CN103011751B - High-strength composite plate or profile for construction and production method thereof - Google Patents
High-strength composite plate or profile for construction and production method thereof Download PDFInfo
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- CN103011751B CN103011751B CN201310001759.7A CN201310001759A CN103011751B CN 103011751 B CN103011751 B CN 103011751B CN 201310001759 A CN201310001759 A CN 201310001759A CN 103011751 B CN103011751 B CN 103011751B
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- 239000002131 composite material Substances 0.000 title claims abstract description 37
- 238000010276 construction Methods 0.000 title claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 title abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 148
- 239000003365 glass fiber Substances 0.000 claims abstract description 128
- 239000002002 slurry Substances 0.000 claims abstract description 102
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 66
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 58
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 31
- 239000001913 cellulose Substances 0.000 claims abstract description 29
- 229920002678 cellulose Polymers 0.000 claims abstract description 29
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 29
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 84
- 239000000843 powder Substances 0.000 claims description 42
- 239000004744 fabric Substances 0.000 claims description 28
- 235000006408 oxalic acid Nutrition 0.000 claims description 28
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 27
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 15
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 15
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 15
- 239000010438 granite Substances 0.000 claims description 14
- 239000004575 stone Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 abstract description 18
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 28
- 230000001680 brushing effect Effects 0.000 description 24
- 239000002994 raw material Substances 0.000 description 23
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 239000011152 fibreglass Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
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Abstract
本发明公开了一种建筑用高强度复合板材或型材及其生产方法,其高强度复合板材或型材主要通过氯化镁40~50份,粉碎并与水30~50份混合,重量百分比浓度为5~12%的稀硫酸5~17份,与轻质氧化镁80~100份、硬脂酸锌0.7~1.0份、滑石粉20~50份、纤维素0.75~1.5份、树脂1.5~2.5份混合均匀得浆状混合物,再与玻璃纤维编织物复合构成至少两层玻璃纤维编织物与其之间的浆状混合物的层状复合材料。与现有技术相比,本发明可以制成各种建筑用板材、型材或预制构件,重量轻,强度大,搬运和安装施工方便,特别是抗压和抗变形能力强,并具有防腐、防潮的特点,适用于各种建筑设施中的支撑件,如涵洞、竖井等,尤其是工作面窄小的场合中使用。The invention discloses a high-strength composite plate or profile for construction and a production method thereof. The high-strength composite plate or profile is mainly prepared by crushing 40-50 parts of magnesium chloride and mixing it with 30-50 parts of water, and then mixing 5-17 parts of dilute sulfuric acid with a weight percentage concentration of 5-12% with 80-100 parts of light magnesium oxide, 0.7-1.0 parts of zinc stearate, 20-50 parts of talcum powder, 0.75-1.5 parts of cellulose, and 1.5-2.5 parts of resin to obtain a slurry mixture, and then compounding it with glass fiber braid to form a layered composite material of at least two layers of glass fiber braid and the slurry mixture therebetween. Compared with the prior art, the invention can be made into various building plates, profiles or prefabricated components, which are light in weight, high in strength, easy to carry and install, and particularly strong in compression and deformation resistance, and have the characteristics of corrosion resistance and moisture resistance. It is suitable for supporting parts in various building facilities, such as culverts, shafts, etc., especially for use in occasions with narrow working surfaces.
Description
技术领域 technical field
本发明涉及一种建筑复合板材或型材其生产方法,特别一种建筑用高强度复合板材或型材及其生产方法。 The invention relates to a building composite plate or profile and its production method, in particular to a high-strength building composite plate or profile and its production method.
背景技术 Background technique
目前的建筑用板材或型材,特别是人造建筑用板材或型材强度较低,抗压和抗变形能力弱。而如混凝土一类高强度建筑用板材或型材重量大,搬运和安装均不够方便,并不适用于工作面窄小的场合。 The current building boards or profiles, especially man-made building boards or profiles, have low strength and weak compression and deformation resistance. However, high-strength building plates or profiles such as concrete are heavy, and it is not convenient to carry and install, so it is not suitable for narrow and small working surfaces.
发明内容 Contents of the invention
本发明的目的是提供一种建筑复合板材或型材其生产方法,特别一种建筑用高强度复合板材或型材及其生产方法。 The object of the present invention is to provide a kind of building composite plate or profile and its production method, especially a kind of high-strength composite plate or profile for building and its production method.
本发明的建筑用高强度复合板材或型材主要通过以下工艺过程生产:按重量取氯化镁40~50份,粉碎并与水30~50份混合,重量百分比浓度为5~12%的稀硫酸5~17份,与轻质氧化镁80~100份、硬脂酸锌 0.7~1.0份、滑石粉20~50份、纤维素0.75~1.5份、树脂1.5~2.5份混合均匀得浆状混合物。 The high-strength composite board or profile for construction of the present invention is mainly produced through the following process: take 40-50 parts of magnesium chloride by weight, pulverize and mix with 30-50 parts of water, and 5-50 parts of dilute sulfuric acid with a concentration of 5-12% by weight 17 parts, mixed with 80-100 parts of light magnesium oxide, 0.7-1.0 parts of zinc stearate, 20-50 parts of talcum powder, 0.75-1.5 parts of cellulose, and 1.5-2.5 parts of resin to obtain a slurry mixture.
当然,上述的稀硫酸也可用浓硫酸加水稀释成重量百分比浓度为5~12%的稀硫酸。 Of course, the above-mentioned dilute sulfuric acid can also be diluted with concentrated sulfuric acid and water to form a dilute sulfuric acid with a concentration of 5 to 12% by weight.
