CN103013249B - Boundling cable aluminum component antioxidation protection coating - Google Patents
Boundling cable aluminum component antioxidation protection coating Download PDFInfo
- Publication number
- CN103013249B CN103013249B CN201110285839.0A CN201110285839A CN103013249B CN 103013249 B CN103013249 B CN 103013249B CN 201110285839 A CN201110285839 A CN 201110285839A CN 103013249 B CN103013249 B CN 103013249B
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- CN
- China
- Prior art keywords
- agent
- coating
- cable
- boundling
- aluminum component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000011248 coating agent Substances 0.000 claims abstract description 52
- 238000000576 coating method Methods 0.000 claims abstract description 51
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011230 binding agent Substances 0.000 claims abstract description 16
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- 239000012046 mixed solvent Substances 0.000 claims abstract description 13
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000006185 dispersion Substances 0.000 claims abstract description 11
- 239000006224 matting agent Substances 0.000 claims abstract description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 8
- 239000004411 aluminium Substances 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 239000000178 monomer Substances 0.000 claims abstract description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 4
- 230000003064 anti-oxidating effect Effects 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 3
- -1 divinyl diamines Chemical class 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 3
- 238000003618 dip coating Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000000643 oven drying Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000428 dust Substances 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical group O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 101150039167 Bex3 gene Proteins 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of coating for big machinery boundling cable aluminum component protection against oxidation; be prepared from by resin binder, auxiliary agent and mixed solvent; resin binder is wherein polyacrylic resin and aliphatic firming agent or vibrin and aliphatic firming agent; auxiliary agent is matting agent, flow agent and dispersion agent, and mixed solvent is N-BUTYL ACETATE and/or vinyl acetic monomer and/or dimethylbenzene and/or pimelinketone and/or butanone and/or ethyl cellosolve acetate.Formula of the present invention rationally, easy construction, cheap, it has fabulous resistance toly to put forth effort at cable aluminium workpiece surface, by overhauling boundling cable entirety or coating cable can being made to have fabulous outside durabitity after carrying out intensive treatment in advance to anew cable, not easily xanthochromia, can use in the environment of various harshness such as acid, alkali, salt and dust storm, lhv gas etc., thus significantly improve the result of use of boundling cable, reduce manufacture and the use cost of all kinds of outdoor mechanical means, be suitable for and apply.
Description
Technical field
The invention belongs to chemical coating agent technical field, relate to a kind of coating for big machinery boundling cable aluminum component protection against oxidation.
Background technology
All kinds of mechanical means used out of doors are at present particularly as in the heavy mechanical equipment of road machine, paver etc., the aluminum metal assembly of boundling cable is easy to oxidized, often equipment is not also sold and is dispatched from the factory, and aluminum component is just corroded, and the high-grade boundling comprising import is also there's no one who doesn't or isn't like this.Because the price of heavy mechanical equipment boundling cable is very expensive, above-mentioned phenomenon both caused the huge wasting of resources to enterprise, badly influenced again the result of use of heavy mechanical equipment.
Summary of the invention
The object of the invention is to solve prior art Problems existing, provide a kind of and fill a prescription rationally, easy construction, cheap, every profession and trade heavy mechanical equipment boundling cable aluminum metal assembly surface can be widely used in make it have the boundling cable aluminum component antioxidation protection coating of good result of use.
For achieving the above object and adopt technical solution be such: the boundling cable aluminum component antioxidation protection coating provided is prepared from by the raw material of substance of following weight per-cent:
Resin binder 50% ~ 80%,
Auxiliary agent 2% ~ 5%,
Mixed solvent surplus;
Wherein, said resin binder is polyacrylic resin and aliphatic firming agent, and the weight proportion between the two is 4 ~ 5: 1, or vibrin and aliphatic firming agent, and the weight proportion between the two is 4 ~ 5: 1; Said auxiliary agent is matting agent, flow agent and dispersion agent; Said mixed solvent is N-BUTYL ACETATE and/or vinyl acetic monomer and/or dimethylbenzene and/or pimelinketone and/or butanone and/or ethyl cellosolve acetate.
Technical solution of the present invention also comprises: said aliphatic firming agent is hexamethylene diisocyanate (HDI) or divinyl diamines (DETA); Said matting agent is syloidED-5 (W. R. Grace & Co of U.S. product), and said flow agent is modaflow9200, and said dispersion agent is the TD-01 product of Tianjin chemical research institute development & production.
