CN103011438A - Non-toxic and non-pollution water quality purification material - Google Patents
Non-toxic and non-pollution water quality purification material Download PDFInfo
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- CN103011438A CN103011438A CN2012105954680A CN201210595468A CN103011438A CN 103011438 A CN103011438 A CN 103011438A CN 2012105954680 A CN2012105954680 A CN 2012105954680A CN 201210595468 A CN201210595468 A CN 201210595468A CN 103011438 A CN103011438 A CN 103011438A
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- 239000000463 material Substances 0.000 title claims abstract description 51
- 238000000746 purification Methods 0.000 title claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 231100000252 nontoxic Toxicity 0.000 title claims abstract description 9
- 230000003000 nontoxic effect Effects 0.000 title claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000004576 sand Substances 0.000 claims abstract description 17
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 15
- 239000011572 manganese Substances 0.000 claims abstract description 15
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000010457 zeolite Substances 0.000 claims abstract description 14
- 239000004575 stone Substances 0.000 claims abstract description 12
- 241000195493 Cryptophyta Species 0.000 claims abstract description 3
- 229910000365 copper sulfate Inorganic materials 0.000 claims abstract description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000011347 resin Substances 0.000 claims abstract description 3
- 229920005989 resin Polymers 0.000 claims abstract description 3
- 239000011435 rock Substances 0.000 claims description 14
- 229960000892 attapulgite Drugs 0.000 claims description 13
- 229910052625 palygorskite Inorganic materials 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
- 239000010433 feldspar Substances 0.000 claims 3
- 229940072033 potash Drugs 0.000 claims 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 3
- 235000015320 potassium carbonate Nutrition 0.000 claims 3
- 235000019580 granularity Nutrition 0.000 claims 1
- 239000010865 sewage Substances 0.000 abstract description 10
- 239000002245 particle Substances 0.000 abstract description 9
- 241000282414 Homo sapiens Species 0.000 abstract description 6
- 241000251468 Actinopterygii Species 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000011021 lapis lazuli Substances 0.000 abstract 2
- 239000011022 opal Substances 0.000 abstract 2
- 239000010451 perlite Substances 0.000 abstract 2
- 235000019362 perlite Nutrition 0.000 abstract 2
- 239000002023 wood Substances 0.000 abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 abstract 1
- 229910001603 clinoptilolite Inorganic materials 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 10
- 229910052652 orthoclase Inorganic materials 0.000 description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 229910052785 arsenic Inorganic materials 0.000 description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- OWTFKEBRIAXSMO-UHFFFAOYSA-N arsenite(3-) Chemical compound [O-][As]([O-])[O-] OWTFKEBRIAXSMO-UHFFFAOYSA-N 0.000 description 3
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical compound [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229940000489 arsenate Drugs 0.000 description 2
- -1 arsenate ions Chemical class 0.000 description 2
- 150000001495 arsenic compounds Chemical class 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 229940093920 gynecological arsenic compound Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 208000008316 Arsenic Poisoning Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 208000026889 Cell metabolism disease Diseases 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 208000018522 Gastrointestinal disease Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- 208000001647 Renal Insufficiency Diseases 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229940006020 arsenite ion Drugs 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 201000006370 kidney failure Diseases 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
Abstract
本发明公开了一种无毒无污染水质净化材料，所述水质净化材料由非金属矿岩物料蛋白石、斜发沸石、天青石、木鱼石、麦饭石、珍珠岩、锰砂、紫砂、及载银活性炭组成，各种矿岩物料以不同的粒度和不同的料层厚度分层铺设或混配组成。所述的各种矿岩物料的适用粒度范围为：蛋白石、沸石、麦饭石、天青石、木鱼石、珍珠岩、锰砂、活性炭皆为5-60目，紫砂20目以上。本发明水质净化材料代替传统使用的由海流石、毛石、交换树脂、活性炭、硫酸铜、藻类等水净化材料，不但使水质提高，达到国家标准要求，而且降低净化费用本发明可滤除水中对人体有害的物质，代替传统使用的净化滤料，提高了水质和工业污水净化度。The invention discloses a non-toxic and pollution-free water purification material, which is composed of non-metallic ore materials such as opal, clinoptilolite, lapis lazuli, wood fish stone, medical stone, perlite, manganese sand, purple sand, and It is composed of silver-loaded activated carbon, and various ore materials are layered or mixed with different particle sizes and different material layer thicknesses. The applicable particle size ranges of the various ore materials are: opal, zeolite, medical stone, lapis lazuli, wood fish stone, perlite, manganese sand, and activated carbon are all 5-60 mesh, and purple sand is above 20 mesh. The water purification material of the present invention replaces the traditionally used water purification materials such as sea stone, rubble, exchange resin, activated carbon, copper sulfate, algae, etc., which not only improves the water quality and meets the requirements of national standards, but also reduces the purification cost. The present invention can filter out water Substances harmful to the human body, instead of the traditionally used purification filter material, improve the water quality and the purification degree of industrial sewage.