所述轻质氧化镁和硬脂酸锌粉碎至180μm以下,所述的树脂为脲醛树脂或不饱和聚酯树脂中的一种。 The light magnesium oxide and zinc stearate are pulverized to less than 180 μm, and the resin is one of urea-formaldehyde resin or unsaturated polyester resin.
取玻璃纤维编织物铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复,构成至少两层玻璃纤维编织物与其之间的浆状混合物的层状复合材料。 Take the glass fiber braid and lay it in the mold, evenly brush the above slurry mixture on the glass fiber braid, and then spread the glass fiber braid layer on the slurry mixture, and repeat this process to form at least two layers of glass fiber braid A layered composite with a paste-like mixture in between.
上述的玻璃纤维编织物可以为玻璃纤维布或玻璃纤维丝中的一种或两种的混用,采用玻璃纤维丝时,玻璃纤维丝最好呈纵横交错状铺设。所述的纵横交错状铺设可以是相邻的玻璃纤维丝层的纹路纵横交错状铺设,也可是在同一层中的玻璃纤维丝呈纵横交错状铺设。 The above-mentioned glass fiber braid can be one or a combination of glass fiber cloth or glass fiber yarn. When glass fiber yarn is used, the glass fiber yarn is preferably laid in a criss-cross pattern. The criss-cross laying may be the criss-cross pattern of adjacent glass fiber filament layers, or the criss-cross pattern of glass fiber filaments in the same layer.
上述的浆状混合物中最好按重量加入下列中的一种或几种:树丁脂0.3~0.6份,过氧化甲乙酮(白水)0.45~0.5份,草酸0.2~0.3份,防水粉1.5~2份。 It is best to add one or more of the following by weight to the above slurry mixture: 0.3-0.6 parts of resin, 0.45-0.5 parts of methyl ethyl ketone peroxide (white water), 0.2-0.3 parts of oxalic acid, 1.5-2 parts of waterproof powder share.
上述滑石粉最好由180μm以下的花岗岩石粉所替换,优选为75μm以下。 The above-mentioned talc powder is preferably replaced by granite stone powder with a diameter of less than 180 μm, preferably less than 75 μm.
与现有技术相比,本发明可以制成各种建筑用板材、型材或预制构件,重量轻,强度大,搬运和安装施工方便,特别是抗压和抗变形能力强,并具有防腐、防潮的特点,适用于各种建筑设施中的支撑件,如涵洞、竖井等,尤其是工作面窄小的场合中使用。 Compared with the prior art, the present invention can be made into various building boards, profiles or prefabricated components, which are light in weight, high in strength, convenient in handling and installation, especially strong in compression and deformation resistance, and have anti-corrosion and moisture-proof properties. It is suitable for supporting parts in various building facilities, such as culverts, shafts, etc., especially in places with narrow working surfaces.
具体实施方式 Detailed ways
实施例1:按重量取:氯化镁50份,粉碎并与水30~50份混合,重量百分比浓度为10%的稀硫酸10份,轻质氧化镁100份和硬脂酸锌1.0份, 粉碎至180μm以下,滑石粉30份,纤维素0.75~1.5份,脲醛树脂2份,树丁脂0.3份,过氧化甲乙酮0.5份,草酸0.2份,防水粉1.5份,将上述原料混合均匀得浆状混合物。 Embodiment 1: Take by weight: 50 parts of magnesium chloride, pulverized and mixed with 30 to 50 parts of water, 10 parts of dilute sulfuric acid with a concentration of 10% by weight, 100 parts of light magnesium oxide and 1.0 part of zinc stearate, pulverized to Below 180 μm, 30 parts of talcum powder, 0.75-1.5 parts of cellulose, 2 parts of urea-formaldehyde resin, 0.3 part of resin, 0.5 part of methyl ethyl ketone peroxide, 0.2 part of oxalic acid, 1.5 parts of waterproof powder, mix the above materials evenly to get a slurry mixture .
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3~5mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复3次,构成4层玻璃纤维编织物与其之间的浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3-5mm, and then spread the glass fiber braid layer on the slurry mixture, repeat this process for 3 Second, a layered composite member consisting of 4 layers of fiberglass braids with a paste-like mixture in between.
实施例2:按重量取:氯化镁40份,粉碎并与水40份混合,取发烟浓硫酸稀释成重量百分比浓度为12%的稀硫酸,再取配制好的的稀硫酸8份,,轻质氧化镁100份和硬脂酸锌 0.7份,均粉碎至150μm以下,滑石粉20份,纤维素0.75份,脲醛树脂1.5份,树丁脂0.6份,过氧化甲乙酮0.5份,草酸0.25份,防水粉2份,将上述原料混合均匀得浆状混合物。 Embodiment 2: Take by weight: 40 parts of magnesium chloride, pulverize and mix with 40 parts of water, get fuming concentrated sulfuric acid and dilute into the dilute sulfuric acid that concentration is 12% by weight, then get 8 parts of prepared dilute sulfuric acid, lightly 100 parts of high-quality magnesium oxide and 0.7 parts of zinc stearate, all crushed to less than 150 μm, 20 parts of talcum powder, 0.75 parts of cellulose, 1.5 parts of urea-formaldehyde resin, 0.6 parts of resin, 0.5 parts of methyl ethyl ketone peroxide, 0.25 parts of oxalic acid, 2 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture.
在模具中铺设1层玻璃纤维布,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3~5mm,再在浆状混合物上铺覆玻璃纤维布,如此反复操作5次,构成6层玻璃纤维编织物与其之间的浆状混合物的层状复合材料构件。 Lay a layer of glass fiber cloth in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3-5mm, and then spread the glass fiber cloth on the slurry mixture, and repeat the operation for 5 Second, a layered composite member consisting of 6 layers of fiberglass braids with a paste-like mixture in between.
