CN102977638A - Composition, preparation method and application thereof, textile and textile product - Google Patents
Composition, preparation method and application thereof, textile and textile product Download PDFInfo
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- CN102977638A CN102977638A CN2012105527572A CN201210552757A CN102977638A CN 102977638 A CN102977638 A CN 102977638A CN 2012105527572 A CN2012105527572 A CN 2012105527572A CN 201210552757 A CN201210552757 A CN 201210552757A CN 102977638 A CN102977638 A CN 102977638A
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- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000004753 textile Substances 0.000 title claims abstract description 8
- 238000004043 dyeing Methods 0.000 claims abstract description 28
- 239000000975 dye Substances 0.000 claims abstract description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000460 chlorine Substances 0.000 claims abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 4
- 239000011737 fluorine Substances 0.000 claims abstract description 4
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- 239000011591 potassium Substances 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 239000011734 sodium Substances 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 59
- 239000012752 auxiliary agent Substances 0.000 claims description 21
- 239000004744 fabric Substances 0.000 claims description 20
- 229920000742 Cotton Polymers 0.000 claims description 16
- 239000000985 reactive dye Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 238000007639 printing Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 abstract description 3
- 239000001043 yellow dye Substances 0.000 abstract description 3
- 238000005057 refrigeration Methods 0.000 abstract description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 60
- 238000006482 condensation reaction Methods 0.000 description 40
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 38
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 description 23
- 238000005859 coupling reaction Methods 0.000 description 21
- 238000006193 diazotization reaction Methods 0.000 description 21
- 239000002585 base Substances 0.000 description 20
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 18
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 18
- 235000017557 sodium bicarbonate Nutrition 0.000 description 18
- PEMGGJDINLGTON-UHFFFAOYSA-N n-(3-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=CC(N)=C1 PEMGGJDINLGTON-UHFFFAOYSA-N 0.000 description 13
- 239000002253 acid Substances 0.000 description 11
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 9
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 229950000244 sulfanilic acid Drugs 0.000 description 9
- ZNXSFVXZQBETRJ-UHFFFAOYSA-N (3-aminophenyl)urea Chemical compound NC(=O)NC1=CC=CC(N)=C1 ZNXSFVXZQBETRJ-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 229940056729 sodium sulfate anhydrous Drugs 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical group 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- VMKJWLXVLHBJNK-UHFFFAOYSA-N cyanuric fluoride Chemical compound FC1=NC(F)=NC(F)=N1 VMKJWLXVLHBJNK-UHFFFAOYSA-N 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005183 environmental health Effects 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
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Abstract
The invention provides a composition, a preparation method and application thereof, textile and a textile product. The composition comprises the following raw materials in parts by weight: 190 parts of component A, 10-99 parts of component B and 0-30 parts of optional assistant, wherein the component A is shown in Formula (I); the component B is shown in Formula (II); and in Formula (I) and Formula (II), R1 and R2 are respectively C1-4 alkyl or -NH2 independently, M1 and M2 are hydrogen, sodium or potassium, X1 and X2 are respectively are chlorine or fluorine independently, and n1 and n2 are respectively an integral number of 0-3 independently. According to the invention, when being used as a reactive yellow dye, the provided composition has the advantages of brilliant color light, high build-up property, favorable level-dyeing property and dyeing stability, excellent wet rubbing fastness and fine dye solution refrigeration property.
Description
Technical field
The present invention relates to a kind of composition, particularly relate to a kind of active yellow dye composition, also relate to preparation method and purposes and yarn fabric and the yarn fabric goods of said composition.
Background technology
Along with the day by day raising of people to sense comfortable and easy to wear and environmental health requirement, textile product is more and more concentrated to cotton fabric, and the demand of reactive dyestuffs also increases thereupon, becomes the most widely one of synthetic dyestuff of current application.
How to make dyestuff have one of exploitation direction that higher lifting force becomes reactive dyestuffs instantly.Because have high lifting force so that when carrying out the printing and dyeing of high dye level the usage quantity of dyestuff relatively reduce, thereby reduce the dyeing cost.And general wet rubbing fastness of reactive dye is all lower, can not satisfying the market the requirement of development.And after monochromatic kind dyestuff was printed and dyed to fiber, various performance index were difficult to reach people's requirement.Therefore the blending of two or more dyestuff is used and has been caused people's concern and attention.
