CN102960853B - Method of utilizing ammoniation technology to improve quality of tobacco stalk extracting solution - Google Patents
Method of utilizing ammoniation technology to improve quality of tobacco stalk extracting solution Download PDFInfo
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- CN102960853B CN102960853B CN201210535669.1A CN201210535669A CN102960853B CN 102960853 B CN102960853 B CN 102960853B CN 201210535669 A CN201210535669 A CN 201210535669A CN 102960853 B CN102960853 B CN 102960853B
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- offal
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- ammonification
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- 241000208125 Nicotiana Species 0.000 title claims abstract description 51
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 238000004176 ammonification Methods 0.000 claims description 54
- 238000000605 extraction Methods 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
- 239000002994 raw material Substances 0.000 claims description 44
- 239000006071 cream Substances 0.000 claims description 42
- 239000000284 extract Substances 0.000 claims description 41
- 239000007788 liquid Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 35
- 150000003863 ammonium salts Chemical class 0.000 claims description 34
- 235000001014 amino acid Nutrition 0.000 claims description 31
- 150000001413 amino acids Chemical class 0.000 claims description 31
- 239000007787 solid Substances 0.000 claims description 31
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 26
- 235000019504 cigarettes Nutrition 0.000 claims description 24
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 13
- 239000004251 Ammonium lactate Substances 0.000 claims description 13
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 13
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 13
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 claims description 13
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 claims description 13
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 claims description 13
- 239000001099 ammonium carbonate Substances 0.000 claims description 13
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 13
- 229940059265 ammonium lactate Drugs 0.000 claims description 13
- 235000019286 ammonium lactate Nutrition 0.000 claims description 13
- 235000003704 aspartic acid Nutrition 0.000 claims description 13
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 claims description 13
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 13
- 239000008103 glucose Substances 0.000 claims description 13
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 claims description 13
- 238000012360 testing method Methods 0.000 claims description 13
- 239000004474 valine Substances 0.000 claims description 13
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000012141 concentrate Substances 0.000 claims description 12
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims description 6
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 5
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 5
- 239000001630 malic acid Substances 0.000 claims description 5
- 235000011090 malic acid Nutrition 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 230000006229 amino acid addition Effects 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 238000002203 pretreatment Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 230000000391 smoking effect Effects 0.000 abstract description 9
- 230000007794 irritation Effects 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 description 33
- 229960003487 xylose Drugs 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000003892 spreading Methods 0.000 description 9
- SRBFZHDQGSBBOR-LECHCGJUSA-N alpha-D-xylose Chemical compound O[C@@H]1CO[C@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-LECHCGJUSA-N 0.000 description 7
- 239000012496 blank sample Substances 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 235000013305 food Nutrition 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009776 industrial production Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000208292 Solanaceae Species 0.000 description 1
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 235000013409 condiments Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
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- 210000003462 vein Anatomy 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Manufacture Of Tobacco Products (AREA)
Abstract
The invention relates to a method of utilizing an ammoniation technology to improve quality of a tobacco stalk extracting solution. The method comprises steps of pretreatment of tobacco stalk, preparation of the tobacco stalk extracting solution, and ammoniation and concentration of the tobacco stalk extracting solution. As the tobacco stalk extracting solution is processed by the ammoniation technology, the smoking quality of the tobacco stalk extracting solution is improved. Compared with the tobacco stalk concentrated paste that is not performed with ammoniation, the tobacco sheet is obviously improved in aspects of aroma, offensive odor, irritation and remaining taste.
Description
[technical field]
The present invention relates to technical field of tobacco processing.More specifically, the present invention relates to a kind of by ammonification technical finesse stem extracting solution to reach the method for improving stem extracting solution quality.