实施例3:按重量取:氯化镁45份,粉碎并与水40份混合,重量百分比浓度为7%的稀硫酸10份,轻质氧化镁90份和硬脂酸锌 0.8份,均粉碎至75μm以下,滑石粉40份,纤维素1份,脲醛树脂1.8份,树丁脂0.4份,过氧化甲乙酮0.46份,草酸0.25份,防水粉1.5份,将上述原料混合均匀得浆状混合物。 Embodiment 3: Take by weight: 45 parts of magnesium chloride, pulverized and mixed with 40 parts of water, 10 parts of dilute sulfuric acid with a concentration of 7% by weight, 90 parts of light magnesium oxide and 0.8 part of zinc stearate, all pulverized to 75 μm Next, 40 parts of talcum powder, 1 part of cellulose, 1.8 parts of urea-formaldehyde resin, 0.4 part of resin, 0.46 parts of methyl ethyl ketone peroxide, 0.25 parts of oxalic acid, 1.5 parts of waterproof powder, mix the above raw materials uniformly to obtain a slurry mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在4~6mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作2次,构成由3层玻璃纤维编织物与其之间的浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 4-6mm, and then spread the glass fiber braid layer on the slurry mixture, and so on. 2 times to form a layered composite member consisting of 3 layers of glass fiber braids and a paste-like mixture between them.
实施例4:按重量取:氯化镁48份,粉碎并与水45份混合,重量百分比浓度为10%的稀硫酸10份,轻质氧化镁80份和硬脂酸锌 0.9份,均粉碎至180μm以下,滑石粉45份,纤维素1.5份,脲醛树脂1.5份,草酸0.25份,防水粉2份,将上述原料混合均匀得浆状混合物。 Embodiment 4: Take by weight: 48 parts of magnesium chloride, pulverized and mixed with 45 parts of water, 10 parts of dilute sulfuric acid with a concentration of 10% by weight, 80 parts of light magnesium oxide and 0.9 part of zinc stearate, all pulverized to 180 μm Next, 45 parts of talcum powder, 1.5 parts of cellulose, 1.5 parts of urea-formaldehyde resin, 0.25 parts of oxalic acid, and 2 parts of waterproof powder are mixed uniformly to obtain a slurry mixture.
取玻璃纤维丝铺设于模具中,厚度控制在1~2mm,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3~4mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作5次,再用模具加压固形,构成由6层玻璃纤维编织物与其之间的浆状混合物的层状复合材料构件。 Take glass fiber filaments and lay them in the mold with a thickness of 1-2mm. Apply the above-mentioned slurry mixture evenly on the glass fiber braid, control the thickness of the brushing at 3-4mm, and then spread glass fibers on the slurry mixture. The braid layer is repeated five times, and then pressurized and solidified with a mold to form a layered composite member consisting of 6 layers of glass fiber braids and the slurry-like mixture between them.
实施例5:按重量取:氯化镁42份,粉碎并与水50份混合,重量百分比浓度为8%的稀硫酸15份,轻质氧化镁80份和硬脂酸锌1.0份,均粉碎至180μm以下,与滑石粉40份,纤维素1份,不饱和聚酯树脂2.5份,过氧化甲乙酮0.5份,草酸0.2份,防水粉1.5份,混合均匀得浆状混合物。 Embodiment 5: Take by weight: 42 parts of magnesium chloride, pulverized and mixed with 50 parts of water, 15 parts of dilute sulfuric acid with a concentration of 8% by weight, 80 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 180 μm Next, mix with 40 parts of talcum powder, 1 part of cellulose, 2.5 parts of unsaturated polyester resin, 0.5 part of methyl ethyl ketone peroxide, 0.2 part of oxalic acid, and 1.5 parts of waterproof powder to obtain a slurry mixture.
取玻璃纤维布铺设于竖井管模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,再在浆状混合物上铺覆玻璃纤维编织物层,涂刷厚度控制在5mm,如此反复操作5次,构成竖井井管预制件。 Take the glass fiber cloth and lay it in the shaft pipe mold, paint the above slurry mixture evenly on the glass fiber braid, and then spread the glass fiber braid layer on the slurry mixture, control the thickness of the brushing at 5mm, and repeat the operation 5 times to form the prefabricated shaft well pipe.
实施例6:按重量取:氯化镁44份,粉碎并与水35份混合,重量百分比浓度为6%的稀硫酸17份,轻质氧化镁90份和硬脂酸锌 0.8份,均粉碎至75μm以下,与滑石粉30份,纤维素1.2份,脲醛树脂2.2份,树丁脂0.5份,过氧化甲乙酮50.5份,草酸0.25份,防水粉1.8份,将上述原料混合均匀得浆状混合物。 Embodiment 6: Take by weight: 44 parts of magnesium chloride, pulverized and mixed with 35 parts of water, 17 parts of dilute sulfuric acid with a concentration of 6% by weight, 90 parts of light magnesium oxide and 0.8 part of zinc stearate, all pulverized to 75 μm Next, with 30 parts of talcum powder, 1.2 parts of cellulose, 2.2 parts of urea-formaldehyde resin, 0.5 part of resin, 50.5 parts of methyl ethyl ketone peroxide, 0.25 parts of oxalic acid, 1.8 parts of waterproof powder, mix the above raw materials uniformly to obtain a slurry mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在10mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作4次,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 10mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 4 times. , constitutes a layered composite member of a glass fiber braid and a slurry mixture.
