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CN103000674B - Transistor and manufacturing method thereof - Google Patents

Transistor and manufacturing method thereof Download PDF

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CN103000674B
CN103000674B CN201210544375.5A CN201210544375A CN103000674B CN 103000674 B CN103000674 B CN 103000674B CN 201210544375 A CN201210544375 A CN 201210544375A CN 103000674 B CN103000674 B CN 103000674B
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transistor
base
emitter
layer
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CN103000674A (en
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吴东平
付超超
张世理
张卫
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Fudan University
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Abstract

晶体管具有倒置异质结结构,其中,在形成基极层和集电极层之前形成发射极层。通过为关键的基区形貌和掺杂分布控制提供更好的热预算,可以获得更高的截止频率(fT);通过最小化集电区和基区的接触面积,可以显著减少寄生电容、提高最高振荡频率(fmax)。这样可以显著提高晶体管的频率特性。这种倒置的异质结结构,可以采用ALE工艺通过在预先形成的外延单晶金属硅化物上形成发射极层,在发射极层上形成基极层,在基极层上形成集电极层制备得到。

The transistor has an inverted heterojunction structure in which the emitter layer is formed before the base and collector layers are formed. Higher cut-off frequency (f T ) can be achieved by providing better thermal budget for critical base topography and doping profile control; parasitic capacitance can be significantly reduced by minimizing collector and base contact area , Increase the highest oscillation frequency (f max ). This can significantly improve the frequency characteristics of the transistor. This inverted heterojunction structure can be prepared by forming an emitter layer on a pre-formed epitaxial monocrystalline metal silicide, a base layer on the emitter layer, and a collector layer on the base layer using the ALE process. get.

Description

一种晶体管及其制造方法A kind of transistor and its manufacturing method

技术领域technical field

本发明涉及电子器件技术,特别涉及一种晶体管及其制造方法。The invention relates to electronic device technology, in particular to a transistor and a manufacturing method thereof.

背景技术Background technique

在0.5至6太赫兹(THz,即1012赫兹)频率体系,成像和光谱系统在安全、卫生、遥感和基础科学等领域具有重要的应用。太赫兹波在水中具有很强的衰减强度,但对生物组织具有较大的穿透深度,而不会对生物组织造成损害。因此,他们特别适合于涉及透过不透明的物体进行低风险成像的安全应用,比如透过衣服、牙齿、纸张、塑料和陶瓷材料的成像。太赫兹波在卫生应用中也非常理想,比如皮肤癌的早期诊断。因此,近来已经对许多涉及安全、医药、生物分析、用于环境监测的遥感和减轻自然灾害的社会基础应用进行了广泛地研究。凭借其高频率,太赫兹波也同样适用于极限宽带通信。In the 0.5 to 6 terahertz (THz, ie 10 12 Hz) frequency system, imaging and spectroscopy systems have important applications in the fields of security, health, remote sensing, and basic science. Terahertz waves have strong attenuation strength in water, but have a greater penetration depth to biological tissues without causing damage to biological tissues. They are therefore particularly suitable for security applications involving low-risk imaging through opaque objects, such as through clothing, teeth, paper, plastic and ceramic materials. Terahertz waves are also ideal for health applications, such as early diagnosis of skin cancer. Consequently, many socially based applications involving security, medicine, bioanalysis, remote sensing for environmental monitoring, and natural disaster mitigation have recently been extensively studied. With their high frequency, terahertz waves are also suitable for extreme broadband communications.

然而,到目前为止,太赫兹频段区域在日常中的应用却非常少。这就导致了“太赫兹空隙”(THz gap)这一表述的出现,它不精确地描述了缺乏足够的技术,来有效地弥合低于1THz的微波频率和高于6THz的光频率之间的频段,特别是,在这个特定的频率范围内缺乏具有有用功率水平的实际源。现在,半导体电子和激光光学元件从各自相反的方向来缩小这个太赫兹空隙。先进的半导体技术,包括硅-互补金属氧化物半导体(Silicon-CMOS)、锗硅异质结双极型晶体管(SiGe HBT)和化合物半导体HEMT器件(高电子迁移率晶体管),极大地促进了毫米波技术的发展。然而,通过最强大的和具有成本效益的SiGe HBT技术预计可达到的频率在目前约为0.5THz。在光学领域,依靠从良好定义的电子态转换的现代固态激光器,在打破6THz壁垒时,遇到了严重的挑战,因为这样的频率的光能量等于室温下热波动的能量,即kT=26毫电子伏特(meV)。However, so far, the terahertz frequency band region has very few daily applications. This has led to the expression "THz gap," which loosely describes the lack of sufficient technology to effectively bridge the gap between microwave frequencies below 1 THz and optical frequencies above 6 THz. Frequency bands, in particular, lack practical sources with useful power levels in this particular frequency range. Now, semiconductor electronics and laser optics work in opposite directions to narrow this terahertz gap. Advanced semiconductor technologies, including silicon-complementary metal-oxide semiconductor (Silicon-CMOS), silicon-germanium heterojunction bipolar transistor (SiGe HBT), and compound semiconductor HEMT devices (high electron mobility transistors), have greatly facilitated mm development of wave technology. However, the expected achievable frequency by the most powerful and cost-effective SiGe HBT technology is currently around 0.5 THz. In optics, modern solid-state lasers relying on transitions from well-defined electronic states encounter serious challenges in breaking the 6 THz barrier, since the energy of light at such frequencies is equal to the energy of thermal fluctuations at room temperature, i.e. kT = 26 millielectrons Volts (meV).