[background technology]
Reconstituted tobacoo (having another name called reconstituted tobacco) is a kind of taking offal, offal, the cigarette industry leftover bits and pieces such as cigarette is broken, cigarette is excellent as primary raw material, processes by certain technological means sheet or the thread reconstituted tobacco product that processing combines again.Along with the development of cigarette technology, reconstituted tobacoo is as the important inserts of cigarette product, mix the classification of joining for cigarette and expand to gradually one, two and five class cigarette compositions from three, four class cigarette in the past, mixed ratio example is more and more higher, and the demand of high-quality thin slice is also increased year by year.Reconstituted tobacoo is for cigarette, replace on the one hand part tobacco leaf, the effective and reasonable tobacco material that utilizes, adjusting to a certain extent on the other hand physical property and the chemical composition of cigarette, improve the interior quality of cigarette, is also the important technical of cigarette " reducing tar and reducing harm ".
Offal is the Main By product of cigarette industry, accounts for 25% ~ 30% of tobacco leaf gross weight, and output is huge, has every year the offal of tens thousand of tons rationally to be utilized and thrown aside at present.Offal, as the important composition raw material of producing reconstituted tobacoo, adopts the stem extracting solution that traditional handicraft is extracted to contain a large amount of carbohydrates (polysaccharide, monose) and nitrogenous (protein and free amino acid etc.) compound.Sugar can affect burn rate and combustion completion, increases the growing amount of tar in combustion process; When protein burning, producing a kind of stink that burns feather, is the precursor of flue gas harmful substance, comprises quinoline, HCN and other nitrogen-containing compounds; The assorted gas of reconstituted tobacoo that the method is produced is heavier, jealous poor, has affected its result of use.Therefore, be necessary stem extracting solution to process, improve its application and jealous present situation.Existing research sets about processing stem extracting solution from enzyme and microorganism fermentation, but its cost is high or consuming time longer, research and empirical discovery, containing nitrogen compound (as ammonium salt, amino acid etc.) and glucide under certain condition product can effectively reduce reconstituted tobacoo assorted gas, abirritate and increase fragrance, meet the developing direction of tobacco business.
Use at present nitrogen-containing compound (as ammonium salt, amino acid etc.) and glucide processing (ammonification technology) stem extracting solution, improve it and thin slice suction quality has no report.The present invention, on prior art basis, intends utilizing ammonification technical finesse stem extracting solution, improves its quality.
[summary of the invention]
[technical problem that will solve]
The object of this invention is to provide a kind of method of utilizing ammonification technology to improve stem extracting solution quality.
[technical scheme]
The present invention is achieved through the following technical solutions.
The present invention relates to a kind of method of utilizing ammonification technology to improve stem extracting solution quality, it is characterized in that the method comprises the steps:
A, offal pre-treatment: offal is removed to silt and foreign material, and cutting be length between 0.5 ~ 3cm, obtain tobacco stalk raw material;
B, stem extracting solution preparation: take the tobacco stalk raw material in steps A, after three extractions, Separation of Solid and Liquid, obtains stem extracting solution;
C, stem extracting solution ammonification concentrate: stem extracting solution adjust pH to 4.0 ~ 9.0 that step B is obtained, add wherein ammonium salt, amino acid and reduced sugar, and rotation is concentrated, obtains offal ammonification condensed cream; Wherein ammonium salt addition is 0.10 ~ 0.60 % by weight of tobacco stalk raw material weight, and amino acid addition is 0.05 ~ 0.30 % by weight of tobacco stalk raw material weight, and reduced sugar addition is 0.03 ~ 0.20 % by weight of tobacco stalk raw material weight;
D, the condensed cream that step C is obtained add coating fluid, coat tobacco-based plate sheet, oven dry, chopping, balance, beat cigarette, smoke panel test.
According to another kind of preferred embodiment of the present invention, it is characterized in that described offal is minister's stalk on tobacco, under neutralization, tobacco stalk raw material moisture content remains on 11 ~ 13 % by weight, and regulating the solution of pH value is respectively the malic acid of 2.0M and the NaOH of 2.0M.