实施例7:按重量取:氯化镁46份,粉碎并与水40份混合,重量百分比浓度为5%的稀硫酸15份,轻质氧化镁95份和硬脂酸锌 0.95份,均粉碎至38μm以下,粉碎至粒度38μm以下的花岗岩石粉30份,纤维素1.5份,不饱和聚酯树脂1.5份,树丁脂0.6份,过氧化甲乙酮0.5份,草酸0.3份,防水粉1.5份,将上述原料混合均匀得浆状混合物。 Embodiment 7: Take by weight: 46 parts of magnesium chloride, pulverized and mixed with 40 parts of water, 15 parts of dilute sulfuric acid with a concentration of 5% by weight, 95 parts of light magnesium oxide and 0.95 part of zinc stearate, all pulverized to 38 μm Below, 30 parts of granite stone powder, 1.5 parts of cellulose, 1.5 parts of unsaturated polyester resin, 0.6 part of resin, 0.5 part of methyl ethyl ketone peroxide, 0.3 part of oxalic acid, 1.5 parts of waterproof powder, and the above raw materials Mix evenly to obtain a slurry mixture.
取玻璃纤维丝铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在10mm,再在浆状混合物上铺覆玻璃纤维编织物层,相邻的玻璃纤维丝纹路纵横交错,如此反复操作4次,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Lay the glass fiber filaments in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 10mm, and then spread the glass fiber braid layer on the slurry mixture, and the adjacent glass fiber The silk lines are criss-crossed, and this operation is repeated 4 times to form a layered composite material member of a glass fiber braid and a slurry mixture.
实施例8:按重量取:氯化镁48份,粉碎并与水30份混合,重量百分比浓度为9%的稀硫酸8份,轻质氧化镁100份和硬脂酸锌 0.7份,均粉碎至44μm以下,粒度44μm以下的花岗岩石粉40份,纤维素1.5份,脲醛树脂2份,树丁脂0.45份,过氧化甲乙酮0.48份,草酸0.22份,防水粉1.7份,将上述原料混合均匀得浆状混合物。 Embodiment 8: Take by weight: 48 parts of magnesium chloride, pulverized and mixed with 30 parts of water, 8 parts of dilute sulfuric acid with a concentration of 9% by weight, 100 parts of light magnesium oxide and 0.7 part of zinc stearate, all pulverized to 44 μm Below, 40 parts of granite stone powder with particle size below 44 μm, 1.5 parts of cellulose, 2 parts of urea-formaldehyde resin, 0.45 parts of resin, 0.48 parts of methyl ethyl ketone peroxide, 0.22 parts of oxalic acid, 1.7 parts of waterproof powder, mix the above raw materials evenly to get a slurry mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在4~5mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作5次,构成玻璃纤维编织物层与其之间的浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 4-5mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation. 5 times to form a layered composite member of a fiberglass braid layer with a paste-like mixture therebetween.
实施例9:按重量取:氯化镁50份,粉碎并与水30份混合,重量百分比浓度为7%的稀硫酸12份,轻质氧化镁100份和硬脂酸锌1.0份,均粉碎至44μm以下,44μm以下的花岗岩石粉50份,纤维素1.4份,不饱和聚酯树脂1.5份,树丁脂0.45份,过氧化甲乙酮0.45份,草酸0.25份,防水粉2份,将上述原料混合均匀得浆状混合物。 Embodiment 9: Take by weight: 50 parts of magnesium chloride, pulverized and mixed with 30 parts of water, 12 parts of dilute sulfuric acid with a concentration of 7% by weight, 100 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 44 μm Below, 50 parts of granite stone powder below 44 μm, 1.4 parts of cellulose, 1.5 parts of unsaturated polyester resin, 0.45 parts of resin, 0.45 parts of methyl ethyl ketone peroxide, 0.25 parts of oxalic acid, 2 parts of waterproof powder, mix the above raw materials evenly to obtain Paste mixture.
取玻璃纤维布铺设于平板上,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在5mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作4次,构成玻璃纤维编织物与浆状混合物的层状复合材料板。 Take the glass fiber cloth and lay it on the flat plate, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 5mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 4 times. , a layered composite board that constitutes a glass fiber braid and paste mixture.
实施例10:按重量取:氯化镁45份,粉碎并与水40份混合,重量百分比浓度为11%的稀硫酸10份,轻质氧化镁100份和硬脂酸锌 0.7份,均粉碎至38μm以下,44μm以下的花岗岩石粉30份,纤维素0.8份,不饱和聚酯树脂2.5份,树丁脂0.55份,过氧化甲乙酮0.47份,草酸0.28份,防水粉1.8份,将上述原料混合均匀得浆状混合物。 Example 10: Take by weight: 45 parts of magnesium chloride, pulverized and mixed with 40 parts of water, 10 parts of dilute sulfuric acid with a concentration of 11% by weight, 100 parts of light magnesium oxide and 0.7 part of zinc stearate, all pulverized to 38 μm Below, 30 parts of granite stone powder below 44 μm, 0.8 parts of cellulose, 2.5 parts of unsaturated polyester resin, 0.55 parts of resin, 0.47 parts of methyl ethyl ketone peroxide, 0.28 parts of oxalic acid, 1.8 parts of waterproof powder, mix the above raw materials evenly to obtain Paste mixture.
取玻璃纤维布铺设于平板上,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3~5mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作5次,在完全凝固前加压固型,构成玻璃纤维编织物与浆状混合物的层状复合材料板。 Take the glass fiber cloth and lay it on the flat plate, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3-5mm, and then spread the glass fiber braid layer on the slurry mixture, and so on repeatedly. 5 times, press and solidify before complete solidification to form a layered composite material board of a glass fiber braid and slurry mixture.
