CN102919824B - Processing method for improving quality of canned edible mushrooms - Google Patents
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Abstract
Description
(一)技术领域 (1) Technical field
本发明涉及一种改善食用菌罐头品质的加工方法。The invention relates to a processing method for improving the quality of canned edible mushrooms.
(二)背景技术 (2) Background technology
食用菌(Edible Fungi)是一类可食用、菇体大型的高等真菌的总称,具有肉质或胶质的子实体,如香菇、茶树菇、银耳、木耳、灵芝等,其味道鲜美,口感脆嫩,深受消费者的喜爱。食用菌在提高人体免疫功能、抗癌等方面的功效研究也越来越多的受到了研究者的关注和认可。Edible Fungi (Edible Fungi) is a general term for a class of edible, large-scale higher fungi with fleshy or gelatinous fruiting bodies, such as shiitake mushrooms, tea tree mushrooms, white fungus, fungus, ganoderma, etc., which are delicious and crispy in taste , deeply loved by consumers. Research on the efficacy of edible fungi in improving human immune function and anti-cancer has also received more and more attention and recognition from researchers.
由于食用菌的季节性和营养价值决定其价格较高,属于高端产品。食用菌通过加工成罐头,既能达到长期贮存的目的,又能较好地保持原有形状和风味。因此,目前市场上的食用菌以注汤的罐头包装形式出现,由于食用菌新鲜原料含水量高达85%以上,且富含酚类物质和多酚氧化酶;汤料长时间浸泡,组织软烂损失其营养及鲜味物质,经过高温杀菌后,褐变严重,降低了消费者的认可度,而干制品食用菌的色泽问题一直是困扰生产的最关键的步骤。要进一步打开食用菌罐头产品市场,就必须在保证产品货架期下突破产品的色泽及口感的技术瓶颈的制约。此项研究对扩大企业生产、销售规模,提高企业的经济效益有着至关重要的作用。Due to the seasonality and nutritional value of edible fungi, their prices are relatively high, and they are high-end products. Edible mushrooms can be processed into cans, which can not only achieve the purpose of long-term storage, but also better maintain the original shape and flavor. Therefore, the edible mushrooms currently on the market appear in the form of soup-filled cans, because the fresh raw materials of edible mushrooms have a water content of more than 85%, and are rich in phenolic substances and polyphenol oxidase; the soup is soaked for a long time, and the tissue is soft and rotten. It loses its nutrients and umami substances, and after high-temperature sterilization, it will brown seriously, which reduces the acceptance of consumers, and the color of dried edible fungi has always been the most critical step that plagues production. In order to further open up the edible mushroom canned product market, it is necessary to break through the technical bottleneck of the product's color and taste while ensuring the shelf life of the product. This research plays a vital role in expanding the production and sales scale of enterprises and improving the economic benefits of enterprises.
羧甲基纤维素(CMC),是纤维素的羧甲基团取代产物,在食品应用中不仅是良好的乳化稳定剂、增稠剂,而且具有优异的冻结、熔化稳定性,并能提高产品的风味,延长贮藏时间。与植物油形成性能稳定的乳化分散液,防止油水分层,能使其形成性能稳定的匀质乳状液。同时改善制品组织的粘结性以及制品内部组织的均一性和持水作用,防止菇体空隙中残留的空气氧化引起的菇体的褐变。在应用于食用菌罐头中还没有得到全面的开发利用。为了进一步开发食用菌罐头资源,尤其是对食用菌水分进行有效地控制,有必要对羧甲基纤维素(CMC)对于罐头食品的质构和稳定性的改善提供一定的科学理论参考。Carboxymethyl cellulose (CMC), which is a carboxymethyl group substitution product of cellulose, is not only a good emulsification stabilizer and thickener in food applications, but also has excellent freezing and melting stability, and can improve product quality. flavor and prolong storage time. Form a stable emulsified dispersion with vegetable oil, prevent oil-water stratification, and enable it to form a stable homogeneous emulsion. At the same time, it improves the cohesiveness of the product tissue and the uniformity and water holding effect of the internal structure of the product, and prevents the browning of the mushroom body caused by the oxidation of the residual air in the gap of the mushroom body. It has not been fully developed and utilized in canned edible mushrooms. In order to further develop canned edible mushroom resources, especially to effectively control the water content of edible fungi, it is necessary to provide some scientific theoretical reference for the improvement of the texture and stability of canned food by carboxymethyl cellulose (CMC).