According to another kind of preferred embodiment of the present invention, it is characterized in that offal for the first time extraction temperature be 55 DEG C, offal and clear water feed liquid weight ratio are to extract 40min under 1:4 condition; Offal for the second time and for the third time extraction temperature is 55 DEG C, and offal and clear water feed liquid weight ratio are to extract 40min under 1:3 condition; The solidliquid mixture obtaining after extraction for the first time obtains offal extract for the first time after 200 order filtered through gauze; The solidliquid mixture obtaining after extraction for the second time and for the third time obtains offal for the second time equally respectively and extract for the third time after 200 order filtered through gauze; Described stem extracting solution is that three extracts merging obtain.
According to another kind of preferred embodiment of the present invention, it is characterized in that described ammonium salt is the mixture of ammonium lactate, ammonium carbonate and formamide.
According to another kind of preferred embodiment of the present invention, the weight ratio that it is characterized in that ammonium lactate described in ammonium salt, ammonium carbonate, formamide is 1:0.03 ~ 0.15:0.07 ~ 0.35.
According to another kind of preferred embodiment of the present invention, it is characterized in that described amino acid is the mixture of aspartic acid, phenylalanine and valine.
According to another kind of preferred embodiment of the present invention, the weight ratio that it is characterized in that aspartic acid in amino acid, phenylalanine and valine is 1:0.06 ~ 0.18:0.30 ~ 1.20.
According to another kind of preferred embodiment of the present invention, it is characterized in that described reduced sugar is the mixture of glucose and xylose, the weight ratio of described glucose and xylose is 1:0.40 ~ 2.50.
According to another kind of preferred embodiment of the present invention, it is characterized in that the mode of adding ammonium salt, amino acid and reduced sugar in stem extracting solution for adding or adding in concentration process before concentrated, described concentration process for adding ammonium salt, amino acid and reduced sugar in the time that concentrate solid content is 15 ~ 50 % by weight.
According to another kind of preferred embodiment of the present invention, it is characterized in that ammonification is concentrated under 55 ~ 65 DEG C, 0.085 ~ 0.095MP condition is concentrated into solid content 64 ~ 66 % by weight, described coating fluid is the online water cream of industrial production, and offal condensed cream addition with online water paste ratio example is: solid content weight content ratio is 1:0.6 ~ 9.0; Spreading rate is 42%.
The present invention will be described below in more detail.
The present invention relates to a kind of method of utilizing ammonification technology to improve stem extracting solution quality.
The step of the method is as follows:
A, offal pre-treatment, remove silt and foreign material by offal, and cutting be length between 0.5 ~ 3cm, obtain tobacco stalk raw material;
Tobacco is Solanaceae annual herb plant, and offal is the thick and stiff vein of tobacco leaf, accounts for the 25-30% of tobacco leaf gross weight.Offal is the accessory substance of tobacco industry, is also valuable natural resources simultaneously, and output is huge, makes Disposal at present more.
Described offal is to use water rinse offal to remove the foreign material such as silt, then processes and obtain through cutting stalk.
Described offal length is at 0.5 ~ 3cm.If offal is long or too short,, be unfavorable for the preparation of reconstituted tobacoo.
Described tobacco stalk raw material moisture content remains on 11% ~ 13 % by weight.
B, stem extracting solution preparation: take the tobacco stalk raw material in steps A, after three extractions, Separation of Solid and Liquid, obtains stem extracting solution;
Three times described extractions are the static extraction of laboratory water-bath constant temperature.
Described thermostat water bath is common water-bath on the market.
Described extractant is clear water (running water).
It is 55 DEG C of temperature that described offal extracts for the first time, under offal and clear water (55 DEG C) feed liquid weight ratio 1:4 condition, extracts 40min.
After extraction for the first time, extract by 200 order filtered through gauze, leave and take filtrate, filter residue is for extraction for the first time.
It is 55 DEG C of temperature that described offal extracts for the second time, under offal and clear water (55 DEG C) feed liquid weight ratio 1:3 condition, extracts 40min.
Through for the second time extraction after, extract with 200 order filtered through gauze, leave and take filtrate, and with extract for the first time filtrate merge, filter residue for for the third time extract.
It is 55 DEG C of temperature that described offal extracts for the third time, under offal and clear water (55 DEG C) feed liquid weight ratio 1:3 condition, extracts 40min.