实施例11:按重量取:氯化镁50份,粉碎并与水50份混合,重量百分比浓度为10%的稀硫酸15份,轻质氧化镁100份和硬脂酸锌 0.8份,均粉碎至74μm以下,74μm以下的花岗岩石粉40份,纤维素1份,不饱和聚酯树脂2份,树丁脂0.5份,过氧化甲乙酮50.5份,草酸0.3份,防水粉1.5份,将上述原料混合均匀得浆状混合物。 Example 11: Take by weight: 50 parts of magnesium chloride, pulverized and mixed with 50 parts of water, 15 parts of dilute sulfuric acid with a concentration of 10% by weight, 100 parts of light magnesium oxide and 0.8 part of zinc stearate, all pulverized to 74 μm Below, 40 parts of granite stone powder below 74 μm, 1 part of cellulose, 2 parts of unsaturated polyester resin, 0.5 part of resin, 50.5 parts of methyl ethyl ketone peroxide, 0.3 part of oxalic acid, 1.5 parts of waterproof powder, mix the above raw materials evenly to obtain Paste mixture.
取玻璃纤维布铺设于平板,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3~4mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作8次,在完全凝固前加压至1MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料板。 Take the glass fiber cloth and lay it on the flat plate, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3-4mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation for 8 Second, pressurize to 1MPa to solidify before completely solidifying to form a layered composite material board of a glass fiber braid and slurry mixture.
实施例12:按重量取:氯化镁45份,粉碎至1mm以下并与水30份混合,重量百分比浓度为10%的稀硫酸8份,轻质氧化镁100份和硬脂酸锌 0.9份,均粉碎至44μm以下,滑石粉50份,纤维素1.5份,脲醛树脂2份,树丁脂0.45份,过氧化甲乙酮0.45份,草酸0.25份,防水粉1.6份,将上述原料混合均匀得浆状混合物。 Embodiment 12: Take by weight: 45 parts of magnesium chloride, crushed to below 1mm and mixed with 30 parts of water, 8 parts of dilute sulfuric acid with a concentration of 10% by weight, 100 parts of light magnesium oxide and 0.9 part of zinc stearate, all Grinding to below 44 μm, 50 parts of talc powder, 1.5 parts of cellulose, 2 parts of urea-formaldehyde resin, 0.45 parts of resin, 0.45 parts of methyl ethyl ketone peroxide, 0.25 parts of oxalic acid, 1.6 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture .
取玻璃纤维丝铺设于平板上,厚度控制在1mm,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3mm,再在浆状混合物上铺覆玻璃纤维编织物层,相邻的玻璃纤维丝纹路纵横交错,如此反复操作4次,在铺覆最后一层玻璃纤维编织物层且浆状混合物完全凝固前加压至5MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料板。 Lay glass fiber filaments on a flat plate with a thickness of 1mm, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, and control the thickness of the brushing at 3mm, and then spread a glass fiber braid layer on the slurry mixture, Adjacent glass fiber threads are criss-crossed, and this operation is repeated 4 times. Before the last layer of glass fiber braid is laid and the slurry mixture is completely solidified, it is pressurized to 5MPa to form a glass fiber braid and slurry mixture. layered composite panels.
实施例13:按重量取:氯化镁50份,粉碎并与水30份混合,重量百分比浓度为5~12%的稀硫酸5~17份,轻质氧化镁80份和硬脂酸锌1.0份,均粉碎至38μm以下,38μm以下的花岗岩石粉35份,纤维素1份,脲醛树脂2.5份,树丁脂0.6份,过氧化甲乙酮0.48份,草酸0.28份,防水粉1.8份,将上述原料混合均匀得浆状混合物。 Embodiment 13: Take by weight: 50 parts of magnesium chloride, pulverized and mixed with 30 parts of water, 5 to 17 parts of dilute sulfuric acid with a concentration of 5 to 12% by weight, 80 parts of light magnesium oxide and 1.0 part of zinc stearate, All crushed to below 38 μm, 35 parts of granite stone powder below 38 μm, 1 part of cellulose, 2.5 parts of urea-formaldehyde resin, 0.6 part of resin, 0.48 parts of methyl ethyl ketone peroxide, 0.28 parts of oxalic acid, 1.8 parts of waterproof powder, mix the above raw materials evenly A slurry mixture was obtained.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在10mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作4次,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 10mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 4 times. , constitutes a layered composite member of a glass fiber braid and a slurry mixture.
实施例14:按重量取:氯化镁45份,粉碎并与水50份混合,重量百分比浓度为5%的稀硫酸10份,轻质氧化镁100份和硬脂酸锌1.0份,均粉碎至180μm以下,滑石粉40份,纤维素1份,脲醛树脂2份,树丁脂0.5份,过氧化甲乙酮50.5份,草酸0.2份,防水粉2份,将上述原料混合均匀得浆状混合物。 Example 14: Take by weight: 45 parts of magnesium chloride, pulverized and mixed with 50 parts of water, 10 parts of dilute sulfuric acid with a concentration of 5% by weight, 100 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 180 μm Next, 40 parts of talcum powder, 1 part of cellulose, 2 parts of urea-formaldehyde resin, 0.5 part of resin, 50.5 parts of methyl ethyl ketone peroxide, 0.2 parts of oxalic acid, 2 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作5次,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 5 times. , constitute a layered composite member of a glass fiber braid and a slurry mixture.
实施例15:按重量取:氯化镁45份,粉碎并与水45份混合,重量百分比浓度为10%的稀硫酸15份,轻质氧化镁100份和硬脂酸锌 0.8份,均粉碎至38μm以下,与滑石粉50份,纤维素1.5份,不饱和聚酯树脂1.5份,树丁脂0.3份,过氧化甲乙酮0.5份,草酸0.2份,防水粉1.5份,将上述原料混合均匀得浆状混合物。 Example 15: Take by weight: 45 parts of magnesium chloride, pulverized and mixed with 45 parts of water, 15 parts of dilute sulfuric acid with a concentration of 10% by weight, 100 parts of light magnesium oxide and 0.8 part of zinc stearate, all pulverized to 38 μm Below, with 50 parts of talcum powder, 1.5 parts of cellulose, 1.5 parts of unsaturated polyester resin, 0.3 parts of resin, 0.5 parts of methyl ethyl ketone peroxide, 0.2 parts of oxalic acid, 1.5 parts of waterproof powder, mix the above raw materials evenly to get a slurry mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在4mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作4次,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 4mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 4 times. , constitutes a layered composite member of a glass fiber braid and a slurry mixture.