(三)发明内容 (3) Contents of the invention
本发明目的是提供一种可改善食用菌罐头品质的加工方法。The purpose of the invention is to provide a processing method capable of improving the quality of canned edible mushrooms.
本发明采用的技术方案是:The technical scheme adopted in the present invention is:
一种改善食用菌罐头品质的加工方法,所述方法包括:A processing method for improving the quality of canned edible fungi, said method comprising:
(1)复水:将食用菌干制品先用流水(流动的自来水)浸泡10~20min,再静水(静置的自来水)浸泡1~2小时;原料要求为无霉变、无杂质、无其他菌菇干,大小均匀、色泽稳定的菌菇干制品;(1) Rehydration: Soak the dried mushroom products in running water (flowing tap water) for 10-20 minutes, and then soak in still water (stationary tap water) for 1-2 hours; the raw material requirements are no mildew, no impurities, and no other Dried mushrooms, dried mushroom products with uniform size and stable color;
(2)定色:将浸泡后的食用菌沥干,倒入装有定色液的槽中,浸泡10~30min;所述定色液质量组成如下:氯化钠0.1%~1%,柠檬酸0.1%~0.5%, EDTA-2Na (乙二胺四乙酸二钠)0.05~0.10%,溶剂为水;(2) Color fixation: Drain the soaked edible fungi, pour them into a tank with a fixative solution, and soak for 10-30 minutes; the quality composition of the fixer solution is as follows: 0.1%-1% sodium chloride, lemon Acid 0.1%~0.5%, EDTA-2Na (disodium ethylenediamine tetraacetate) 0.05~0.10%, solvent is water;
(3)沥水:将定色后的食用菌捞出,在离心锅离心10~20s,除去表面水分;(3) Drain water: take out the edible fungus after fixing the color, and centrifuge in a centrifuge pot for 10~20s to remove the surface moisture;
(4)调味:将沥水后的食用菌放入真空滚揉机,并放入调味料,控制真空度在0.8~1.0MPa,滚揉1小时(此为总时间,操作时为间歇操作,即揉滚1~5分钟后间歇1~5分钟);调味料以质量为食用菌(沥水后的)质量百分比质量计组成为:食用盐1~1.5%,料酒1.5~2.0%,植物油2~2.5%,生姜0.1~0.25%,味精0.5~1.0%,白砂糖1.0~2.0%,辣椒粉0.5~1.2%,CMC0.1~0.3%,Vc 0.2~0.5%;其中生姜需碾碎;(4) Seasoning: Put the drained edible fungus into a vacuum tumbler and seasoning, control the vacuum degree at 0.8~1.0MPa, and tumble for 1 hour (this is the total time, and the operation is intermittent operation, that is, Knead for 1-5 minutes and then rest for 1-5 minutes); the seasoning is based on the mass of edible fungus (after draining) and the composition is: 1-1.5% of edible salt, 1.5-2.0% of cooking wine, 2-2.5% of vegetable oil %, ginger 0.1~0.25%, monosodium glutamate 0.5~1.0%, white sugar 1.0~2.0%, chili powder 0.5~1.2%, CMC 0.1~0.3%, Vc 0.2~0.5%; the ginger needs to be crushed;
(5)后处理:调味后的食用菌真空包装、高温高压杀菌(121℃,30MPa,10~20min)后在0~10℃条件下冷藏。(5) Post-processing: seasoned edible mushrooms are vacuum-packed, sterilized under high temperature and high pressure (121°C, 30MPa, 10-20min), and then refrigerated at 0-10°C.
