CN103011371A - Method for removing germanium in sewage - Google Patents
Method for removing germanium in sewage Download PDFInfo
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- CN103011371A CN103011371A CN2012105954661A CN201210595466A CN103011371A CN 103011371 A CN103011371 A CN 103011371A CN 2012105954661 A CN2012105954661 A CN 2012105954661A CN 201210595466 A CN201210595466 A CN 201210595466A CN 103011371 A CN103011371 A CN 103011371A
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- Prior art keywords
- add
- germanium
- water
- stir
- flask
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- 229910052732 germanium Inorganic materials 0.000 title claims abstract description 24
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 15
- 239000010865 sewage Substances 0.000 title claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002351 wastewater Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims abstract description 10
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- GNHOJBNSNUXZQA-UHFFFAOYSA-J potassium aluminium sulfate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GNHOJBNSNUXZQA-UHFFFAOYSA-J 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims abstract 2
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 claims abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- 239000002699 waste material Substances 0.000 claims description 10
- 239000000376 reactant Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000001556 precipitation Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 3
- 150000004706 metal oxides Chemical class 0.000 abstract description 3
- 239000010802 sludge Substances 0.000 abstract description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Removal Of Specific Substances (AREA)
Abstract
本发明公开了一种去除污水中锗的方法，属于环境保护中污水处理领域。本发明取三氧化铝置于三角圆底烧瓶中；向烧瓶加入十二水硫酸铝钾、硫酸镁、水；加温，并不断搅拌，当温度上升时加入铝酸钙粉；在向上述反应物中加入三氯化铁和十八烷基三甲基溴化铵搅拌混合均匀；取上述物质加入到含锗的废水中搅拌、静置、沉淀、出水排入清水池中即可。本发明具有工艺流程简单，操作简单，运行费用较低，无污泥产生，除锗效果高等，无沉淀产生，不会引起二次污染，且出水和废水中的金属氧化物均可回收利用。The invention discloses a method for removing germanium in sewage, which belongs to the field of sewage treatment in environmental protection. The present invention gets aluminum oxide and places triangular round-bottomed flask; Add aluminum potassium sulfate dodecahydrate, magnesium sulfate, water to flask; Heat, and constantly stir, add calcium aluminate powder when temperature rises; Add ferric chloride and octadecyltrimethylammonium bromide to the mixture and stir to mix evenly; take the above substances and add them to germanium-containing wastewater for stirring, let stand, settle, and discharge the water into a clear water pool. The invention has the advantages of simple process flow, simple operation, low operating cost, no sludge generation, high germanium removal effect, no precipitation, no secondary pollution, and metal oxides in effluent and waste water can be recycled.
Description
Technical field
The present invention relates to a kind of method of removing germanium in the sewage, particularly process the waste water of germanium concentration in 10～100mg/L scope, belong to field of waste water treatment in the environment protection.
Background technology
The discharging that contains heavy metal germanium waste water has serious harm to HUMAN HEALTH and industrial or agricultural activity, have the harm such as persistence, toxicity be large, seriously polluted, in case can not be biodegradable behind the entered environment, great majority participate in the food chain circulation, and finally in vivo accumulation, destroy organism normal physiological Metabolic activity, be detrimental to health.Along with the day by day increase of the mankind to activities in production such as the exploitation of heavy metal, smelting, processing, the heavy metal germanium waste water of generation is all greatly to increase in quantity or on the kind, has caused serious environmental pollution and the wasting of resources.Therefore the improvement that contains heavy metal germanium waste water is still a problems to be solved in world's field of Environment Protection.Notification number is that CN86106414 discloses the method that a kind of electrolytic process is processed germanic waste water, and the water quality after the method is processed is good, recyclable germanium, and occupation area of equipment is large, and technical process is complicated, one-time investment is high.
Summary of the invention
The objective of the invention is provides a kind of method of removing germanium in the sewage for overcoming the deficiencies in the prior art, and this invented technology flow process is simple, running cost is low, and obvious processing effect produces without precipitation, can not cause secondary pollution, and the equal recoverable of the metal oxide in water outlet and the waste water.