After extraction for the third time, extract with 200 order filtered through gauze, leave and take filtrate, and with extract for the first time and for the second time filtrate merging, filter residue as a part for reconstituted tobacoo production.
C, stem extracting solution ammonification concentrate: stem extracting solution adjust pH to 4.0 ~ 9.0 that step B is obtained, add wherein ammonium salt, amino acid and reduced sugar, and rotation is concentrated, obtains offal ammonification condensed cream; Wherein ammonium salt addition is 0.10 ~ 0.60 % by weight of tobacco stalk raw material weight, and amino acid addition is 0.05 ~ 0.30 % by weight of tobacco stalk raw material weight, and reduced sugar addition is 0.03 ~ 0.20 % by weight of tobacco stalk raw material weight;
Described stem extracting solution pH value is adjusted to 4.0 ~ 9.0.
The solution of described adjusting pH value is respectively the malic acid of 2.0M and the NaOH of 2.0M, and malic acid and NaOH are industrial food level.
The instrument of described adjusting pH is commercially available hand held pH meter.
Described ammonium salt is ammonium lactate, ammonium carbonate, formamide, is industrial food level.
The weight ratio of described ammonium lactate, ammonium carbonate, formamide is 1:0.03-0.15:0.07-0.35.
Described ammonium salt addition is 0.10 ~ 0.60% of raw material offal weight.
Described amino acid is aspartic acid, phenylalanine and valine, is industrial food level.
The weight ratio of described aspartic acid, phenylalanine and valine is 1:0.06-0.18:0.30-1.20.
Described amino acid addition is 0.05 ~ 0.30% of raw material offal weight.
Described reduced sugar is glucose and xylose, is industrial food level.
The weight ratio of described glucose and xylose is 1:0.40-2.50.
Described reduced sugar addition is 0.03 ~ 0.20% of raw material offal weight.
The described mode to adding ammonium salt, amino acid and reduced sugar in stem extracting solution for before concentrated, add and concentration process in add.
Research shows, in this test ammonification technology, relate to such an extent that carbonyl ammonia react (browning reaction or Maillard reaction) need carry out under certain moisture condition, generally be easier to carry out at moisture 11% ~ 90% carbonyl ammonia react, moisture is too high or too low all to be slowed down or suppresses its reaction.Therefore, preferably, in conjunction with industrial practical condition, described concentration process for to add ammonium salt, amino acid and reduced sugar in the time that concentrate solid content is 15 ~ 50%, and reacting original water content is 50 ~ 85%.
Described ammonification is concentrated under 55 ~ 65 DEG C, 0.085 ~ 0.095MP condition and is concentrated into solid content 64 ~ 66%.
Described concentrator is commercially available rotary evaporator.
D, the condensed cream that step C is obtained add coating fluid, coat tobacco-based plate sheet, oven dry, chopping, balance, beat cigarette, smoke panel test.
Described coating fluid is the online water cream of industrial production.
Described offal condensed cream addition with online water paste ratio example is: solid content weight ratio is 1:0.6 ~ 9.0.
Described spreading rate is 42%.
Described oven dry, chopping baking oven used, filament cutter are commercially available prod.
Described balance is interpreted as and makes, for making sheet and shreds humidity reach 11.0 ~ 13.0%, under the condition of 20 ~ 24 ° of C of temperature and relative humidity 55 ~ 65%, to carry out balance 16 ~ 48h.
According to the regulation of Law of the People's Republic of China on Tobacco Monopoly, the described product of smokeing panel test is reconstituted tobacoo.
Five cigarettes that described sensory evaluating smoking's authentication method is Huabao Edible Essence & Condiment (Shanghai) by our company form evaluation group with perfumer, adopt the method for secretly commenting, the fragrance of setting up according to our company, harmony, assorted gas, stimulate, six index classification standards of strength and pleasant impression are carried out performance rating, to compare with the tobacco sheet quality that uses ammonification processing stalk liquid of the present invention to produce using not ammonification to process stalk liquid, result of the test shows that the reconstituted tobacoo that uses ammonification of the present invention to process the production of stalk liquid is at fragrance, assorted gas, excitant and pleasant impression aspect have very significantly to be improved.
