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CN102978681A - Copper strip electrochemical oil removal method in clad-welding method copper-clad aluminum wire production line and device thereof - Google Patents

Copper strip electrochemical oil removal method in clad-welding method copper-clad aluminum wire production line and device thereof Download PDF

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Publication number
CN102978681A
CN102978681A CN2012104831698A CN201210483169A CN102978681A CN 102978681 A CN102978681 A CN 102978681A CN 2012104831698 A CN2012104831698 A CN 2012104831698A CN 201210483169 A CN201210483169 A CN 201210483169A CN 102978681 A CN102978681 A CN 102978681A
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copper
degreaser
clad
copper strip
production line
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CN2012104831698A
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CN102978681B (en
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戴雅康
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Dalian Tong Fa Trustworthiness Technology Co ltd
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Dalian TTOFF New Material Development Co Ltd
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  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention relates to a copper strip electrochemical oil removal method in a clad-welding method copper-clad aluminum wire production line and a device thereof. Specifically, according to the shortcoming that oil stains on the surface of a copper strip in the clad-welding method copper-clad aluminum wire production line can not be thoroughly cleaned, the invention discloses a copper strip electrochemical oil removal agent formula, an oil removal method and a device thereof. A copper strip is processed in a normal-temperature oil removal agent for about 10 seconds, and then the oil stains can be thoroughly removed. The copper strip oil removal device provided by the invention has the structural characteristics that the device is provided with a rectifying power supply; the copper strip is processed for at least 10 seconds in the oil removal agent in the clad-welding production lines at different operation speeds; when the production line stops, the copper strip automatically leaves the oil removal agent; and the copper strip after oil removal is cleaned and dried immediately.

