CN102898618A - Preparation method of shock-absorbing sole material - Google Patents
Preparation method of shock-absorbing sole material Download PDFInfo
- Publication number
- CN102898618A CN102898618A CN2012103558665A CN201210355866A CN102898618A CN 102898618 A CN102898618 A CN 102898618A CN 2012103558665 A CN2012103558665 A CN 2012103558665A CN 201210355866 A CN201210355866 A CN 201210355866A CN 102898618 A CN102898618 A CN 102898618A
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- mass parts
- mass
- parts
- shock
- sole material
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- 239000000463 material Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 8
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 4
- PZBFGYYEXUXCOF-UHFFFAOYSA-N TCEP Chemical compound OC(=O)CCP(CCC(O)=O)CCC(O)=O PZBFGYYEXUXCOF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000009775 high-speed stirring Methods 0.000 claims abstract description 4
- 235000009566 rice Nutrition 0.000 claims abstract description 4
- 239000003381 stabilizer Substances 0.000 claims abstract description 4
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- 239000004135 Bone phosphate Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 150000004072 triols Chemical class 0.000 abstract 1
- 238000013016 damping Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a preparation method of a shock-absorbing sole material. The method includes the preparation steps of: putting 60-66 parts by mass of isocyanate T-80, 45-50 parts by mass of polyether triols, 10-12 parts by mass of rice bran, 3 parts by mass of a foam stabilizer, 3-6 parts by mass of organic tin, 5-6 parts by mass of cyclopentane, 3-6 parts by mass of TCEP and 2.5-5 parts by mass of AC into a high-speed stirring mixer to mix them for 10min; and then adding the mixture into a twin-screw extruder to carry out melt grafting for 3h, thus obtaining the sole material. The method has a simple preparation process and a low production cost, and the prepared sole material has good elasticity and can play an effective shock-absorbing role.
Description
Technical field
The present invention relates to a kind of shock-absorbing sole material preparation method.
Technical background
At present; the measured footwear of a pair of matter can well be protected people's pin; in order to prevent motion or when walking; minimizing is to the impact of sole; sole need to have the material of the function of shock-absorbing or damping and make; and sole great majority on the market have light; comfortable; the performances such as machine-shaping is fast are although that the flexibility of material reaches its damping effect of requirement is undesirable, so in order further to improve performance; generally to mix a large amount of fillers; resin and oil product, the production cost that can greatly improve like this affects work-ing life of sole.
Summary of the invention
The present invention seeks in order to overcome the deficiencies in the prior art, a kind of shock-absorbing sole material preparation method is provided, it is strong that the method makes the material for sole of shoe wear resistance, and the preparation technology of the method is simple.
For addressing the above problem, a technical scheme of the present invention is: a kind of shock-absorbing sole material preparation method, and the preparation process of the method is as follows: 60-66 mass parts isocyanic ester T-80,45-50 mass parts polyether-tribasic alcohol, 10-12 mass parts rice bran, 3 mass parts suds-stabilizing agents, 3-6 mass parts organotin, 5-6 mass parts pentamethylene, 3-6 mass parts TCEP and 2.5-5 mass parts AC are added in the high-speed stirring mixer mix 10min; Then join in the twin screw extruder behind the fusion-grafting 3h, namely obtain described material for sole of shoe.
Beneficial effect of the present invention: the preparation technology of the method is simple, and production cost is low, and the product wear resistance of preparing is high, and good springiness can effectively play the effect of damping.
Embodiment
Embodiment 1
A kind of shock-absorbing sole material preparation method, the preparation process of the method is as follows: 60-66 mass parts isocyanic ester T-80,45-50 mass parts polyether-tribasic alcohol, 10-12 mass parts rice bran, 3 mass parts suds-stabilizing agents, 3-6 mass parts organotin, 5-6 mass parts pentamethylene, 3-6 mass parts TCEP and 2.5-5 mass parts AC are added in the high-speed stirring mixer mix 10min; Then join in the twin screw extruder behind the fusion-grafting 3h, namely obtain described material for sole of shoe.Performance Detection effect to this material for sole of shoe is as follows: relative density: 0.2, and tensile strength/MPa:2.8, rebound degree: 30%.
Claims (1)
1. a shock-absorbing sole material preparation method is characterized in that the step of the method is as follows: 60-66 mass parts isocyanic ester T-80,45-50 mass parts polyether-tribasic alcohol, 10-12 mass parts rice bran, 3 mass parts suds-stabilizing agents, 3-6 mass parts organotin, 5-6 mass parts pentamethylene, 3-6 mass parts TCEP and 2.5-5 mass parts AC are added in the high-speed stirring mixer mix 10min; Then join in the twin screw extruder behind the fusion-grafting 3h, namely obtain described material for sole of shoe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103558665A CN102898618A (en) | 2012-09-24 | 2012-09-24 | Preparation method of shock-absorbing sole material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103558665A CN102898618A (en) | 2012-09-24 | 2012-09-24 | Preparation method of shock-absorbing sole material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102898618A true CN102898618A (en) | 2013-01-30 |
Family
ID=47571130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103558665A Withdrawn CN102898618A (en) | 2012-09-24 | 2012-09-24 | Preparation method of shock-absorbing sole material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102898618A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004067607A2 (en) * | 2003-01-27 | 2004-08-12 | Basf Aktiengesellschaft | Method for producing polyurethane integral foam materials |
| KR20060118989A (en) * | 2005-05-18 | 2006-11-24 | 최재호 | Sole and its manufacturing method |
| WO2008127926A1 (en) * | 2007-04-11 | 2008-10-23 | Dow Global Technologies Inc. | Polyurethane elastomer with enhanced hydrolysis resistance |
| CN101565517A (en) * | 2008-11-05 | 2009-10-28 | 邵棠 | Modified thermoplastic styrene butadiene rubber sole material and preparation method thereof |
| CN102617821A (en) * | 2012-04-17 | 2012-08-01 | 中国工程物理研究院化工材料研究所 | Polyurethane foaming plastic taking rice hull as raw material as well as preparation method of polyurethane foaming plastic |
-
2012
- 2012-09-24 CN CN2012103558665A patent/CN102898618A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004067607A2 (en) * | 2003-01-27 | 2004-08-12 | Basf Aktiengesellschaft | Method for producing polyurethane integral foam materials |
| KR20060118989A (en) * | 2005-05-18 | 2006-11-24 | 최재호 | Sole and its manufacturing method |
| WO2008127926A1 (en) * | 2007-04-11 | 2008-10-23 | Dow Global Technologies Inc. | Polyurethane elastomer with enhanced hydrolysis resistance |
| CN101565517A (en) * | 2008-11-05 | 2009-10-28 | 邵棠 | Modified thermoplastic styrene butadiene rubber sole material and preparation method thereof |
| CN102617821A (en) * | 2012-04-17 | 2012-08-01 | 中国工程物理研究院化工材料研究所 | Polyurethane foaming plastic taking rice hull as raw material as well as preparation method of polyurethane foaming plastic |
Non-Patent Citations (3)
| Title |
|---|
| 刘益军: "《聚氨酯原料及助剂手册》", 30 April 2005, 化学工业出版社 * |
| 朱吕民，刘益军等: "《聚氨酯泡沫塑料》", 31 January 2005, 化学工业出版社 * |
| 秦蓓等: "稻壳添加聚氨酯泡沫塑料", 《化工进展》 * |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20130130 |