CN103053613A - Improved biological control by using chlorine-stabilizing agent mixture - Google Patents
Improved biological control by using chlorine-stabilizing agent mixture Download PDFInfo
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- CN103053613A CN103053613A CN2011103285841A CN201110328584A CN103053613A CN 103053613 A CN103053613 A CN 103053613A CN 2011103285841 A CN2011103285841 A CN 2011103285841A CN 201110328584 A CN201110328584 A CN 201110328584A CN 103053613 A CN103053613 A CN 103053613A
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- 239000000203 mixture Substances 0.000 title claims abstract description 140
- 239000003381 stabilizer Substances 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 claims abstract description 95
- 150000002367 halogens Chemical class 0.000 claims abstract description 67
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 65
- 230000008569 process Effects 0.000 claims abstract description 54
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000004202 carbamide Substances 0.000 claims abstract description 36
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000126 substance Substances 0.000 claims abstract description 24
- 238000002156 mixing Methods 0.000 claims abstract description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 3
- 239000000123 paper Substances 0.000 claims description 37
- 239000000460 chlorine Substances 0.000 claims description 26
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 22
- 229910052801 chlorine Inorganic materials 0.000 claims description 22
- 239000003513 alkali Substances 0.000 claims description 17
- 238000005516 engineering process Methods 0.000 claims description 17
- 230000006641 stabilisation Effects 0.000 claims description 15
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 12
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 12
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 241000233866 Fungi Species 0.000 claims description 6
- ZCJHFOLNXNSZJG-UHFFFAOYSA-N [Na].NS(O)(=O)=O Chemical compound [Na].NS(O)(=O)=O ZCJHFOLNXNSZJG-UHFFFAOYSA-N 0.000 claims description 6
- 238000010009 beating Methods 0.000 claims description 6
- 230000000975 bioactive effect Effects 0.000 claims description 6
- 238000012544 monitoring process Methods 0.000 claims description 6
- 238000005070 sampling Methods 0.000 claims description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 4
- 229910019093 NaOCl Inorganic materials 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 239000004471 Glycine Substances 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 claims description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 2
- 229960002317 succinimide Drugs 0.000 claims description 2
- 230000003115 biocidal effect Effects 0.000 abstract description 54
- 239000003139 biocide Substances 0.000 abstract description 51
- 230000000694 effects Effects 0.000 abstract description 12
- 239000000654 additive Substances 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 abstract description 3
- 229920001131 Pulp (paper) Polymers 0.000 abstract description 2
- 230000002411 adverse Effects 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 40
- 229910052757 nitrogen Inorganic materials 0.000 description 20
- 239000007800 oxidant agent Substances 0.000 description 19
- 230000001590 oxidative effect Effects 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 15
- 239000000463 material Substances 0.000 description 14
- 244000005700 microbiome Species 0.000 description 14
- 239000005864 Sulphur Substances 0.000 description 12
- 239000000975 dye Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 239000013505 freshwater Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000005457 optimization Methods 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- ZALMZWWJQXBYQA-UHFFFAOYSA-N [N].[Cl] Chemical compound [N].[Cl] ZALMZWWJQXBYQA-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000000813 microbial effect Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 2
- FSNCEEGOMTYXKY-JTQLQIEISA-N Lycoperodine 1 Natural products N1C2=CC=CC=C2C2=C1CN[C@H](C(=O)O)C2 FSNCEEGOMTYXKY-JTQLQIEISA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- YUMNNMSNSLHINV-UHFFFAOYSA-N chloro sulfamate Chemical compound NS(=O)(=O)OCl YUMNNMSNSLHINV-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000006081 fluorescent whitening agent Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 229950009390 symclosene Drugs 0.000 description 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
- ZKHQWZAMYRWXGA-KQYNXXCUSA-J ATP(4-) Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O)[C@@H](O)[C@H]1O ZKHQWZAMYRWXGA-KQYNXXCUSA-J 0.000 description 1
- ZKHQWZAMYRWXGA-UHFFFAOYSA-N Adenosine triphosphate Natural products C1=NC=2C(N)=NC=NC=2N1C1OC(COP(O)(=O)OP(O)(=O)OP(O)(O)=O)C(O)C1O ZKHQWZAMYRWXGA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010010071 Coma Diseases 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- TTWYZDPBDWHJOR-IDIVVRGQSA-L adenosine triphosphate disodium Chemical compound [Na+].[Na+].C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OP(O)(=O)OP([O-])([O-])=O)[C@@H](O)[C@H]1O TTWYZDPBDWHJOR-IDIVVRGQSA-L 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- -1 halide ion Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/11—Halides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paper (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention relates to improved biological control by using a chlorine-stabilizing agent mixture. The invention discloses a composition and an application method thereof. The composition comprises a halogen source, urea, an extra halogen stabilizing agent excluding urea and optional alkalis with concentrations enough to provide a pH value more than 10 for the composition, and does not comprise stable bromine compounds optionally. Besides, the invention discloses a method for reducing bioactivity in a process stream. Through the optimized mixing ratio of the halogen and the stabilizing agent and mixing ratio of ammonium salt and sulfamic acid or sulfamate, synergy appears, which not only improves the effect of the composition as a biocide but also avoids adverse effects on other chemicals (such as paper pulp and paper additives in the papermaking water flow) in the water flow.
