CN103031034A - White finish coat photocurable UV (ultraviolet) paint and preparation method thereof - Google Patents
White finish coat photocurable UV (ultraviolet) paint and preparation method thereof Download PDFInfo
- Publication number
- CN103031034A CN103031034A CN2012105352915A CN201210535291A CN103031034A CN 103031034 A CN103031034 A CN 103031034A CN 2012105352915 A CN2012105352915 A CN 2012105352915A CN 201210535291 A CN201210535291 A CN 201210535291A CN 103031034 A CN103031034 A CN 103031034A
- Authority
- CN
- China
- Prior art keywords
- finish paint
- white finish
- optical curing
- polyurethane
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229920002635 polyurethane Polymers 0.000 claims abstract description 42
- 239000004814 polyurethane Substances 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- YFPJFKYCVYXDJK-UHFFFAOYSA-N Diphenylphosphine oxide Chemical compound C=1C=CC=CC=1[P+](=O)C1=CC=CC=C1 YFPJFKYCVYXDJK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 9
- QCCDLTOVEPVEJK-UHFFFAOYSA-N phenylacetone Chemical compound CC(=O)CC1=CC=CC=C1 QCCDLTOVEPVEJK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 35
- 239000011248 coating agent Substances 0.000 claims description 33
- 238000000576 coating method Methods 0.000 claims description 33
- 239000004922 lacquer Substances 0.000 claims description 28
- 230000003287 optical effect Effects 0.000 claims description 24
- 125000001931 aliphatic group Chemical group 0.000 claims description 22
- 238000013019 agitation Methods 0.000 claims description 19
- -1 polysiloxane Polymers 0.000 claims description 19
- 239000004408 titanium dioxide Substances 0.000 claims description 19
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 18
- 229920001296 polysiloxane Polymers 0.000 claims description 18
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 17
- 229920000570 polyether Polymers 0.000 claims description 17
- RDLGTRBJUAWSAF-UHFFFAOYSA-N 1-(6-hydroxy-6-methylcyclohexa-2,4-dien-1-yl)propan-2-one Chemical compound CC(=O)CC1C=CC=CC1(C)O RDLGTRBJUAWSAF-UHFFFAOYSA-N 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 16
- 239000003822 epoxy resin Substances 0.000 claims description 16
- 229920000647 polyepoxide Polymers 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 229920005749 polyurethane resin Polymers 0.000 claims description 9
- 239000004576 sand Substances 0.000 claims description 9
- 238000003801 milling Methods 0.000 claims description 7
- 125000000524 functional group Chemical group 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 claims 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 229940042596 viscoat Drugs 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- 235000010215 titanium dioxide Nutrition 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 16
- 238000000016 photochemical curing Methods 0.000 description 13
- 239000002904 solvent Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical class C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 230000001376 precipitating effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 241001122767 Theaceae Species 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000052 vinegar Substances 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- TXTCTCUXLQYGLA-UHFFFAOYSA-L calcium;prop-2-enoate Chemical compound [Ca+2].[O-]C(=O)C=C.[O-]C(=O)C=C TXTCTCUXLQYGLA-UHFFFAOYSA-L 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- ASUOLLHGALPRFK-UHFFFAOYSA-N phenylphosphonoylbenzene Chemical class C=1C=CC=CC=1P(=O)C1=CC=CC=C1 ASUOLLHGALPRFK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention belongs to the field of chemical industry, and particularly discloses white finish coat photocurable UV (ultraviolet) paint and a preparation method thereof. The photocurable UV paint comprises the following components in percentage by weight: 20-60% of epoxy acrylate, 20-60% of polyurethane acrylate, 2-5% of phenyl acetone photoinitiator, 0.2-1% of diphenyl phosphine oxide photoinitiator, 0.2-1% of dispersant, 0.2-1% of leveling agent, 1-40% of titanium white TiO2, 5-15% of two-functional-group reactive diluent and 5-30% of three-functional-group reactive diluent. The paint has the characteristics of favorable gloss, adhesive force and leveling property, thus ensuring that the white UV paint can be better applied.
Description
Technical field
The present invention relates to chemical technology field, more particularly, the present invention relates to white finish paint optical curing of UV coating and preparation method thereof.