Description

Copper strips electrochemical degreasing method and the device thereof of clad welded method copper-clad aluminum conductor
Technical field
The present invention relates to the copper strips deoiling method on the clad welded method copper-clad aluminum conductor production line, especially a kind of electrochemical degreasing method and used device thereof.
Background technology
The method of domestic present production copper-clad aluminum conductor mainly is the clad welded method.Copper strips and aluminium bar need Hang Cheongju reason to its Biao face Jin before entering the clad welded device.Wherein copper strips must be Zhong oil removal plant Cheongju except the oil stain on surface, for subsequently the copper metallurgy of aluminium in conjunction with creating conditions.But in used copper strip deoiling device, degreaser is the aqueous solution of a kind of " metal cleaner ", and copper strips is very short the runtime in this degreaser, so deoiling effect is very little, does not reach the purpose of thorough oil removing at all.And Bu Yong Cheongju water flushing after the copper strips oil removing, the surface is remaining solid degreaser vestige, often makes the copper strip surface variable color.
Summary of the invention
The objective of the invention is the deficiency for existing copper strips deoiling method and equipment therefor thereof, provide a kind of and guarantee that thorough end Cheongju except the electrochemistry scheme of oil stain, provides the device that is applicable to this deoiling method simultaneously.
A kind ofly remove the degreaser of copper strip surface oil stain for clad welded method copper-clad aluminum conductor, allocated by a certain percentage forming by following composition: sodium hydroxide, yellow soda ash, sodium phosphate and water glass, the pH that is configured to are 13~14.
Among the present invention, the prescription of degreaser is: sodium hydroxide 20g/L, yellow soda ash 20g/L, sodium phosphate 50g/L and water glass 10g/L.
Among the present invention, need carry out at normal temperatures electrochemical degreasing in the time of use.
Among the present invention, adopt the 8V rectifier power source in the time of use, copper strips connects (-) utmost point, and degreaser connects (+) utmost point.
Among the present invention, the oil removing time is minimum to be 10s.
Among the present invention, the structure of employed copper strip deoiling device should satisfy following requirement during oil removing: with rectifier power source; The clad welded production line of different travelling speed all should make copper strips move at least 10s in degreaser; During production line stop, copper strips leaves degreaser automatically; Clean immediately and dry up after the copper strips oil removing.
The present invention adopts alkaline degreaser.For example, sodium hydroxide 20g/L, yellow soda ash 20g/L, the solution that sodium phosphate 50g/L and water glass 10g/L are made into, the pH value is 13~14.Adopt the 8V rectifier power source, copper strips meets (-), and degreaser meets (+).After copper strips after the oil removing cleaned in clear water, the water on surface was not assembled and is the globule, but evenly spread out wetting, show deoil respond well.
Because the strong basicity degreaser has oxygenizement to copper strip surface, if copper strips storage period in this degreaser is long, will make the surface oxidation variable color.
Oil removal plant is placed a copper strips transit box made of plastic by a degreasing tank that be welded into mild steel plate, that be placed with degreaser in groove, be provided with a plurality of rollers in the case, to transmit copper strips.The base plate of this case has than multiple hole, and is located in the degreasing tank by spring support in four corners of base plate.The side plate of transit box is connected with lever with electromagnet armature.By the combined action of spring and electro-magnet, transmission case body is moved up and down in degreasing tank.When in the magnet coil during making current, armature drives lever and moves down, and makes the spring-compressed of copper strips transit box bottom and enters and carry out oil removing in the degreasing tank.After the magnet coil outage, under the effect of case bottom spring, copper strips transit box item is risen, make copper strips leave degreaser.In order to improve deoiling effect, accelerate in degreasing tank, to be provided with the rectifier power source of 8V, in order to carry out electrochemical degreasing except speed oil.Copper strips after the oil removing enters in the Rinsing Area and cleans, and dries up with hair drier immediately after the washing.
Description of drawings
Accompanying drawing 1 is copper strips electrochemical degreasing apparatus structure synoptic diagram.
Accompanying drawing 2 is copper strips electrochemical degreasing device electrical schematic.
Embodiment
Embodiment 1.
Copper strips electrochemical degreasing apparatus structure synoptic diagram as shown in Figure 1.2 is the degreasing tank that forms with Plastic Welding among the figure.The size of groove: long 1000mm, Wide 100mm, high 200mm.In groove, put into the degreaser of certain depth.
In this device, be provided with in addition 8V rectifier power source (not showing among Fig. 1).Its negative pole (-) contacts with the copper strips of operation by roller, and anodal (+) is placed in the degreasing tank by battery lead plate.
As shown in Figure 2, magnet coil 2 (being 10 among Fig. 1) and rectifier power source 3 elementary all is connected on the supply lead of production line master motor M.When contactor C connection, production line, lower armature is inhaled in energising in the magnet coil 2.As seen from Figure 1, armature drive this moment lever 11 is depressed into (spring 5 is compressed) in the degreasing tank with transmission case, and copper strips is moved forward in degreaser.Meanwhile, the elementary of rectifier power source also connected, and produces the 8V volts DS, makes copper strips carry out electrochemical degreasing.When contactor C disconnects, main motor M stall, it is mobile that production line is stopped.Meanwhile, magnet coil outage loses the gravitation to armature, make the copper strips transit box rely on Fig. 1 medi-spring 5 the elastic force effect and on move, break away from degreaser.At this moment, the elementary of rectifier power source also cut off the power supply simultaneously, do not have the function of electrochemical degreasing.
Copper strips after the oil removing is drawn together the remaining degreaser in surface through drawing together hydrophone 6, enters in the tank 7.After the flushing with clean water of copper strips through flowing, draw together the remaining moisture content in surface through drawing together hydrophone 8, then by large power, electrically blower 9 surface is dried up.
The travelling speed of the domestic copper-clad aluminum conductor clad welded production line that makes has two kinds at present.A kind of is that tradition coats welding production line, and travelling speed is 7.5m/min, and another kind is intelligent clad welded production line, and travelling speed is 15m/min.In order to guarantee that copper strips must move 10s in degreaser, can calculate for front a kind of production line, the running length of copper strips in degreaser is 1250mm.Just in time be the shown length of distance between each roller designed among Fig. 1.For intelligent clad welded production line, because travelling speed is very fast, the roller B among Fig. 1 can be installed to the C position, then the shown copper strips length of distance is 2500mm between each roller, satisfies the requirement that the production line travelling speed is 15m/min.
The present invention is described by embodiment, and those skilled in the art know, in the situation that does not break away from the spirit and scope of the present invention, can carry out various changes or equivalence replacement to these features and embodiment.In addition, under guidance of the present invention, can make amendment to adapt to concrete situation and material to these features and embodiment and can not break away from the spirit and scope of the present invention.Therefore, the present invention is not subjected to the restriction of specific embodiment disclosed herein, and all interior embodiment of claim scope that fall into the application belong to protection scope of the present invention.