目前,可以通过无源器件,比如频率乘法器,进入THz频段。然而,这样的器件普遍具有显著的功率损耗,这导致在实际应用中使用这些器件时功率和系统体积比将不切实际的小。因此,小而高效的有源THz器件是唯一的解决办法。真空电子器件,包括速调管,已被视为一种用于弥合THz空隙的方式。这种器件或许可以应用到军事和航空航天领域,但可以预见,其大尺寸、显著的能量消耗和糟糕的可靠性,将阻碍它们向安全卫生等广阔的民用领域渗透。因此,基于先进半导体的固态电子器件是唯一能用于我们日常生活的,特别是使用电池供电的便携式太赫兹系统。Currently, access to the THz band is possible through passive components such as frequency multipliers. However, such devices generally have significant power losses, which results in impractically small power-to-system volume ratios when using these devices in practical applications. Therefore, small and efficient active THz devices are the only solution. Vacuum electronics, including klystrons, have been considered as a way to bridge the THz gap. Such devices may be applied to military and aerospace fields, but it is foreseeable that their large size, significant energy consumption, and poor reliability will hinder their penetration into broad civilian fields such as safety and health. Therefore, solid-state electronics based on advanced semiconductors are the only ones that can be used in our daily life, especially portable terahertz systems using battery power.

在1THz运行的基于CMOS的解决方案需要具有10纳米(nm)沟道长度的晶体管。然而,在这个栅极长度,由于量子隧道效应,晶体管会输出非常低的功率。凭借优越的跨导和噪声特性,SiGe HBT技术被普遍认为给新兴的高频率市场提供了最强大的和具有成本效益的解决方案。目前,SiGe HBT的基础技术是通过化学气相沉积(CVD)的SiGe。目前最先进的SiGe HBT在室温下具有0.4THz的截止频率。正在进行的名为“DOTFIVE”的欧洲FP7计划,包括主要的欧洲半导体企业,试图在2013年推出0.5THz的SiGe HBT技术。值得注意是,在DOTFIVE计划中,用于0.325THz的完整的频率乘法器链的电路设计代表了目前的最高发展水平,但这不但是一个非常有损耗的方法,也还未能进入THz空隙。A CMOS-based solution operating at 1 THz requires transistors with channel lengths of 10 nanometers (nm). However, at this gate length, the transistor outputs very low power due to quantum tunneling. With superior transconductance and noise characteristics, SiGe HBT technology is generally considered to provide the most robust and cost-effective solution for the emerging high-frequency market. Currently, the underlying technology for SiGe HBTs is SiGe by chemical vapor deposition (CVD). The current state-of-the-art SiGe HBT has a cut-off frequency of 0.4THz at room temperature. The ongoing European FP7 project called "DOTFIVE", including major European semiconductor companies, is trying to launch 0.5THz SiGe HBT technology in 2013. It is worth noting that in the DOTFIVE project, the circuit design of a complete frequency multiplier chain for 0.325 THz represents the current state of the art, but this is not only a very lossy approach, but it has not yet entered the THz gap.

发明内容Contents of the invention

在一个实施例中,SiGe HBT可以在外延的金属硅化物上通过原子层外延(ALE)法形成超薄(例如,小于或者等于10nm)半导体的异质结。应力工程可以应用于HBT部分区域或全部区域上,用来提高横向空穴和纵向电子导电。SiGe HBT具有倒置异质结结构,并通过减少寄生效应、并为关键的基区形貌控制提供更好的热处理预算,从而得到最大化的频率性能。可以通过采用ALE技术,在预先外延形成的金属硅化物上外延形成发射区、在发射区上外延形成基区,然后在基区上外延形成集电区,来制备得到倒置异质结结构。采用新的接触方式,以在某些或所有的HBT引出端中提供极低的接触电阻。In one embodiment, the SiGe HBT can form an ultra-thin (for example, less than or equal to 10 nm) semiconductor heterojunction on an epitaxial metal silicide by atomic layer epitaxy (ALE). Stress engineering can be applied to some or all regions of the HBT to improve lateral hole and vertical electron conduction. SiGe HBTs have an inverted heterojunction structure and maximize frequency performance by reducing parasitics and providing better thermal budget for critical base topography control. An inverted heterojunction structure can be prepared by using ALE technology to epitaxially form an emitter region on a pre-epitaxially formed metal silicide, epitaxially form a base region on the emitter region, and then epitaxially form a collector region on the base region. A new contact method is used to provide extremely low contact resistance in some or all of the HBT terminals.

SiGe HBT可以采用适合于工业化生产的CMOS技术制备。SiGe HBT can be prepared by using CMOS technology suitable for industrial production.

在一个实施例中,一个HBT包括生长在半导体衬底上的超薄单晶外延金属硅化物层,其厚度为10nm或更薄,在该金属硅化物层上形成单晶硅发射极,在发射极上形成基极,基极具有约10nm或更小的宽度;并在基极上形成单晶硅集电极。该HBT具有集电极更靠近HBT表面的倒置结构。In one embodiment, an HBT includes an ultra-thin monocrystalline epitaxial metal silicide layer grown on a semiconductor substrate, with a thickness of 10 nm or less, on which a monocrystalline silicon emitter is formed. A base electrode is formed on the electrode, and the base electrode has a width of about 10 nm or less; and a monocrystalline silicon collector electrode is formed on the base electrode. The HBT has an inverted structure with the collector closer to the surface of the HBT.

在进一步的实施例中,发射极是碳掺杂的。In a further embodiment, the emitter is carbon doped.

在进一步的实施例中,单晶外延金属硅化物是在Si(100)衬底上的超薄外延NiSi2膜。In a further embodiment, the monocrystalline epitaxial metal suicide is an ultrathin epitaxial NiSi2 film on a Si(100) substrate.

在进一步的实施例中,发射极和集电极分别具有约10nm或更薄的厚度。In a further embodiment, the emitter and collector each have a thickness of about 10 nm or less.

在进一步的实施例中,发射极、基极和集电极中的至少一个通过至少一个ALE过程形成。In a further embodiment, at least one of the emitter, base and collector is formed by at least one ALE process.

在进一步的实施例中,基极包括锗化硅(SiGe)。In a further embodiment, the base comprises silicon germanium (SiGe).