Chinese patent application CN1807517A discloses a kind of composite reactive yellow dye, count by weight, by one or more of 30-99 part shown in structural formula (1) dyestuff A and one or more dyestuff B shown in structural formula (2) of 1-70 part form
In its Chinese style (1) and (2), R
1, R
2Be H, C independently of one another
1~ C
4Alkyl, C
1~ C
4Alkoxyl group ,-NHCOR' or-NHCONH
2, R' is C
1~ C
4Alkyl; R
3, R
4, R
6, R
7Be H, C independently of one another
1~ C
4Alkyl, C
1~ C
4Alkoxyl group or sulfonic group; R
5Be H or C
1~ C
4Alkyl; N is 0 ~ 3 integer; M respectively do for oneself H or alkali metal atom; X is-CH=CH
2Or-C
2H
4OSO
3M', M' are H or alkali metal atom.
Chinese patent application CN1076706A discloses a kind of dye composite, specifically discloses a kind of composition in the embodiment 10, and it comprises the compound shown in the compound shown in the following formula (3) and the following formula (4):
The dyeing behavior of disclosed dyestuff all can not the growing demand of satisfying the market in above-mentioned two kinds of patents.
Summary of the invention
The object of the invention is to overcome the defective of above-mentioned prior art, the equal excellence of a kind of every dyeing behavior, the composition that can meet the need of market are provided.
The invention provides a kind of composition, it comprises component A, B component and optional auxiliary agent; Described component A is by one or more compounds shown in the formula (I), and described B component is by one or more compounds shown in the formula (II); The content of described component A is 190 weight parts, and the content of described B component is 10～99 weight parts, and the content of described auxiliary agent is 0～30 weight part;
Formula (I) and (II) in, R
1, R
2Be C independently of one another
1-C
4Alkyl or-NH
2M
1, M
2Be hydrogen, sodium or potassium; X
1, X
2Be chlorine or fluorine independently of one another; n
1, n
2Be 0～3 integer independently of one another.
The present invention also provides the preparation method of described composition, and the method comprises one of following method:
(1) dry powder of component A, dry powder and the optional auxiliary agent of B component are mixed to get product;
(2) slurry of the slurry of component A, B component and optional auxiliary agent are mixed and stir, then carry out drying and obtain granular or powder-like product.
The present invention also provides the purposes of described composition, and said composition is as Yellow reactive dyes.
The present invention also provides a kind of yarn fabric, and it adopts according to composition provided by the invention and dyes and/or stamp obtains.
The present invention also provides a kind of yarn fabric goods, and it is used according to yarn fabric provided by the invention and makes.
According to composition of the present invention, it has the following advantages during as Yellow reactive dyes: coloured light is bright-coloured, lifting force is high, good level-dyeing property, dye stability are good, and fastness to wet rubbing is excellent, and dye liquor refrigeration property is good.Composition of the present invention is used for the dyeing of cellulosic fibre material, such as the printing and dyeing of cotton, artificial cotton, fiber crops, regenerated fibre and yarn fabric thereof, also is applicable in addition the dyeing of tynex, protein fibre and yarn fabric thereof.
Embodiment
Composition provided by the invention, it comprises component A, B component and optional auxiliary agent; Described component A is by one or more compounds shown in the formula (I), and described B component is by one or more compounds shown in the formula (II); The content of described component A is 190 weight parts, and the content of described B component is 10～99 weight parts, and the content of described auxiliary agent is 0～30 weight part;
Formula (I) and (II) in, R
1, R
2Be C independently of one another
1-C
4Alkyl or-NH
2M
1, M
2Be hydrogen, sodium or potassium; X
1, X
2Be chlorine or fluorine independently of one another; n
1, n
2Be 0～3 integer independently of one another.
According to composition provided by the invention, the compound shown in formula (I) and the formula (II) can the preparation method by the known condensation of routine, diazotization and coupling obtain or market on directly buy.For example its preparation method can be prepared according to disclosed method among the patent CN102108214A.The product of the plain trade mark of auspicious China that the compound shown in the formula that is obtained commercially (I) and the formula (II) is for example produced by Zhejiang Ruihua Chemical Co., Ltd..
According to composition provided by the invention, the content of described component A is preferably 30～90 weight parts, more preferably 45～65 weight parts.
According to composition provided by the invention, the content of described B component is preferably 10～70 weight parts, more preferably 35～55 weight parts.
According to composition provided by the invention, the content of described auxiliary agent is preferably 0～30 weight part.
According to composition provided by the invention, in the preferred case, said composition is comprised of described component A and described B component, and the content of described component A is 45～65 weight parts more preferably, and the content of described B component is 35～55 weight parts more preferably.
According to composition provided by the invention, in the preferred case, described component A is selected from by in the following compounds one or more:
In the preferred case, described B component is selected from by in the following compounds one or more:
According to composition provided by the invention, described auxiliary agent can be the combination of following one or more arbitrary proportions: Sodium sulfate anhydrous.min(99) (industrial sulphuric acid sodium), naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, benzyl naphthalene sulfonic formaldehyde condensation compound.Described auxiliary agent accounts for the weight part of 0-30 in composition provided by the invention.