Description
技术领域technical field
本发明涉及一种多种天然矿物组成的水净化材料，具体地说是一种无毒无污染水质净化材料。The invention relates to a water purification material composed of various natural minerals, in particular to a non-toxic and pollution-free water purification material.
背景技术Background technique
近年来，随着经济的发展，工农业的进步，随之带来的是对人类生存环境的破坏，对自然的破坏。各种产品的生产和运用中伴随的副产品导致对环境的污染已经到了很严重的地步。人类赖以生存的淡水资源的污染也日益加重。水污染中，砷的污染已经引起了广泛的关注。水中砷的主要存在形态是亚砷酸根离子和砷酸根离子。在水体的表层，以亚砷酸根形式存在的砷常常被氧化成砷酸根。亚砷酸根和砷酸根离子进入土壤，即与土壤中的铁、铝、钙、镁等离子作用生成难溶性的砷化合物累积于土壤表层。冶金工业、玻璃陶瓷、制革、染料和杀虫剂生产的废水中都含有砷或砷的化合物。砷中毒还会引起细胞代谢紊乱、肠胃道失常、肾衰退等。另外，饮用水中的氟污染也越来越受到关注，当氟离子的浓度达到一定量时，对人体的危害很大，同时也会破坏环境中的土壤质量，还可能导致人类和自然界生物的中毒，所以，有待寻求新的水净化技术和质优价廉的水净化材料。In recent years, with the development of the economy and the progress of industry and agriculture, it has brought about the destruction of the living environment of human beings and the destruction of nature. The by-products accompanying the production and use of various products have caused serious environmental pollution. The pollution of fresh water resources that human beings depend on is also increasing day by day. Among water pollution, arsenic pollution has attracted widespread attention. The main forms of arsenic in water are arsenite ion and arsenate ion. At the surface of water bodies, arsenic in the form of arsenite is often oxidized to arsenate. Arsenite and arsenate ions enter the soil, that is, react with iron, aluminum, calcium, magnesium and other ions in the soil to form insoluble arsenic compounds and accumulate on the soil surface. Wastewater from metallurgical industry, glass ceramics, tanning, dyestuffs and pesticide production all contain arsenic or arsenic compounds. Arsenic poisoning can also cause cell metabolism disorders, gastrointestinal disorders, and kidney failure. In addition, the fluoride pollution in drinking water has also attracted more and more attention. When the concentration of fluoride ions reaches a certain amount, it will cause great harm to the human body, and it will also damage the soil quality in the environment, and may also cause human and natural organisms Poisoning, so, to seek new water purification technology and water purification materials of high quality and low price.
发明内容Contents of the invention
本发明的目的在于提供一种以火山石、沸石、正长石、凹凸棒土、锰砂、及载铜活性炭组成，各种矿岩物料以不同的粒度和不同的料层厚度分层铺设或混配组成的水质净化材料。用于滤除水中对人体和环境有害的物质及杂质，提高水源水质或净化工业污水。The object of the present invention is to provide a kind of volcanic stone, zeolite, orthoclase, attapulgite, manganese sand, and copper-loaded activated carbon, and various ore materials are layered or laid with different particle sizes and different material layer thicknesses. A water purification material composed of a mixture. It is used to filter out substances and impurities harmful to human body and environment in water, improve water quality of water sources or purify industrial sewage.
