CN102977583B - Noryl and prepare the method for base material based on Noryl - Google Patents
Noryl and prepare the method for base material based on Noryl Download PDFInfo
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- CN102977583B CN102977583B CN201110260997.0A CN201110260997A CN102977583B CN 102977583 B CN102977583 B CN 102977583B CN 201110260997 A CN201110260997 A CN 201110260997A CN 102977583 B CN102977583 B CN 102977583B
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- solvent
- noryl
- aluminium hydroxide
- base material
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- 239000004727 Noryl Substances 0.000 title claims abstract description 39
- 229920001207 Noryl Polymers 0.000 title claims abstract description 39
- 239000000463 material Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 22
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000002904 solvent Substances 0.000 claims abstract description 42
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 31
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 27
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 27
- 239000011159 matrix material Substances 0.000 claims abstract description 26
- 229940102396 methyl bromide Drugs 0.000 claims abstract description 25
- 239000000758 substrate Substances 0.000 claims abstract description 16
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 64
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 48
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 23
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 16
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 15
- 229960001866 silicon dioxide Drugs 0.000 claims description 13
- 235000012239 silicon dioxide Nutrition 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003063 flame retardant Substances 0.000 abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 229920006380 polyphenylene oxide Polymers 0.000 description 27
- -1 amino silicane Chemical compound 0.000 description 10
- 239000007822 coupling agent Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920002492 poly(sulfone) Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Embodiments provide a kind of Noryl, component comprises by weight: methyl bromide PPO 5-100 part, aluminium hydroxide 0-50 part and solvent 0-40 part; Wherein, the value of aluminium hydroxide and solvent is not 0.The embodiment of the present invention additionally provides a kind of method preparing base material based on Noryl, the method comprises: the solvent of the methyl bromide PPO of 5-100 part, the aluminium hydroxide of 0-50 part and 0-40 part is placed in container by component by weight, be stirred to dissolving, obtain matrix material; Apply described matrix material on an insulating substrate; The insulating substrate being coated with matrix material is dried, arrange plate, hot-forming, dismounting and processing, obtain base material; Wherein, the value of aluminium hydroxide and solvent is not 0.When moderate cost, the base material with good dielectricity, thermotolerance, water tolerance, flame retardant resistance and dimensional stability can be obtained by the present invention.
Description
[technical field]
The present invention relates to Meta Materials technical field, particularly relate to a kind of Noryl and prepare the method for base material based on Noryl.
[background technology]
Modern electronic technology develops rapidly, and process, the transmission of digital circuit enter the high frequency stage, and at this moment the performance of substrate will have a strong impact on circuit characteristic, wherein particularly important with several performances such as dielectric properties, thermotolerance, dimensional stability, wet fastnesss.And the performance of substrate depends primarily on material used, high performance base material is therefore selected to be the prerequisite realizing high-performance substrate.Traditional base material many employings resol and epoxy resin, the epoxy resin board FR-4 of what current application was maximum is glass fiber reinforcement, this material is owing to having low cost of manufacture, cost performance advantages of higher, good application is had in low-frequency electronic product, but in high frequency circuit, due to its dielectric properties and resistance to elevated temperatures poor, therefore, FR-4 is not suitable for being applied in high frequency circuit.
In prior art, the substrate applied in high frequency circuit, be generally directly adopt new high-performance matrix resin, conventional high-performance matrix resin has tetrafluoroethylene (PTFE), polyphenylene oxide (PPO), cyanic acid resin (CE), BT resin, polyimide (PI), polysulfones (PSF) etc.PTFE has high temperature resistant, resistance to chemical attack and electrical insulating property, but the more difficult processing of PTFE, and surface is in inertia, is difficult to bond with Copper Foil.Polyphenylene oxide has good dielectricity, dimensional stability, flame retardant resistance etc., but polyphenylene oxide processing difficulties and non-refractory.Polymide dielectric, thermotolerance and dimensional stability are all better.Polysulfones also has good dielectricity, thermotolerance and dimensional stability.Although use high performance matrix resin to prepare dielectricity and thermotolerance that base material can improve base material, the matrix resin of high property is expensive, and production cost is higher.
[summary of the invention]
Technical problem to be solved by this invention is to provide a kind of Noryl and prepares the method for base material based on Noryl, when can improve substrate dielectric, thermotolerance, water tolerance, flame retardant resistance and dimensional stability, reduces production cost.
Technical problem to be solved by this invention is to provide a kind of Noryl, and component comprises by weight: methyl bromide PPO 5-100 part, aluminium hydroxide 0-50 part and solvent 0-40 part; Wherein, the value of aluminium hydroxide and solvent is not 0.
For solving the problems of the technologies described above, one embodiment of the invention provides a kind of method preparing base material based on Noryl, and the method comprises:
The solvent of the methyl bromide PPO of 5-100 part, the aluminium hydroxide of 0-50 part and 0-40 part is placed in container by component by weight, is stirred to dissolving, obtains matrix material;
Apply described matrix material on an insulating substrate;
The insulating substrate being coated with matrix material is dried, arrange plate, hot-forming, dismounting and processing, obtain base material;
Wherein, the value of aluminium hydroxide and solvent is not 0.
Compared with prior art, technique scheme has the following advantages: because methyl bromide PPO has good dielectricity, thermotolerance, water tolerance, flame retardant resistance and dimensional stability, therefore in methyl bromide PPO, mineral filler is added, when modified methyl bromide PPO has good dielectricity, thermotolerance, water tolerance, flame retardant resistance and dimensional stability, and moderate cost.
[embodiment]
Be clearly and completely described the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
(1) embodiment for matrix material comprises:
Embodiment one,
The Noryl that the present embodiment provides by weight component comprises: methyl bromide PPO 80 parts, 20 parts, aluminium hydroxide and solvent 20 parts.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO).
In the present embodiment, because methyl bromide PPO has good dielectricity, thermotolerance, water tolerance, flame retardant resistance and dimensional stability, therefore in methyl bromide PPO, mineral filler is added, when modified methyl bromide PPO has good dielectricity, thermotolerance, water tolerance, flame retardant resistance and dimensional stability, and moderate cost.
Embodiment two,
The Noryl that the present embodiment provides by weight component comprises: methyl bromide PPO 80 parts, 20 parts, aluminium hydroxide, dispersion agent 0.5 part and solvent 20 parts.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO).
The relative embodiment one of the present embodiment, owing to adding dispersion agent, thus improves chemical stability and the thermostability of Noryl.
Embodiment three,
The Noryl that the present embodiment provides by weight component comprises: methyl bromide PPO 80 parts, 20 parts, aluminium hydroxide, dispersion agent 0.5 part, silane coupling agent 0.5 part and solvent 20 parts.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
The relative embodiment two of the present embodiment, owing to adding silane coupling agent, thus improves the cementability between methyl bromide PPO and aluminium hydroxide.
Embodiment four,
The Noryl that the present embodiment provides by weight component comprises: methyl bromide PPO 80 parts, 20 parts, aluminium hydroxide, silicon-dioxide 20 parts, dispersion agent 0.5 part, silane coupling agent 0.5 part and solvent 20 parts.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
The relative embodiment three of the present embodiment, owing to adding silicon-dioxide, thus enhances the mechanical property of matrix material.
Embodiment five,
The Noryl that the present embodiment provides by weight component comprises: methyl bromide PPO 90 parts, 25 parts, aluminium hydroxide, silicon-dioxide 20 parts, dispersion agent 0.5 part, silane coupling agent 0.5 part and solvent 20 parts.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
The present embodiment is relative to embodiment four, and the content of each component is different, and in the present embodiment, each component is with reference to implementing one to embodiment four, can also draw other embodiments, repeat no more herein.
Embodiment six,
The Noryl that the present embodiment provides by weight component comprises: methyl bromide PPO 90 parts, 30 parts, aluminium hydroxide, silicon-dioxide 25 parts, dispersion agent 0.5 part, silane coupling agent 0.5 part and solvent 25 parts.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
The present embodiment is relative to embodiment four, and the content of each component is different, and in the present embodiment, each component is with reference to implementing one to embodiment four, can also draw other embodiments, repeat no more herein.
Embodiment seven,
The Noryl that the present embodiment provides by weight component comprises: methyl bromide PPO 90 parts, 40 parts, aluminium hydroxide, silicon-dioxide 40 parts, dispersion agent 1 part, silane coupling agent 1 part and solvent 23 parts.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
The present embodiment is relative to embodiment four, and the content of each component is different, and in the present embodiment, each component is with reference to implementing one to embodiment four, can also draw other embodiments, repeat no more herein.
(2) comprise for the embodiment preparing base material based on Noryl:
Embodiment one,
Present embodiments provide a kind of method preparing base material based on Noryl, comprising:
S11: the solvent of the methyl bromide PPO of 80 parts, the aluminium hydroxide of 20 parts and 20 parts is placed in container by component by weight, is stirred to dissolving, obtains matrix material.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO).
S12: apply the matrix material that S11 step obtains on an insulating substrate.
Concrete, according to the content of required matrix material, the gluing speed of adjustment adhesive applicator, by insulating substrate coating composite materials on adhesive applicator.
Wherein, insulating substrate can be electronic-grade glass fiber cloth.
S13: the insulating substrate being coated with matrix material is dried, obtains prepreg.
Concrete, adjustment oven for gluing machine temperature, dries the insulating substrate being coated with matrix material, obtains prepreg.
S14: to S13 step to prepreg carry out row's plate.
Concrete, prepreg is carried out folded joining according to the thickness requirement of required base material, is then covered with Copper Foil.
S15: temperature, pressure, the hot pressing time of adjustment thermocompressor, be assemblied in hot-forming sheet material in thermocompressor by the prepreg after typesetting.
S16: shaping sheet material is dismantled, utilized sheet shears to carry out sharp processing, obtains required base material.
In concrete implementation process, also need the step comprising the examination and test of products.
In the present embodiment, Noryl is adopted to prepare base material, because Noryl has good dielectricity, thermotolerance, water tolerance, flame retardant resistance and dimensional stability, and moderate cost, therefore the base material prepared also has good dielectricity, thermotolerance, water tolerance, flame retardant resistance and dimensional stability, and cheap, can be used as the base material of high frequency printed circuit board or Meta Materials.
Embodiment two,
Present embodiments provide a kind of method preparing base material based on Noryl, comprising:
S21: the solvent of the methyl bromide PPO of 80 parts, the aluminium hydroxide of 20 parts, the dispersion agent of 0.5 part and 20 parts is placed in container by component by weight, is stirred to dissolving, obtains matrix material.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO).
Other steps are identical with the step of S12 to S16 in embodiment one, repeat no more herein.
The present embodiment, relative to embodiment one, improves chemical stability and the thermostability of the base material of preparation.
Embodiment three,
Present embodiments provide a kind of method preparing base material based on Noryl, comprising:
S31: the solvent of the methyl bromide PPO of 80 parts, the aluminium hydroxide of 20 parts, the dispersion agent of 0.5 part, the silane coupling agent of 0.5 part and 20 parts is placed in container by component by weight, is stirred to dissolving, obtains matrix material.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
Other steps are identical with the step of S12 to S16 in embodiment one, repeat no more herein.
The present embodiment, relative to embodiment two, improves the cohesive force of the base material of preparation.
Embodiment four,
Present embodiments provide a kind of method preparing base material based on Noryl, comprising:
S41: the solvent of the methyl bromide PPO of 80 parts, the aluminium hydroxide of 20 parts, the silicon-dioxide of 20 parts, the dispersion agent of 0.5 part, the silane coupling agent of 0.5 part and 20 parts is placed in container by component by weight, is stirred to dissolving, obtains matrix material.
Wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
Other steps are identical with the step of S12 to S16 in embodiment one, repeat no more herein.
The present embodiment, relative to embodiment three, improves the mechanical property of the base material of preparation.