Background technology
The optical curing of UV coating products is applicable to multiple substrate surface: paper, woodenware, stone material, leather, pottery, metal, glass, plastics, concrete etc., and especially applicable to some thermo-responsive materials especially.Photocuring technology is the surface treatment technology of material of a kind of efficient, environment, energy-conservation, high-quality, it is to utilize UV-light to cause to have chemically reactive liquid material rapid polymerization crosslinked, instantaneous solidification becomes solid material, therefore it does not contain volatile solvent (VOC) substantially, can not cause atmospheric pollution and to the harm of human body and the danger of fire.Photocuring only needs the radiating capacity for light trigger, and also will evaporate solvent or the water of removing dilution usefulness unlike thermofixation or volatile paint, expends large energy, saved space that work in-process stack and enhanced productivity and save the waste resource.A kind of UV curing glass plated film coating is disclosed such as Chinese patent CN201110047998.7, comprise priming paint and finish paint, described priming paint comprises epoxy acrylate resin, Gao Guanneng reunion chlorinated polyethylene, high monomer, simple function group monomer, thermoplastic acrylic resin, light trigger 184, silicone based leveling auxiliary agent, amido organosilane multipolymer and organic solvent; Described finish paint comprises: hexafunctional aliphatic urethane acrylates resin, phenol aldehyde modified epoxy acrylate, thermoplastic acrylic resin, trifunctional monomer, light trigger 184, silicone based leveling auxiliary agent, amido organosilane multipolymer and organic solvent.But still there are the problems such as gloss is low, levelling is poor, sticking power is bad in this coating.
Summary of the invention
For above-mentioned technical problem, technical problem solved by the invention provide a kind ofly have high gloss, snappiness is good, hardness is strong, the white finish paint optical curing of UV coating of strong adhesion.
For solving the problems of the technologies described above, technical scheme of the present invention is achieved in that a kind of white finish paint optical curing of UV coating, be by weight percentage: epoxy acrylate 20%～60 ﹪, polyurethane acroleic acid fat 20%～60 ﹪, phenyl-acetone light trigger 2%～5 ﹪, basic phosphine oxide photoinitiator 0.2%～1 ﹪, dispersion agent 0.2%～1 ﹪, flow agent 0.2%～1 ﹪, titanium dioxide TiO2 1%～40,2 functional group's reactive thinners, 5%～15 ﹪, 3 functional group's reactive thinners, 5%～30 ﹪, the kind of the component of above-mentioned each material is 100%.
Further: in above-mentioned white finish paint optical curing of UV coating, preferred weight percent is amine-modified epoxy resin 33%～37%, aliphatic polyurethane resin 23%～27%, 2-hydroxy-2-methyl-phenyl-acetone light trigger 2.3%～2.7%, diphenyl phosphine oxide light trigger 0.3%～0.7%, modified polyurethane high polymer dispersant 0.5%～0.7%, polysiloxane polyether copolymer flow agent 0.3%～0.5%, titanium dioxide TiO
2Titanium dioxide 8%～12%, 1,6 hexanediol diacrylate reactive thinner 11%～13%, Viscoat 295 reactive thinner 13%～15%, the kind of the component of above-mentioned each material are 100%.
Further again: in above-mentioned white finish paint optical curing of UV coating, described epoxy acrylate is the epoxy acrylate of primary amine or secondary amine modification, functionality is 3, molecular weight is 40,000～60,000, the viscosity under 25 ° is 30000-50000 mPa.s, preferably peaceful 3660, the cyanogen spy 2200 of section, Sartomer CN2100.Described polyurethane acroleic acid fat is the naphthenic hydrocarbon aliphatic polyurethane resin, and functionality is 6, molecular weight is 40,000～100,000, and the viscosity under 25 ° is 30000 ± mPa.s, and preferably Changxing is 6145-100, Bayer VA2959, BASF UA9030V.Described light trigger is that 2-hydroxy-2-methyl-phenyl-acetone, molecular weight are 250～450, and preferably vapour clings at least a in the 2959 light trigger diphenyl phosphine oxides, preferred Sartomer 819.Described dispersion agent is the modified polyurethane superpolymer, and preferably EFKA 4010, the modest DP983 of DS, enlightening are high by 168.Described flow agent is polysiloxane polyether copolymer.Modest 432, the BYK371 of high by 440, the DS of enlightening preferably.Described reactive thinner is 1,6 hexanediol diacrylate, Viscoat 295, functionality 2～3, preferably Changxing HDDA and TMPTA, loose tail HDDA and TMPTA.Among the present invention in each the code name of material all be that producer is to the concrete code name of related products or the code name of commercially available prod.