本发明的目的是这样实现的：在水净化或工厂污水处理的净化设备、净化池中，将加工成不同粒度的矿岩主料和辅料按不同厚度自上而下分层铺设或将主料辅料混合均匀铺设。The purpose of the present invention is achieved in this way: in the purification equipment and purification tanks of water purification or factory sewage treatment, the ore main materials and auxiliary materials processed into different particle sizes are layered from top to bottom according to different thicknesses or the main materials The auxiliary materials are mixed and laid evenly.
所述的水质净化材料由火山石、沸石、正长石、凹凸棒土、锰砂、及载铜活性炭组成，各种矿岩物料以不同的粒度和不同的料层厚度分层铺设或混配组成。The water purification material is composed of volcanic stone, zeolite, orthoclase, attapulgite, manganese sand, and copper-loaded activated carbon. Various ore materials are layered or mixed with different particle sizes and different material layer thicknesses. composition.
所述的各种矿岩物料的适用粒度范围为：火山石、正长石、沸石、凹凸棒土、及载铜活性炭皆为5-60目，锰砂20目以上。The applicable particle size ranges of the various ore materials are: volcanic rock, orthoclase, zeolite, attapulgite, and copper-loaded activated carbon are all 5-60 mesh, and manganese sand is more than 20 mesh.
所述的各种矿岩物料适用重量配比范围为：火山石30-55％，沸石25-45％，正长石1-2％，凹凸棒土5-10％，锰砂1-5％，活性炭1-10％。The applicable weight ratio range of the various ore materials is: 30-55% of volcanic rock, 25-45% of zeolite, 1-2% of orthoclase, 5-10% of attapulgite, and 1-5% of manganese sand , activated carbon 1-10%.
所述的无毒无污染水质净化材料代替传统使用的由海流石、毛石、交换树脂、活性炭、硫酸铜、藻类等水净化材料。The non-toxic and non-polluting water purification material replaces the traditionally used water purification materials such as sea stone, rubble, exchange resin, activated carbon, copper sulfate, and algae.
本发明的特点：Features of the present invention:
(1)不但使水质提高，达到国家标准要求，而且降低净化费用；(1) It not only improves the water quality to meet the national standard requirements, but also reduces the purification cost;
(2)避免了传统方法净化的水中的气味；(2) the odor in the water purified by traditional methods is avoided;
(3)不但可用于水源提高水质、工业污水处理，并可用于生产优质饮水，还可用于养鱼池、游泳池等场合的水净化。(3) It can not only be used to improve water quality and industrial sewage treatment, but also can be used to produce high-quality drinking water, and can also be used for water purification in fish ponds, swimming pools and other occasions.
具体实施方式Detailed ways
实例1Example 1
在水净化或工厂污水处理的净化设备、净化池中，将加工成不同粒度的矿岩主料(火山石、正长石、沸石、凹凸棒土、及载铜活性炭皆为50目，锰砂20目以上。)和辅料按不同重量比(火山石30％，沸石25％，正长石1％，凹凸棒土5％，锰砂1％，活性炭1％。)自上而下分层铺设或将主料辅料混合均匀铺设后，将此水质净化材料投入到50mg/L的污水中，充分接触20min后，水质净化效率达到99.9％。In the purification equipment and purification tanks of water purification or factory sewage treatment, the main materials of ore rocks with different particle sizes (volcanic rock, orthoclase, zeolite, attapulgite, and copper-loaded activated carbon are all 50 mesh, manganese sand 20 mesh or more.) and auxiliary materials according to different weight ratios (30% volcanic stone, 25% zeolite, 1% orthoclase, 5% attapulgite, 1% manganese sand, 1% activated carbon.) Layered from top to bottom Or after mixing the main materials and auxiliary materials evenly and laying them, put this water purification material into 50mg/L sewage, and after fully contacting for 20 minutes, the water purification efficiency will reach 99.9%.