优选的,步骤(5)调味料组成为:食用盐1.25%,料酒1.78%,植物油2.23%,生姜0.18%,味精0.71%,白砂糖1.78%,辣椒粉0.89%, CMC0.2%,Vc 0.4%。Preferably, the seasoning composition in step (5) is: 1.25% edible salt, 1.78% cooking wine, 2.23% vegetable oil, 0.18% ginger, 0.71% monosodium glutamate, 1.78% white sugar, 0.89% chili powder, 0.2% CMC, 0.4 Vc %.
所述食用菌为常规可用于罐头加工的食用菌,优选为下列之一:香菇、茶树菇、黑木耳、银耳、蘑菇、草菇、口蘑。The edible fungi are conventional edible fungi that can be used for canning, preferably one of the following: shiitake mushrooms, tea tree mushrooms, black fungus, white fungus, mushrooms, straw mushrooms, and Tricholoma.
本发明工艺流程:原料(干制品食用菌)—复水—定色—甩干—真空滚揉调味—真空包装—高温高压杀菌—贮存The process flow of the present invention: raw material (dried edible fungus)—rehydration—fixing color—drying—vacuum rolling seasoning—vacuum packaging—high temperature and high pressure sterilization—storage
传统工艺流程:原料(新鲜食用菌)—漂白—预煮—护色—灌汤包装—沸水杀菌—贮存Traditional process: raw material (fresh edible fungus)—bleaching—precooking—color protection—soup filling—boiling water sterilization—storage
本发明工艺与传统工艺相比具体优势见下表:The specific advantages of the process of the present invention compared with the traditional process are shown in the following table:
本发明的食用菌罐头加工方法,克服了干制品最大的褐变的障碍,生产效率高,储存时间长,开袋即食,营养美味,是一种可进行大批量工业化生产的,具有食用菌特色,兼具有保健功能的一种食用菌罐头的加工方法。通过采用复配护色剂以及一定浓度的羧甲基纤维素处理,结合真空滚揉过程针对不同的小包装休闲食用菌罐头采用合适的工艺,最终可以得到品质好,货架期长的休闲软罐头,解决了产品杀菌过程的严重褐变或灌汤处理带来的种种弊端。The canned edible mushroom processing method of the present invention overcomes the biggest obstacle of browning of dry products, has high production efficiency, long storage time, can be eaten immediately after opening the bag, and is nutritious and delicious. , a processing method of canned edible mushrooms with health care functions. Through the use of compound color-protecting agent and a certain concentration of carboxymethyl cellulose treatment, combined with the vacuum tumbling process, the appropriate process is adopted for different small-package leisure edible fungus cans, and finally you can get leisure soft cans with good quality and long shelf life , to solve the serious browning of the product sterilization process or the various disadvantages caused by soup filling.
本发明的有益效果主要体现在:The beneficial effects of the present invention are mainly reflected in:
(1)首次发明以干制品为原料,明显提高利用率(1) It is the first invention to use dry products as raw materials, which significantly improves the utilization rate
本发明首次以食用菌干制品为原料,大大降低原料成本。由于新鲜食用菌具有季节性不易储存,并且含水量高,极易发生褐变,且生产工艺复杂,不易大批量生产。而食用菌的干制过程会引起营养成分及品质的变化。本发明采用的是自然干制的方式的原料,不仅有利于保存,还能改善菌类品质和提高营养价值,晒制还能促使食用菌中所含的维生素D原转化成维生素D2;干制品的水分活度低,酶的活性也受到抑制,易于保存,且同样重量的干制品制成罐头食品与新鲜食用菌制成罐头的比例为8:1,有效降低其生产成本;在加工生产过程中,复水过程与护色过程同时进行,节省复水时间以及用水量。为企业的大规模生产提供了有利的条件。The invention uses dried edible fungus as raw material for the first time, greatly reducing raw material cost. Since fresh edible fungi are seasonal and difficult to store, and have high water content, they are prone to browning, and the production process is complicated, so it is not easy to produce in large quantities. The drying process of edible fungi will cause changes in nutritional content and quality. What the present invention adopts is the raw material of the mode of natural drying, not only is beneficial to preserve, can also improve the quality of fungus and increase nutritional value, drying can also promote the provitamin D contained in edible fungus to convert into vitamin D2; Dried product Its water activity is low, and the activity of enzymes is also inhibited, so it is easy to preserve, and the ratio of canned food made of dry products of the same weight to canned food made of fresh edible fungi is 8:1, which effectively reduces its production cost; In the middle, the rehydration process and the color protection process are carried out at the same time, saving rehydration time and water consumption. It provides favorable conditions for large-scale production of enterprises.
