CN103013392A - Special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries - Google Patents
Special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries Download PDFInfo
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- CN103013392A CN103013392A CN2012104792655A CN201210479265A CN103013392A CN 103013392 A CN103013392 A CN 103013392A CN 2012104792655 A CN2012104792655 A CN 2012104792655A CN 201210479265 A CN201210479265 A CN 201210479265A CN 103013392 A CN103013392 A CN 103013392A
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- woven fabric
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- binding agent
- butyl ester
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- 239000002759 woven fabric Substances 0.000 title claims abstract description 35
- 235000012343 cottonseed oil Nutrition 0.000 title claims abstract description 21
- 239000011230 binding agent Substances 0.000 title claims abstract description 16
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 title abstract 3
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims abstract description 15
- 239000002956 ash Substances 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 6
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 6
- 239000011425 bamboo Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 5
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012188 paraffin wax Substances 0.000 claims abstract description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004593 Epoxy Substances 0.000 claims description 24
- 239000002253 acid Substances 0.000 claims description 18
- 239000002385 cottonseed oil Substances 0.000 claims description 18
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 18
- 238000005215 recombination Methods 0.000 claims description 17
- 230000006798 recombination Effects 0.000 claims description 17
- 238000005520 cutting process Methods 0.000 claims description 16
- 230000004048 modification Effects 0.000 claims description 13
- 238000012986 modification Methods 0.000 claims description 13
- 239000000853 adhesive Substances 0.000 claims description 12
- 230000001070 adhesive effect Effects 0.000 claims description 12
- 239000012467 final product Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 239000004744 fabric Substances 0.000 claims description 9
- 229920001651 Cyanoacrylate Polymers 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 229920003987 resole Polymers 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 241001330002 Bambuseae Species 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 2
- 239000003610 charcoal Substances 0.000 abstract 2
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical group CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 abstract 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 abstract 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 abstract 1
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 abstract 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 abstract 1
- 239000004209 oxidized polyethylene wax Substances 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- 229960002622 triacetin Drugs 0.000 abstract 1
- 238000003825 pressing Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
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Abstract
The invention discloses a special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries. The binding agent is prepared from the following raw materials in parts by weight: 60-65 parts of EVA (ethylene-vinyl acetate), 15-20 parts of terpene resin T-120, 12-15 parts of phenolic resin 2402, 3-5 parts of paraffin wax, 0.5-1 of oxidized polyethylene wax, 2-4 parts of modified shale powder, 3.5-6.8 parts of tree ashes, 1.5-2.5 parts of nano bamboo charcoal, 0.8-1.7 parts of silane coupling agent A-1510, 0.4-0.6 of n-butyl methacrylate, 0.2-0.5 of fungacetin, 1-2 parts of epoxidized cottonseed butyl oleate, 1-2 parts of epoxidized sobean oil, 1-2 parts of antioxidant 168, 0.1-0.3 of antioxidant T501, and 1-2 parts of ferrocene. As the raw materials for preparation contain the nano bamboo charcoal and the modified tree ashes, the binding agent is good in temperature resistance, very applicable to composition of the woven fabric on the surface of the automotive upholsteries, the composition effect is smooth, and no bubbles are produced after automotive upholsteries are used for a long time.
Description
Technical field
The invention belongs to the binding agent field, relate in particular to a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester.
Background technology
In the decorative material on automotive upholstery surface knit fabric or leather etc. are arranged at present, the moulding process of product is mould pressing process or low-pressure injection molding technology.Many employings cut first cloth during mold pressing, mold pressing bound edge again, the cutting technologist uses maximum, the methods of everyone cutting are different, so the consistence of product can't ensure that the production efficiency of mould pressing process is low, fraction defective is high, use artificial quantity large, the whole Production Flow Chart from work in-process to the finished product is complicated.And the high cost of low-pressure injection molding technology, equipment investment is large, the extension of fabric is required high, is badly in need of a kind of automotive upholstery glue of excellent performance, satisfies need of production.
Summary of the invention
The purpose of this invention is to provide a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester.