HBT进一步包括在发射极、基极和集电极上分别具有金属硅化物接触,并且金属硅化物接触具有非常低的约45毫欧·厘米的电阻率。The HBT further includes metal suicide contacts on the emitter, base and collector respectively, and the metal suicide contacts have a very low resistivity of about 45 milliohm·cm.

在进一步的实施例中,集电极在传输方向上进行应力处理以提高电子迁移率。In a further embodiment, the collector is stressed in the transport direction to increase electron mobility.

在进一步的实施例中,集电极为轻掺杂的硅且在表面有金属硅化物层。In a further embodiment, the collector electrode is lightly doped silicon with a metal silicide layer on the surface.

在进一步的实施例中,基极进行应力处理,以增强在基极的横向空穴和纵向电子传导,并在另外一个方向上进行进一步的形变处理。In a further embodiment, the base is subjected to stress treatment to enhance lateral hole and vertical electron conduction in the base, and further deformed in another direction.

在一个实施例中,一种HBT的制造方法包含以下步骤:在半导体衬底上外延生长单晶金属硅化物层,且该金属硅化物层具有10nm或更薄的厚度;在所述金属硅化物层上外延生长单晶硅发射极;在发射极上外延生长SiGe基极;在SiGe基极上外延生长单晶硅集电极。In one embodiment, a method for manufacturing an HBT includes the following steps: epitaxially growing a single crystal metal silicide layer on a semiconductor substrate, and the metal silicide layer has a thickness of 10 nm or less; Epitaxial growth of single crystal silicon emitter on the layer; epitaxial growth of SiGe base on the emitter; epitaxial growth of single crystal silicon collector on the SiGe base.

在进一步的实施例中,金属硅化物层是通过固态反应(SSR)过程生长在Si(100)上的NiSi2,该方法包括溅射沉积一层约等于2纳米厚的Ni膜和快速热处理。In a further embodiment, the metal silicide layer is NiSi2 grown on Si(100) by a solid state reaction (SSR) process comprising sputter deposition of a Ni film approximately equal to 2 nm thick and rapid thermal treatment.

在进一步的实施例中,发射极使用ALE过程生长,并在ALE过程中进行原位碳掺杂。In a further embodiment, the emitter is grown using an ALE process and is doped with carbon in situ during the ALE process.

在进一步的实施例中,在ALE过程中使用从激光源发出的光子,帮助从衬底表面释放氢原子。In a further embodiment, photons emitted from a laser source are used in the ALE process to assist in the release of hydrogen atoms from the substrate surface.

在进一步的实施例中,硅发射极层与SiGe基极层均进行了应变处理,并且SiGe基极层在多个方向上进行了应变处理。In a further embodiment, both the silicon emitter layer and the SiGe base layer are strained, and the SiGe base layer is strained in multiple directions.

在进一步的实施例中,由于倒置结构,机械应力从HBT顶部表面施加到集电极层上。In a further embodiment, mechanical stress is applied to the collector layer from the top surface of the HBT due to the inverted structure.

附图说明Description of drawings

图1是根据一个实施例的SiGe HBT器件的横截面示意图;1 is a schematic cross-sectional view of a SiGe HBT device according to one embodiment;

图2是根据一个实施例的SiGe HBT器件制备方法的流程图;2 is a flow chart of a method for fabricating a SiGe HBT device according to an embodiment;

图3a至3h是根据一个实施例的SiGe HBT器件制备方法各步骤对应的横截面示意图;3a to 3h are schematic cross-sectional views corresponding to each step of a method for fabricating a SiGe HBT device according to an embodiment;

图4A是根据一个实施例的使用SSR在Si(100)上生长6nm厚的外延NiSi2的透射型电子显微镜(TEM)图像。4A is a transmission electron microscope (TEM) image of 6 nm thick epitaxial NiSi 2 grown on Si(100) using SSR according to one embodiment.

图4B是使用分子束外延在NiSi2上生长10nm厚的外延Si的RHEED图像。Figure 4B is a RHEED image of 10 nm thick epitaxial Si grown on NiSi2 using molecular beam epitaxy.

图5是根据一个实施例的为大注入工作优化的SiGe HBT的工作频率(fT)与集电极电流密度Jc之间关系的仿真结果示意图。5 is a schematic diagram of simulation results of the relationship between the operating frequency (f T ) and the collector current density Jc of a SiGe HBT optimized for large implant operation according to one embodiment.

具体实施方式detailed description

根据本发明的一个实施例,提供了一种新型、能够从微波方向渗透到太赫兹空隙(THz gap)频段工作的“倒置”锗硅异质结双极型晶体管(SiGe HBT)器件。通过采用与材料、工艺技术和器件结构有关的革命性薄膜技术创新,比如,在Si上采用固态反应(SSR)外延生长NiSi2以及在NiSi2上采用原子层外延法生长Si等,进行制备SiGe HBT,该HBT器件能工作在太赫兹空隙频段中。According to an embodiment of the present invention, a novel "inverted" silicon-germanium heterojunction bipolar transistor (SiGe HBT) device capable of penetrating into the terahertz gap (THz gap) frequency band from the microwave direction is provided. Preparation of SiGe by employing revolutionary thin-film technology innovations related to materials, process technologies and device structures, such as solid-state reaction (SSR) epitaxial growth of NiSi 2 on Si and atomic layer epitaxy on NiSi 2 , etc. HBT, the HBT device can work in the terahertz gap frequency band.