Concrete treatment step of the present invention is:
(1) getting the alchlor mass content is that waste hydrochloric acid 100～120mL of 10～17% places 500mL triangle round-bottomed flask, and described waste hydrochloric acid acidity is that 10.5%, pH is 1.0～1.5;
(2) add 5～10g Potassium aluminum sulfate dodecahydrate, 6～8g sal epsom, 50～68g water to flask;
(3) heat, and constantly stir, when temperature rises to 68 ℃, add 50～60g calcium aluminate powder;
(4) continue to heat up, reaction is 4～5 hours when temperature rises to 110 ℃～115 ℃;
(5) in above-mentioned reactant, adding 5～10g iron trichloride and 6～9g Cetyltrimethylammonium bromide, mix;
(6) get above-mentioned substance and join in the germanic waste water, the amount of adding is 100～150mg/L, and rapid stirring 10 minutes slowly stirred 30～45 minutes again, leave standstill, and precipitation, water outlet is drained in the clean water basin.
Application method of the present invention is: get alchlor and place the triangle round-bottomed flask; Add Potassium aluminum sulfate dodecahydrate, sal epsom, water to flask; Heat, and constantly stir, when temperature rises, add calcium aluminate powder; Mix at adding iron trichloride and Cetyltrimethylammonium bromide in above-mentioned reactant; Get above-mentioned substance join in the germanic waste water stir, leave standstill, precipitation, water outlet enter in the clean water basin and get final product.
The invention has the beneficial effects as follows: it is simple that the present invention has technical process, simple to operate, and working cost is lower, high except the germanium effect without sludge creation, produces without precipitation, can not cause secondary pollution, and the equal recoverable of the metal oxide in water outlet and the waste water.
Embodiment
Enforcement case row 1:
(1) getting the alchlor mass content is that 10% waste hydrochloric acid 100mL places 500mL triangle round-bottomed flask, and described waste hydrochloric acid acidity is that 10.5%, pH is 1.0;
(2) add 5g Potassium aluminum sulfate dodecahydrate, 6g sal epsom, 50g water to flask;
(3) heat, and constantly stir, when temperature rises to 68 ℃, add the 50g calcium aluminate powder;
(4) continue to heat up, reaction is 4 hours when temperature rises to 110 ℃;
(5) in above-mentioned reactant, adding 5g iron trichloride and 6g Cetyltrimethylammonium bromide, mix;
(6) getting above-mentioned substance joins in the germanic waste water of 30mg/L, the amount that above-mentioned substance adds is 100mg/L, rapid stirring 10 minutes, slowly stirred again 30 minutes, leave standstill, precipitation, water outlet is drained in the clean water basin, the resulting germanium that removes in the germanium waste water drops to 0.55mg/L, and the germanium clearance has reached 98.16%.
Enforcement case row 2:
(1) getting the alchlor mass content is that 14% waste hydrochloric acid 110mL places 500mL triangle round-bottomed flask, and described waste hydrochloric acid acidity is that 10.5%, pH is 1.2;
(2) add 8g Potassium aluminum sulfate dodecahydrate, 7g sal epsom, 58g water to flask;
(3) heat, and constantly stir, when temperature rises to 68 ℃, add the 55g calcium aluminate powder;
(4) continue to heat up, reaction is 4.5 hours when temperature rises to 113 ℃;
(5) in above-mentioned reactant, adding 7g iron trichloride and 8g Cetyltrimethylammonium bromide, mix;
(6) getting above-mentioned substance joins in the germanic waste water of 75mg/L, the amount that above-mentioned substance adds is 125mg/L, rapid stirring 10 minutes, slowly stirred again 35 minutes, leave standstill, precipitation, water outlet is drained in the clean water basin, the resulting germanium that removes in the germanium waste water drops to 1.35mg/L, and the germanium clearance has reached 99.71%.