Embodiment five,
Present embodiments provide a kind of method preparing base material based on Noryl, comprising:
S51: the solvent of the methyl bromide PPO of 90 parts, the aluminium hydroxide of 25 parts, the silicon-dioxide of 20 parts, the dispersion agent of 0.5 part, the silane coupling agent of 0.5 part and 20 parts is placed in container by component by weight, is stirred to dissolving, obtains matrix material.
Wherein, wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
Other steps are identical with the step of S12 to S16 in embodiment one, repeat no more herein.
The present embodiment is relative to embodiment four, and in Noryl, the content of each component is different, and in the present embodiment, in Noryl, each component, with reference to implementing one to embodiment four, can also draw other embodiments, repeat no more herein.
Embodiment six,
Present embodiments provide a kind of method preparing base material based on Noryl, comprising:
S61: the solvent of the methyl bromide PPO of 90 parts, the aluminium hydroxide of 30 parts, the silicon-dioxide of 25 parts, the dispersion agent of 0.5 part, the silane coupling agent of 0.5 part and 25 parts is placed in container by component by weight, is stirred to dissolving, obtains matrix material.
Wherein, wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
Other steps are identical with the step of S12 to S16 in embodiment one, repeat no more herein.
The present embodiment is relative to embodiment four, and in Noryl, the content of each component is different, and in the present embodiment, in Noryl, each component, with reference to implementing one to embodiment four, can also draw other embodiments, repeat no more herein.
Embodiment seven,
Present embodiments provide a kind of method preparing base material based on Noryl, comprising:
S71: the solvent of the methyl bromide PPO of 90 parts, the aluminium hydroxide of 40 parts, the silicon-dioxide of 40 parts, the dispersion agent of 1 part, the silane coupling agent of 1 part and 23 parts is placed in container by component by weight, is stirred to dissolving, obtains matrix material.
Wherein, wherein, solvent can be: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO); Silane coupling agent is amino silicane coupling agent.
Other steps are identical with the step of S12 to S16 in embodiment one, repeat no more herein.
The present embodiment is relative to embodiment four, and in Noryl, the content of each component is different, and in the present embodiment, in Noryl, each component, with reference to implementing one to embodiment four, can also draw other embodiments, repeat no more herein.
Be described in detail the embodiment of the present invention above, apply specific case herein and set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping; Meanwhile, for one of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (4)
1. a Noryl, is characterized in that, component comprises by weight: methyl bromide PPO 5-100 part, aluminium hydroxide 0-50 part, silane coupling agent 0.1-2 part, dispersion agent 0.1-2 part, silicon-dioxide 0-50 part and solvent 0-40 part; Wherein, the value of aluminium hydroxide and solvent is not 0, silicon-dioxide value is not 0.
2. Noryl according to claim 1, is characterized in that, described solvent is: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO).
3. prepare a method for base material based on Noryl, it is characterized in that, described method comprises:
The solvent of the silicon-dioxide of the dispersion agent of the aluminium hydroxide of the methyl bromide PPO of 5-100 part, 0-50 part, 0.1-2 part, 0-50 part, the silane coupling agent of 0.1-2 part and 0-40 part is placed in container by component by weight, be stirred to dissolving, obtain matrix material;
Apply described matrix material on an insulating substrate;
The insulating substrate being coated with matrix material is dried, arrange plate, hot-forming, dismounting and processing, obtain base material;
Wherein, the value of aluminium hydroxide and solvent is not 0, silicon-dioxide value is not 0.
4. method according to claim 3, is characterized in that, described solvent is: dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-Methyl pyrrolidone or dimethyl sulfoxide (DMSO).
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|---|---|---|---|---|
| CN101668806A (en) * | 2007-04-26 | 2010-03-10 | 日立化成工业株式会社 | Process for producing resin varnish containing semi-ipn composite thermosetting resin and, provided using the same, resin varnish for printed wiring board, prepreg and metal-clad laminate |
| CN102093666A (en) * | 2010-12-23 | 2011-06-15 | 广东生益科技股份有限公司 | Halogen-free resin composition and manufacturing method of halogen-free copper-clad laminate using same |
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