Description
The cross reference of related application
Nothing.
About the research of federal funding or the statement of exploitation
Inapplicable.
Background technology
At least one invention relates to for reducing bioactive composition and method in process flow such as the aqueous process stream.Biologically active in the process flow has problems because of a variety of causes, includes but not limited to hygienic issues, process equipment efficiency and product quality problem.For example, in paper technology, operation has adverse effect to the high bioactivity level to equipment.Particular type paper such as problem that thin paper/the recycled writing paper goods are relevant are more remarkable with making, this is because high fungus levels shows the dilemma, and namely providing is enough to the stable biocide agent so that it is not easy the biocide that is consumed the biocide scheme of (good continuation) and adequate level is provided to resist the contradiction between the bioactive periodicity crest (continuation of the less stabilisation of needs/reduction).And, the bleaching of regenerated fiber/processing shows other dilemmas to papermaker, this is because papermaker is wanted the adding (this can eliminate halogen such as chlorine) of the sulphite after the balance regenerated fiber is bleached/processed and the needs of the chlorine in the keeping system, more specifically, keep the constant level of chlorine in the papermaking systems and do not add contradiction between the needs of more halogen/chlorine.Therefore, require further improvement biocide-stabilizer formula and delivering method, it can mode treatment system more effective and more environmental protection, and as using chlorine/halogen still less, this also further reduces the formation of halogen accessory substance.
At least one invention relates to is stablizing effective method and composition on the oxidant biocide.Oxidant biocide such as peroxidating acid and halogen chemical such as clorox have been widely used in paper pulp and the paper industry.These oxidant biocides in time kill on a large amount of microorganisms very efficient.Unfortunately, after they were introduced in the fresh water (FW) system, oxidant biocide itself was unstable, and they are easy to Quick Oxidation and lose in time their effectiveness.In the environment that contains very high population microorganism, as in the fresh water (FW) that is rich in the organic and inorganic material that microorganism can eat, a large amount of microorganisms can survives until the oxidant biocide is lost effectiveness.Therefore, unless there are a lot of residual biocides to exist, microbial population will recover rapidly after the oxidant biocide is processed.In some cases, the bacterial strain of halogen resistant is grown because of the single-oxidizer biocide that repeats to introduce.This can cause system to be subject to the impact of bacterial growth out of control.(referring to such as textbook: Disinfection, Sterilization, and Preservation, the 5th edition,
Seymour S.Block, Lippincott Williams ﹠amp; Wilkins, (2001) are at least at pp.31-57).
This problem since in many cases the repeated application of oxidant biocide be commercial infeasible fact and more complicated.Many oxidant biocides have disadvantageous side effect to other required additives of the commercial acceptable paper products of paper brightener, dyestuff and production.Repeat to add also corrodible many papermaking machines of oxidant biocide.
A kind of technology that is used for head it off is that stabilisation oxidant biocide makes it suppress the viability of microorganism in long-time section, weakens simultaneously the negative effect to gained paper and paper making equipment that the oxide biocide has.Such as United States Patent (USP) 3,328,294,3,749,672,3,170,883,5,565,109 and 7,651,622 is described, and previous trial on stabilisation oxidant biocide comprises uses sulfamic acid, salt-stabilized chlorine, monochloro amine, the halogen of DMH stabilisation, the AmBr-Cl of sulfamic acid
2Chlorine with the organic nitrogen stabilisation.Although stable a little, proved that these trials are the biocide than required more poor efficiency.The N-hydrogen source also has been used to stabilisation oxidant biocide, but they are also unsatisfactory, and this is because they are volatile and their dosage requires too strict.This stringency has hindered various flexibly molar ratios regulates, and this regulates the specific condition that often needs to adapt to its specific water system of processing.Therefore, to efficient, with other biocide compatible and on dosage and concentration variable higher stabilisation halogen biocide have and clearly need and practicality.
Another technical description of head it off is in U.S. publication application 2006/0231505A and 2003/0029812A1, and they disclose the application of biocide blend.More long-acting but the biocide of poor efficiency of the another kind that the oxidant halogen of initially killing in a large number organism is provided and provides long-acting microbial more to suppress is be provided this mixture.Unfortunately, many biocides itself are incompatible with other biocide, and use the excess investment that the multiple biocide of the various problems that have they self preparation and add need to be on complicated applications equipment.And multiple biocide dispenser is installed in along on each aspect of paper production line, has therefore greatly increased the complexity of cost and adding biocide.Therefore, need to simplify production biocide and put-on method.
Except as otherwise noted, the technology of this part description is not to admit that any patent, publication or out of Memory that this paper quotes are " prior aries " with respect to the present invention.In addition, this part should not be construed as other relevant information existence that is studied or does not have definition among the 37CFR § 1.56 (a).