图1是根据本发明一个实施例的倒置HBT 100的横截面示意图。如图1所示,该倒置HBT 100包含位于半导体(如,硅)衬底101上的外延层110、位于外延层110上的发射极120、位于发射极120上的基极130、和位于基极层上的集电极140。因此,倒置HBT 100中的发射极120、基极130和集电极140的顺序与传统的双极型晶体管中的顺序是相反的。这种布局的一个好处是,与传统的双极型晶体管中发射极引出端在集电极-发射极(CE)结构中接地不一样,本实施例HBT 100中的发射极靠近衬底101中的低电势区域。另一方面,集电极接近HBT100的顶部或表面102,因此,集电极更接近或直接和与HBT相连的电路金属层(图中未示出)接触,并且易于从器件顶部接入。其结果是,使得寄生效应的影响(特别是,集电极-基极电容Cbc)显著减少,从而能实现在性能上的增益。FIG. 1 is a schematic cross-sectional view of an inverted HBT 100 according to one embodiment of the present invention. As shown in FIG. 1, the inverted HBT 100 includes an epitaxial layer 110 on a semiconductor (eg, silicon) substrate 101, an emitter 120 on the epitaxial layer 110, a base 130 on the emitter 120, and a The collector electrode 140 on the electrode layer. Therefore, the order of the emitter 120, base 130, and collector 140 in the inverted HBT 100 is reversed from that in a conventional bipolar transistor. One advantage of this layout is that, unlike conventional bipolar transistors where the emitter terminal is grounded in a collector-emitter (CE) structure, the emitter in the HBT 100 of this embodiment is close to the ground in the substrate 101. low potential area. On the other hand, the collector is close to the top or surface 102 of the HBT 100, therefore, the collector is closer to or directly contacts the circuit metal layer (not shown) connected to the HBT and is easily accessible from the top of the device. As a result, the influence of parasitic effects (in particular, collector-base capacitance C bc ) is significantly reduced, enabling a gain in performance to be achieved.

在一个实施例中,外延层110包含异相外延生长过程中所形成的单晶硅化物,发射极包含外延生长硅。在改进的实施例中,发射极包含碳掺杂硅(Si(C)),该碳掺杂硅具有比硅(Si)更大的能带隙,可以实现更加增强的载流子注入。由于能够在其上形成良好的异质外延硅(Si)或锗化硅(SiGe)的基极,外延硅发射极能够带来良好的高频性能。在一个实施例中,基极通过原子层外延(ALE)方法制备,其宽度w可以非常薄,从而使基极传输时间不会显著地限制HBT的性能。In one embodiment, the epitaxial layer 110 includes monocrystalline silicide formed during heteroepitaxial growth, and the emitter includes epitaxially grown silicon. In an improved embodiment, the emitter comprises carbon-doped silicon (Si(C)), which has a larger energy bandgap than silicon (Si), enabling more enhanced carrier injection. The epitaxial silicon emitter can bring good high frequency performance due to the ability to form a good heteroepitaxial silicon (Si) or silicon germanium (SiGe) base thereon. In one embodiment, the base is fabricated by atomic layer epitaxy (ALE), and its width w can be very thin so that the base transit time does not significantly limit the performance of the HBT.

这样的“倒置双极型”结构能够允许对集电极进行简单的掺杂优化,以便可以形成特殊的异质结结构,使器件能在更高的电流密度下工作,以达到更高的频率极限。此外,该倒置结构能够大大简化对在太赫兹频段工作很重要的形变的施加。Such an "inverted bipolar" structure can allow simple doping optimization of the collector so that special heterojunction structures can be formed, enabling devices to operate at higher current densities to reach higher frequency limits . Furthermore, the inverted structure can greatly simplify the application of deformations that are important for operation in the terahertz frequency range.

在一个实施例中,外延层110包含外延金属硅化物,该金属硅化物具有约50欧姆/方块的薄层电阻,以便使载流子渡越时间和串联电阻最小化,并改善散热管理。In one embodiment, the epitaxial layer 110 comprises an epitaxial metal suicide having a sheet resistance of about 50 ohms/square in order to minimize carrier transit time and series resistance and improve thermal management.

在一个实施例中,基极层包含Si或SiGe。通过形成具有SiGe的基极可以获得更高的工作频率。虽然硅基极也是可行的,但是下面的讨论将主要集中在具有SiGe基极层的HBT100,并且下面以SiGe HBT 100代替HBT100。在一个实施例中,基极层采用应力工程增强基底中横向空穴和纵向电子的传导。在一个实施例中,除了采用进行应力处理的SiGe层之外,在另外一个方向施加压力,以便更大幅度地改善器件的性能。已经发展成熟的应力技术,比如异质结外延处理和氮化硅拉伸及压缩应力,已被广泛应用在最先进的互补金属氧化物半导体(CMOS)技术中,同样也可用于本发明讨论的应力应用中。In one embodiment, the base layer comprises Si or SiGe. Higher operating frequencies can be obtained by forming the base with SiGe. Although a silicon base is also feasible, the following discussion will mainly focus on HBT 100 with a SiGe base layer, and SiGe HBT 100 is substituted for HBT 100 below. In one embodiment, the base layer employs stress engineering to enhance conduction of holes laterally and electrons vertically in the substrate. In one embodiment, in addition to using the stressed SiGe layer, the stress is applied in another direction in order to further improve the performance of the device. Well-developed stress techniques, such as heterojunction epitaxy processing and silicon nitride tensile and compressive stress, have been widely used in state-of-the-art complementary metal-oxide-semiconductor (CMOS) technology, and can also be used in the discussion of the present invention stress application.

在一个实施例中,SiGe HBT 100的基极130包含非本征基极区130a和本征基极区130b。在一个实施例中,本征基极区的厚度约为10nm或者更薄。为了避免如此薄的本征基极区而导致的不必要的高电阻,发射极条带120被做得非常狭窄(比如,约20纳米或更窄),HBT100可以具有多个发射极条带以优化性能。在一个实施例中,发射极使用电子束光刻或者浸润式光刻技术进行图案化,以获得高分辨率。In one embodiment, the base 130 of the SiGe HBT 100 includes an extrinsic base region 130a and an intrinsic base region 130b. In one embodiment, the thickness of the intrinsic base region is about 10 nm or less. To avoid unnecessarily high resistance caused by such a thin intrinsic base region, the emitter strip 120 is made very narrow (e.g., about 20 nanometers or less), and the HBT 100 can have multiple emitter strips to Optimize performance. In one embodiment, the emitter is patterned using electron beam lithography or immersion lithography to achieve high resolution.