The present invention also provides the preparation method of above-mentioned 8 white finish paint optical curing of UV coating, and its preparation process is followed successively by,
A, the amine-modified epoxy resin of getting 38 ﹪～42 ﹪ join in the system lacquer cylinder with aliphatic polyurethane, drop into the modified polyurethane high polymer dispersant under the condition that stirs, and stir;
B, in the mixture of steps A, add titanium dioxide, after stirring, through the shredder sand milling, to the mixture of fineness at 10～15 microns;
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, the polysiloxane polyether copolymer flow agent put in the system lacquer cylinder, after stirring, detect packing again.
Compared with prior art, white finish paint optical curing of UV coating of the present invention selects a kind ofly have polymer or amine modified epoxy, polyethers, urethane, polyester acrylic resin etc. to do main film forming oligopolymer, and it shows good hardness, snappiness, high gloss, anti-xanthochromia, chemical resistant properties etc. simultaneously; Select that oil number is little, transparency good, anti-settling performance is good, good dispersity, titanium dioxide that whiteness is good, can play like that brighten, the effect of dilatation, reduction cost.Select polyacrylate, silicone resin, fluorocarbon resin etc. to make levelling property, improve the wettability to base material, change the smooth planarization of filming, do not affect recoatability.Select high molecular polymer, contain acidic-group multipolymer, polyacrylate etc., they can be fine compatible with paint binder, in dispersion and process of lapping, and the caking of can again not reuniting.The production dispersing technology of selecting sand mill to grind, make dispersion after the fineness of UV coating accomplish 10～15 microns, just avoid the ill effects such as particle, lustre lacking uniformity, shrinkage cavity, tangerine peel in filming like that.White finish paint optical curing of UV coating of the present invention is by in Polyurethane CALCIUM ACRYLATE and the epoxy acrylate molecule ammoniacum key being arranged, can between macromolecular chain, form multiple hydrogen bond, main chain is saturated alkane and naphthenic hydrocarbon, it is with polyisocyanates, long chain diol and crylic acid hydroxy ester two-step reaction, the hydroxyl of side chain is conducive to adhering to of polar substrates simultaneously, also favourable pigment is wetting, makes the photocuring film forming have high gloss, sticking power, is difficult for xanthochromia, the excellent physicalies such as snappiness, hardness, levelling property.Among the preparation method of the present invention, its production efficiency is high, energy consumption is low and the uv equipment investment is relatively low, easily realizes streamline production; Save great amount of investment, reduce pollute, saving resource, the white UV coating of producing with the method can have and better is used in various base materials top layer and forms the physics protective membrane.
Embodiment
Below in conjunction with embodiment content of the present invention is described in further detail.
Embodiment 1
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 40%
Aliphatic polyurethane resin (photocuring): 20%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2.5%
Diphenyl phosphine oxide (light trigger): 0.5%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
According to the examination criteria of national standard " indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009) ", performance test is as described in Table 1:
Table 1
1: after drawing hundred lattice, do not come off with 3 hours paint films of (100 ℃) poach, good sticking power is arranged
2: paint film can demixing phenomenon not reduce the polishing time by fine recoat yet
3: the bad sample at the bottom of fine opacifying power reduces the sand leakage is like that arranged
4: paint film has high gloss, opacifying power, levelling, hardness, sticking power, pliable and tough texts
5: fineness will be ground to 10UM can reduce particle point and lustre lacking uniformity phenomenon like that, to precipitating, store, transport, have more stability
Embodiment 2
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 35%
Aliphatic polyurethane resin (photocuring): 25%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2.5%
Diphenyl phosphine oxide (light trigger): 0.5%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance test such as table 2: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 2
1: minimizing amine modified epoxy 5 ﹪ add in the 5 ﹪ aliphatic polyurethanes and can provide better snappiness, gloss.