Summary of the invention
At least one embodiment of the present invention relates to a kind of composition, and said composition comprises: halogen source, urea and do not comprise the extra halogen stabilizer of urea, concentration provides alkali greater than 10 pH for being enough to described composition alternatively.Alternatively, said composition does not comprise the bromine compounds of stabilisation.This stabilizing agent can comprise by one in following the composition: N-hydrogen compound, ammonia, ammonium salt, Amcide Ammate, ammonium sulfate, sulfamic acid, sulfamic acid sodium, cyanuric acid, succinimide, urea, glycoluril, glycine, amino acid and their any combination.Stabilizing agent can comprise at least two kinds of composition of matter that play separately the halogen stabilizer function.The group of the following at least a kind of composition of the optional freedom of halogen source: chlorine source, alkaline hypohalite, Cl
2Gas, NaOCl, Ca (OCl)
2Chlorine with the electricity generation.Said composition can comprise: alkaline hypohalite, urea and Amcide Ammate.Urea and extra halogen stabilizer can be 50: 50 ratio each other.
At least one embodiment of the present invention relates to a kind of for reducing bioactive method in the process flow, comprises composition is offered process flow.Described composition can following adding mode be added in the process flow: forming concentration and being is enough to keep pH in the final composition greater than 10 at least a alkali and the mixture of alkaline hypohalite, and mix subsequently described mixture and the second mixture that comprises urea and described extra stabilizing agent, the wherein said mixing subsequently finishes with the T-blender alternatively.Process flow can be paper technology stream.Paper technology is the technique that is selected from by the following group that forms: thin paper (tissue) and/or paper handkerchief (towel), cardboard (board); Packing; Making beating; And circulation beating.Process flow can comprise fungi.Process flow can have the sulfite concentration of 2ppm to 50ppm.The method can further be included in and add described composition before and afterwards, monitor the biologically active in the process flow.Biologically active can be by following monitoring: sampling and be coated onto described sample on culture dish or the similar devices or by measuring the ATP level from the sample of process flow from described process flow, or by from the sampling of described process flow and monitoring dissolved oxygen and alternatively described sample redox potential and alternatively by increase or reduce one or more amounts that add the chemicals the described process flow and respond, wherein said chemicals comprises described composition.The method can further comprise and adds the second composition to comprising halogen, urea and not comprising the described process flow of extra N-hydrogen compound.
At least one embodiment of the present invention relates to a kind of method that prevents growth of microorganism in the technique current.The method comprises composition is added to step in the technique current.Said composition comprises: the halogen stabilizer of the mixture of halogen source, the sulphur-containing substance that comprises arbitrary proportion and urea and/or ammonium sulfate, and optional alkali.Sulphur-containing substance comprises sulfamic acid or its salt of equal value.The molar ratio of sulfamic acid and halogen atom was greater than 2: 1 in the halogen source.
Sulphur-containing substance can further comprise the nitrogen stabilizing agent.The nitrogen stabilizing agent can be and is selected from a kind of in the group that is comprised of ammonium sulfate, sulfamic acid sodium and their any combination.The molar ratio of whole sulphur was greater than 2: 1 in halogen and the sulphur-containing substance.Alkali can be sodium hydroxide.Halogen can be chlorine, clorox, 1,3,5-TCCA (Trichloroisocyanuric acid) (TCCA), 1-bromo-3-chloro-5,5-dimethyl-2,4-imidazolidimedione (1-bromo-3-chloro-5,5-dimethyl-2,4-imidazolidedione, BCDMH) and 1,3-, two chloro-5,5-dimethyl 2,4-imidazolidimedione (1,3-dichloro-5,5-dimethyl-2,4-imidazolidedione, DCDMH).The method can further comprise the step that at first alkali is added sulfamic acid and add subsequently urea and/or sodium sulphate.
Described technique current can be rich in the food of microorganism so that single halogen oxidant biocide effectively the elimination of micro-organisms population but described composition can be eliminated.The technique current can be and are selected from a kind of in the group that is comprised of cooling tower current and paper technology current.The ratio of sulfamic acid or its salt and nitrogen stabilizing agent can pay close attention to biocidal efficacy and on the technique current in any ratio between the impact of contained chemical addition agent be optimized.The ratio of sulfamic acid or its salt and nitrogen stabilizing agent can paid close attention to biocidal efficacy and any ratio between the corrosion of the equipment in the technique current is being optimized.When being used in described composition in the paper technology, composition may not can reduce OBA and DYE additive to the efficient of the paper of explained hereafter thus.Described salt can be sulfamic acid sodium.
Other feature and advantage are described in this article and will be clearer from following embodiment.
Description of drawings
Specific descriptions of the present invention will be hereinafter by specifically describing, wherein with reference to the accompanying drawings:
Fig. 1 is the flow chart of a kind of method of explanation combination Biocidal composition composition.
Fig. 2 is the second flow chart of a kind of method of explanation combination Biocidal composition composition.
Fig. 3 is the 3rd flow chart of a kind of method of explanation combination Biocidal composition composition.
Fig. 4 is for showing the figure that shows the data that the present invention renders a service.
Embodiment
Provide to give a definition to determine how to explain term used among the application and particularly claim.Only organizing of these definition is restricted to any particular type in order to make things convenient for and to be not intended to any definition.