实施例16:按重量取:氯化镁40份,粉碎并与水50份混合,重量百分比浓度为12%的稀硫酸10份,轻质氧化镁95份和硬脂酸锌1.0份,均粉碎至25μm以下,25μm以下的花岗岩石粉40份,纤维素1.5份,不饱和聚酯树脂1.5份,树丁脂0.6份,过氧化甲乙酮0.45份,草酸0.3份,防水粉2份,将上述原料混合均匀得浆状混合物。 Example 16: Take by weight: 40 parts of magnesium chloride, pulverized and mixed with 50 parts of water, 10 parts of dilute sulfuric acid with a concentration of 12% by weight, 95 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 25 μm Below, 40 parts of granite stone powder below 25 μm, 1.5 parts of cellulose, 1.5 parts of unsaturated polyester resin, 0.6 parts of resin, 0.45 parts of methyl ethyl ketone peroxide, 0.3 parts of oxalic acid, 2 parts of waterproof powder, mix the above raw materials evenly to obtain Paste mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作6次,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 6 times. , constitutes a layered composite member of a glass fiber braid and a slurry mixture.
实施例17:按重量取:氯化镁40份,粉碎并与水45份混合,重量百分比浓度为5%的稀硫酸15份,轻质氧化镁80份和硬脂酸锌1.0份,均粉碎至18μm以下,18μm以下的花岗岩石粉30份,纤维素0.75份,不饱和聚酯树脂1.5份,树丁脂0.3份,过氧化甲乙酮0.5份,草酸0.2份,防水粉1.5份,将上述原料混合均匀得浆状混合物。 Example 17: Take by weight: 40 parts of magnesium chloride, pulverized and mixed with 45 parts of water, 15 parts of dilute sulfuric acid with a concentration of 5% by weight, 80 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 18 μm Below, 30 parts of granite stone powder below 18 μm, 0.75 parts of cellulose, 1.5 parts of unsaturated polyester resin, 0.3 parts of resin, 0.5 parts of methyl ethyl ketone peroxide, 0.2 parts of oxalic acid, 1.5 parts of waterproof powder, mix the above raw materials evenly to obtain Paste mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在5mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作2次,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 5mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation twice. , constitutes a layered composite member of a glass fiber braid and a slurry mixture.
实施例18:按重量取:氯化镁48份,粉碎并与水35份混合,重量百分比浓度为12%的稀硫酸10份,轻质氧化镁85份和硬脂酸锌 0.8份,均粉碎至25μm以下,25μm以下的花岗岩石粉40份,纤维素1.2份,脲醛树脂2.2份,树丁脂0.5份,过氧化甲乙酮0.45份,草酸0.27份,防水粉1.75份,将上述原料混合均匀得浆状混合物。 Example 18: Take by weight: 48 parts of magnesium chloride, pulverized and mixed with 35 parts of water, 10 parts of dilute sulfuric acid with a concentration of 12% by weight, 85 parts of light magnesium oxide and 0.8 part of zinc stearate, all pulverized to 25 μm Below, 40 parts of granite stone powder below 25 μm, 1.2 parts of cellulose, 2.2 parts of urea-formaldehyde resin, 0.5 part of resin, 0.45 parts of methyl ethyl ketone peroxide, 0.27 parts of oxalic acid, 1.75 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture .
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在15mm,再在浆状混合物上铺覆玻璃纤维编织物层,在完全凝固前加压至5MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid. Press to 5MPa to solidify to form a layered composite member of a glass fiber braid and slurry mixture.
实施例19:按重量取:氯化镁45份,粉碎并与水30份混合,重量百分比浓度为6%的稀硫酸15份,轻质氧化镁100份和硬脂酸锌1.0份,均粉碎至149μm以下,149μm以下的花岗岩石粉35份,纤维素1份,脲醛树脂1.8份,树丁脂0.6份,过氧化甲乙酮0.5份,草酸0.2份,防水粉1.5份,将上述原料混合均匀得浆状混合物。 Example 19: Take by weight: 45 parts of magnesium chloride, pulverized and mixed with 30 parts of water, 15 parts of dilute sulfuric acid with a concentration of 6% by weight, 100 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 149 μm Below, 35 parts of granite stone powder below 149 μm, 1 part of cellulose, 1.8 parts of urea-formaldehyde resin, 0.6 part of resin, 0.5 part of methyl ethyl ketone peroxide, 0.2 part of oxalic acid, 1.5 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture .
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在20mm,再在浆状混合物上铺覆玻璃纤维编织物层,在完全凝固前加压至3MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 20mm, and then spread the glass fiber braid layer on the slurry mixture, and add it before it is completely solidified. Press to 3MPa to solidify to form a layered composite member of a glass fiber braid and slurry mixture.