2: some are wanted snappiness, can be suitable for the base material of the high paint film of folding endurance
3: to precipitating, store, transport, have more stability
Embodiment 3
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 28%
Aliphatic polyurethane resin (photocuring): 32%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2.5%
Diphenyl phosphine oxide (light trigger): 0.5%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance test is as shown in table 3: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 3
| Test event | Test result |
| Grindometer (hand is scraped) 〉=15/um | 10 (UM) are without crystalline polamer |
| Non-volatile part of % (105 ± 2 ℃ of 1h) | 1MG |
| Package stability [(50 ± 2) ℃, 7d] | Not rotten |
| Glossometer (60 °) 〉=1 | 97° |
| Hardness (scratch) | 3H |
| Pliable and tough (bending) 15 mm | 1-2mm |
| Sticking power (drawing hundred lattice) 〉=1 | 〉=0 grade |
| Opacifying power (hand stripping) | Lose the black and white lattice |
| Hot water resistance (100 ℃) | (poach 3 hours) is without unusual |
| Alkali resistance (50g/L, NaHCO 3） | Without unusual |
| Alcohol resistance (50%, 1h) | Without unusual |
| Anti-vinegar (1h) | Without unusual |
| Anti-green tea (1h) | Without unusual |
| Dry heat resistance [(70 ± 2) ℃, 15min] | Without unusual |
1: snappiness, sticking power, levelling property, hardness texts can improve, and anti-xanthochromia can be than adding the not good enough of amine modified epoxy
2: to precipitating, store, transport, have more stability
Embodiment 4
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 26%
Aliphatic polyurethane resin (photocuring): 34%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2%
Diphenyl phosphine oxide (light trigger): 0.3%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12.7%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, get 40 ﹪ amine-modified epoxy resins and join in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance is following as shown in table 4: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 4
| Test event | Test result |
| Grindometer (hand is scraped) 〉=15/um | 10 (UM) are without crystalline polamer |
| Non-volatile part of % (105 ± 2 ℃ of 1h) | ≥1MG |
| Package stability [(50 ± 2) ℃, 7d] | Not rotten |
| Glossometer (60 °) 〉=1 | 97° |
| Sclerometer (scratch) | 3H |
| Pliable and tough meter (bending) 15mm | 1mm |
| Sticking power (drawing hundred lattice) | 〉=0 grade |
| Opacifying power (hand stripping) | Lose the black and white lattice |
| Hot water resistance (100 ℃) | (poach 3 hours) is without unusual |
| Alkali resistance (50g/L, NaHCO 3） | Without unusual |
| Alcohol resistance (50%, 1h) | Without unusual |
| Anti-vinegar (1h) | Without unusual |
| Anti-green tea (1h) | Without unusual |
| Dry heat resistance [(70 ± 2) ℃, 15min] | Without unusual |
1: curing speed can improve the use that can reduce light trigger can reduce cost
2: paint film has better snappiness, sticking power, levelling property, hardness, opacifying power texts
3: to precipitating, store, transport, have more stability
Embodiment 5
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 20%
Aliphatic polyurethane resin (photocuring): 40%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2%
Diphenyl phosphine oxide (light trigger): 0.3%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12.7%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir;
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns;
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir;
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance test is as shown in table 5: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 5
| Test event | Test result |
| Grindometer (hand is scraped) 〉=15/um | 10 (UM) are without crystalline polamer |
| Non-volatile part of % (105 ± 2 ℃ of 1h) | ≥1MG |
| Package stability [(50 ± 2) ℃, 7d] | Not rotten |
| Glossometer (60 °) 〉=1 | 98° |
| Hardness (scratch) HB | 3H |
| Pliable and tough (bending) 15mm | 1mm |
| Sticking power (drawing hundred lattice) 〉=5 | 〉=0 grade |
| Opacifying power (hand stripping) | Lose the black and white lattice |
| Hot water resistance (100 ℃) | (poach 3 hours) is without unusual |
| Alkali resistance (50g/L, NaHCO 3） | Without unusual |
| Alcohol resistance (50%, 1h) | Without unusual |
| Anti-vinegar (1h) | Without unusual |
| Anti-green tea (1h) | Without unusual |
| Dry heat resistance [(70 ± 2) ℃, 15min] | Without unusual |
There are change, its stability of resin not have unusual variation, still provide the physical and chemical performances such as high gloss, sticking power, opacifying power, levelling property, hardness in the above example; the above is that institute obtains in experiment and the practice; do not contain volatility and harmful material that waits, be meet national environmental protection, European standard, be that country advocates efficiently, environmental protection, energy-conservation, high-quality coating.
