.3% of the fertile gross weight of medicine, wherein
Aqueous solvent: 0.3%;
Stablizer: 0.2%, by potassium primary phosphate and 2,6 ditertiary butyl p cresol 1:3 compatibility by weight;
Diffusant: 0.3%, by methyl sodiosul foaliphatate and Sodium dodecylbenzene sulfonate 1:2 compatibility by weight;
Sustained release dosage: 0.4%, by polyoxyethylene glycol and beta-cyclodextrin 1:5 compatibility by weight;
Safener: 0.1%, by fenclorim and allyl dichloride amine 1:2 compatibility by weight;
With reference to the method for embodiment 1, produce the agent for removing grass in paddy field insecticide fertilizer granule containing the careless amine disosultap of 2.2% benbbensulfuronmethyl third.
Using method and effect: after paddy rice throws cultivation, use in 5-15 days fields, sowing amount 10-15kg/ mu, after executing, maintain water in field 3-5 centimetre of water layer 5-7 days, can effectively control the harm of the weeds harm such as the Semen Euphorbiae, barnyard grass, Herba Cyperi Difformis, Sheathed Monochoria of rice terrace and rice-stem borer, yellow rice borer and Cnaphalocrocis medinali(rice leaf roller), paddy rice be had to topdress simultaneously and put forward the effect of seedling.
Embodiment 4
Agent for removing grass in paddy field insecticide fertilizer---the careless amine ethiprole of 0.34% benbbensulfuronmethyl third fertilizer granules, mainly press row weight percent by weedicide, sterilant, carrier fertilizer and auxiliary agent and make:
Weedicide: account for 0.24% of the fertile gross weight of medicine, be mixed with by weight 1:7 by benbbensulfuronmethyl and the third careless amine;
Sterilant: account for 0.1% of the fertile gross weight of medicine, be mixed with by agricultural chemicals ethiprole;
Carrier fertilizer: account for 98.46% of the fertile gross weight of medicine, be made up of urea, ammonium chloride and filler kaolin powder, wherein total nitrogen (N) accounts for 20%.
Auxiliary agent: account for 1.2% of the fertile gross weight of medicine, wherein
Aqueous solvent: 0.3%;
Stablizer: 0.2%, by potassium primary phosphate and 2,6 ditertiary butyl p cresol 1:3 compatibility by weight;
Diffusant: 0.3%, by methyl sodiosul foaliphatate and Sodium dodecylbenzene sulfonate 1:2 compatibility by weight;
Sustained release dosage: 0.3%, by polyoxyethylene glycol and beta-cyclodextrin 1:3 compatibility by weight;
Safener: 0.1%, by fenclorim and allyl dichloride amine 1:2 compatibility by weight;
With reference to the method for embodiment 1, produce the agent for removing grass in paddy field insecticide fertilizer granule containing the careless amine ethiprole of 0.34% benbbensulfuronmethyl third.
Using method and effect: after paddy rice throws cultivation, use in 5-10 days fields, sowing amount 8-10kg/ mu, after executing, maintain water in field 3-5 centimetre of water layer 5-7 days, can effectively control the harm of the weeds harm such as the Semen Euphorbiae, barnyard grass, Herba Cyperi Difformis, Sheathed Monochoria of rice terrace and rice hoppers, striped rice borer, yellow rice borer and Cnaphalocrocis medinali(rice leaf roller), realize fertilizing and weeding desinsection synchronous effect.
Embodiment 5
Agent for removing grass in paddy field insecticide fertilizer---0.86% benbbensulfuronmethyl the third metazachlor worm quinoline fertilizer granules, mainly press row weight percent by weedicide, sterilant, carrier fertilizer and auxiliary agent and make:
Weedicide: account for 0.36% of the fertile gross weight of medicine, be mixed with by weight 1:5 by benbbensulfuronmethyl and the third careless amine;
Sterilant: account for 0.5% of the fertile gross weight of medicine, be mixed with by pesticide imidacloprid;
Carrier fertilizer: account for 97.64% of the fertile gross weight of medicine, be made up of urea, ammonium chloride and filler kaolin powder, wherein total nitrogen (N) accounts for 23%.
Auxiliary agent: account for 1.5% of the fertile gross weight of medicine, wherein
Aqueous solvent: 0.3%;
Stablizer: 0.2%, by potassium primary phosphate and 2,6 ditertiary butyl p cresol 1:3 compatibility by weight;
Diffusant: 0.4%, by methyl sodiosul foaliphatate and Sodium dodecylbenzene sulfonate 1:3 compatibility by weight;
Sustained release dosage: 0.5%, by polyoxyethylene glycol and Sudan Gum-arabic 1:2 compatibility by weight;
Safener: 0.1%, by fenclorim and allyl dichloride amine 1:2 compatibility by weight;
With reference to the method for embodiment 1, produce the agent for removing grass in paddy field insecticide fertilizer granule containing 0.86% benbbensulfuronmethyl the third metazachlor worm quinoline.
Using method and effect: after paddy rice throws cultivation, use in 5-10 days fields, sowing amount 5-8kg/ mu, after executing, maintain water in field 3-5 centimetre of water layer 5-7 days, can effectively control the weeds harm such as Semen Euphorbiae, barnyard grass, Herba Cyperi Difformis, Sheathed Monochoria of rice terrace and the harm of rice hoppers, realize fertilizing and weeding desinsection synchronous effect.
Claims (5)
1. containing a herbicide pesticide medicine fertilizer for benzyl third, it is characterized in that mainly pressing row weight percent by weedicide, sterilant, carrier fertilizer and auxiliary agent makes:
Weedicide: benbbensulfuronmethyl 0.01%-0.3%, the third careless amine 0.05%-5.0%,
Sterilant: 0.05%-5.0%,
Carrier fertilizer: 78.7%-99.04%,
Auxiliary agent: aqueous solvent 0.2%-3.0%, stablizer 0.1%-1.0%, diffusant 0.2%-2.0%, sustained release dosage 0.3%-3.0%, safener 0.05%-2.0%;
Described weedicide accounts for the 0.1%-1.0% of the fertile gross weight of medicine, and wherein benbbensulfuronmethyl and the third careless amine weight ratio are 1:5-11;
Described sterilant is the one in neires toxin, nicotinoids, acetamiprid, ethiprole, Rynaxypyr; Described neires toxin is disosultap, desinsection list or cartap, and described nicotinoids is Provado, Diacloden, clothianidin or MTI-446;
Described carrier fertilizer is by n-p-k element fertilizer and media assemblage, carrier Nitrogen constituent content accounts for the 15-25% of the fertile gross weight of medicine, nitrogen element is from one or more in urea, ammonium chloride, ammonium sulfate, phosphoric is from one or more in monoammonium phosphate, diammonium phosphate, fused(calcium magnesium)phosphate, and potassium element is from one or more in Repone K, potassium sulfate, saltpetre.
2. the herbicide pesticide medicine fertilizer containing benzyl third according to claim 1, is characterized in that: described filler is one or more in kaolin powder, clay powder, diatomite.
3. the herbicide pesticide medicine fertilizer containing benzyl third according to claim 1, is characterized in that: described stablizer is the mixture of potassium primary phosphate and 2,6 ditertiary butyl p cresol or sodium-acetate and 2,6 ditertiary butyl p cresol; Described diffusant is one or more in methyl sodiosul foaliphatate, Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether; Described sustained release dosage is one or more in polyoxyethylene glycol, beta-cyclodextrin, polyacrylic ester, sodium polystyrene sulfonate, gelatin, Sudan Gum-arabic; Described safener is allyl dichloride amine, how to pacify, in fenclorim any two kinds.
4. contain according to claim 1 the production method of the herbicide pesticide medicine fertilizer of benzyl third, it is characterized in that comprising the following steps: <1> prepares agricultural-chemical suspension mixture taking water as solvent, former benbbensulfuronmethyl medicine, the former medicine of the third careless amine, preparing protodrug, stablizer, diffusant, sustained release dosage, safener and water are added in sand mill, reach below 5 microns to material particular diameter through shearing sand milling, to obtain final product;
<2> prepares carrier fertiliser granulates n-p-k element fertilizer and filler compatibility is mixed, and through drum granulating, Drying and cooling, screening, to obtain final product;
<3> prepares agricultural chemicals herbicide pesticide fertilizer granules and adopts spraying coating method, the agricultural-chemical suspension mixture of step <1> is sprayed to coating on the carrier fertiliser granulates of step <2>, mix, to obtain final product.
5. according to claim 1 containing the application of the herbicide pesticide medicine fertilizer of benzyl third, it is characterized in that using early stage so that fertilization of rice is shortly turned green at rice terrace, weeding and prevention rice borer, planthopper.
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