" alkali " refers to the composition as the material of the tincture performance function that changes pH.
" DYE " or " dyestuff " refers to be used in the paper industry to change one or more compositions of substrate optical property.Dyestuff often comprises chromophore and auxochrome, and has good affinity and have good compatibility with other additive in the paper industry with fiber.
" nitrogen stabilizing agent " refers to comprise the stabilizing agent of at least a nitrogen-atoms.
" OBA " refers to dyestuff or the pigment fluorescent whitening agent as the component of the coating formulation that is usually used in the paper substrate.Ultraviolet radiation-absorbing and with upper frequency in the visible spectrum (blueness) again with its emission, the outward appearance that therefore realized the dyestuff of white or pigment blast.
" pigment " refers to be used in the paper technology to change the solid material of substrate optical property.
" halogen source " refers to halogen atom itself or the halogen atom of being combined with the cation counter pair.
" halogen stabilizer " refers to halogen-containing material, its existence close to the material composition that plays the effect of oxidation biocide has increased described composition and has kept abundant chemical state to continue to play the time of biocide effect, and it includes but not limited to keep the material of the oxidability (or oxidability percent of loss of reduction Biocidal composition) of Biocidal composition.
" stabilizing agent " refers to increase the oxidation halide ion and keeps the time span of oxidability and can slowly discharge dissociated ion with the composition of the material of effective biocide in the liquid hold-up environment.
" substrate " refers to that the scraps of paper, paper precursor sheet, coma maybe can be converted into by paper technology any other cellulose family or the man-made fibre material of the scraps of paper.
The above-mentioned definition of describing in this application or description and dictionary or when inconsistent with reference to the implication commonly used described in the source of incorporating into (clear and definite or in secret), application and claim belong to and are interpreted as especially according to the application's definition or describe and make up, but not according to usual definition, dictionary definition or the definition incorporated into by reference.In view of above-mentioned, if in the time only understanding the term that is made up by dictionary, if term is by Kirk-Othmer Encyclopedia of Chemical Technology, 5th Edition, (2005), (Published by Wiley, John﹠amp; Sons, Inc.) define, how this definition will be controlled this term will be limited in the claims.
As mentioned above, the invention provides composition and use the method for described composition, it is by providing more efficient biocide should be used for reducing biologically active in the process flow.And then more effectively utilize biocide, as in system, increasing when needed the persistence of biocide, this can provide environmental benefit, spread all over process flow as comprising various types of microorganisms and the bacterium of Aquo System because technological operation person can resist with less biocide, wherein a kind of example of Aquo System is papermaking systems.
Described composition comprises following at least component: halogen, urea and the extra halogen stabilizer except urea.Stabilizing agent can mix with chlorine or bromine to produce gentle oxidant.The advantage of halogen stabilisation comprises that the growth of microorganism that the persistence of halogen residue thing increases to improve in the system that biomembrane or surface deposits neutralization have long residual time and high halogen needs controls.
Halogen-stabilisation also can be improved the compatibility that halogen and susceptibility processing additive comprise dyestuff, fluorescent whitening agent, polymer and corrosion control product.Yet, to have observed in some instances when halogen is mixed with stabilizing agent such as urea, it is too lasting that halogen becomes.Therefore, program possibly can't be controlled fungi and some bacterioids fully, comprises false flat born of the same parents Pseudomonas (sphingomonads) and spore forming bacteria.The stabilisation halogen of some forms is more volatile, and this has reduced the halogen residue of aqueous phase and has caused the vapor phase corrosion.
In at least one embodiment, alternatively, extra component is arranged: concentration is enough to provide the alkali greater than 10 pH.In at least one embodiment, this pH is greater than 12.In another embodiment, the scope of pH is 12 to about 13.5.Alkali can comprise one or more in the following chemicals: sodium hydroxide and potassium hydroxide.
Alternatively, extra component is arranged: do not comprise stable bromine compounds in the described composition.
For halogen, at least one embodiment, halogen is selected from lower at least one: chlorine source, alkaline hypohalite, Cl
2Gas is (as adding H before mixing
2O stream), NaOCl, Ca (OCl)
2Chlorine with the electricity generation.
In at least one embodiment, said composition comprises urea and the combination that comprises other stabilizing agent of Amcide Ammate, with the stable halogen that is used for BIOLOGICAL CONTROL.
In at least one embodiment, stabilizing agent is the N-hydrogen compound.
In at least one embodiment, the N-hydrogen compound is Amcide Ammate.
In at least one embodiment, the N-hydrogen compound does not comprise ammonium sulfate.
In at least one embodiment, composition comprises: alkaline hypohalite, urea and Amcide Ammate.
The ratio of urea and extra stabilizing agent can change according to the level of system condition such as fungi.For example, can consider chemical kinetics between following: (a) urea and halogen; (b) extra stabilizing agent and halogen; (c) mixture and the halogen of urea and extra stabilizing agent.
In at least one embodiment, the stabilizer blend (ratio) between urea and the extra stabilizing agent is 50: 50.