In above-mentioned substance composition of raw materials, resin binder is the main filmogen of coating, react with after paint spraying, generation is cross-linked with each other, and make macromolecular material form " netted " structure, molecular weight is tending towards " infinity ", matting agent is bonded together by resin binder, fully be coated on every particle sub-surface, after coating dry solidification, form continuous and closely knit film, make coating can be attached to aluminum substrates anode oxide film surface securely; This resin binder gives coating fabulous outside durabitity, can resist ultraviolet radiation and not " chain rupture " (namely efflorescence, xanthochromia not easily occur coating), while the also acid-and base-resisting of imparting coating, salt severe rugged environment ability.
Auxiliary agent in formula is matting agent, flow agent and dispersion agent, arranges between three by 1: 1 ~ 2: 1 ~ 2.The gloss that matting agent makes coating have to specify and smooth feel; Flow agent can make dry coating flat smooth, and the paint such as " crater ", " pin hole ", " Bei Nade whirlpool " is sick to avoid coating to occur; Dispersion agent can make resin play good immersional wetting to matting agent, is easy to " boundling " Granular composite to open, and impels every particle sub-surface can by resin-coated.
Mixed solvent in formula can make resin binder be dissolved into homogeneous phase liquid, thick coating is diluted to the viscosity of applicable application.
Method for the preparation of this boundling cable aluminum component antioxidation protection coating comprises following processing step:
(1), add in container by the resin binder of formula ratio 10% ~ 30%, under agitation slowly add auxiliary agent, the high speed dispersor of employing 2000 revs/min or more afterwards makes material dispersion even;
(2), by the resin binder of residue formula ratio and mixed solvent all add in container, filter with 200 order tiffanys after stirring, filtrate is finished product coating.
This boundling cable aluminum component antioxidation protection coating is utilized to the method that boundling cable aluminium workpiece surface applies to be: the coating made is coated on Wire/cable contact member aluminium workpiece surface with the method for spraying or dip-coating; adopt from doing or making coating drying, solidification with the method for 50 DEG C ~ 60 DEG C of oven drying at low temperatures, form the dry coating of 30 μm ~ 40 μm.
Compared with prior art, the formula of coating of the present invention rationally, easy construction, cheap, it has fabulous resistance toly to put forth effort at cable aluminium workpiece surface, by overhauling boundling cable entirety or coating cable can being made to have fabulous outside durabitity after carrying out intensive treatment in advance to anew cable, not easily xanthochromia, can use in the environment of various harshness such as acid, alkali, salt and dust storm, lhv gas etc.Above-mentioned advantage substantially increases the result of use of boundling cable, has saved resource, and reduce manufacture and the use cost of all kinds of outdoor mechanical means, remarkable in economical benefits, is suitable for and promotes the popularization use.
Embodiment
Embodiment one
A kind of boundling cable aluminum component antioxidation protection coating, is prepared from by the raw material of substance of following weight per-cent:
Polyacrylic resin in above-mentioned formula and hexamethylene diisocyanate are coating resin base-material, the auxiliary agent that syloidED-5 (matting agent), modaflow9200 (flow agent), TD-01 (dispersion agent) are coating, N-BUTYL ACETATE is the mixed solvent of coating.
The preparation method of this boundling cable aluminum component antioxidation protection coating is:
(1), add in container by the resin binder of formula ratio 10% ~ 30%, under agitation slowly add auxiliary agent, the high speed dispersor of employing 2000 revs/min or more afterwards makes material dispersion even;
(2), by the resin binder of residue formula ratio and mixed solvent all add in container, filter with 200 order tiffanys after stirring, filtrate is finished product coating.
Adopt the paint spay-coating of above-mentioned formula and preparation method's making at boundling Wire/cable contact member aluminium workpiece surface and be applied on 21 large-scale construction road machineries, outdoor test run(s) through 1 ~ 2 year is observed, overall boundling cable aluminum component coating is almost unchanged, have no the variable color of coating, pulverization situation, also have no that foaming, scaling appear in coating, the phenomenon such as come off, quality meets design requirements completely, and result of use is fabulous.