Claims (9)
1. white finish paint optical curing of UV coating is: epoxy acrylate 20%～60 ﹪, polyurethane acroleic acid fat 20%～60 ﹪, phenyl-acetone light trigger 2%～5 ﹪, basic phosphine oxide photoinitiator 0.2%～1 ﹪, dispersion agent 0.2%～1 ﹪, flow agent 0.2%～1 ﹪, titanium dioxide TiO by weight percentage
21%～40%, 2 functional group's reactive thinners, 5%～15 ﹪, 3 functional group's reactive thinners, 5%～30 ﹪, the kind of the component of above-mentioned each material is 100%.
2. white finish paint optical curing of UV coating according to claim 1, it is characterized in that: preferred weight percent is amine-modified epoxy resin 33%～37%, aliphatic polyurethane resin 23%～27%, 2-hydroxy-2-methyl-phenyl-acetone light trigger 2.3%～2.7%, diphenyl phosphine oxide light trigger 0.3%～0.7%, modified polyurethane high polymer dispersant 0.5%～0.7%, polysiloxane polyether copolymer flow agent 0.3%～0.5%, titanium dioxide TiO
2Titanium dioxide 8%～12%, 1,6 hexanediol diacrylate reactive thinner 11%～13%, Viscoat 295 reactive thinner 13%～15%, the kind of the component of above-mentioned each material are 100%.
3. white finish paint optical curing of UV coating according to claim 2, it is characterized in that: described epoxy acrylate is the epoxy acrylate of primary amine or secondary amine modification, and functionality is 3, molecular weight is 40,000～60,000, the viscosity under 25 ° is 30000-50000 mPa.s.
4. white finish paint optical curing of UV coating according to claim 3, it is characterized in that: described polyurethane acroleic acid fat is the naphthenic hydrocarbon aliphatic polyurethane resin, functionality is 6, molecular weight is 40,000～100,000, the viscosity under 25 ° is 30000 ± mPa.s.
5. white finish paint optical curing of UV coating according to claim 4, it is characterized in that: described phenyl-acetone light trigger is that 2-hydroxy-2-methyl-phenyl-acetone, molecular weight are 250～450; Described basic phosphine oxide photoinitiator is at least a in the diphenyl phosphine oxide.
6. white finish paint optical curing of UV coating according to claim 5, it is characterized in that: described dispersion agent is the modified polyurethane superpolymer.
7. white finish paint optical curing of UV coating according to claim 6, it is characterized in that: described flow agent is polysiloxane polyether copolymer.
8. white finish paint optical curing of UV coating according to claim 7, it is characterized in that: described 2 functional group's reactive thinners are 1,6 hexanediol diacrylates; Described 3 functional group's reactive thinners are Viscoat 295s.