在一个实施例中,集电极包含硅,并进行了应力处理。在一个实施例中,集电极为轻掺杂的硅且在上表面有金属硅化物层,并在传输方向上进行了应力处理,以提高电子迁移率。倒置的接近表面102的集电极区域结构方便进行应力的施加和控制。在一个实施例中,在集电极顶部的硅化物接触区150的尺寸可以与集电极一样大,以便使接触电阻最小化。In one embodiment, the collector comprises silicon and is stress treated. In one embodiment, the collector is lightly doped silicon with a metal silicide layer on the upper surface, and is stress-treated in the transport direction to increase electron mobility. The inverted collector region structure close to the surface 102 facilitates stress application and control. In one embodiment, the size of the suicide contact region 150 on top of the collector can be as large as the collector to minimize contact resistance.

在一个实施例中,SiGe HBT 100还包含在其引出端的低电阻率接触区150。例如,可以是在发射极和基极具有极低接触电阻(例如,低于10-8Ωcm2),和在集电极具有极低肖特基势垒(SBH)(例如,约为0.1eV)的镍硅(NiSi)接触区。In one embodiment, SiGe HBT 100 also includes low-resistivity contact regions 150 at its terminals. For example, it can be very low contact resistance (for example, below 10 -8 Ωcm 2 ) at the emitter and base, and a very low Schottky barrier (SBH) at the collector (for example, about 0.1eV) The nickel silicon (NiSi) contact area.

在一个实施例中,采用先进的ALE和外延硅化物技术制造工作频率超过1THz的高性能HBT。在如此高的频率下,应特别注意使所有包括内部的和外部的的寄生元件最小化,如果不是这样的话,将给有源器件带来不利影响。In one embodiment, advanced ALE and epitaxial silicide technologies are used to fabricate high-performance HBTs operating at frequencies exceeding 1 THz. At such high frequencies, special care should be taken to minimize all parasitic components, both internal and external, which would otherwise adversely affect active devices.

每次沉积一个原子层的ALE处理,确保在低温沉积过程中一层中的原子最终沉积在正确的晶格位置。因此,与需要非常高沉积温度的传统化学气相沉积(CVD)相比,ALE不需要额外的高温步骤。与也能达到原子级沉积控制的分子束外延(MBE)相比,ALE有利于获得在实际太赫兹元件中非常期望实现的狭窄的分布形貌。在一个实施例中,超高真空(UHV)ALE用于生长碳掺杂硅(以Si(C)表示)发射极、锗硅基极和硅集电极。The ALE process, which deposits one atomic layer at a time, ensures that the atoms in a layer end up deposited in the correct lattice positions during the low-temperature deposition process. Therefore, ALE does not require an additional high-temperature step compared to conventional chemical vapor deposition (CVD), which requires very high deposition temperatures. Compared with molecular beam epitaxy (MBE), which can also achieve atomic-level deposition control, ALE is beneficial to obtain narrow distribution profiles that are highly desirable in practical terahertz devices. In one embodiment, ultra-high vacuum (UHV) ALE is used to grow carbon-doped silicon (denoted Si(C)) emitter, germanium-silicon base, and silicon collector.

图2是根据本发明的一个实施例的SiGe HBT制备过程200的流程图。图3a至3h是SiGe HBT制备过程200中各步骤对应的横截面图。如图2和3a所示,提供半导体衬底301(步骤201)。半导体衬底101可以是硅衬底或绝缘体上硅(SOI)衬底。FIG. 2 is a flowchart of a SiGe HBT fabrication process 200 according to one embodiment of the present invention. 3a to 3h are cross-sectional views corresponding to each step in the SiGe HBT manufacturing process 200. FIG. As shown in Figures 2 and 3a, a semiconductor substrate 301 is provided (step 201). The semiconductor substrate 101 may be a silicon substrate or a silicon-on-insulator (SOI) substrate.

如图2和3b所示,通过异质结外延工艺在半导体衬底上生长单晶金属硅化物层110(步骤210)。该外延硅化物层110取代传统上使用的厚的做为子集电极的高掺杂硅层,具有适合于太赫兹频率工作的50Ω以下的薄层电阻。由于硅化物层可以非常薄(≤10nm),因此与子发射极的任何侧壁相连的寄生边缘电容会大大减小。As shown in Figures 2 and 3b, a single crystal metal silicide layer 110 is grown on a semiconductor substrate by a heterojunction epitaxy process (step 210). The epitaxial silicide layer 110 replaces the traditionally used thick highly doped silicon layer as a sub-collector, and has a sheet resistance below 50Ω suitable for terahertz frequency operation. Since the silicide layer can be very thin (≤10nm), the parasitic fringe capacitance connected to any sidewall of the sub-emitter is greatly reduced.

在一个实施例中,外延硅化层110是采用固态反应(SSR)工艺生长在硅衬底100上的超薄NiSi2薄膜。在一个实施例中,SSR过程首先以溅射方式沉积一层约2纳米厚的Ni膜,接着在约700℃温度下进行简短热处理。如图4A所示,在Si(100)上生长的6纳米厚的外延NiSi2膜的厚度是均匀的,并在原子层级别具有尖锐的界面和光滑的表面。此外,该膜具有非常低的电阻率,例如,45μΩ-cm,或约单位面积75Ω的薄层电阻。In one embodiment, the epitaxial silicide layer 110 is an ultra-thin NiSi 2 film grown on the silicon substrate 100 by a solid state reaction (SSR) process. In one embodiment, the SSR process first deposits a Ni film about 2 nm thick by sputtering, followed by a brief heat treatment at about 700°C. As shown in Fig. 4A, the thickness of the 6 nm-thick epitaxial NiSi2 film grown on Si(100) is uniform, and has sharp interfaces and smooth surfaces at the atomic layer level. In addition, the film has very low resistivity, eg, 45 μΩ-cm, or a sheet resistance of about 75Ω per unit area.