Also disclose for reducing bioactive method in the process flow, as be included in process flow in the water system.The method comprises: provide composition to process flow, wherein said composition comprises: halogen, urea and do not comprise the extra stabilizing agent of urea, concentration provides alkali greater than 10 pH for being enough to described composition alternatively; Described composition does not comprise the bromine compounds of stabilisation alternatively.
In at least one embodiment, described composition can following adding mode be added in the process flow: form concentration for being enough to provide pH greater than 10 at least a alkali and the mixture of alkaline hypohalite, and mix subsequently described mixture and the second mixture that comprises urea and described extra stabilizing agent, the wherein said mixing subsequently finishes with the T-blender alternatively.
In at least one embodiment, the method comprises: add the second composition to comprising halogen, urea and not comprising the described process flow of extra N-hydrogen compound.
For the order that adds component, in at least one embodiment, described composition can following adding mode be added in the process flow: forming concentration provides pH greater than 10 for being enough to, preferred 12 to 13.5 at least a alkali and the mixture of alkaline hypohalite, and mix subsequently described mixture and the second mixture that comprises urea and described extra stabilizing agent.Those skilled in the art can mix the first mixture and the second mixture such as device by various technology.
In at least one embodiment, the first mixture and the second mixture mix by the T blender.It will be appreciated by those skilled in the art that what is the T blender.
In at least one embodiment, those skilled in the art can utilize mixing chamber, and are disclosed a kind of such as No. the 7th, 550,060, the United States Patent (USP) of incorporating by reference this paper into, to carry out the blend step of chemicals.
Methodology of the present invention can be applicable to various process flow or water-based system or Aquo System or industrial class system or their combination.
In at least one embodiment, process flow is paper technology stream.
In at least one embodiment, paper technology is the technique that is selected from by the following group that forms: thin paper and/or paper handkerchief, cardboard; Packing; Making beating; And circulation beating.
In at least one embodiment, process flow comprises fungi.
In at least one embodiment, process flow can have the sulfite concentration of 2ppm to 50ppm.
Composition reduces bioactive effect and can measure by various analytical technologies and control program.
In at least one embodiment, process flow further is included in and adds described composition before and afterwards, monitor the described biologically active in the described process flow.
In at least one embodiment, biologically active is by placing culture dish or similar device to monitor from described process flow sampling and with described sample.
In at least one embodiment, biologically active is monitored from ATP (adenosine triphosphate) level of the sample of described process flow by mensuration.
In at least one embodiment, biologically active is by with the monitoring of getting off: the redox potential of sampling and monitoring dissolved oxygen and optional described sample and alternatively by increase or reduce one or more amounts that add the chemicals in the described process flow and respond from described process flow, wherein said chemicals comprises described composition.
Composition itself or can outside process flow, prepare or (original position) preparation in process flow for the treatment of the composition of process flow, or be their combination.
In at least one embodiment, provide to comprise halogen, halogen stabilizer and the composition of alkali alternatively, to suppress microbial growth in the papermaking environment.Stabilizing agent is the composition of sulfur-bearing.Sulphur-containing substance comprises sulfamic acid (or its salt of equal value such as sulfamic acid sodium).The mol ratio of halogen and sulfamic acid was greater than 2: 1.By having this kind vast scale of halogen and stabilizing agent, observed the unexpected biocidal effect of generation.Be very in surprise when halogen and sulfamic acid are 1: 1 mol ratio, observe without significant antibiont and render a service.And, because need stabilizing agent to stablize halogen, thus wish have more stabilizing agent will better stablize halogen with respect to halogen, however true on the contrary.
In at least one embodiment, stabilizing agent is the composition that comprises the mixture of sulphur-containing substance and urea.Halogen and sulfamic acid are with nitrogen and the cl molar ratio mixed in molar ratio greater than 2: 1.By having the stabilizer blend of this kind stabilisation halogen, observed unexpected synergy, this causes halogen to keep stablizing the long period and does not damage quality or the corrosion paper making equipment of the paper of producing.
In at least one embodiment, stabilizing agent is the composition that comprises the mixture of sulphur-containing substance and ammonium sulfate.
In at least one embodiment, sulphur-containing substance further comprises the nitrogen stabilizing agent.
In at least one embodiment, the nitrogen stabilizing agent can be and is selected from a kind of in the group that is comprised of ammonium sulfate, sulfamic acid sodium and their any combination.
In at least one embodiment, the molar ratio of whole sulphur was greater than 2: 1 in halogen and the sulphur-containing substance.
In at least one embodiment, alkali is sodium hydroxide.
In at least one embodiment, halogen is chlorine, clorox, 1,3,5-TCCA (Trichloroisocyanuric acid) (TCCA), 1-bromo-3-chloro-5,5-dimethyl-2,4-imidazolidimedione (BCDMH) and 1,3-two chloro-5,5-dimethyl 2,4-imidazolidimedione (DCDMH).
In at least one embodiment, sulfamic acid at first mixes and adds subsequently urea/sulphur acid ammonium with alkali.Clorox is added said mixture.
In at least one embodiment, the nitrogen of sulfur-bearing at first take nitrogen and chlorine than as being combined clorox greater than 2: 1 mol ratio, and be added to subsequently urea or ammonium sulfate.