(2)采用更安全有效的协同护色方案,解决了干制品最大的极易褐变难题(2) Adopt a safer and more effective collaborative color protection scheme to solve the biggest problem of easy browning of dry products
本发明采用无硫护色省去漂白、脱硫步骤,柠檬酸、氯化钠和EDTA-2Na配制成的复合护色液,明显改善加工过程中的酶促褐变问题。传统的护色剂为焦亚硫酸钠,但其残留的SO2对人体有害,而且需要进一步的烫漂、脱硫。而本发明中的柠檬酸能使产品的pH值降低,降低多酚氧化酶的活性。EDTA-2Na能减慢原料固有色素的褪色速度,保持其色泽稳定性。氯化钠在一定浓度下可以驱除水溶液中的氧气,使酚类底物难以与氧气接触,降低罐头的pH,从而更好的延长保质期。本发明中的复合护色液对抑制酶促褐变以及杀菌过程中的褐变问题起到进一步的协同效用;调味料中添加的0.2%Vc进一步防止在杀菌和加工储藏过程中的非酶促褐变问题,起到了锦上添花的作用。The invention adopts sulfur-free color-protecting solution, which saves the steps of bleaching and desulfurization, and is formulated with citric acid, sodium chloride and EDTA-2Na to obviously improve the problem of enzymatic browning in the processing process. The traditional color-protecting agent is sodium pyrosulfite, but its residual SO 2 is harmful to the human body, and further blanching and desulfurization are required. However, the citric acid in the present invention can reduce the pH value of the product and reduce the activity of polyphenol oxidase. EDTA-2Na can slow down the fading speed of the inherent pigment of the raw material and maintain its color stability. Sodium chloride can drive away oxygen in aqueous solution at a certain concentration, making it difficult for phenolic substrates to come into contact with oxygen, lowering the pH of canned food, thereby extending the shelf life better. The composite color protection solution in the present invention has further synergistic effect on the problem of inhibiting enzymatic browning and browning in the sterilization process; the 0.2% Vc added in the seasoning further prevents non-enzymatic browning in the process of sterilization and processing and storage. The browning problem played the role of icing on the cake.
(3)通过控制含水量,添加少量增稠剂,更好的延长货架期(3) By controlling the water content and adding a small amount of thickener, the shelf life is better extended
罐头食品的生产,其水分含量直接影响到产品的脆嫩度以及保质期,本发明首次添加羧甲基纤维素(CMC)和真空滚揉过程,有效控制水分在60%左右,钝化酶活性,增加物料稠度。由于食用菌复水后含水量较大,且在甩干的情况下还是会有多余的水分和气体残留在菇体内部缝隙中,要想排除菇体组织内滞留的气体,传统的做法是用沸水预煮,但是煮制过程中菇体组织收缩、软化,失去原有的脆性,而羧甲基纤维素具有钝化食用菌的酶活性,改善制品组织的粘结性的特点,可以使菇体内水分凝聚,真空滚揉过程可以起到进一步的收水效果,经实验证明,在水分含量为60%左右其产品质构和口感更佳。In the production of canned food, the moisture content directly affects the crispness and shelf life of the product. This invention adds carboxymethyl cellulose (CMC) and vacuum tumbling process for the first time, effectively controlling the moisture content at about 60%, inactivating the enzyme activity, Increase material consistency. Since the water content of edible fungi is relatively large after rehydration, and there will still be excess water and gas remaining in the gaps inside the mushroom body after being dried, the traditional method is to use Precooking in boiling water, but the mushroom tissue shrinks and softens during the cooking process, and loses its original brittleness, while carboxymethyl cellulose has the characteristics of inactivating the enzyme activity of edible fungi and improving the cohesiveness of the product tissue, which can make the mushroom The moisture in the body condenses, and the vacuum tumbling process can further absorb water. It has been proved by experiments that the texture and taste of the product are better when the moisture content is about 60%.
(四)具体实施方式 (4) Specific implementation methods
下面结合具体实施例对本发明进行进一步描述,但本发明的保护范围并不仅限于此:The present invention is further described below in conjunction with specific embodiment, but protection scope of the present invention is not limited thereto:
实施例1:茶树菇干制品软罐头的加工方法Embodiment 1: the processing method of tea tree mushroom dried product soft can
a. 挑选无霉变、无杂质、无其他菌菇干的茶树菇干100kg;a. Select 100kg of dried tea tree mushrooms without mildew, impurities and other dried mushrooms;
b. 采用1:20的菇水比进行复水,先将茶树菇干采用流动自来水浸泡15min,再静水浸泡1小时;b. Use the ratio of mushroom to water of 1:20 for rehydration, first soak the dried tea tree mushroom in running tap water for 15 minutes, and then soak in still water for 1 hour;
c. 加入已配好的复合护色剂,浸泡15 min,漂洗,并去除残留的杂质;护色剂质量组成:0.5%氯化钠,0.2%柠檬酸和0.075%的EDTA-2Na,溶剂为水;c. Add the prepared composite color-protecting agent, soak for 15 minutes, rinse, and remove residual impurities; the quality composition of the color-protecting agent: 0.5% sodium chloride, 0.2% citric acid and 0.075% EDTA-2Na, the solvent is water;
d. 将定色后的茶树菇捞出,在离心锅离心10s,以便除去表面水分;d. Take out the tea tree mushroom after fixing the color, and centrifuge it in the centrifuge pot for 10s to remove the surface moisture;
e. 将预先配制好的调味料和茶树菇装入真空滚揉机中,同时放入预先按重量比例配好的调味料(食用盐1.25%;料酒1.78%;植物油2.23%;生姜0.18%;味精0.71%;白砂糖1.78%;辣椒粉0.89%;CMC0.2%;Vc0.4%,占沥水后的茶树菇质量百分比);设定真空度为0.8~1.0MPa,总时间为1小时,滚揉2分钟,停止1分钟,;e. Put the pre-prepared seasoning and tea tree mushroom into the vacuum tumbler, and put in the pre-prepared seasoning according to the weight ratio (edible salt 1.25%; cooking wine 1.78%; vegetable oil 2.23%; ginger 0.18%; 0.71% monosodium glutamate; 1.78% white sugar; 0.89% chili powder; 0.2% CMC; Roll and knead for 2 minutes, stop for 1 minute;
f. 采用真空包装后121℃高温高压杀菌,其杀菌方式为121℃、30MPa下15~20min,然后冷却至室温。f. Vacuum-packed and sterilized at 121°C under high temperature and high pressure. The sterilization method is 15-20min at 121°C and 30MPa, and then cooled to room temperature.
既得水分含量约为60%;蛋白质含量为6.5%;色差△E在20~23的低酸性香辣茶树菇软罐头休闲食品。The obtained moisture content is about 60%; the protein content is 6.5%; the color difference △E is 20~23, and the low-acidity spicy tea tree mushroom soft canned snack food.