如图2和3c所示,碳掺杂硅(Si(C))发射极120和SiGe基极130采用ALE工艺被连续地形成在外延硅化物层110上(分别对应步骤220和230)。在ALE工艺中,可以实现单原子层精度的厚度和成分控制,不同的化学物质和材料也能迅速地进行处理。发射极120进行原位掺杂,以实现原子层级别的陡峭的杂质分布。具有单原子层控制能力的ALE工艺通常依赖于两个前驱体的循环处理,以形成AxBy型二元化合物,如III-V或II-VI族半导体。ALE工艺230的关键特征是自限制性,该特性通过在超高真空(UHV)环境,低于400℃的温度下的化学吸附过程实现。以这种方式,可以在每个周期中生长出成分A或B中的至多一个单层,且与生长周期的长度无关。对于单元素的硅膜的生长,循环处理可以通过使用六氯化二硅(Si2Cl6)和六氢化二硅(Si2H6)实现。然而,这个过程并不是真正的自限制,因为在400℃以上Si2H6很容易分解。就这一点而言,基极130中锗硅合金的ALE预期会更加困难,因为诸如锗甲烷(GeH4)或六氢化二锗(Ge2H6)的锗前驱体易于在更低的温度下分解。为了实现原子层级别的自限制生长,需要在低的温度下进行生长工艺。低温生长的一个挑战是从正在生长的硅表面进行氢原子的脱附,为后续的硅吸附和沉积留有余地。使用光子或等离子体可以帮助释放氢原子,从而实现硅原子层外延。为了避免等离子体诱导损伤,可以采用光子方法进行Si和SiGe的外延,以实现单原子层控制。带有外部激光源的常规超高真空ALE或ALD系统可以用于实现本发明的ALE工艺。As shown in FIGS. 2 and 3 c , a carbon-doped silicon (Si(C)) emitter 120 and a SiGe base 130 are sequentially formed on the epitaxial silicide layer 110 using an ALE process (corresponding to steps 220 and 230 , respectively). In the ALE process, thickness and composition control with monoatomic layer precision can be achieved, and different chemicals and materials can be processed rapidly. The emitter 120 is doped in-situ to achieve a steep impurity distribution at the atomic layer level. ALE processes with single-atom-layer control typically rely on the cyclic processing of two precursors to form AxBy - type binary compounds, such as III-V or II-VI semiconductors. A key feature of the ALE process 230 is self-limitation, which is achieved through a chemisorption process at temperatures below 400°C in an ultra-high vacuum (UHV) environment. In this way, at most one monolayer of composition A or B can be grown per cycle, independently of the length of the growth cycle. For the growth of single-element silicon films, cyclic processing can be achieved by using silicon hexachloride (Si 2 Cl 6 ) and silicon hexahydrogen (Si 2 H 6 ). However, this process is not truly self - limiting because Si2H6 is easily decomposed above 400 °C. In this regard, ALE of germanium-silicon alloys in base 130 is expected to be more difficult because germanium precursors such as germanium methane (GeH 4 ) or digermanium hexahydrogenate (Ge 2 H 6 ) tend to be more difficult at lower temperatures. break down. In order to achieve self-limited growth at the atomic layer level, the growth process needs to be performed at a low temperature. One challenge of low-temperature growth is the desorption of hydrogen atoms from the growing silicon surface, leaving room for subsequent silicon adsorption and deposition. Using photons or plasmas can help release hydrogen atoms, enabling atomic layer epitaxy of silicon. To avoid plasmon-induced damage, epitaxy of Si and SiGe can be performed using photonic methods to achieve monoatomic layer control. A conventional ultra-high vacuum ALE or ALD system with an external laser source can be used to implement the ALE process of the present invention.

如图2所示,过程200进一步包括:对Si发射极120(步骤225)和SiGe基极130(步骤235)进行适当的应力处理,以缩短渡越时间,实现工作频率(fT)大于1.1太赫兹的SiGeHBT。通过在异质结结构中引入单轴和双轴应力的组合,载流子迁移率以及受载流子迁移率影响的器件的工作频率可以显着地增加。这可以通过内在的异质结外延生长和外在的应变层沉积来实现。同样地,众所周知,异质结有利于载流子的注入和载流子的输运。正如在CMOS技术中的成功应用一样,使用应变层进行应力处理可以为载流子迁移率增强提供更大的自由度。As shown in FIG. 2, the process 200 further includes: performing appropriate stress treatment on the Si emitter 120 (step 225) and the SiGe base 130 (step 235) to shorten the transit time and achieve an operating frequency (fT) greater than 1.1 Ω Hertz's SiGeHBT. By introducing a combination of uniaxial and biaxial stresses in the heterojunction structure, the carrier mobility and the operating frequency of the carrier-mobility-affected devices can be significantly increased. This can be achieved by intrinsic heterojunction epitaxial growth and extrinsic strained layer deposition. Likewise, it is well known that heterojunctions are beneficial for carrier injection and carrier transport. As successfully applied in CMOS technology, the use of strained layers for stress treatment can provide more degrees of freedom for carrier mobility enhancement.

如图2和3d所示,硅层140通过异质结外延工艺形成(步骤240)。为了保持不同层之间陡峭的掺杂分布,并以形成一个NPN HBT为例,在ALE工艺过程中发射极120,基极130和集电极140分别进行N型、P型和N型原位掺杂。对于根据一个实施例的NPN HBT,在正常工作期间,基极和发射极之间的偏压(VBE)是正的,基极和集电极之间的偏压(VBC)是负的。As shown in Figures 2 and 3d, silicon layer 140 is formed by a heterojunction epitaxial process (step 240). In order to maintain a steep doping profile between different layers, and taking the formation of an NPN HBT as an example, the emitter 120, the base 130 and the collector 140 are respectively N-type, P-type and N-type in-situ doped during the ALE process. miscellaneous. For an NPN HBT according to one embodiment, during normal operation, the bias voltage between the base and emitter (V BE ) is positive and the bias voltage between the base and collector (V BC ) is negative.