In at least one embodiment, urea or ammonium sulfate is in conjunction with clorox, and is added in varing proportions subsequently the nitrogen of sulfur-bearing.Order is very important, because different stabilisation halogen species produces with different rates because of the different equilibrium constants.These differences are attributable to add halogen with difference amount and different order.In addition, chlorine can be converted into from the chlorine of stabilisation other nitrogen materials, so that the order of combination can compensate this.
In at least one embodiment, composition does not comprise buffer.
In at least one embodiment, composition does not comprise alkali.
In at least one embodiment, composition can by with these components with these components are mixed before halogen oxidant mixes on-the-spot preparation.
In at least one embodiment, composition can be by coming on-the-spot preparation such as any these components of described mixing among Fig. 1,2 and/or 3.
In at least one embodiment, the microorganism that killed by biocide is set.In at least one embodiment, the microorganism that is killed by biocide is take plankton as food.
Noticeable advantage of the present invention is that sulfamic acid and nitrogen stabilizing agent are easy to combination, so that when mixing two kinds of materials, realizes high products collection efficiency and some waste is only arranged.In addition, different from the single stable agent that contains the inorganic nitrogen stabilizing agent, the mixture of sulfamic acid and nitrogen stabilizing agent works under many different ratio content.Therefore, the relative amount of sulfamic acid or nitrogen stabilizing agent can be according to the corresponding increase of its specific environment that will be used for or minimizing.For example, can disturb at the nitrogen stabilizing agent in the situation of specific Paper additive such as OBA or DYE, will increase the relative amount of sulfamic acid.On the contrary, have at sulfamic acid in the situation of consistency problem, can increase the content of nitrogen stabilizing agent.
In at least one embodiment, the content of pharmaceutical formulation is directed to biological character of invading and harassing.For example, if bacterium has just begun to permeate one or more process equipments, use contains the preparation of relative equivalent sulfamic acid and nitrogen stabilizing agent, this is because optimization is to cause low impact and the low-level corrosion on additive, this is the effect of more expecting than efficient biocide when invasion is very slight.On the contrary, when polluting very serious or long-term clustered, the effect of biocide is more important on the impact of additive or corrosion than the time, therefore uses the preparation of the more sulfamic acid of molar content that contains relative nitrogen stabilizing agent.Therefore, by using the preparation only have two kinds of variablees, can provide a large amount of condition special ratios, this needs the simple input system can be in industrial equipment dynamic response different condition in the life-span.
In at least one embodiment, with composition as the biocide in the cooling tower.
In at least one embodiment, reduce the biomembrane on surface with composition.Biomembrane is the gathering of the fixing organism on the equipment surface.Because reduced the surface of the available exposure that biocide works, usually caused particular problem so this assembles.And, usually exist biocide effect and biocide on the compromise between the biomembranous impact, yet but the present invention has avoided the illeffects of process equipment has effectively neutralized biomembrane.
In at least one embodiment, process microorganism in the film system with composition.When microorganism finds that when possessing attractability, the film system is easy to the biomembrane clustered usually for their surface (because composition, shape or the two).A little less than because also be highly brittle with respect to the process equipment film system of other form, compromise problem roughly is in film even more important.Fortunately be that said composition is effectively processed the biomembrane of film and they are not damaged.In at least one embodiment, the film system is the porous film.In at least one embodiment, film is the part of water treatment system.
In at least one embodiment, before with composition adding system, said composition has specific pH.In at least one embodiment, pH is greater than 5 and less than 12, and most preferably between 8 and 10.
In at least one embodiment, the ratio of the content of balanced combination thing is with optimization composition efficient and practicality.In the prior art, to use chloro amido sulfonate with 1: 1 ratio of chlorine.This causes stronger than the combination of desirable chlorine, and therefore this has reduced the speed that discharges sulfamate from sulphate, reduces the efficient of composition with this.In at least one embodiment, ratio is different, so composition is more effective.In at least one embodiment, the ratio of sulfamate and stabilizing agent is (less than 4) in the composition: 1 and (greater than 1): between 1.Experimental data shown in some cases the ratio of 1: 1 and 4: 1 not exclusively work or act on poor, 8: 1 to 4: 1 ratio slightly work and 3: 1 very effective as biocide.This shows that not only the beyond thought synergy based on concentration works, and this is absolute novel and beyond thought.
Embodiment
Can understand better aforementioned content by reference following examples, the purpose of following examples is explanations, and is not intended to and limits the scope of the invention.
Prepare a large amount of biocide preparations and be applied to fresh water (FW) sample from the paper mill.Their composition and efficient are listed among Fig. 4 and the table 1.Table 1 has illustrated that the composition that contains 12% sulfamic acid and 3% ammonium sulfate can realize high products collection efficiency and need not add NaOH.It also illustrates NaOH is added the feasibility that can improve mixed stabilizer under different proportion in the bleaching agent.
The optimization that is used for the mixing condition of mixed stabilizer and clorox
*The SA sulfamic acid
*AS: ammonium sulfate
* *TRO: total residual oxidant
* * *FRO: free residual oxidant
Table 1
Fig. 4 illustrates that the ammonium sulfate of 12% sulfamic acid and 3% more has activity to other combinations that biologically active suppresses to demonstrate than stabilizing agent.