Claims (6)

1. one kind is used for the degreaser that clad welded method copper-clad aluminum conductor is removed the copper strip surface oil stain, and allocated by a certain percentage forming by following composition: sodium hydroxide, yellow soda ash, sodium phosphate and water glass, the pH that is configured to are 13~14.
2. degreaser according to claim 1 is characterized in that: form sodium hydroxide 20g/L, yellow soda ash 20g/L, sodium phosphate 50g/L and water glass 10g/L by the following ingredients allotment.
3. a right to use requires the method for 1 described degreaser, it is characterized in that: need carry out at normal temperatures electrochemical degreasing in the time of use.
4. a kind of right to use of root requires the method for 1 described degreaser, it is characterized in that: adopt the 8V rectifier power source in the time of use, copper strips connects (-) utmost point, and degreaser connects (+) utmost point.
5. a right to use requires the method for 1 described degreaser, it is characterized in that: the oil removing time is minimum to be 10s.
6. a right to use requires the method for 1 described degreaser, it is characterized in that the structure of employed copper strip deoiling device should satisfy following requirement during oil removing: with rectifier power source; The clad welded production line of different travelling speed all should make copper strips move at least 10s in degreaser; During production line stop, copper strips leaves degreaser automatically; Clean immediately and dry up after the copper strips oil removing.
CN201210483169.8A 2012-11-26 2012-11-26 The copper strips electrochemical degreasing method and its device of tube-weld cladding technique copper-clad aluminum conductor Active CN102978681B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103510147A (en) * 2013-10-30 2014-01-15 重庆大学 Method for cleaning residual degreasant in inner cavity of metal product
CN104831206A (en) * 2015-04-12 2015-08-12 江苏太阳光伏科技有限公司 Solar solder strip tin-soldering device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101215708A (en) * 2008-01-08 2008-07-09 厦门大学 A kind of preparation method of corrosion-resistant nickel/chromium steel strip
CN101280443A (en) * 2008-05-21 2008-10-08 厦门大学 A kind of preparation method of secondary alloying electroplating nickel-molybdenum steel strip
CN201616277U (en) * 2009-12-29 2010-10-27 大连通发新材料开发有限公司 Silver-plated copper-clad steel wire with zinc layer
CN102234804A (en) * 2010-05-05 2011-11-09 肖云捷 Surface treatment method for abrasion-proof accessories
CN203112957U (en) * 2012-11-26 2013-08-07 大连通发复合线缆科技发展有限公司 Oil removal device for copper belt on clad-welding process copper-clad aluminium conductor production line

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101215708A (en) * 2008-01-08 2008-07-09 厦门大学 A kind of preparation method of corrosion-resistant nickel/chromium steel strip
CN101280443A (en) * 2008-05-21 2008-10-08 厦门大学 A kind of preparation method of secondary alloying electroplating nickel-molybdenum steel strip
CN201616277U (en) * 2009-12-29 2010-10-27 大连通发新材料开发有限公司 Silver-plated copper-clad steel wire with zinc layer
CN102234804A (en) * 2010-05-05 2011-11-09 肖云捷 Surface treatment method for abrasion-proof accessories
CN203112957U (en) * 2012-11-26 2013-08-07 大连通发复合线缆科技发展有限公司 Oil removal device for copper belt on clad-welding process copper-clad aluminium conductor production line

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103510147A (en) * 2013-10-30 2014-01-15 重庆大学 Method for cleaning residual degreasant in inner cavity of metal product
CN103510147B (en) * 2013-10-30 2015-11-18 重庆大学 A kind ofly wash the method that metal products inner chamber remains grease-removing agent
CN104831206A (en) * 2015-04-12 2015-08-12 江苏太阳光伏科技有限公司 Solar solder strip tin-soldering device

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