9. method for preparing the described white finish paint optical curing of UV coating of any one among the claim 1-7, it is characterized in that: preparation process is followed successively by,
A, the amine-modified epoxy resin of getting 38 ﹪～42 ﹪ join in the system lacquer cylinder with aliphatic polyurethane, drop into the modified polyurethane high polymer dispersant under the condition that stirs, and stir;
B, in the mixture of steps A, add titanium dioxide, after stirring, through the shredder sand milling, to the mixture of fineness at 10～15 microns;
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir;
D, under agitation condition, the polysiloxane polyether copolymer flow agent put in the system lacquer cylinder, after stirring, detect packing again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210535291.5A CN103031034B (en) | 2012-12-12 | 2012-12-12 | A kind of white finish paint optical curing of UV coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210535291.5A CN103031034B (en) | 2012-12-12 | 2012-12-12 | A kind of white finish paint optical curing of UV coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103031034A true CN103031034A (en) | 2013-04-10 |
| CN103031034B CN103031034B (en) | 2016-07-06 |
Family
ID=48018453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210535291.5A Active CN103031034B (en) | 2012-12-12 | 2012-12-12 | A kind of white finish paint optical curing of UV coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103031034B (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589323A (en) * | 2013-10-24 | 2014-02-19 | 惠州市长润发涂料有限公司 | Anti-yellowing UV woodware varnish |
| CN103602224A (en) * | 2013-11-20 | 2014-02-26 | 广东美涂士建材股份有限公司 | White solvent-free finish paint as well as preparation method and construction process of white solvent-free finish paint |
| CN103709906A (en) * | 2014-01-15 | 2014-04-09 | 东周化学工业（昆山）有限公司 | White ultraviolet curing finishing coat |
| CN104028441A (en) * | 2014-05-30 | 2014-09-10 | 东莞劲胜精密组件股份有限公司 | Method for manufacturing surface of shell of product |
| CN104151896A (en) * | 2014-08-28 | 2014-11-19 | 苏州洛特兰新材料科技有限公司 | Radiation curing epoxy resin powder coating used for ceramic |
| CN104177889A (en) * | 2014-09-09 | 2014-12-03 | 苏州圣谱拉新材料科技有限公司 | Ultraviolet-curable epoxy acrylate coating for ceramic |
| CN104804620A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | A weather-resistant UV curing coating |
| CN105925149A (en) * | 2016-07-05 | 2016-09-07 | 苏州镓祥新材料科技有限公司 | UV digital printing based surface photocuring coating for treating metal material for sheet-metal working |
| CN106116179A (en) * | 2016-06-16 | 2016-11-16 | 杭州福斯特光伏材料股份有限公司 | A kind of cured film protecting photovoltaic glass antireflection layer |
| CN106243991A (en) * | 2016-08-31 | 2016-12-21 | 广东希贵光固化材料有限公司 | A kind of UV solidification repair paint and method for repairing and mending thereof |
| CN106752252A (en) * | 2017-02-10 | 2017-05-31 | 湖南容佳新材料技术有限公司 | A kind of LED UV Wood putties and preparation method thereof |
| CN108299886A (en) * | 2016-08-10 | 2018-07-20 | 上海长悦涂料有限公司 | A kind of solvent-free UV spray paints coating and preparation method thereof |
| CN108299924A (en) * | 2017-08-13 | 2018-07-20 | 安徽康瑞高科新材料技术工程有限公司 | A kind of white paint and preparation method thereof brightened |
| CN109355003A (en) * | 2018-09-17 | 2019-02-19 | 东莞星晖真空镀膜塑胶制品有限公司 | A kind of hardware bottle cap product surface treatment process |
| CN109444137A (en) * | 2018-11-11 | 2019-03-08 | 廊坊立邦涂料有限公司 | A kind of detection method of coating black and white lattice covering power |
| CN110054977A (en) * | 2019-05-21 | 2019-07-26 | 临沂优彩新能源环保科技有限公司 | A kind of UV woodenware printing coating and its preparation process |
| CN111073478A (en) * | 2019-12-31 | 2020-04-28 | 海聚高分子材料科技（广州）有限公司 | High-covering-rate finish UV coating and preparation method thereof |
| CN111471375A (en) * | 2020-04-30 | 2020-07-31 | 上海展辰涂料有限公司 | Anti-scratch photocuring odorless matte white finish |