The present invention also provides the preparation method of composition of the present invention, and the method comprises one of following method:
(1) dry powder of component A, dry powder and the optional auxiliary agent of B component are mixed to get product;
(2) slurry of the slurry of component A, B component and optional auxiliary agent are mixed and stir, then carry out drying and obtain granular or powder-like product.
Preferably, the preparation method of above-mentioned composition (1) after crushed first, then mixes the dry powder of component A, B component and auxiliary agent (if needing to add auxiliary agent) with mixing tank, make product.Mixing tank can be taper, drum-type or pears cutter formula.
Preferably, the preparation method of above-mentioned composition (2) is that the slurry that will produce good component A, slurry and the auxiliary agent (if needing to add auxiliary agent) of B component add the toning storage tank with stirrer in proportion, start stirrer and stir, make liquiform product; Or carry out drying and obtain granular or powder-like product.Described drying can adopt various drying means well known by persons skilled in the art, such as carrying out dry method through spray tower, drying room or flash distillation etc.
The present invention also provides the purposes of described composition, and said composition is as Yellow reactive dyes.Said composition is preferred for dyeing or the stamp of textiles, and described dyeing or stamp are the printing and dyeing of cotton, fiber crops, regenerated fibre or their yarn fabrics, perhaps dyeing or the stamp of tynex, protein fibre or their yarn fabric.
The present invention also provides a kind of yarn fabric, and it adopts according to composition provided by the invention and dyes and/or stamp obtains.
The present invention also provides a kind of yarn fabric goods, and it is used according to textiles provided by the invention and makes.Below adopt the mode of embodiment that the present invention is described in further detail, but the present invention is not limited in described embodiment (compound of describing as formula among the embodiment is expressed as the form of its sodium salt or sylvite, because it usually prepares and separate with the form of sodium salt or sylvite).
Embodiment
Now will adopt specific embodiment to describe the present invention in detail, but the invention is not restricted to described embodiment.And employed Amino C Acid is for having the compound of following structural formula (5) in following examples:
Structural formula (5):
Employed amino K acid is for having the compound of following structural formula (6) in the following comparative example 3:
Structural formula (6):
Embodiment 1
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
The B component of compound shown in the component A of compound shown in the 30 weight part formulas (I-1) and the 70 weight part formulas (II-1) is carried out dry powder blend by mixed assembly machine, namely get composition 1, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Embodiment 2
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and m-aminophenyl urea carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-2).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and m-aminophenyl urea carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-2).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With the B component of compound shown in the component A of compound shown in the 90 weight part formulas (I-2) and the 10 weight part formulas (II-2) be dissolved in the water stir after in baking oven 80 ℃ of lower oven dry, namely get composition 2, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Embodiment 3
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and m-aminophenyl urea carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-2).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
The B component of compound shown in the component A of compound shown in the 5 weight part formulas (I-1), the 70 weight part formulas (II-2) and 25 weight parts are carried out dry powder blend as the Sodium sulfate anhydrous.min(99) of weighting agent by mixed assembly machine, namely get composition 3, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Embodiment 4
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and m-aminophenyl urea carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-2).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response fully after and cyanuric chloride carry out the condensation reaction first time, 5-10 ℃ of temperature of reaction of control, pH5.0-6.0, question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and control 45-50 ℃ of temperature of reaction, pH4.5-5.5, the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and m-aminophenyl urea carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-2).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
The B component of compound shown in compound shown in the component A of compound shown in compound shown in the 20 weight part formulas (I-1), the 20 weight part formulas (I-2) and the 30 weight part formulas (II-1), the 30 weight part formulas (II-2) is carried out dry powder blend by mixed assembly machine, namely get composition 4, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Embodiment 5
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-4).In above-mentioned each reactions steps, all adopt saleratus to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-4).In above-mentioned each reactions steps, all adopt saleratus to regulate the pH value.