Except as otherwise noted, other compounds as used in this specification are known commercially available prod.
[beneficial effect]
The present invention uses ammonification technical finesse stem extracting solution, improve stem extracting solution suction quality, use offal ammonification condensed cream of the present invention compared with using not ammonification offal condensed cream, reconstituted tobacoo is having very significantly and is improving aspect fragrance, assorted gas, excitant and pleasant impression.Meanwhile, in industrial production, most of offal extract is discarded, and not only wastes resource but also cause serious environmental pollution, and offal ammonification condensed cream of the present invention can partly replace the part of online water cream as coating fluid, has both saved cost, reduces again environmental pollution.
[brief description of the drawings]
Fig. 1 is that the present invention utilizes ammonification technology to improve stem extracting solution quality processing method process chart.
[detailed description of the invention]
Will further profoundly understand the present invention by following embodiment.
Embodiment 1: utilize ammonification technology to improve stem extracting solution quality
Take the tobacco stalk raw material 100g after removal of impurities, 55 DEG C of temperature, under offal and clear water (55 DEG C) solid-liquid ratio 1:4 condition, extract after 40min, obtain solidliquid mixture, after extracting by 200 order filtered through gauze, leave and take filtrate; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the second time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the third time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue is as reconstituted tobacoo raw materials for production.Merge three extraction filtrates (pH value approximately 4.9), with 2.0M malic acid solution adjusting extracting liquid pH value to 4.0.In extract, add raw material offal weight
0.10% ammonium salt, 0.05% amino acid and 0.03% reduced sugar, wherein consisting of of ammonium salt: m(ammonium lactate): m(ammonium carbonate): m(formamide)=1:03:0.07, amino acid whose consisting of: m(aspartic acid): m(phenylalanine): m(valine)=1:0.06:0.30, the consisting of of reduced sugar: m(glucose): m(wood sugar)=1:0.40.Under 55 ~ 65 DEG C, 0.085 ~ 0.095MP condition, rotation is concentrated into solid content 64 ~ 66%, obtains offal ammonification condensed cream.Offal ammonification condensed cream and online water cream are coated to substrate by solid content 1:0.6, spreading rate 42%, the not ammonification offal condensed cream that simultaneously does same extraction and concentration technology is blank sample, oven dry, chopping, balance, beats cigarette, smokes panel test.Result is as shown in table 1.
Table 1 smoking result
Embodiment 2: utilize ammonification technology to improve stem extracting solution quality
Take the tobacco stalk raw material 100g after removal of impurities, 55 DEG C of temperature, under offal and clear water (55 DEG C) solid-liquid ratio 1:4 condition, extract after 40min, obtain solidliquid mixture, after extracting by 200 order filtered through gauze, leave and take filtrate; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the second time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the third time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue is as reconstituted tobacoo raw materials for production.Merge three extraction filtrates (pH value approximately 4.9), with 2.0NaOH solution adjusting extracting liquid pH value to 9.0.At 55 ~ 65 DEG C, when under 0.085 ~ 0.095MP condition, rotation is concentrated into solid content 50%, to the ammonium salt that adds raw material offal weight 0.60% in concentrate, 0.30% amino acid and 0.20% reduced sugar, wherein consisting of of ammonium salt: m(ammonium lactate): m(ammonium carbonate): m(formamide)=1:0.15:0.35, amino acid whose consisting of: m(aspartic acid): m(phenylalanine): m(valine)=1:0.18:1.20, consisting of of reduced sugar: m(glucose): m(wood sugar)=1:2.50, continue with being concentrated into solid content 64 ~ 66% under condition, obtain offal ammonification condensed cream.Offal ammonification condensed cream and online water cream are coated to substrate by solid content 1:9.0, spreading rate 42%, the not ammonification offal condensed cream that simultaneously does same extraction and concentration technology is blank sample, oven dry, chopping, balance, beats cigarette, smokes panel test.Result is as shown in table 2.