| CN111690310A (en) * | 2020-06-19 | 2020-09-22 | 广东立邦长润发科技材料有限公司 | UV white primer for spraying mechanical arm and preparation method thereof |
| CN112898894A (en) * | 2021-01-19 | 2021-06-04 | 广东美涂士建材股份有限公司 | LED (light-emitting diode) cured high-gloss finish paint |
| CN117285865A (en) * | 2023-07-28 | 2023-12-26 | 武汉理工大学 | Photo-cured coating for concrete reinforced protection and preparation method of photo-cured coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
| CN102002315A (en) * | 2009-09-03 | 2011-04-06 | 澳达树熊涂料(惠州)有限公司 | Oily UV white light surface wood lacquer |
| CN102942822A (en) * | 2012-10-30 | 2013-02-27 | 广东壮丽彩印股份有限公司 | Antimicrobial UV curing printing ink and preparation method thereof |
-
2012
- 2012-12-12 CN CN201210535291.5A patent/CN103031034B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
| CN102002315A (en) * | 2009-09-03 | 2011-04-06 | 澳达树熊涂料(惠州)有限公司 | Oily UV white light surface wood lacquer |
| CN102942822A (en) * | 2012-10-30 | 2013-02-27 | 广东壮丽彩印股份有限公司 | Antimicrobial UV curing printing ink and preparation method thereof |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589323B (en) * | 2013-10-24 | 2016-03-30 | 惠州市长润发涂料有限公司 | A kind of color inhibition UV woodenware lacquer |
| CN103589323A (en) * | 2013-10-24 | 2014-02-19 | 惠州市长润发涂料有限公司 | Anti-yellowing UV woodware varnish |
| CN103602224A (en) * | 2013-11-20 | 2014-02-26 | 广东美涂士建材股份有限公司 | White solvent-free finish paint as well as preparation method and construction process of white solvent-free finish paint |
| CN103709906A (en) * | 2014-01-15 | 2014-04-09 | 东周化学工业（昆山）有限公司 | White ultraviolet curing finishing coat |
| CN103709906B (en) * | 2014-01-15 | 2016-08-24 | 东周化学工业（昆山）有限公司 | Ultraviolet light polymerization white finish paint |
| CN104028441A (en) * | 2014-05-30 | 2014-09-10 | 东莞劲胜精密组件股份有限公司 | Method for manufacturing surface of shell of product |
| CN104028441B (en) * | 2014-05-30 | 2015-06-17 | 东莞劲胜精密组件股份有限公司 | Method for manufacturing surface of shell of product |
| CN104151896A (en) * | 2014-08-28 | 2014-11-19 | 苏州洛特兰新材料科技有限公司 | Radiation curing epoxy resin powder coating used for ceramic |
| CN104177889A (en) * | 2014-09-09 | 2014-12-03 | 苏州圣谱拉新材料科技有限公司 | Ultraviolet-curable epoxy acrylate coating for ceramic |
| CN104177889B (en) * | 2014-09-09 | 2016-08-24 | 苏州圣谱拉新材料科技有限公司 | A UV-curable epoxy acrylate coating for ceramics |
| CN104804620A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | A weather-resistant UV curing coating |
| CN106116179A (en) * | 2016-06-16 | 2016-11-16 | 杭州福斯特光伏材料股份有限公司 | A kind of cured film protecting photovoltaic glass antireflection layer |
| CN106116179B (en) * | 2016-06-16 | 2019-01-22 | 杭州福斯特应用材料股份有限公司 | A kind of cured film for protecting photovoltaic glass antireflection layer |
| CN105925149A (en) * | 2016-07-05 | 2016-09-07 | 苏州镓祥新材料科技有限公司 | UV digital printing based surface photocuring coating for treating metal material for sheet-metal working |
| CN108299886A (en) * | 2016-08-10 | 2018-07-20 | 上海长悦涂料有限公司 | A kind of solvent-free UV spray paints coating and preparation method thereof |
| CN106243991A (en) * | 2016-08-31 | 2016-12-21 | 广东希贵光固化材料有限公司 | A kind of UV solidification repair paint and method for repairing and mending thereof |
| CN106752252A (en) * | 2017-02-10 | 2017-05-31 | 湖南容佳新材料技术有限公司 | A kind of LED UV Wood putties and preparation method thereof |
| CN108299924A (en) * | 2017-08-13 | 2018-07-20 | 安徽康瑞高科新材料技术工程有限公司 | A kind of white paint and preparation method thereof brightened |
| CN109355003A (en) * | 2018-09-17 | 2019-02-19 | 东莞星晖真空镀膜塑胶制品有限公司 | A kind of hardware bottle cap product surface treatment process |
| CN109444137A (en) * | 2018-11-11 | 2019-03-08 | 廊坊立邦涂料有限公司 | A kind of detection method of coating black and white lattice covering power |
| CN110054977A (en) * | 2019-05-21 | 2019-07-26 | 临沂优彩新能源环保科技有限公司 | A kind of UV woodenware printing coating and its preparation process |