Embodiment two
A kind of boundling cable aluminum component antioxidation protection coating, is prepared from by the raw material of substance of following weight per-cent:
Vibrin in above-mentioned formula and hexamethylene diisocyanate are coating resin base-material, and syloidED-5, modaflow9200 and TD-01 are the auxiliary agent of coating, and N-BUTYL ACETATE and vinyl acetic monomer are the mixed solvent of coating.
The preparation method of this boundling cable aluminum component antioxidation protection coating is with embodiment one.
Embodiment three
A kind of boundling cable aluminum component antioxidation protection coating, is prepared from by the raw material of substance of following weight per-cent:
Vibrin in above-mentioned formula and divinyl diamines are coating resin base-material, and syloidED-5, modaflow9200 and TD-01 are the auxiliary agent of coating, and dimethylbenzene is the mixed solvent of coating.
The preparation method of this boundling cable aluminum component antioxidation protection coating is with embodiment one.
Claims (2)
1. a boundling cable aluminum component antioxidation protection coating, is characterized in that being prepared from by the raw material of substance of following weight per-cent:
Resin binder 50% ~ 80%,
Auxiliary agent 2% ~ 5%,
Mixed solvent surplus;
Said resin binder is polyacrylic resin and aliphatic firming agent, and the weight proportion between the two is 4 ~ 5: 1, or vibrin and aliphatic firming agent, and the weight proportion between the two is 4 ~ 5: 1, and wherein said aliphatic firming agent is divinyl diamines; Said auxiliary agent is matting agent, flow agent and dispersion agent, and wherein, said matting agent is syloidED-5, and said flow agent is modaflow9200, and said dispersion agent is TD-01; Said mixed solvent is N-BUTYL ACETATE, or N-BUTYL ACETATE and vinyl acetic monomer, or dimethylbenzene;
Method for the preparation of this boundling cable aluminum component antioxidation protection coating comprises following processing step:
(1), add in container by the resin binder of formula ratio 10% ~ 30%, under agitation slowly add auxiliary agent, the high speed dispersor of employing 2000 revs/min or more afterwards makes material dispersion even;
(2), by the resin binder of residue formula ratio and mixed solvent all add in container, filter with 200 order tiffanys after stirring, filtrate is finished product coating.
2. one kind adopts the method that described in claim 1, boundling cable aluminum component antioxidation protection coating applies boundling cable aluminium workpiece surface; it is characterized in that: the coating made is coated on Wire/cable contact member aluminium workpiece surface with the method for spraying or dip-coating; adopt from doing or making coating drying, solidification with the method for 50 DEG C ~ 60 DEG C of oven drying at low temperatures, form the dry coating of 30 μm ~ 40 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110285839.0A CN103013249B (en) | 2011-09-23 | 2011-09-23 | Boundling cable aluminum component antioxidation protection coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110285839.0A CN103013249B (en) | 2011-09-23 | 2011-09-23 | Boundling cable aluminum component antioxidation protection coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103013249A CN103013249A (en) | 2013-04-03 |
| CN103013249B true CN103013249B (en) | 2015-12-02 |
Family
ID=47962378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110285839.0A Expired - Fee Related CN103013249B (en) | 2011-09-23 | 2011-09-23 | Boundling cable aluminum component antioxidation protection coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103013249B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1396224A (en) * | 2002-08-12 | 2003-02-12 | 中国化工建设总公司常州涂料化工研究院 | Solvent-type high-solid paint containing rheologically modified resin |
| CN101781519A (en) * | 2009-12-22 | 2010-07-21 | 北京航材百慕新材料技术工程股份有限公司 | Transparent anti-graffiti dirt-resistant anti-weathering coating |
-
2011
- 2011-09-23 CN CN201110285839.0A patent/CN103013249B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1396224A (en) * | 2002-08-12 | 2003-02-12 | 中国化工建设总公司常州涂料化工研究院 | Solvent-type high-solid paint containing rheologically modified resin |
| CN101781519A (en) * | 2009-12-22 | 2010-07-21 | 北京航材百慕新材料技术工程股份有限公司 | Transparent anti-graffiti dirt-resistant anti-weathering coating |
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| Publication number | Publication date |
|---|---|
| CN103013249A (en) | 2013-04-03 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151202 Termination date: 20170923 |