The present invention adopts following technical scheme to achieve these goals:
A kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester, it is characterized in that, it is that raw material by following weight parts makes: EVA 60-65, terpine resin T-120 15-20, resol 2402 12-15, paraffin 3-5, oxidized polyethlene wax 0.5-1, modification shale powder 2-4, modification trees ashes 3.5-6.8, nano bamboo powdered carbon 1.5-2.5, silane coupling A-151 0.8-1.7, n-BMA 0.4-0.6, Vanay 0.2-0.5, epoxy cotton seed oil acid butyl ester 1-2, epoxy soybean oil 1-2, irgasfos 168 1-2, oxidation inhibitor T501 0.1-0.3, ferrocene 1-2;
The preparation method of modification shale powder is:
(1), shale was calcined 8-10 hour down pulverizing, excessively 100-200 mesh sieve in 500-600 ℃;
(2), again the shale powder concentration after will sieving is that the acetic acid solution of 10-12% soaked after 4-6 hour, and is extremely neutral with deionized water wash again, oven dry;
(3), add in the shale powder after oven dry and be equivalent to the epoxy soybean oil of its weight 1.5-2.5%, the a-cyanoacrylate of 2-3%, 3000-4000 rev/min lower stir 30-40 minute after, oven dry is pulverized, and crosses the 400-500 mesh sieve, and get final product;
The preparation method of modification trees ashes is:
(1), trees ashes concentration is that the hydrogen peroxide solution of 10-15% soaked after 4-6 hour, again with deionized water wash to neutral, oven dry;
(3), add in the trees ashes after oven dry and be equivalent to the clorafin of its weight 1-2%, the a-cyanoacrylate of 2.5-3.5%, 4000-4600 rev/min lower stir 20-30 minute after, oven dry is pulverized, and get final product.
Described a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester, it is characterized in that: described EVA is Dupont 560.
Described a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester, it is characterized in that: the preparation method of described binding agent may further comprise the steps:
(1) kneader preheats to wall temperature 190-205 ℃;
(2) then add by weight EVA, terpine resin T-120, resol 2402, silane coupling A-151, epoxy cotton seed oil acid butyl ester, irgasfos 168, oxidation inhibitor T501, mediate 40-60min;
(3) add by weight surplus stock after, in the 170-190 ℃ of lower 30-50min that mediates, taking-up is cooled off and be get final product.
Described a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester is characterized in that: utilize described binding agent in the method for automotive upholstery surface recombination woven fabric to be:
(1), needing the inside gadget surface spraying binding agent of compounding machine knitted fabric;
(2), inside gadget is positioned in the counterdie on the boss fixing, and the outside of the counterdie boss around the inside gadget is provided with the annular cavity that holds die-cutting rule;
(3), the woven fabric of rolling is pulled to the boss place and covers on the inside gadget;
(4), patrix presses down, the 20-25Mpa that exerts pressure, patrix die head lower surface and inside gadget surface shape are coincide, and woven fabric is compressed fit in the inside gadget surface, shaping cycle 13-17 second, pressurize 10-15 second;
(5), adopt the manual unnecessary woven fabric of inside gadget periphery that cuts; Perhaps in the composite material process, patrix die head periphery is provided with the cutting knife of elastic telescopic, and cutting knife sinks, and extend in the described annular cavity the unnecessary woven fabric of excision inside gadget periphery;
(6), the patrix resilience, take out and to be compounded with the woven fabric inside gadget, manually unnecessary fabric is carried out bound edge, and get final product.
Beneficial effect of the present invention: the raw materials of binding agent of the present invention contains nano bamboo powdered carbon and modification trees ashes, and temperature tolerance is good, and cohesive strength is high, is highly suitable for automotive upholstery surface recombination woven fabric, and composite effect is smooth, and life-time service can not bubble.
Description of drawings
Fig. 1 is the mould structure synoptic diagram that utilizes the present invention to use at automotive upholstery surface recombination woven fabric.
Embodiment,
A kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester, it is that raw material by following weight parts (kg) makes: Dupont 560 EVA 63, terpine resin T-120 20, resol 2,402 14.5, paraffin 5, oxidized polyethlene wax 0.6, modification shale powder 4, modification trees ashes 6.8, nano bamboo powdered carbon 2.5, silane coupling A-151 1.2, n-BMA 0.5, Vanay 0.5, epoxy cotton seed oil acid butyl ester 1.4, epoxy soybean oil 1.2, irgasfos 168 2, oxidation inhibitor T501 0.13, ferrocene 1.4;
The preparation method of modification shale powder is:
(1), shale was calcined 10 hours down pulverizing, excessively 200 mesh sieves in 560 ℃;
(2), again the shale powder concentration after will sieving is that 11.5% acetic acid solution soaked after 5 hours, again with deionized water wash to neutral, oven dry;
(3), add in the shale powder after oven dry and be equivalent to the epoxy soybean oil of its weight 2.2%, 2.3% a-cyanoacrylate, 4000 rev/mins lower stir 40 minutes after, oven dry is pulverized, and crosses 500 mesh sieves, and get final product;
The preparation method of modification trees ashes is:
(1), trees ashes concentration is that 10% hydrogen peroxide solution soaked after 4 hours, again with deionized water wash to neutral, oven dry;
(3), add in the trees ashes after oven dry and be equivalent to the clorafin of its weight 1%, 2.8% a-cyanoacrylate, 4000 rev/mins lower stir 30 minutes after, oven dry is pulverized, and get final product.
The preparation method of described binding agent may further comprise the steps:
(1) kneader preheats to 197 ℃ of wall temperatures;
(2) then add by weight EVA, terpine resin T-120, resol 2402, silane coupling A-151, epoxy cotton seed oil acid butyl ester, irgasfos 168, oxidation inhibitor T501, mediate 60min;
(3) add by weight surplus stock after, in 175 ℃ of lower 50min that mediate, taking-up is cooled off and be get final product.
Referring to accompanying drawing, mould of the present invention includes patrix 6, counterdie 4, has on the counterdie 4 for inside gadget 3 to place fixing boss 1, is stained with leather on the inside gadget 5, on the counterdie 4, boss 1 periphery is surrounded with the annular cavity 2 that holds die-cutting rule 3; Upper die-cutting rule 3 is ring structure, and slip cap is contained in patrix 6 die heads periphery, by being arranged on the other driving mechanism on the patrix 6, promoting patrix 6 cutting knifes and moves to realize cutting function.Above-mentioned upper die-cutting rule 3 structures can not established yet, and adopt and manually cut the limit.Mould of the present invention has left and right two boss, can carry out simultaneously the composite material of two different structure inside gadgets 5.
Utilize described binding agent in the method for automotive upholstery surface recombination woven fabric to be:
(1), needing the inside gadget surface spraying binding agent of compounding machine knitted fabric;
(2), inside gadget is positioned in the counterdie on the boss fixing, and the outside of the counterdie boss around the inside gadget is provided with the annular cavity that holds die-cutting rule;
(3), the woven fabric of rolling is pulled to the boss place and covers on the inside gadget;
(4), patrix presses down, the 23Mpa that exerts pressure, patrix die head lower surface and inside gadget surface shape are coincide, and woven fabric is compressed fit in the inside gadget surface, shaping cycle 13 seconds, pressurize 13 seconds;
(5), adopt the manual unnecessary woven fabric of inside gadget periphery that cuts; Perhaps in the composite material process, patrix die head periphery is provided with the cutting knife of elastic telescopic, and cutting knife sinks, and extend in the described annular cavity the unnecessary woven fabric of excision inside gadget periphery;
(6), the patrix resilience, take out and to be compounded with the woven fabric inside gadget, manually unnecessary fabric is carried out bound edge, and get final product.
Through actual verification, composite efficiency increases by 2 times, and single-piece reduces 3-4 manually, and economic benefit is obvious.
The apparent viscosity of the binding agent of present embodiment is 4800MPa.s, and stripping strength 150N/2.5cm, initial bonding strength reach steel ball No. 5,137 ℃ of softening temperatures, and open hour 36s, thermally-stabilised proterties was stable in 24 hours.
Claims (4)
1. automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester, it is characterized in that, it is that raw material by following weight parts makes: EVA 60-65, terpine resin T-120 15-20, resol 2402 12-15, paraffin 3-5, oxidized polyethlene wax 0.5-1, modification shale powder 2-4, modification trees ashes 3.5-6.8, nano bamboo powdered carbon 1.5-2.5, silane coupling A-151 0.8-1.7, n-BMA 0.4-0.6, Vanay 0.2-0.5, epoxy cotton seed oil acid butyl ester 1-2, epoxy soybean oil 1-2, irgasfos 168 1-2, oxidation inhibitor T501 0.1-0.3, ferrocene 1-2;
The preparation method of modification shale powder is:
(1), shale was calcined 8-10 hour down pulverizing, excessively 100-200 mesh sieve in 500-600 ℃;
(2), again the shale powder concentration after will sieving is that the acetic acid solution of 10-12% soaked after 4-6 hour, and is extremely neutral with deionized water wash again, oven dry;
(3), add in the shale powder after oven dry and be equivalent to the epoxy soybean oil of its weight 1.5-2.5%, the a-cyanoacrylate of 2-3%, 3000-4000 rev/min lower stir 30-40 minute after, oven dry is pulverized, and crosses the 400-500 mesh sieve, and get final product;
The preparation method of modification trees ashes is:
(1), trees ashes concentration is that the hydrogen peroxide solution of 10-15% soaked after 4-6 hour, again with deionized water wash to neutral, oven dry;
(3), add in the trees ashes after oven dry and be equivalent to the clorafin of its weight 1-2%, the a-cyanoacrylate of 2.5-3.5%, 4000-4600 rev/min lower stir 20-30 minute after, oven dry is pulverized, and get final product.
2. a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester according to claim 1, it is characterized in that: described EVA is Dupont 560.
3. a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester according to claim 1 and 2, it is characterized in that: the preparation method of described binding agent may further comprise the steps:
(1) kneader preheats to wall temperature 190-205 ℃;
(2) then add by weight EVA, terpine resin T-120, resol 2402, silane coupling A-151, epoxy cotton seed oil acid butyl ester, irgasfos 168, oxidation inhibitor T501, mediate 40-60min;
(3) add by weight surplus stock after, in the 170-190 ℃ of lower 30-50min that mediates, taking-up is cooled off and be get final product.
4. a kind of automotive upholstery surface recombination woven fabric adhesive special that contains the epoxy cotton seed oil acid butyl ester according to claim 1 is characterized in that: utilize described binding agent in the method for automotive upholstery surface recombination woven fabric to be:
(1), needing the inside gadget surface spraying binding agent of compounding machine knitted fabric;
(2), inside gadget is positioned in the counterdie on the boss fixing, and the outside of the counterdie boss around the inside gadget is provided with the annular cavity that holds die-cutting rule;
(3), the woven fabric of rolling is pulled to the boss place and covers on the inside gadget;
(4), patrix presses down, the 20-25Mpa that exerts pressure, patrix die head lower surface and inside gadget surface shape are coincide, and woven fabric is compressed fit in the inside gadget surface, shaping cycle 13-17 second, pressurize 10-15 second;
(5), adopt the manual unnecessary woven fabric of inside gadget periphery that cuts; Perhaps in the composite material process, patrix die head periphery is provided with the cutting knife of elastic telescopic, and cutting knife sinks, and extend in the described annular cavity the unnecessary woven fabric of excision inside gadget periphery;
(6), the patrix resilience, take out and to be compounded with the woven fabric inside gadget, manually unnecessary fabric is carried out bound edge, and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104792655A CN103013392A (en) | 2012-11-22 | 2012-11-22 | Special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries |
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|---|---|---|---|
| CN2012104792655A CN103013392A (en) | 2012-11-22 | 2012-11-22 | Special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571407A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Automotive upholstery hot melt adhesive not easy to crack |
| CN103571387A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Special hot melt adhesive for automotive upholstery |
| CN103571376A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
| CN108806981A (en) * | 2018-06-11 | 2018-11-13 | 铜陵市胜美达电子制造有限公司 | A kind of preparation method of capacitor impregnant |
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2012
- 2012-11-22 CN CN2012104792655A patent/CN103013392A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571407A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Automotive upholstery hot melt adhesive not easy to crack |
| CN103571387A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Special hot melt adhesive for automotive upholstery |
| CN103571376A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
| CN103571407B (en) * | 2013-10-24 | 2015-06-17 | 芜湖众力部件有限公司 | Automotive upholstery hot melt adhesive not easy to crack |
| CN108806981A (en) * | 2018-06-11 | 2018-11-13 | 铜陵市胜美达电子制造有限公司 | A kind of preparation method of capacitor impregnant |
| CN108806981B (en) * | 2018-06-11 | 2020-03-20 | 铜陵市胜美达电子制造有限公司 | Preparation method of capacitor impregnant |
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Application publication date: 20130403 |