实例2Example 2
在水净化或工厂污水处理的净化设备、净化池中，将加工成不同粒度的矿岩主料(火山石、正长石、沸石、凹凸棒土、及载铜活性炭皆为60目，锰砂20目以上。)和辅料按不同重量比(火山石55％，沸石45％，正长石2％，凹凸棒土10％，锰砂5％，活性炭10％。)自上而下分层铺设或将主料辅料混合均匀铺设后，将此水质净化材料投入到50mg/L的污水中，充分接触30min后，水质净化效率达到99.9％。In the purification equipment and purification pools of water purification or factory sewage treatment, the main materials of ore rocks with different particle sizes (volcanic rock, orthoclase, zeolite, attapulgite, and copper-loaded activated carbon are all 60 mesh, manganese sand 20 mesh or more.) and auxiliary materials according to different weight ratios (55% volcanic stone, 45% zeolite, 2% orthoclase, 10% attapulgite, 5% manganese sand, 10% activated carbon.) Layered from top to bottom Or after mixing the main materials and auxiliary materials evenly and laying them, put this water purification material into 50mg/L sewage, and after fully contacting for 30 minutes, the water purification efficiency will reach 99.9%.
实例3Example 3
在水净化或工厂污水处理的净化设备、净化池中，将加工成不同粒度的矿岩主料(火山石、正长石、沸石、凹凸棒土、及载铜活性炭皆为40目，锰砂20目以上。)和辅料按不同重量比(火山石40％，沸石30％，正长石2％，凹凸棒土8％，锰砂4％，活性炭7％。)自上而下分层铺设或将主料辅料混合均匀铺设后，将此水质净化材料投入到50mg/L的污水中，充分接触25min后，水质净化效率达到99.9％。In the purification equipment and purification tanks of water purification or factory sewage treatment, the main materials of ore rocks with different particle sizes (volcanic rock, orthoclase, zeolite, attapulgite, and copper-loaded activated carbon are all 40 mesh, manganese sand 20 mesh or more.) and auxiliary materials according to different weight ratios (40% volcanic stone, 30% zeolite, 2% orthoclase, 8% attapulgite, 4% manganese sand, 7% activated carbon.) Layered from top to bottom Or after mixing the main materials and auxiliary materials evenly, put this water purification material into 50mg/L sewage, and after fully contacting for 25 minutes, the water purification efficiency will reach 99.9%.
Claims (4)
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Cited By (5)
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| CN106966460A (en) * | 2017-05-27 | 2017-07-21 | 刘华文 | Water quality treater |
| CN106986436A (en) * | 2017-05-27 | 2017-07-28 | 刘华文 | A kind of hot water water quality treater |
| CN107837786A (en) * | 2017-10-25 | 2018-03-27 | 江苏省宜兴中等专业学校 | A kind of high concentration heavy metal adsorption filtrate |
| CN109437872A (en) * | 2018-12-22 | 2019-03-08 | 洛阳脉渡文化传播有限公司 | A kind of medical stone mud embryo and preparation method |
| CN115636511A (en) * | 2022-08-29 | 2023-01-24 | 宁夏农林科学院农业资源与环境研究所（宁夏土壤与植物营养重点实验室） | Attapulgite adsorption combined ecological floating bed and water quality purification method thereof |
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| CN106966460A (en) * | 2017-05-27 | 2017-07-21 | 刘华文 | Water quality treater |
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| CN107837786A (en) * | 2017-10-25 | 2018-03-27 | 江苏省宜兴中等专业学校 | A kind of high concentration heavy metal adsorption filtrate |
| CN109437872A (en) * | 2018-12-22 | 2019-03-08 | 洛阳脉渡文化传播有限公司 | A kind of medical stone mud embryo and preparation method |
| CN115636511A (en) * | 2022-08-29 | 2023-01-24 | 宁夏农林科学院农业资源与环境研究所（宁夏土壤与植物营养重点实验室） | Attapulgite adsorption combined ecological floating bed and water quality purification method thereof |
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| CN103011438B (en) | 2014-07-09 |
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