| CN111073478A (en) * | 2019-12-31 | 2020-04-28 | 海聚高分子材料科技（广州）有限公司 | High-covering-rate finish UV coating and preparation method thereof |
| CN111471375A (en) * | 2020-04-30 | 2020-07-31 | 上海展辰涂料有限公司 | Anti-scratch photocuring odorless matte white finish |
| CN111471375B (en) * | 2020-04-30 | 2022-06-28 | 上海展辰涂料有限公司 | Anti-scratch photocuring odorless matte white finish |
| CN111690310A (en) * | 2020-06-19 | 2020-09-22 | 广东立邦长润发科技材料有限公司 | UV white primer for spraying mechanical arm and preparation method thereof |
| CN112898894A (en) * | 2021-01-19 | 2021-06-04 | 广东美涂士建材股份有限公司 | LED (light-emitting diode) cured high-gloss finish paint |
| CN112898894B (en) * | 2021-01-19 | 2022-04-15 | 广东美涂士建材股份有限公司 | LED (light-emitting diode) cured high-gloss finish paint |
| CN117285865A (en) * | 2023-07-28 | 2023-12-26 | 武汉理工大学 | Photo-cured coating for concrete reinforced protection and preparation method of photo-cured coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103031034B (en) | 2016-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103031034A (en) | White finish coat photocurable UV (ultraviolet) paint and preparation method thereof | |
| CN101348611B (en) | Acroleic acid modified polysiloxane resin and coating thereof | |
| CN1844229A (en) | A kind of UV-curable water-based resin composition | |
| CN111423809B (en) | LED-UV spraying matte finish paint and preparation method thereof | |
| CN103602224B (en) | A kind of white solvent-free finish paint and its preparation method and construction technology | |
| CN104387945A (en) | Odorless staining-resistant anti-yellowing UV coated matt finish paint coating, and preparation method and construction technology thereof | |
| EP3067395A1 (en) | Ultraviolet radiation-curable composition, and recorded matter | |
| EP2594612A2 (en) | Anti-glare coating composition and anti-glare coating film having superior abrasion resistance and contamination resistance | |
| CN109609002B (en) | Ultraviolet curing primer for wood surface and preparation method thereof | |
| CN102101945A (en) | Ultraviolet curing paint and preparation method thereof | |
| CN110698975A (en) | Ultraviolet-cured matt scratch-resistant floor coating and preparation method thereof | |
| CN109517433B (en) | Recoatable high-coverage UV ink and preparation method and application thereof | |
| CN112126340B (en) | UV color-repairing essential oil | |
| CN104263208A (en) | UV (Ultraviolet) laminated topcoat gloss coating with performances of smell removal, stain resistance and yellowing resistance as well as preparation method and construction process thereof | |
| CN113861808B (en) | Roller-coated UV white primer with excellent UV ink wettability and preparation method thereof | |
| CN106833362A (en) | A kind of gloss oil on tin printing ink | |
| CN114716903A (en) | Wear-resistant stain-resistant UV-cured skin-feel coating and preparation method thereof | |
| EP3067396B1 (en) | Ultraviolet curable composition and recorded object | |
| CN105419621A (en) | High abrasion-resistance ultraviolet (UV) matte coating capable of recoating, preparation method thereof and appliance | |
| CN112980318A (en) | Composite board high-wear-resistance fingerprint-resistant matte UV (ultraviolet) hardening liquid and preparation method thereof | |
| CN102408827A (en) | Water-based ultraviolet-curing transparent primer and preparation method thereof | |
| CN107513344B (en) | A kind of LED-UV ultraviolet curing wood nano-coating and preparation method thereof | |
| CN111334169A (en) | LED-UV spraying primer and preparation method thereof | |
| CN116463017A (en) | A skin-feeling stain-resistant and wear-resistant UV topcoat and preparation method thereof | |
| JP5466612B2 (en) | Method for producing resin-coated metal oxide particle resin dispersion composition and substrate with transparent coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |