CN102964723B - Polyvinyl chloride (PVC) cable material for automobile data transmission wire - Google Patents
Polyvinyl chloride (PVC) cable material for automobile data transmission wire Download PDFInfo
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- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 37
- 230000005540 biological transmission Effects 0.000 title claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 68
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 47
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 38
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims abstract description 21
- -1 polyethylene Polymers 0.000 claims abstract description 21
- 239000003381 stabilizer Substances 0.000 claims abstract description 21
- 239000004698 Polyethylene Substances 0.000 claims abstract description 18
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 18
- 229920000573 polyethylene Polymers 0.000 claims abstract description 18
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 15
- 239000003549 soybean oil Substances 0.000 claims abstract description 15
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 14
- 238000012545 processing Methods 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical group [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 22
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 20
- 239000004902 Softening Agent Substances 0.000 claims description 17
- 239000004593 Epoxy Substances 0.000 claims description 14
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 10
- 150000002910 rare earth metals Chemical class 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 6
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000002530 phenolic antioxidant Substances 0.000 claims description 3
- 150000008301 phosphite esters Chemical class 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005299 abrasion Methods 0.000 abstract description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 239000004014 plasticizer Substances 0.000 abstract 4
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N oxygen(2-);yttrium(3+) Chemical class [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 2
- 235000011006 sodium potassium tartrate Nutrition 0.000 description 2
- 229940095064 tartrate Drugs 0.000 description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a polyvinyl chloride (PVC) cable material for an automobile data transmission wire. The PVC material comprises the components based on parts by weight: 100 parts of SG3 type PVC resin, 25-30 parts of plasticizer 1, 3-5 parts of plasticizer 2, 10-12 parts of calcium carbonate, 8-12 parts of stabilizer, 0.8-1.2 parts of polyethylene wax, 2-4 parts of ACR impact modifier, 0.1-0.5 part of antioxidant, 2-3 parts of nano barium sulfate and 0.3-0.8 part of silicone powder, wherein the plasticizer 1 comprises one or two selected from trioctyl trimellitate or purified terephthalic acid dioctyl ester; the plasticizer 2 comprises one or two selected from epoxidized soybean oil and terephthalic acid dioctyl ester; and the silicone powder is silica powder treated by silicone. The PVC cable material has the temperature classification of 105 DEG C, thus having good processability under the condition of high-speed processing; and the obtained cable has excellent abrasion resistance and mechanical property, and the odor can be eliminated.
Description
Technical field
The present invention relates to the technical field of insulated cable material, in particular, the present invention relates to a kind of data transmission automotive line PVC CABLE MATERIALS.
Background technology
Pvc material has good rigidly, intensity is high, fire-retardant, corrosion-resistant, electric insulating quality is good; And processing characteristics is good, cheap, thereby have a wide range of applications in CABLE MATERIALS industry.Conventionally automobile electric wire is also taking polyvinyl chloride (PVC) RESINS as base-material conventionally, adds softening agent, stablizer and processing aid, processes through special kneading device.Automobile electric wire cable is different from general electric wire, is specially for the needs of automobile design.Because automotive interior is a very complicated subenvironment, there are the various complex conditions such as vibrations, friction, greasy dirt, high heat, cold and electromagnetic radiation, thereby require automobile electric wire to there are the various functions such as heat-resisting, cold-resistant, wear-resisting, tasteless and anti-interference.
One of gordian technique of PVC automobile cable material is exactly the Improvement of wear resisting property, automotive line is because its use location is special, automobile cannot be avoided the mutual friction of etween the lines in operational process, once the worn out meeting of plastics jacket directly causes short circuit to cause hidden peril of accident, so automobile-used electric wire requires to have enough wear resisting propertys.But in prior art for the wear resistance of PVC CABLE MATERIALS, common CABLE MATERIALS can not meet the demands far away.EP0915485A1 discloses a kind of PVC blend formula for automobile thin-walled insulation electric wire, and it is by adding urethane to improve the wear resistance of electric wire.EP1209697A1 has introduced a kind of unleaded PVC blend, and for automobile thin-walled insulation cable, tool has good wearability and resistance to elevated temperatures.But CABLE MATERIALS wear resistance in above-mentioned patent need further raising.In recent years, along with the development of irradiation technique, promoted the development of crosslinked electric cable material, cross-linking radiation PVC Insulation Material can significantly improve the wear resisting property of material, but complex process, cost is higher.
Summary of the invention
In order to solve the above-mentioned technical problem existing in prior art, the object of the present invention is to provide a kind of data transmission automotive line PVC CABLE MATERIALS.This PVC CABLE MATERIALS is temperature classification the CABLE MATERIALS of 105 DEG C, and under High-speed machining condition, still has good processing characteristics, and the cable preparing has excellent scratch-resistant performance and mechanical property, and has eliminated peculiar smell.
In order to solve the problems of the technologies described above and realize above-mentioned purpose, the present invention takes following technical scheme:
A kind of data transmission automotive line PVC CABLE MATERIALS, its raw material comprises the component of following weight part: the polyvinyl chloride resin of SG3 type: 100 parts, softening agent 1:25-30 part, softening agent 2:3-5 part, calcium carbonate: 10-12 part, stablizer: 8-12 part, polyethylene wax: 0.8-1.2 part, ACR impact modifier: 2-4 part, oxidation inhibitor: 0.1-0.5 part, nano barium sulfate: 2-3 part, silicone powder: 0.3-0.8 part; Wherein softening agent 1 is selected from one or both of trioctyl trimellitate (TOTM) or pure terephthalic acid's dioctyl ester; Softening agent 2 is selected from one or both in epoxy soybean oil, dioctyl terephthalate (DOTP); Described silicone powder is the coated SiO 2 powder of processing of silicone powder.
Wherein, described softening agent 1 is trioctyl trimellitate, and softening agent 2 is epoxy soybean oil and dioctyl terephthalate, and the ratio of weight and number of epoxy soybean oil and dioctyl terephthalate is 1:2.
Wherein, described stablizer is calcium zinc stabilizer or rare earth calcium zinc one package stabilizer.
Wherein, described polyethylene wax is fusing point higher than the high melting point polyethylene wax of 105 DEG C.
Wherein, described calcium carbonate is calcene, nano-calcium carbonate or water-ground limestone.
Wherein, described SiO 2 powder is nano amorphous SiO 2 powder.
Wherein, described oxidation inhibitor is selected from one or more in phenolic antioxidant, amine antioxidants, sulfur type antioxidant and phosphite ester kind antioxidant.
In described silicone powder, the parts by weight of silicone powder are 0.1-0.2 part, and the weight fraction of SiO 2 powder is 0.2-0.6 part.
Compared with prior art the present invention has following beneficial effect:
(1) product of the present invention is by design and the selection of component, basically eliminate the peculiar smell of PVC CABLE MATERIALS.
(2) product of the present invention contains silicon-dioxide by interpolation silicone powder and ultra-fine barium sulfate, significantly improved the wear resistance of product, also strengthened the erosion resistance of product simultaneously.
(3) temperature classification of product of the present invention is more than 105 DEG C, can reach 120 DEG C under optimum condition, and Drawing abillity is good, and technique is simple, and cost is lower, has good market outlook.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is further elaborated, but embodiments of the present invention are not limited to this.
Data transmission automotive line PVC CABLE MATERIALS in described embodiment, its raw material comprises the component of following weight part: the polyvinyl chloride resin of SG3 type: 100 parts, softening agent 1:25-30 part, softening agent 2:3-8 part, calcium carbonate: 10-12 part, calcium zinc stabilizer or rare earth calcium zinc one package stabilizer: 8-12 part, polyethylene wax: 0.8-1.2 part, ACR impact modifier: 2-4 part, oxidation inhibitor: 0.1-0.5 part, nano barium sulfate: 2-3 part, silicone powder: 0.3-0.8 part; Wherein softening agent 1 is selected from one or both of trioctyl trimellitate (TOTM) or pure terephthalic acid's dioctyl ester; Softening agent 2 is selected from one or both in epoxy soybean oil, dioctyl terephthalate (DOTP); Described silicone powder is the coated SiO 2 powder of processing of silicone powder.Wherein said oxidation inhibitor is selected from one or more in phenolic antioxidant, amine antioxidants, sulfur type antioxidant and phosphite ester kind antioxidant, for example dihydroxyphenyl propane.In addition as required, can also be in data transmission automotive line of the present invention such as, with adding other component, fire retardant, lubricant etc. in PVC CABLE MATERIALS.Data transmission automotive line of the present invention can adopt conventional method to prepare by PVC CABLE MATERIALS.For example various raw materials are mixed to get to mixture, then by mixture extruding pelletization.In addition, automobile cable can be prepared by above-mentioned CABLE MATERIALS.And the preparation method of automobile cable has been conventionally known to one of skill in the art, needn't repeat at this.
embodiment 1
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 25 parts, epoxy soybean oil: 2 parts, dioctyl terephthalate: 3 parts, nano-calcium carbonate: 10 parts, commercially available calcium zinc stabilizer: 8 parts, polyethylene wax: 0.8 part, ACR impact modifier: 4 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, silicone powder: 0.6 part; Described silicone powder is the coated nanocrystalline SiO 2 powder (parts by weight of silicone powder are 0.2 part, and the parts by weight of SiO 2 powder are 0.4 part) of processing of silicone.
embodiment 2
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 30 parts, dioctyl terephthalate: 3 parts, nano-calcium carbonate: 12 parts, commercially available calcium zinc stabilizer: 12 parts, polyethylene wax: 1.2 parts, ACR impact modifier: 3 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, silicone powder: 0.6 part; Described silicone powder is the coated nanocrystalline SiO 2 powder (parts by weight of silicone powder are 0.2 part, and the parts by weight of SiO 2 powder are 0.4 part) of processing of silicone.
embodiment 3
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 28 parts, epoxy soybean oil: 2 parts, dioctyl terephthalate: 2 parts, nano-calcium carbonate: 10 parts, commercially available calcium zinc stabilizer: 10 parts, polyethylene wax: 0.8 part, ACR impact modifier: 2 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, silicone powder: 0.6 part; Described silicone powder is the coated nano amorphous SiO 2 powder (parts by weight of silicone powder are 0.2 part, and the parts by weight of SiO 2 powder are 0.4 part) of processing of silicone.
Commercially available calcium zinc stabilizer described in embodiment 1-3 is the 519A calcium zinc stabilizer that is applicable to electric wire that Jiangxi Hongyuan Chemical Co., Ltd. produces.
embodiment 4
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 25 parts, epoxy soybean oil: 2 parts, dioctyl terephthalate: 3 parts, nano-calcium carbonate: 10 parts, rare earth calcium zinc one package stabilizer: 8 parts, polyethylene wax: 0.8 part, ACR impact modifier: 4 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, silicone powder: 0.6 part; Described silicone powder is the coated nanocrystalline SiO 2 powder (parts by weight of silicone powder are 0.2 part, and the parts by weight of SiO 2 powder are 0.4 part) of processing of silicone.
embodiment 5
The polyvinyl chloride resin of SG3 type: 100 parts, rare earth calcium zinc one package stabilizer: 30 parts, dioctyl terephthalate: 3 parts, nano-calcium carbonate: 12 parts, commercially available calcium zinc stabilizer: 12 parts, polyethylene wax: 1.2 parts, ACR impact modifier: 3 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, silicone powder: 0.6 part; Described silicone powder is the coated nanocrystalline SiO 2 powder (parts by weight of silicone powder are 0.2 part, and the parts by weight of SiO 2 powder are 0.4 part) of processing of silicone.
embodiment 6
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 28 parts, epoxy soybean oil: 2 parts, dioctyl terephthalate: 2 parts, nano-calcium carbonate: 10 parts, rare earth calcium zinc one package stabilizer: 10 parts, polyethylene wax: 0.8 part, ACR impact modifier: 2 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, silicone powder: 0.6 part; Described silicone powder is the coated nano amorphous SiO 2 powder (parts by weight of silicone powder are 0.2 part, and the parts by weight of SiO 2 powder are 0.4 part) of processing of silicone.
Rare earth calcium zinc one package stabilizer described in embodiment 4-6 is made up of 5 weight part yttrium oxides, 1 weight part Indium sesquioxide, 15 weight part tartrate, 3 weight part Seignette salts, 32 weight part Calucium Silicate powder, 38 weight part Zinic stearass, 2 parts of phosphorous acid and 10 parts of silicone powder, described preparation method is: by 15 weight part tartrate, 3 weight part Seignette salts add in the water of 60 weight parts and are mixed and heated to 60 DEG C, add 2 parts of phosphorous acid, then continue to be heated to 85 DEG C, add 5 weight part yttrium oxides and the reaction of 1 weight part Indium sesquioxide 1 hour, then add 32 weight part Calucium Silicate powder and 38 weight part Zinic stearass to continue reaction 1.5 hours, last centrifugation is also dried and obtains rare earth calcium zinc compound under the temperature condition of 100 DEG C, then described rare earth calcium zinc compound and 10 parts of silicone powder are stirred and obtain described rare earth calcium zinc one package stabilizer.
comparative example 1
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 25 parts, epoxy soybean oil: 2 parts, dioctyl terephthalate: 3 parts, nano-calcium carbonate: 10 parts, commercially available calcium zinc stabilizer: 8 parts, polyethylene wax: 0.8 part, ACR impact modifier: 4 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, nanocrystalline SiO 2 powder: 0.6 part.
comparative example 2
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 30 parts, dioctyl terephthalate: 3 parts, nano-calcium carbonate: 12 parts, commercially available calcium zinc stabilizer: 12 parts, polyethylene wax: 1.2 parts, ACR impact modifier: 3 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, silicone powder: 0.6 part.
comparative example 3
The polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 28 parts, epoxy soybean oil: 2 parts, dioctyl terephthalate: 2 parts, nano-calcium carbonate: 10 parts, commercially available calcium zinc stabilizer: 10 parts, polyethylene wax: 0.8 part, ACR impact modifier: 2 parts, dihydroxyphenyl propane: 0.2 part, nano barium sulfate: 2 parts, nano amorphous SiO 2 powder: 0.6 part.
The testing method preparation that tensile strength adopts GB/T1040-1992 to specify, and draw speed is 250mm/min.
The testing method preparation that volume specific resistance adopts GB/T1410-2006 to specify.
Wearability test: material is pressed into 3 mm thin slices, takes quality, be accurate to 0.1 mg; Thin slice is fixed on wear-resistant tester, carries out under the same conditions the scraping of certain number of times; Take off thin slice and weigh, the quality of wearing and tearing can be used as the parameter of evaluating material wear resistance.
Senile experiment: under the condition of 80 DEG C by CABLE MATERIALS burin-in process 14d.
Smell test: under the condition of 80 DEG C, 100g CABLE MATERIALS is placed to 1d in the enclosed space of 100L, with its scent of whether of olfactometry.
table 1 tensile strength Mpa
table 2 volume specific resistance ohm meter 10
13
table 3 wearability test result abrasion loss mg
In table 1-3, A is the test result before aging, and B is the test result after aging according to quick aging method of the present invention.
table 4 smell test result
Unless otherwise defined, all technical terms described in present specification and scientific terminology are the implication that those of ordinary skill in the art is general understood, and the implication in its implication and common dictionary or technology dictionary is basically identical, unless otherwise defined, its intension should not dwindled or excessively be expanded the explanation of its implication.
Although embodiment part elaborates technical scheme of the present invention by embodiment, but those of ordinary skill in the art is to be understood that can be without departing from the scope of the present disclosure, can adopt to be equal to and replace or the enforcement of equivalent transformation form.Therefore, protection scope of the present invention is not limited to the specific embodiment of embodiment part, as long as no the embodiment that departs from invention essence, within being all interpreted as having dropped on the protection domain of requirement of the present invention.
Claims (8)
1. a data transmission automotive line PVC CABLE MATERIALS, it is characterized in that raw material is made up of the component of following weight part: the polyvinyl chloride resin of SG3 type: 100 parts, softening agent 1:25-30 part, softening agent 2:3-5 part, calcium carbonate: 10-12 part, stablizer: 8-12 part, polyethylene wax: 0.8-1.2 part, ACR impact modifier: 2-4 part, oxidation inhibitor: 0.1-0.5 part, nano barium sulfate: 2-3 part, and silicone powder: 0.3-0.8 part; Wherein softening agent 1 is selected from one or both of trioctyl trimellitate or pure terephthalic acid's dioctyl ester; Softening agent 2 is selected from one or both in epoxy soybean oil, dioctyl terephthalate; Described silicone powder is the coated SiO 2 powder of processing of silicone powder, and wherein the parts by weight of silicone powder are 0.1-0.2 part, and the parts by weight of SiO 2 powder are 0.2-0.6 part.
2. data transmission automotive line PVC CABLE MATERIALS claimed in claim 1, it is characterized in that described softening agent 1 is for trioctyl trimellitate, softening agent 2 is epoxy soybean oil and dioctyl terephthalate, and the ratio of weight and number of epoxy soybean oil and dioctyl terephthalate is 1:2.
3. the data transmission automotive line PVC CABLE MATERIALS described in claim 1 or 2, is characterized in that described stablizer is calcium zinc stabilizer or rare earth calcium zinc one package stabilizer.
4. the data transmission automotive line PVC CABLE MATERIALS described in claim 1 or 2, is characterized in that described polyethylene wax is fusing point higher than the high melting point polyethylene wax of 105 DEG C.
5. the data transmission automotive line PVC CABLE MATERIALS described in claim 1 or 2, is characterized in that described calcium carbonate is calcene, nano-calcium carbonate or water-ground limestone.
6. data transmission automotive line PVC CABLE MATERIALS claimed in claim 1, is characterized in that described SiO 2 powder is nano amorphous SiO 2 powder.
7. data transmission automotive line PVC CABLE MATERIALS claimed in claim 1, is characterized in that described oxidation inhibitor is selected from one or more in phenolic antioxidant, amine antioxidants, sulfur type antioxidant and phosphite ester kind antioxidant.
8. data transmission automotive line PVC CABLE MATERIALS claimed in claim 1, it is characterized in that raw material is made up of the component of following weight part: the polyvinyl chloride resin of SG3 type: 100 parts, trioctyl trimellitate: 25-30 part, epoxy soybean oil: 1-2 part, dioctyl terephthalate: 2-4 part, nano-calcium carbonate: 10-12 part, stablizer: 8-12 part, polyethylene wax: 0.8-1.2 part, ACR impact modifier: 2-4 part, oxidation inhibitor: 0.1-0.5 part, nano barium sulfate: 2-3 part, and silicone powder: 0.3-0.8 part; Described silicone powder is the coated SiO 2 powder of processing of silicone powder, and wherein the parts by weight of silicone powder are 0.1-0.2 part, and the parts by weight of SiO 2 powder are 0.2-0.6 part.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410286921.9A CN104045938B (en) | 2012-11-29 | 2012-11-29 | Heat-resistance PVC (polyvinyl chloride) cable material |
| CN201410286782.XA CN104045937B (en) | 2012-11-29 | 2012-11-29 | The preparation technology of wear-resisting data cable CABLE MATERIALS |
| CN201210495892.8A CN102964723B (en) | 2012-11-29 | 2012-11-29 | Polyvinyl chloride (PVC) cable material for automobile data transmission wire |
| CN201410286923.8A CN104045940B (en) | 2012-11-29 | 2012-11-29 | Corrosion-resistant polyvinyl chloride cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210495892.8A CN102964723B (en) | 2012-11-29 | 2012-11-29 | Polyvinyl chloride (PVC) cable material for automobile data transmission wire |
Related Child Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410286924.2A Division CN104045941B (en) | 2012-11-29 | 2012-11-29 | Data transmission automotive line CABLE MATERIALS |
| CN201410286782.XA Division CN104045937B (en) | 2012-11-29 | 2012-11-29 | The preparation technology of wear-resisting data cable CABLE MATERIALS |
| CN201410286921.9A Division CN104045938B (en) | 2012-11-29 | 2012-11-29 | Heat-resistance PVC (polyvinyl chloride) cable material |
| CN201410286923.8A Division CN104045940B (en) | 2012-11-29 | 2012-11-29 | Corrosion-resistant polyvinyl chloride cable material |
| CN201410286922.3A Division CN104045939A (en) | 2012-11-29 | 2012-11-29 | Modified polyvinyl chloride (PVC) cable material for data cables |
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| Publication Number | Publication Date |
|---|---|
| CN102964723A CN102964723A (en) | 2013-03-13 |
| CN102964723B true CN102964723B (en) | 2014-06-18 |
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| CN201210495892.8A Active CN102964723B (en) | 2012-11-29 | 2012-11-29 | Polyvinyl chloride (PVC) cable material for automobile data transmission wire |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR101907252B1 (en) | 2015-03-20 | 2018-10-11 | 주식회사 엘지화학 | Plasticizer, resin composition and method for preparing them |
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| JPS6394503A (en) * | 1986-10-07 | 1988-04-25 | 信越化学工業株式会社 | Cover conductor for vehicle |
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| TWI386451B (en) * | 2009-05-12 | 2013-02-21 | Nanya Plastics Corp | Pvc composite and its product |
| CN102585338A (en) * | 2011-01-13 | 2012-07-18 | 苏州汉扬精密电子有限公司 | Anti-wear halogen-free flame-retardant cable material |
| CN102382391B (en) * | 2011-09-19 | 2013-04-10 | 潘成玉 | Polyvinyl chloride cable material |
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