实施例20:按重量取:氯化镁50份,粉碎并与水50份混合,重量百分比浓度为5%的稀硫酸17份,轻质氧化镁80份和硬脂酸锌 0.7份,均粉碎至180μm以下,180μm以下的花岗岩石粉45份,纤维素1.5份,不饱和聚酯树脂2.5份,树丁脂0.6份,过氧化甲乙酮0.45份,草酸0.2份,防水粉1.5,将上述原料混合均匀得浆状混合物。 Example 20: Take by weight: 50 parts of magnesium chloride, pulverized and mixed with 50 parts of water, 17 parts of dilute sulfuric acid with a concentration of 5% by weight, 80 parts of light magnesium oxide and 0.7 part of zinc stearate, all pulverized to 180 μm Below, 45 parts of granite stone powder below 180 μm, 1.5 parts of cellulose, 2.5 parts of unsaturated polyester resin, 0.6 parts of resin, 0.45 parts of methyl ethyl ketone peroxide, 0.2 parts of oxalic acid, 1.5 parts of waterproof powder, mix the above raw materials evenly to obtain slurry shape mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在15mm,再在浆状混合物上铺覆玻璃纤维编织物层,在完全凝固前加压至3MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid. Press to 3MPa to solidify to form a layered composite member of a glass fiber braid and slurry mixture.
实施例21:按重量取:氯化镁44份,粉碎并与水45份混合,重量百分比浓度为8%的稀硫酸15份,轻质氧化镁100份和硬脂酸锌 0.7份,均粉碎至180μm以下,滑石粉40份,纤维素1.25份,不饱和聚酯树脂2.25份,树丁脂0.35份,过氧化甲乙酮0.49份,草酸0.28份,防水粉1.8份,将上述原料混合均匀得浆状混合物。 Example 21: Take by weight: 44 parts of magnesium chloride, pulverized and mixed with 45 parts of water, 15 parts of dilute sulfuric acid with a concentration of 8% by weight, 100 parts of light magnesium oxide and 0.7 part of zinc stearate, all pulverized to 180 μm Below, 40 parts of talcum powder, 1.25 parts of cellulose, 2.25 parts of unsaturated polyester resin, 0.35 parts of resin, 0.49 parts of methyl ethyl ketone peroxide, 0.28 parts of oxalic acid, 1.8 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture .
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在10mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作1次,在完全凝固前加压至3MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 10mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation once , pressurized to 3MPa solidified before complete solidification, constituting a layered composite member of glass fiber braid and slurry mixture.
实施例22:按重量取:氯化镁46份,粉碎并与水40份混合,重量百分比浓度为12%的稀硫酸15份,轻质氧化镁100份和硬脂酸锌1.0份,均粉碎至150μm以下,滑石粉50份,纤维素1.1份,不饱和聚酯树脂2.1份,树丁脂0.4份,过氧化甲乙酮0.47份,草酸0.26份,防水粉1.7份,将上述原料混合均匀得浆状混合物。 Example 22: Take by weight: 46 parts of magnesium chloride, pulverized and mixed with 40 parts of water, 15 parts of dilute sulfuric acid with a concentration of 12% by weight, 100 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 150 μm Below, 50 parts of talcum powder, 1.1 parts of cellulose, 2.1 parts of unsaturated polyester resin, 0.4 parts of resin, 0.47 parts of methyl ethyl ketone peroxide, 0.26 parts of oxalic acid, 1.7 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture .
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在7mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作1次,在完全凝固前加压至5MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 7mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation once , pressurized to 5MPa solidified before complete solidification to form a layered composite member of a glass fiber braid and slurry mixture.
实施例23:按重量取:氯化镁45份,粉碎并与水35份混合,重量百分比浓度为9%的稀硫酸15份,轻质氧化镁100份和硬脂酸锌 0.8份,均粉碎至108μm以下,滑石粉40份,纤维素1.5份,不饱和聚酯树脂2.4份,树丁脂0.45份,过氧化甲乙酮0.45份,草酸0.25份,防水粉1.7份,将上述原料混合均匀得浆状混合物。 Example 23: Take by weight: 45 parts of magnesium chloride, pulverized and mixed with 35 parts of water, 15 parts of dilute sulfuric acid with a concentration of 9% by weight, 100 parts of light magnesium oxide and 0.8 part of zinc stearate, all pulverized to 108 μm Below, 40 parts of talcum powder, 1.5 parts of cellulose, 2.4 parts of unsaturated polyester resin, 0.45 parts of resin, 0.45 parts of methyl ethyl ketone peroxide, 0.25 parts of oxalic acid, 1.7 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture .
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在5mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作4次,在完全凝固前加压至10MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 5mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 4 times. , pressurized to 10MPa before complete solidification to form a layered composite member of a glass fiber braid and slurry mixture.
实施例24:按重量取:氯化镁40份,粉碎并与水50份混合,重量百分比浓度为5%的稀硫酸17份,轻质氧化镁100份和硬脂酸锌1.0份,均粉碎至100μm以下,滑石粉50份,纤维素1.0份,不饱和聚酯树脂2.0份,树丁脂0.5份,过氧化甲乙酮0.5份,草酸0.25份,防水粉1.6份,将上述原料混合均匀得浆状混合物。 Example 24: Take by weight: 40 parts of magnesium chloride, pulverized and mixed with 50 parts of water, 17 parts of dilute sulfuric acid with a concentration of 5% by weight, 100 parts of light magnesium oxide and 1.0 part of zinc stearate, all pulverized to 100 μm Below, 50 parts of talcum powder, 1.0 part of cellulose, 2.0 parts of unsaturated polyester resin, 0.5 part of resin, 0.5 part of methyl ethyl ketone peroxide, 0.25 part of oxalic acid, 1.6 parts of waterproof powder, mix the above raw materials evenly to obtain a slurry mixture .
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在5mm,再在浆状混合物上铺覆玻璃纤维编织物层,如此反复操作3次,在完全凝固前加压至8MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 5mm, and then spread the glass fiber braid layer on the slurry mixture, and repeat the operation 3 times. , pressurized to 8MPa before complete solidification to form a layered composite member of glass fiber braid and slurry mixture.