Enforcement case row 3:
(1) getting the alchlor mass content is that 17% waste hydrochloric acid 120mL places 500mL triangle round-bottomed flask, and described waste hydrochloric acid acidity is that 10.5%, pH is 1.5;
(2) add 10g Potassium aluminum sulfate dodecahydrate, 8g sal epsom, 68g water to flask;
(3) heat, and constantly stir, when temperature rises to 68 ℃, add the 60g calcium aluminate powder;
(4) continue to heat up, reaction is 5 hours when temperature rises to 115 ℃;
(5) in above-mentioned reactant, adding 10g iron trichloride and 9g Cetyltrimethylammonium bromide, mix;
(6) getting above-mentioned substance joins in the germanic waste water of 100mg/L, the amount that above-mentioned substance adds is 150mg/L, rapid stirring 10 minutes, slowly stirred again 45 minutes, leave standstill, precipitation, water outlet is drained in the clean water basin, the resulting germanium that removes in the germanium waste water drops to 1.55mg/L, and the germanium clearance has reached 98.45%.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105954661A CN103011371A (en) | 2012-12-07 | 2012-12-07 | Method for removing germanium in sewage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105954661A CN103011371A (en) | 2012-12-07 | 2012-12-07 | Method for removing germanium in sewage |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103011371A true CN103011371A (en) | 2013-04-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105954661A Pending CN103011371A (en) | 2012-12-07 | 2012-12-07 | Method for removing germanium in sewage |
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| CN (1) | CN103011371A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103420522A (en) * | 2013-08-28 | 2013-12-04 | 中锗科技有限公司 | Method for circulating purification recycling of sewage with germanium simple-substance particles |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1385373A (en) * | 2001-05-15 | 2002-12-18 | 中国科学院南京土壤研究所 | Coagulant for sewage treatment |
| CN101327976A (en) * | 2008-07-15 | 2008-12-24 | 南通立源水处理技术有限公司 | High-efficiency water treatment flocculant |
| CN101885526A (en) * | 2009-05-16 | 2010-11-17 | 兰州大欣水工业有限责任公司 | Ternary composite type flocculant, preparation and application |
| JP4591695B2 (en) * | 2005-07-12 | 2010-12-01 | 株式会社日立プラントテクノロジー | Method for treating wastewater containing phosphoric acid and zinc |
| CN102010045A (en) * | 2010-11-19 | 2011-04-13 | 杭州电子科技大学 | Preparation method for polysilicate-metal flocculant containing titanium |
| CN102531126A (en) * | 2012-01-09 | 2012-07-04 | 南京大学 | Method for treating papermaking black liquor with composite coagulation method |
| CN102633338A (en) * | 2012-04-28 | 2012-08-15 | 江苏双净净化科技有限公司 | PVA (polyvinyl alcohol) desizing wastewater treating agent and preparation method thereof |
-
2012
- 2012-12-07 CN CN2012105954661A patent/CN103011371A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1385373A (en) * | 2001-05-15 | 2002-12-18 | 中国科学院南京土壤研究所 | Coagulant for sewage treatment |
| JP4591695B2 (en) * | 2005-07-12 | 2010-12-01 | 株式会社日立プラントテクノロジー | Method for treating wastewater containing phosphoric acid and zinc |
| CN101327976A (en) * | 2008-07-15 | 2008-12-24 | 南通立源水处理技术有限公司 | High-efficiency water treatment flocculant |
| CN101885526A (en) * | 2009-05-16 | 2010-11-17 | 兰州大欣水工业有限责任公司 | Ternary composite type flocculant, preparation and application |
| CN102010045A (en) * | 2010-11-19 | 2011-04-13 | 杭州电子科技大学 | Preparation method for polysilicate-metal flocculant containing titanium |
| CN102531126A (en) * | 2012-01-09 | 2012-07-04 | 南京大学 | Method for treating papermaking black liquor with composite coagulation method |
| CN102633338A (en) * | 2012-04-28 | 2012-08-15 | 江苏双净净化科技有限公司 | PVA (polyvinyl alcohol) desizing wastewater treating agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103420522A (en) * | 2013-08-28 | 2013-12-04 | 中锗科技有限公司 | Method for circulating purification recycling of sewage with germanium simple-substance particles |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Application publication date: 20130403 |