如图2、3e至3f所示,在步骤145中对发射极120、基极130和集电极140进行图案化和蚀刻,以形成发射极120、基极130和集电极140。如图3g所示,淀积绝缘介电层103,然后平坦化,接着在绝缘介电层103内形成接触孔。接触孔160用于随后在发射极、基极和集电极上形成接触区。As shown in FIGS. 2 , 3e to 3f , the emitter 120 , base 130 and collector 140 are patterned and etched in step 145 to form the emitter 120 , base 130 and collector 140 . As shown in FIG. 3 g , an insulating dielectric layer 103 is deposited, then planarized, and then contact holes are formed in the insulating dielectric layer 103 . The contact holes 160 are used to subsequently form contact regions on the emitter, base and collector.

如图2和3h所示,在发射极、基极和集电极上形成接触区(步骤250)。在一个实施例中,可以采用传统的自对准CMOS工艺形成硅化镍(NiSi)接触区,无需额外的光刻掩模。发射极和基极之间具有超低的接触电阻(例如,低于10-8Ωcm2),采用在CMOS研究中开发的金属-半导体接触杂质分离(DS:dopant segregation)技术,集电极的金属半导体接触可以达到非常低的肖特基势垒高度(SBH)(例如,约为0.1eV)。这将进一步提高SiGe HBT100的频率性能。到目前为止,在传统的HBT研究中电接触区很少受到关注。考虑到HBT的结构约束条件及其相关工艺,通常的重掺杂技术和具有低接触电阻的适当金属选择不容易实现,因此,对于THz器件,接触区成为一个重要问题。为了减小所有三个引出端的接触电阻,可以采用诸如杂质分离的技术来改变金属硅化物和半导体之间的肖特基势垒高度。As shown in Figures 2 and 3h, contact regions are formed on the emitter, base and collector (step 250). In one embodiment, a nickel silicide (NiSi) contact region can be formed using a conventional self-aligned CMOS process without an additional photolithography mask. The emitter and base have ultra-low contact resistance (for example, lower than 10 -8 Ωcm 2 ), using the metal-semiconductor contact impurity separation (DS: dopant segregation) technology developed in CMOS research, the metal of the collector Semiconductor contacts can reach very low Schottky barrier heights (SBH) (eg, about 0.1 eV). This will further improve the frequency performance of SiGe HBT100. So far, electrical contact regions have received little attention in conventional HBT studies. Considering the structural constraints of HBTs and their associated processes, the usual heavy doping techniques and proper metal selection with low contact resistance are not easy to implement, thus, the contact area becomes an important issue for THz devices. In order to reduce the contact resistance of all three terminals, techniques such as impurity separation can be used to change the Schottky barrier height between the metal silicide and the semiconductor.

因此,SiGe HBT通过原子层外延(ALE)形成,具体地说,在外延金属硅化物上形成超薄(例如,小于10纳米)半导体异质结。在HBT一些或所有区域上施加应力技术,使得横向空穴和纵向电子传导能力同时增强。SiGeHBT具有倒置异质结结构,并通过减少寄生效应及为关键的基区形貌和分布控制提供更好的热预算,获得最大化的频率性能。采用新的接触策略,以在某些或所有的HBT引出端中得到极低的接触电阻。Accordingly, SiGe HBTs are formed by atomic layer epitaxy (ALE), specifically, the formation of ultra-thin (eg, less than 10 nanometers) semiconductor heterojunctions on epitaxial metal suicides. Stress techniques are applied on some or all regions of the HBT, resulting in simultaneous enhancement of lateral hole and vertical electron conduction. SiGeHBT has an inverted heterojunction structure and maximizes frequency performance by reducing parasitic effects and providing better thermal budget for critical base topography and distribution control. A new contact strategy is employed to obtain extremely low contact resistance in some or all of the HBT terminals.

因此,能在太赫兹频段工作的良好的倒置SiGe HBT可以采用基于半导体的工艺来制作,采用ALE工艺在单晶硅化物膜上形成Si、SiGe和碳掺杂硅Si(C)结构。或者,分子束外延(MBE)也可用于半导体的生长。外延NiSi2膜所获得的表面与界面性能对促进各种Si或SiGe膜上的外延很重要。例如,如图4B中的反射高能电子衍射(Reflection High-EnergyElectron Diffraction,简称“RHEED”)图像显示,10纳米厚的外延Si可以在380℃下在外延NiSi2膜上生长得到。虽然没有作精心的表面处理,生长表面的质量已经比较合理。Therefore, a good inverted SiGe HBT capable of operating in the terahertz frequency band can be fabricated using a semiconductor-based process using the ALE process to form Si, SiGe, and carbon-doped silicon Si(C) structures on single-crystal silicide films. Alternatively, molecular beam epitaxy (MBE) can also be used for semiconductor growth. The surface and interfacial properties obtained by epitaxial NiSi2 films are important to facilitate epitaxy on various Si or SiGe films. For example, as shown in the reflection high-energy electron diffraction (Reflection High-Energy Electron Diffraction, “RHEED”) image in FIG. 4B , epitaxial Si with a thickness of 10 nm can be grown on epitaxial NiSi 2 film at 380° C. Although not carefully prepared, the quality of the growing surface is already reasonable.

图5是基于本发明一个实施例的为大注入工作条件优化的器件结构仿真结果:SiGe HBT的工作频率(fT)与集电极电流密度Jc之间关系的曲线图。FIG. 5 is a simulation result of a device structure optimized for a large injection working condition based on an embodiment of the present invention: a graph showing the relationship between SiGe HBT operating frequency (f T ) and collector current density Jc.

SiGe HBT的性能优势主要来自于SiGe较小的能带隙以及能带隙梯度导致的载流子纵向电场加速。但是,对基极电阻很重要的纵向电子迁移率和横向空穴迁移率,仅有极小的改进。另一方面,在CMOS技术里,90纳米以下CMOS的关键性能增强因子是通过应力工程实现的横向场迁移率增强。在一个实施例中,能带隙工程和迁移率工程相结合,进一步改善HBT的性能。例如,额外的应力处理可用于改善横向空穴迁移率,从而减小限制SiGe HBT最大工作频率的基极电阻。The performance advantages of SiGe HBT mainly come from the small energy band gap of SiGe and the acceleration of carriers in the longitudinal electric field caused by the energy band gap gradient. However, the longitudinal electron mobility and lateral hole mobility, which are important for the base resistance, are only slightly improved. On the other hand, in CMOS technology, the key performance enhancement factor of CMOS below 90nm is the lateral field mobility enhancement achieved by stress engineering. In one embodiment, bandgap engineering and mobility engineering are combined to further improve the performance of the HBT. For example, additional stress treatments can be used to improve lateral hole mobility, thereby reducing the base resistance that limits the maximum operating frequency of SiGe HBTs.

Claims (21)

1. a kind of transistor, it is characterised in that include:
The single crystal epitaxial metal silicide layer in Semiconductor substrate;
The monocrystalline emitter being formed on the metal silicide layer;
The base stage being formed on the emitter stage;With formation monocrystal silicon colelctor electrode on said base;
The insulation dielectric layer being deposited on the emitter stage, base stage and colelctor electrode, the contact hole being formed in insulation dielectric layer;
It is formed in the contact area of the correspondence contact hole position on emitter stage, base stage and colelctor electrode;
Wherein, the transistor has inverted structure of the colelctor electrode closer to transistor surface.
2. transistor according to claim 1, it is characterised in that the single crystal epitaxial metal silicide is to be located at Si substrates On extension NiSi2Film.
3. transistor according to claim 1, it is characterised in that the single crystal epitaxial metal silicide layer thickness be less than or Person is equal to 10 nanometers, and the base stage has the width less than or equal to 10 nanometers.
4. transistor according to claim 1, it is characterised in that the emitter stage is carbon doping.
5. transistor according to claim 1, it is characterised in that the thickness of the emitter stage and the colelctor electrode is respectively less than Or equal to 10 nanometers.
6. transistor according to claim 1, it is characterised in that in the emitter stage, the base stage and the colelctor electrode At least one is formed by least one ALE techniques.
7. transistor according to claim 1, it is characterised in that the base stage includes SiGe SiGe.
8. transistor according to claim 1, further distinguishes on the emitter stage, the base stage and the colelctor electrode Comprising Metal-silicides Contact area;The Metal-silicides Contact area has the resistivity of low-down 45 micro-ohm cm.
9. transistor according to claim 1, it is characterised in that the colelctor electrode is strained in carrier transport direction Process.
10. transistor according to claim 1, it is characterised in that the extremely lightly doped silicon of the current collection and in upper surface There is metal silicide layer.
11. transistors according to claim 1, it is characterised in that the base stage carries out strained handling.
12. transistors according to claim 11, it is characterised in that the base stage is further entered in an extra direction Row strained handling.
13. a kind of manufacture methods of transistor, it is characterised in that comprise the steps of:
Epitaxial growth single-crystal metal silicide layer on a semiconductor substrate;
In the metal silicide layer Epitaxial growth monocrystalline emitter;
In the emitter stage Epitaxial growth base stage;
Epitaxial growth monocrystal silicon colelctor electrode on said base;
Insulation dielectric layer is deposited on the emitter stage, base stage and colelctor electrode, contact hole is formed in insulation dielectric layer;
The correspondence contact hole position forms contact area on emitter stage, base stage and colelctor electrode.
14. according to claim 13 transistor manufacture method, it is characterised in that the metal silicide layer is using solid State reaction SSR techniques are grown in the NiSi on Si2Film.
15. according to claim 14 transistor manufacture method, it is characterised in that the SSR is processed and is included following sub-step Suddenly:
Ni film of the sputtering sedimentation thickness less than or equal to 2 nanometers;
Heat treatment.
16. according to claim 13 transistor manufacture method, it is characterised in that the emitter stage is given birth to by ALE techniques It is long.
17. according to claim 16 transistor manufacture method, it is characterised in that the emitter stage is in ALE technical processs In carry out carbon doping in situ.
18. according to claim 16 transistor manufacture method, it is characterised in that in ALE technical processs, using from swash The photon that light source sends helps the hydrogen atom on release liners surface.
19. according to claim 16 transistor manufacture method, it is characterised in that further comprise the steps of:To Si Emitter layer carries out strained handling.
20. according to claim 16 transistor manufacture method, it is characterised in that further comprise the steps of:It is right SiGe base layers carry out strained handling in multiple directions.
21. according to claim 16 transistor manufacture method, it is characterised in that further comprise the steps of:To collection Electrode layer applies mechanical stress from the top surface of the transistor.
CN201210544375.5A 2012-12-14 2012-12-14 Transistor and manufacturing method thereof Expired - Fee Related CN103000674B (en)

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US4492971A (en) * 1980-06-05 1985-01-08 At&T Bell Laboratories Metal silicide-silicon heterostructures
JPS5891631A (en) * 1981-11-27 1983-05-31 Hitachi Ltd Semiconductor device
JP2001332565A (en) * 2000-05-25 2001-11-30 Nec Corp Negative differential resistance element and method of manufacturing the same
US6825538B2 (en) * 2002-11-20 2004-11-30 Agere Systems Inc. Semiconductor device using an insulating layer having a seed layer
US7102205B2 (en) * 2004-09-01 2006-09-05 International Business Machines Corporation Bipolar transistor with extrinsic stress layer
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