The not restriction of bound by theory and the scope that the structure claim is provided, believe that according to following balance equation chlorine back and forth is transferred to another kind of chlorine nitrogen material from a kind of chlorine nitrogen material in essence, and the present invention utilizes the different equilibrium constants with the existing of the required reaction of optimization, and this reaction produces effectively the chlorine nitrogen material as the special hope of biocide.
In at least one embodiment, the addition sequence of calibration composition is with the relative equilibrium speed of the various chemical reactions of optimum utilization.Every kind of chemical reaction occurs with different rates, so the Cl material is constant back and forth and at different time has different availabilitys between molecule.In at least one embodiment, will at first join composition for the required reagent of less reaction occurs, and it is reacted or complete reaction before adding the reagent required for faster response slightly.This is avoided faster response and more long response time competition.In at least one embodiment, after chloramines partially or completely formed, the reagent that only needs is made chloro amido sulfonate material and amine react to form chloramines and ammonia was added to composition.
In at least one embodiment, composition is diluted to produce the biocide effect of milder (and few that volatilize, reaction or destruction).In at least one embodiment, be applied in United States Patent (USP) 6,132, the method for disclosed dilution biocide in 628 and 7,067,063.In at least one embodiment, diluted composition, so material exists in the scope of 000ppm at 100ppm to 150.
Although the present invention can many multi-form enforcements, its demonstration is described in detail with the preferred embodiment for the present invention in the accompanying drawings and in this article.The disclosure is the illustration of background and the principle of the invention, is not the embodiment that will limit the invention to elaboration.Any and whole patent, patent application, scientific and technical article, books and other document that the application quotes by reference integral body incorporated into.In addition, some or all of any may the combinations that reaches the various embodiments that merge in the literary composition that illustrates in the literary composition contained in the present invention.
Below openly be used for illustrative and non exhaustive.This specification will be expressed many variations and alternative scheme to those of ordinary skills.All these change and alternative scheme all is included in the scope of claim, and wherein term " comprises " that expression " includes, but are not limited to ".Those people that are proficient in this area can confirm other equivalents of the embodiment that illustrates in the literary composition, and these equivalents also will be contained by claim.
Understand four corner disclosed herein and parameter and contain any or all of subrange that this paper comprises and the every number between the end points.For example, the described scope that should consider " 1 to 10 " comprises whole subranges of (and comprising 1 and 10) between minimum 1 and the peak 10; That is to say, from minimum 1 or larger (such as 1 to 6.1) beginning and whole subranges of finishing with maximum 10 or lower (such as 2.3 to 9.4,3 to 8,4 to 7), and final every number 1,2,3,4,5,6,7,8,9 and 10 is included in this scope.
This finished the present invention preferably with the explanation of alternate embodiment.Those skilled in the art can confirm other equivalents of the embodiment that illustrates in the literary composition, and these equivalents also will be contained by claims.
Claims (17)
1. composition comprises: halogen source, urea and do not comprise the extra halogen stabilizer of urea, concentration provides alkali greater than 10 pH for being enough to described composition alternatively; Described composition does not comprise the bromine compounds of stabilisation alternatively.
2. composition as claimed in claim 1, wherein said stabilizing agent comprises by one in following the composition: N-hydrogen compound, ammonia, ammonium salt, Amcide Ammate, ammonium sulfate, sulfamic acid, sulfamic acid sodium, cyanuric acid, succinimide, urea, glycoluril, glycine, amino acid and their any combination.
3. composition as claimed in claim 1, wherein said stabilizing agent comprises at least two kinds of composition of matter that play separately the halogen stabilizer function.
4. composition as claimed in claim 1, wherein said halogen source are selected from by following at least a kind of group that forms: chlorine source, alkaline hypohalite, Cl
2Gas, NaOCl, Ca (OCl)
2Chlorine with the electricity generation.
5. composition as claimed in claim 1, wherein said composition comprises: alkaline hypohalite, urea and Amcide Ammate.
6. composition as claimed in claim 1, wherein said urea and described extra halogen stabilizer are 50: 50 ratio each other.
7. one kind for reducing bioactive method in the process flow, comprises that the composition with claim 1 offers process flow.
8. method as claimed in claim 7, wherein said composition can following adding mode be added in the process flow: form concentration for being enough to provide or keeping pH in the final composition greater than 10 at least a alkali and the mixture of alkaline hypohalite, and mix subsequently described mixture and the second mixture that comprises urea and described extra stabilizing agent, the wherein said mixing subsequently finishes with the T-blender alternatively.
9. method as claimed in claim 8, wherein said process flow are paper technology stream.
10. method as claimed in claim 9, wherein said paper technology is the technique that is selected from by the following group that forms: thin paper and/or paper handkerchief, cardboard; Packing; Making beating; And circulation beating.
11. method as claimed in claim 9, wherein said process flow comprises fungi.
12. method as claimed in claim 9, wherein said process flow has the sulfite concentration of 2ppm to 50ppm.