With the B component of compound shown in compound shown in the component A of compound shown in compound shown in the 30 weight part formulas (I-1), the 30 weight part formulas (I-4) and the 20 weight part formulas (II-1), the 20 weight part formulas (II-4) be dissolved in the water stir after in baking oven 80 ℃ of lower oven dry, namely get composition 5, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Embodiment 6
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric fluoride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-3).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric fluoride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-3).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
The B component of compound shown in the component A of compound shown in the 40 weight part formulas (I-3) and the 60 weight part formulas (II-3) is carried out dry powder blend by mixed assembly machine, namely get composition 6, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Comparative example 1
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.The fully rear Sulphanilic Acid that adds in a contracting thing of question response carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (I-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With the Sodium sulfate anhydrous.min(99) of compound shown in the 70 weight part formulas (I-1) and 30 weight parts be dissolved in the water stir after in baking oven 80 ℃ of lower oven dry, namely get composition 7, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Comparative example 2
With Amino C Acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and 3-acetylaminoaniline carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (II-1).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With the Sodium sulfate anhydrous.min(99) of compound shown in the 70 weight part formulas (II-1) and 30 weight parts be dissolved in the water stir after in baking oven 80 ℃ of lower oven dry, namely get composition 8, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Comparative example 3
With amino K acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and m-aminophenyl urea carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-2 in a contracting thing, the 4-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the component A of compound shown in the formula (7).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
With amino K acid diazotization under 0 ~ 5 ℃ temperature, then controlling temperature 5-10 ℃, pH5.0-6.5 and m-aminophenyl urea carries out coupled reaction and generates color base, question response carries out the condensation reaction first time with cyanuric chloride after fully, controls 5-10 ℃ of temperature of reaction, pH5.0-6.0.Question response is fully rear to add aniline-3 in a contracting thing, the 5-disulfonic acid carries out the second condensation reaction, and controls 45-50 ℃ of temperature of reaction, pH4.5-5.5, and the afterreaction terminal point arrived in about 8 hours, got the B component of compound shown in the formula (8).In above-mentioned each reactions steps, all adopt sodium bicarbonate to regulate the pH value.
The B component of compound shown in the component A of compound shown in the 30 weight part formulas (7) and the 70 weight part formulas (8) is carried out dry powder blend by mixed assembly machine, namely get composition 1, said composition as Yellow reactive dyes, can be become golden yellow to cotton dyeing.
Performance test
The 100g cotton fabric is put into 1000g 45g/L sodium-chlor and 2g according to the dye bath of embodiment 1～6 and comparative example 1～3 resulting composition, with 1 ℃/minute be warmed up to 60 ℃ after, add the sodium carbonate solution of 100g 20g/L, and under this temperature, dyeed 45 minutes, then the dyeing and weaving thing is washed post rinse and dry after soaping 15 minutes with nonionic detergent.Test its rub resistance, water-fastness and colour fastness to perspiration according to GB/T 3920-2008, GB/T 3921-2008 and GB/T 3922-1995, the result is as shown in table 1 below:
Table 1
As from the foregoing, composition of the present invention is as Yellow reactive dyes, and when being applied to dye, every colour fastness is all better, and fastness to wet rubbing is excellent especially.
Claims (12)
1. composition, it comprises component A, B component and optional auxiliary agent;
Described component A is by one or more compounds shown in the formula (I), and described B component is by one or more compounds shown in the formula (II);
The content of described component A is 1～90 weight part, and the content of described B component is 10～99 weight parts, and the content of described auxiliary agent is 0～30 weight part;
Formula (I) and (II) in, R
1, R
2Be C independently of one another
1-C
4Alkyl or-NH
2M
1, M
2Be hydrogen, sodium or potassium; X
1, X
2Be chlorine or fluorine independently of one another; n
1, n
2Be 0～3 integer independently of one another.
2. composition according to claim 1 is characterized in that, the content of described component A is 30～90 weight parts, and the content of described B component is 10～70 weight parts, and the content of described auxiliary agent is 0～30 weight part.
3. composition according to claim 1 is characterized in that, said composition is comprised of described component A and described B component, and the content of described component A is 45～65 weight parts, and the content of described B component is 35～55 weight parts.
4. each described composition is characterized in that according to claim 1-3, and described component A is selected from by in the following compounds one or more:
5. each described composition is characterized in that according to claim 1-4,
Described B component is selected from by in the following compounds one or more:
6. according to claim 1,2,4 or 5 described compositions, it is characterized in that described auxiliary agent comprises at least a in dispersion agent, diffusant and the weighting agent.
7. the preparation method of each described composition according to claim 1-6, the method comprises one of following method:
(1) dry powder of component A, dry powder and the optional auxiliary agent of B component are mixed to get product;
(2) slurry of the slurry of component A, B component and optional auxiliary agent are mixed and stir, then carry out drying and obtain granular or powder-like product.
8. the purposes of each described composition according to claim 1-6, said composition is as Yellow reactive dyes.
9. purposes according to claim 8, said composition is used for dyeing or the stamp of textiles.
10. purposes according to claim 9, described dyeing or stamp are the printing and dyeing of cotton, artificial cotton, fiber crops, regenerated fibre or their yarn fabrics, perhaps dyeing or the stamp of tynex, protein fibre or their yarn fabric.
11. a yarn fabric, it adopts according to claim 1-6 each described compositions to dye and/or stamp and obtaining.
12. yarn fabric goods, it is made with yarn fabric according to claim 11.
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