实施例25:按重量取:氯化镁40份,粉碎至1mm以下并与水50份混合,重量百分比浓度为10%的稀硫酸15份,轻质氧化镁100份和硬脂酸锌 0.85份,均粉碎至44μm以下,滑石粉40份,纤维素1.8份,脲醛树脂2份,树丁脂0. 5份,过氧化甲乙酮0.5份,草酸0.28份,防水粉1.75份,将上述原料混合均匀得浆状混合物。 Example 25: Take by weight: 40 parts of magnesium chloride, crushed to below 1 mm and mixed with 50 parts of water, 15 parts of dilute sulfuric acid with a concentration of 10% by weight, 100 parts of light magnesium oxide and 0.85 part of zinc stearate, all Grinding to below 44 μm, 40 parts of talcum powder, 1.8 parts of cellulose, 2 parts of urea-formaldehyde resin, 0.5 part of resin, 0.5 part of methyl ethyl ketone peroxide, 0.28 part of oxalic acid, 1.75 parts of waterproof powder, mix the above raw materials evenly to obtain slurry shape mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3mm,再在浆状混合物上铺覆玻璃纤维丝层,玻璃纤维丝层上再均匀涂刷浆状混合物层,如此反复操作5次且相邻的玻璃纤维丝纹路纵横交错,在最后一层浆状混合物上再覆盖一层玻璃纤维布,在浆状混合物完全凝固前加压至5MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3mm, and then lay a glass fiber layer on the slurry mixture, and then coat the glass fiber layer. Apply the slurry mixture layer evenly, repeat this operation 5 times and the adjacent glass fiber filaments are criss-crossed, cover the last layer of slurry mixture with a layer of glass fiber cloth, and pressurize until the slurry mixture is completely solidified. 5MPa solid, constitutes a layered composite member of a glass fiber braid and paste mixture.
实施例26:按重量取:氯化镁42份,粉碎至1mm以下并与水50份混合,重量百分比浓度为8%的稀硫酸17份,轻质氧化镁100份和硬脂酸锌 0.75份,均粉碎至38μm以下,滑石粉40份,纤维素1.8份,脲醛树脂2份,树丁脂0.6份,过氧化甲乙酮0.5份,草酸0.25份,防水粉1. 5份,将上述原料混合均匀得浆状混合物。 Example 26: Take by weight: 42 parts of magnesium chloride, crushed to below 1mm and mixed with 50 parts of water, 17 parts of dilute sulfuric acid with a concentration of 8% by weight, 100 parts of light magnesium oxide and 0.75 parts of zinc stearate, all Grinding to below 38 μm, 40 parts of talcum powder, 1.8 parts of cellulose, 2 parts of urea-formaldehyde resin, 0.6 part of resin, 0.5 part of methyl ethyl ketone peroxide, 0.25 part of oxalic acid, 1.5 parts of waterproof powder, mix the above raw materials evenly to obtain slurry shape mixture.
取玻璃纤维布铺设于模具中,将上述浆状混合物均匀涂刷于玻璃纤维编织物上,涂刷厚度控制在3mm,再在浆状混合物上铺覆玻璃纤维丝层,玻璃纤维丝层上再均匀涂刷浆状混合物层,如此反复操作3次且相邻的玻璃纤维丝纹路纵横交错,在最后一层浆状混合物上再覆盖一层玻璃纤维布,在浆状混合物完全凝固前加压至5MPa固型,构成玻璃纤维编织物与浆状混合物的层状复合材料构件。 Take the glass fiber cloth and lay it in the mold, and evenly brush the above-mentioned slurry mixture on the glass fiber braid, the thickness of the brushing is controlled at 3mm, and then lay a glass fiber layer on the slurry mixture, and then coat the glass fiber layer. Apply the paste mixture layer evenly, repeat the operation 3 times and the adjacent glass fiber filaments are criss-crossed, cover the last layer of paste mixture with a layer of glass fiber cloth, and pressurize until the paste mixture is completely solidified. 5MPa solid, constitutes a layered composite member of a glass fiber braid and paste mixture.
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CN1078448A (en) * | 1993-05-28 | 1993-11-17 | 广元市中区川北贸易公司 | Magnesite cement composite plate |
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CN1169402A (en) * | 1996-06-26 | 1998-01-07 | 吴新疆 | Fire-retardant, moist-proof board and production method thereof |
CN1900006A (en) * | 2005-07-18 | 2007-01-24 | 山东理工大学 | Magnesium oxychloride composite material and pteparing process |
CN101003990A (en) * | 2006-01-18 | 2007-07-25 | 杭州优斯达新型建材有限公司 | Environmental protective type inorganic, composite non-combustible plates, and manufacturing method |
CN101070729A (en) * | 2006-05-13 | 2007-11-14 | 蔡祖树 | Multifunction formboard |
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CN1078448A (en) * | 1993-05-28 | 1993-11-17 | 广元市中区川北贸易公司 | Magnesite cement composite plate |
CN1100033A (en) * | 1994-07-08 | 1995-03-15 | 陈雪海 | Artificial wood board and its producing method |
CN1169402A (en) * | 1996-06-26 | 1998-01-07 | 吴新疆 | Fire-retardant, moist-proof board and production method thereof |
CN1900006A (en) * | 2005-07-18 | 2007-01-24 | 山东理工大学 | Magnesium oxychloride composite material and pteparing process |
CN101003990A (en) * | 2006-01-18 | 2007-07-25 | 杭州优斯达新型建材有限公司 | Environmental protective type inorganic, composite non-combustible plates, and manufacturing method |
CN101070729A (en) * | 2006-05-13 | 2007-11-14 | 蔡祖树 | Multifunction formboard |
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