Table 2 smoking result
Embodiment 3: utilize ammonification technology to improve stem extracting solution quality
Take the tobacco stalk raw material 100g after removal of impurities, 55 DEG C of temperature, under offal and clear water (55 DEG C) solid-liquid ratio 1:4 condition, extract after 40min, obtain solidliquid mixture, after extracting by 200 order filtered through gauze, leave and take filtrate; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the second time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the third time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue is as reconstituted tobacoo raw materials for production.Merge three extraction filtrates (pH value approximately 4.9), with 2.0NaOH solution adjusting extracting liquid pH value to 6.5.At 55 ~ 65 DEG C, when under 0.085 ~ 0.095MP condition, rotation is concentrated into solid content 32%, to the ammonium salt that adds raw material offal weight 0.35% in concentrate, 0.17% amino acid and 0.11% reduced sugar, wherein consisting of of ammonium salt: m(ammonium lactate): m(ammonium carbonate): m(formamide)=1:0.09:0.21, amino acid whose consisting of: m(aspartic acid): m(phenylalanine): m(valine)=1:0.12:0.75, consisting of of reduced sugar: m(glucose): m(wood sugar)=1:1.45, continue with being concentrated into solid content 64 ~ 66% under condition, obtain offal ammonification condensed cream.Offal ammonification condensed cream and online water cream are coated to substrate by solid content 1:4.8, spreading rate 42%, the not ammonification offal condensed cream that simultaneously does same extraction and concentration technology is blank sample, oven dry, chopping, balance, beats cigarette, smokes panel test.Result is as shown in table 3.
Table 3 smoking result
Embodiment 4: utilize ammonification technology to improve stem extracting solution quality
Take the tobacco stalk raw material 100g after removal of impurities, 55 DEG C of temperature, under offal and clear water (55 DEG C) solid-liquid ratio 1:4 condition, extract after 40min, obtain solidliquid mixture, after extracting by 200 order filtered through gauze, leave and take filtrate; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the second time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the third time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue is as reconstituted tobacoo raw materials for production.Merge three extraction filtrates (pH value approximately 4.9), with 2.0NaOH solution adjusting extracting liquid pH value to 8.0.At 55 ~ 65 DEG C, when under 0.085 ~ 0.095MP condition, rotation is concentrated into solid content 25%, to the ammonium salt that adds raw material offal weight 0.45% in concentrate, 0.13% amino acid and 0.10% reduced sugar, wherein consisting of of ammonium salt: m(ammonium lactate): m(ammonium carbonate): m(formamide)=1:0.07:0.25, amino acid whose consisting of: m(aspartic acid): m(phenylalanine): m(valine)=1:0.15:0.50, consisting of of reduced sugar: m(glucose): m(wood sugar)=1:1.0, continue with being concentrated into solid content 64 ~ 66% under condition, obtain offal ammonification condensed cream.Offal ammonification condensed cream and online water cream are coated to substrate by solid content 1:2.5, spreading rate 42%, the not ammonification offal condensed cream that simultaneously does same extraction and concentration technology is blank sample, oven dry, chopping, balance, beats cigarette, smokes panel test.Result is as shown in table 4.
Table 4 smoking result
Embodiment 5: utilize ammonification technology to improve stem extracting solution quality
Take the tobacco stalk raw material 100g after removal of impurities, 55 DEG C of temperature, under offal and clear water (55 DEG C) solid-liquid ratio 1:4 condition, extract after 40min, obtain solidliquid mixture, after extracting by 200 order filtered through gauze, leave and take filtrate; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the second time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the third time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue is as reconstituted tobacoo raw materials for production.Merge three extraction filtrates (pH value approximately 4.9), with 2.0NaOH solution adjusting extracting liquid pH value to 5.5.At 55 ~ 65 DEG C, when under 0.085 ~ 0.095MP condition, rotation is concentrated into solid content 40%, to the ammonium salt that adds raw material offal weight 0.20% in concentrate, 0.25% amino acid and 0.17% reduced sugar, wherein consisting of of ammonium salt: m(ammonium lactate): m(ammonium carbonate): m(formamide)=1:0.11:0.15, amino acid whose consisting of: m(aspartic acid): m(phenylalanine): m(valine)=1:0.09:0.90, consisting of of reduced sugar: m(glucose): m(wood sugar)=1:2.00, continue with being concentrated into solid content 64 ~ 66% under condition, obtain offal ammonification condensed cream.Offal ammonification condensed cream and online water cream are coated to substrate by solid content 1:6.0, spreading rate 42%, the not ammonification offal condensed cream that simultaneously does same extraction and concentration technology is blank sample, oven dry, chopping, balance, beats cigarette, smokes panel test.Result is as shown in table 5.
Table 5 smoking result
Embodiment 6: utilize ammonification technology to improve stem extracting solution quality
Take the tobacco stalk raw material 100g after removal of impurities, 55 DEG C of temperature, under offal and clear water (55 DEG C) solid-liquid ratio 1:4 condition, extract after 40min, obtain solidliquid mixture, after extracting by 200 order filtered through gauze, leave and take filtrate; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the second time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the third time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue is as reconstituted tobacoo raw materials for production.Merge three extraction filtrates (pH value approximately 4.9), with 2.0NaOH solution adjusting extracting liquid pH value to 7.5.At 55 ~ 65 DEG C, when under 0.085 ~ 0.095MP condition, rotation is concentrated into solid content 20%, to the ammonium salt that adds raw material offal weight 0.50% in concentrate, 0.11% amino acid and 0.06% reduced sugar, wherein consisting of of ammonium salt: m(ammonium lactate): m(ammonium carbonate): m(formamide)=1:0.04:0.12, amino acid whose consisting of: m(aspartic acid): m(phenylalanine): m(valine)=1:0.06:0.90, consisting of of reduced sugar: m(glucose): m(wood sugar)=1:0.80, continue with being concentrated into solid content 64 ~ 66% under condition, obtain offal ammonification condensed cream.Offal ammonification condensed cream and online water cream are coated to substrate by solid content 1:1.0, spreading rate 42%, the not ammonification offal condensed cream that simultaneously does same extraction and concentration technology is blank sample, oven dry, chopping, balance, beats cigarette, smokes panel test.Result is as shown in table 6.
Table 6 smoking result
Embodiment 7: utilize ammonification technology to improve stem extracting solution quality
Take the tobacco stalk raw material 100g after removal of impurities, 55 DEG C of temperature, under offal and clear water (55 DEG C) solid-liquid ratio 1:4 condition, extract after 40min, obtain solidliquid mixture, after extracting by 200 order filtered through gauze, leave and take filtrate; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the second time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue, 55 DEG C of temperature, extracts under offal and clear water (55 DEG C) solid-liquid ratio 1:3 condition for the third time, and extraction time 40min, obtains solidliquid mixture, after extracting, leaves and takes filtrate by 200 order filtered through gauze; Filter residue is as reconstituted tobacoo raw materials for production.Merge three extraction filtrates (pH value approximately 4.9), with 2.0NaOH solution adjusting extracting liquid pH value to 7.0.At 55 ~ 65 DEG C, when under 0.085 ~ 0.095MP condition, rotation is concentrated into solid content 30%, to the ammonium salt that adds raw material offal weight 0.37% in concentrate, 0.15% amino acid and 0.10% reduced sugar, wherein consisting of of ammonium salt: m(ammonium lactate): m(ammonium carbonate): m(formamide)=1:0.08:0.20, amino acid whose consisting of: m(aspartic acid): m(phenylalanine): m(valine)=1:0.13:0.75, consisting of of reduced sugar: m(glucose): m(wood sugar)=1:1.00, continue with being concentrated into solid content 64 ~ 66% under condition, obtain offal ammonification condensed cream.Offal ammonification condensed cream and online water cream are coated to substrate by solid content 1:1.0, spreading rate 42%, the not ammonification offal condensed cream that simultaneously does same extraction and concentration technology is blank sample, oven dry, chopping, balance, beats cigarette, smokes panel test.Result is as shown in table 7.