13. method as claimed in claim 9 further is included in the described composition of adding before and afterwards, monitors the described biologically active in the described process flow.
14. method as claimed in claim 13, wherein said biologically active is by placing culture dish or similar device to monitor from described process flow sampling and with described sample.
15. method as claimed in claim 13, wherein said biologically active is monitored from the ATP level of the sample of described process flow by mensuration.
16. method as claimed in claim 13, wherein said biologically active is by with the monitoring of getting off: the redox potential of sampling and monitoring dissolved oxygen and optional described sample and alternatively by increase or reduce one or more amounts that add the chemicals in the described process flow and respond from described process flow, wherein said chemicals comprises described composition.
17. method as claimed in claim 9 further comprises: add the second composition to comprising halogen, urea and not comprising the described process flow of extra N-hydrogen compound.
Priority Applications (18)
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| CN201811424802.XA CN109303064A (en) | 2011-10-21 | 2011-10-21 | By using the improved BIOLOGICAL CONTROL of chloro- stabilizer blend |
| CN2011103285841A CN103053613A (en) | 2011-10-21 | 2011-10-21 | Improved biological control by using chlorine-stabilizing agent mixture |
| US13/289,547 US9161543B2 (en) | 2011-10-21 | 2011-11-04 | Biocontrol through the use of chlorine-stabilizer blends |
| US13/289,578 US9265259B2 (en) | 2011-10-21 | 2011-11-04 | Use of sulfamic acid or its salts as stabilizers especially in combination with ammonium salt and/or ammine for bleach or other halogen containing biocides in the paper area |
| TW101136772A TWI546262B (en) | 2011-10-21 | 2012-10-05 | Improved biological control via the use of a chlorine stabilizer blend |
| AU2012326500A AU2012326500B2 (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| ES12842036.1T ES2635119T3 (en) | 2011-10-21 | 2012-10-12 | Enhanced biocontrol through the use of bleach stabilizer combinations |
| NZ620835A NZ620835B2 (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| MYPI2014001112A MY185106A (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| CA2844833A CA2844833C (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| JP2014537126A JP6110392B2 (en) | 2011-10-21 | 2012-10-12 | Improvement of ecological control by using chlorine stabilizer mixture |
| KR1020147007838A KR102095212B1 (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| PH1/2014/500293A PH12014500293B1 (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| BR112014007142-0A BR112014007142B1 (en) | 2011-10-21 | 2012-10-12 | COMPOSITION AND METHOD FOR REDUCING BIOLOGICAL ACTIVITY IN A PROCESS CURRENT |
| PCT/US2012/059846 WO2013059074A1 (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| EP12842036.1A EP2768538B1 (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| PL12842036T PL2768538T3 (en) | 2011-10-21 | 2012-10-12 | Improved biocontrol through the use of chlorine-stabilizer blends |
| ARP120103878A AR088373A1 (en) | 2011-10-21 | 2012-10-18 | BIOCONTROL IMPROVED THROUGH THE USE OF CHLORINE STABILIZING BLENDS |
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| CN2011103285841A CN103053613A (en) | 2011-10-21 | 2011-10-21 | Improved biological control by using chlorine-stabilizing agent mixture |
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Also Published As
| Publication number | Publication date |
|---|---|
| TW201323349A (en) | 2013-06-16 |
| EP2768538A1 (en) | 2014-08-27 |
| ES2635119T3 (en) | 2017-10-02 |
| JP6110392B2 (en) | 2017-04-05 |
| CA2844833A1 (en) | 2013-04-25 |
| JP2015501307A (en) | 2015-01-15 |
| AU2012326500A1 (en) | 2014-02-27 |
| CA2844833C (en) | 2019-06-18 |
| EP2768538A4 (en) | 2015-05-20 |
| KR20140079767A (en) | 2014-06-27 |
| PH12014500293B1 (en) | 2019-02-20 |
| NZ620835A (en) | 2015-07-31 |
| PH12014500293A1 (en) | 2014-03-24 |
| WO2013059074A1 (en) | 2013-04-25 |
| BR112014007142A2 (en) | 2017-04-04 |
| TWI546262B (en) | 2016-08-21 |
| EP2768538B1 (en) | 2017-05-17 |
| KR102095212B1 (en) | 2020-03-31 |
| AR088373A1 (en) | 2014-05-28 |
| PL2768538T3 (en) | 2017-10-31 |
| BR112014007142B1 (en) | 2019-08-06 |
| MY185106A (en) | 2021-04-30 |
| AU2012326500B2 (en) | 2015-09-10 |
| CN109303064A (en) | 2019-02-05 |
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Inventor after: Rice Laura E. Inventor after: Cooper Andrew J. Inventor after: Luth Elisa M. Inventor after: Tu Wenli Inventor before: Rice Laura E. Inventor before: Cooper Andrew J. Inventor before: Luth Elisa M. Inventor before: Wen Litu |
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Free format text: CORRECT: INVENTOR; FROM: RICE LAURA E. COOPER ANDREW J. LUTH ELISA M. WEN LITU TO: RICE LAURA E. COOPER ANDREW J. LUTH ELISA M. TU WENLI |
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Application publication date: 20130424 |