产品感官品质评价:Product sensory quality evaluation:
成品茶树菇罐头其色差范围小,质地脆嫩,有浓郁的茶树菇特有的鲜味。采用食品储存期加速测试Accelerated Shelf Life Testing(ASLT)作出详细的检验,评估,分析,结论是此产品的商业储存期可达12个月以上。The finished canned tea tree mushroom has a small range of color difference, a crisp and tender texture, and a strong unique umami taste of tea tree mushroom. Accelerated Shelf Life Testing (ASLT) was used to conduct detailed inspection, evaluation and analysis. The conclusion is that the commercial storage period of this product can reach more than 12 months.
实施例2:黑木耳干制品软罐头的加工方法Embodiment 2: the processing method of black fungus dried product soft can
a. 挑选无霉变、无杂质、无其他菌菇干的黑木耳100kg,a. Select 100kg of black fungus without mildew, no impurities, and no other dried mushrooms,
b. 采用1:20的菇水比进行复水,先将黑木耳采用流动自来水浸泡15min, 再静水浸泡2小时,b. Use the ratio of mushroom water to 1:20 for rehydration, first soak the black fungus in running tap water for 15 minutes, then soak in still water for 2 hours,
c. 加入已配好的复合护色剂,浸泡15 min,漂洗,并去除残留的杂质;护色剂质量组成:0.5%氯化钠,0.2%柠檬酸和0.075%的EDTA-2Na,溶剂为水;c. Add the prepared composite color-protecting agent, soak for 15 minutes, rinse, and remove residual impurities; the quality composition of the color-protecting agent: 0.5% sodium chloride, 0.2% citric acid and 0.075% EDTA-2Na, the solvent is water;
d. 将定色后的黑木耳捞出,在离心锅离心10s,以便除去表面水分;d. Take out the black fungus after color fixing, and centrifuge for 10s in a centrifuge pot to remove surface moisture;
e. 将预先配置好的调味料和黑木耳装入真空滚揉机中,同时放入预先按重量比例配好的调味料(食用盐1.25%;料酒1.78%;植物油2.23%;生姜0.18%;味精0.71%;白砂糖1.78%;辣椒粉0.89%;CMC0.2%;Vc0.4%,占沥水后的茶树菇质量百分比),设定真空度为0.8~1.0MPa,时间为1小时,滚揉2分钟,停止1分钟;e. Put the pre-configured seasoning and black fungus into the vacuum tumbler, and at the same time put the pre-prepared seasoning in proportion by weight (1.25% edible salt; 1.78% cooking wine; 2.23% vegetable oil; 0.18% ginger; 0.71% monosodium glutamate; 1.78% white sugar; 0.89% chili powder; 0.2% CMC; Knead for 2 minutes, stop for 1 minute;
f. 采用真空包装后高温高压杀菌其杀菌方式为121℃、30MPa下10~20min,然后冷却至室温。f. Vacuum packaging is used for high temperature and high pressure sterilization. The sterilization method is 121°C, 30MPa for 10~20min, and then cooled to room temperature.
既得水分含量为65%,蛋白质含量为7%,色差△E在15~20的低酸性香辣黑木耳软 罐头休闲食品。The acquired moisture content is 65%, the protein content is 7%, and the low-acidity spicy black fungus soft-canned snack food with a color difference △E of 15-20.
产品感官品质评价:Product sensory quality evaluation:
成品黑木耳罐头其色差范围小,质地脆嫩,有浓郁的黑木耳特有的鲜味。采用食品储存期加速测试Accelerated Shelf Life Testing(ASLT)作出详细的检验,评估,分析,结论是此产品的商业储存期设为12个月是可以保证的。The finished black fungus can has a small range of color difference, a crisp and tender texture, and a rich and unique umami taste of black fungus. Accelerated Shelf Life Testing (ASLT) was used to conduct detailed inspection, evaluation, and analysis. The conclusion is that the commercial storage period of this product is set to 12 months, which can be guaranteed.
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