Table 7 smoking result
Claims (9)
1. utilize ammonification technology to improve a method for stem extracting solution quality, it is characterized in that the method comprises the steps:
A, offal pre-treatment: offal is removed to silt and foreign material, and cutting be length between 0.5～3cm, obtain tobacco stalk raw material;
B, stem extracting solution preparation: take the tobacco stalk raw material in steps A, after three extractions, Separation of Solid and Liquid, obtains stem extracting solution; Wherein, offal for the first time extraction temperature is 55 DEG C, and offal and clear water feed liquid weight ratio are to extract 40min under 1:4 condition; Offal for the second time and for the third time extraction temperature is 55 DEG C, and offal and clear water feed liquid weight ratio are to extract 40min under 1:3 condition; The solidliquid mixture obtaining after extraction for the first time obtains offal extract for the first time after 200 order filtered through gauze; The solidliquid mixture obtaining after extraction for the second time and for the third time obtains offal for the second time equally respectively and extract for the third time after 200 order filtered through gauze; Described stem extracting solution is that three extracts merging obtain;
C, stem extracting solution ammonification concentrate: stem extracting solution adjust pH to 4.0～9.0 that step B is obtained, add wherein ammonium salt, amino acid and reduced sugar, and rotation is concentrated, obtains offal ammonification condensed cream; Wherein ammonium salt addition is 0.10～0.60 % by weight of tobacco stalk raw material weight, and amino acid addition is 0.05～0.30 % by weight of tobacco stalk raw material weight, and reduced sugar addition is 0.03～0.20% of tobacco stalk raw material weight;
D, the condensed cream that step C is obtained add coating fluid, coat tobacco-based plate sheet, oven dry, chopping, balance, beat cigarette, smoke panel test.
2. method according to claim 1, is characterized in that described offal is minister's stalk on tobacco, under neutralization, and tobacco stalk raw material moisture content remains on 11～13 % by weight, and regulating the solution of pH value is respectively the malic acid of 2.0M and the NaOH of 2.0M.
3. method according to claim 1, is characterized in that described ammonium salt is the mixture of ammonium lactate, ammonium carbonate and formamide.
4. method according to claim 3, the weight ratio that it is characterized in that ammonium lactate in ammonium salt, ammonium carbonate, formamide is 1:0.03～0.15:0.07～0.35.
5. method according to claim 1, is characterized in that described amino acid is the mixture of aspartic acid, phenylalanine and valine.
6. method according to claim 5, the weight ratio that it is characterized in that aspartic acid in amino acid, phenylalanine and valine is 1:0.06～0.18:0.30～1.20.
7. method according to claim 1, is characterized in that described reduced sugar is the mixture of glucose and xylose, and wherein the weight ratio of glucose and xylose is 1:0.40～2.50
8. method according to claim 1, it is characterized in that the mode of adding ammonium salt, amino acid and reduced sugar in stem extracting solution for adding or adding in concentration process before concentrated, described concentration process for adding ammonium salt, amino acid and reduced sugar in the time that concentrate solid content is 15～50 % by weight.
9. method according to claim 1, is characterized in that ammonification is concentrated under 55～65 DEG C, 0.085～0.095MPa condition to be concentrated into solid content 64～66 % by weight.
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| CN106820244A (en) * | 2017-01-23 | 2017-06-13 | 江苏中烟工业有限责任公司 | A kind of modified stem extracting solution is used for the method for improving papermaking-method reconstituted tobaccos suction quality |
| CN106551420A (en) * | 2017-01-23 | 2017-04-05 | 江苏中烟工业有限责任公司 | A kind of method that application cabo prepares tobacco juice for electronic smoke |
| CN109077347B (en) * | 2018-07-20 | 2021-07-27 | 河南卷烟工业烟草薄片有限公司 | Coating agent for improving organic nitrogen in paper-making reconstituted tobacco, and preparation method and application thereof |
| CN114903196B (en) * | 2022-05-11 | 2023-03-24 | 河北中烟工业有限责任公司 | Coloring additive for tobacco, preparation method thereof and heated cigarette |
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