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CN102876468A - cleaning composition - Google Patents

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Publication number
CN102876468A
CN102876468A CN2011101971875A CN201110197187A CN102876468A CN 102876468 A CN102876468 A CN 102876468A CN 2011101971875 A CN2011101971875 A CN 2011101971875A CN 201110197187 A CN201110197187 A CN 201110197187A CN 102876468 A CN102876468 A CN 102876468A
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cleaning
weight parts
composition
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陈谊蓁
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Abstract

The invention discloses a detergent composition, comprising: 11-45 parts of natural surfactant, 25-35 parts of mirabilite, 10-40 parts of sodium carbonate, 0.1-5 parts of methylglycine diacetate trisodium salt and 100 parts of cleaning assistant. The mirabilite with a specific proportion can quickly soften hardened surfaces of oil stains and dirt, and simultaneously, the natural surfactant can smoothly penetrate into the oil stains for complete cleaning, and the composition does not contain the following components: formaldehyde, benzene, fluorescer, EDTA, nonyl phenol, heavy metal and other components harmful to the environment, and the biodegradable proportion can reach more than 95 percent, so the invention is a cleaner composition with environmental protection and better cleaning effect.

Description

Cleanser compositions
Technical field
The present invention relates to a kind of composition, particularly relate to a kind of cleanser compositions that is fit to remove greasy dirt, dirt etc. dirty material.
Background technology
Adopted cationic and synthectic detergents non-ionic interfacial agent in the past, usually for example cooperate: formaldehyde (formaldehyde), fluorescent agent (fluorescent agent), benzene (benzene), ethylene diamine tetra acetic acid salt (ethylene diamine tetra acetate, hereinafter to be referred as EDTA), the compound of phosphoric acid salt (phosphate salt) etc., reach take out stains, the purpose of grease.Wherein, the non-ionic surfactant that contains nonyl phenol (nonyl phenol), because the female hormone similar of chemical structure and animal, therefore be called again Environmental Hormone, this Environmental Hormone can disturb the regulation mechanism of organism endocrine hormone, and just can simulate the effect of natural hormone under extremely low concentration, directly stimulates or suppress the endocrine system of biology, and then hinder reproduction, growth function, therefore the healthy and breeding of biology is produced great impact.
In addition, positively charged ion and non-ionic interfacial agent are in the standard that does not meet International Environmental Protection aspect the biological decomposition degree, and the sanitising agent of synthetic is more imperfect for the application of interfacial agent, usually just dirt, grease, greasy dirt are transferred in the water, when sanitising agent and sewage discharge were in the environment, dirt still existed, this not only causes the secondary public hazards of environment, also can polluted source, so endlessly vicious cycle also has serious destruction for ecotope.Although therefore the sanitising agent of synthetic provides convenience in life, can cause to environmental ecology the pollution of height.
Summary of the invention
The purpose of this invention is to provide a kind of environmental protection, and have the cleanser compositions of better cleaning effect.
Cleanser compositions of the present invention comprises:
The natural series interfacial agent of 11~45 weight parts;
The saltcake of 25~35 weight parts;
The yellow soda ash of 10~40 weight parts;
0.1 the methyl glycine two acetic acid trisodium salts of~5 weight parts; And
With the aforementioned cleaning additive that becomes subtotaling 100 weight parts.
Natural series interfacial agent of the present invention is selected from least a: Oleum Cocois (cocoanut oil), coconut powder, hydrogenation castor oil (hydrogentated castor oil0, plam oil; or their combination, wherein Oleum Cocois has quality gentleness, antibacterial and effect such as protection skin etc.Above-mentioned natural series interfacial agent has better osmotic effect, can destroy thoroughly the molecular structure of dirt, greasy dirt, grease, and reaches the effect that the discharge of wastewater process can be decomposed fully by microorganism.
Saltcake used in the present invention is sodium sulfate crystal (Glauber ' s salt), and major ingredient is aqueous sulfuric acid sodium, and in the general field of Chinese medicines, saltcake can be used as the soft stool agent and uses, and it is called again Weathered Sodium Sulfate or Sodium sulfate anhydrous.min(99).Study discovery through the contriver, saltcake except the purposes that can be used as the traditional Chinese medical science, when its as cleaning during purposes, not only meeting water will dissolve, the hardened surface of all right fast softening dirt, greasy dirt makes the natural series interfacial agent can go deep into smoothly the inner also complete cleaning of doing.
And show according to the actual test result of applicant, an amount of saltcake cooperates suitable natural series interfacial agent, can produce to greasy dirt, the grease of stubbornness dynamical emulsification Decomposition, the cooperation of both suitable proportions, can allow the foamy structure of sanitising agent careful, clean easily, and therefore reach water-saving, the good effect of biological decomposition degree.Namely when the usage quantity of saltcake is lower than 25 weight part, it is not enough that the speed on its softening dirt surface is slightly disliked, it is slow that cleaning performance is slightly disliked, and when the usage quantity of saltcake is higher than 35 weight part, although can improve the softening rate of dirt, but can therefore squeeze the ratio of other composition, have influence on final cleaning effect.
Yellow soda ash of the present invention is stain remover, simultaneously methyl glycine two acetic acid trisodium salts (trisodium methylglycine diacetic acid, the abbreviation MGDA-Na to be commonly called as the ecology chelation agent 3) as sequestrant, purpose is to replace the EDTA that in the synthectic detergents in the past environmental ecology is done great damage.Study discovery according to the contriver, methyl glycine two acetic acid trisodium salts used in the present invention, can make sanitising agent also complete at the chelating of heavy metal, it is except removing the dirt, can also replace the dirty precipitate metal ion that zeolite removes calcium phosphate, the biological decomposition degree of methyl glycine two acetic acid trisodium salts is in (28 days) more than 80% simultaneously, therefore, replace EDTA with methyl glycine two acetic acid trisodium salts and not only can improve composition at the cleaning effect aspect the heavy metal, also can reduce the influence degree that sanitising agent causes environmental ecology.
Cleaning additive of the present invention can be divided into main additive and reach two kinds of time additives, and wherein, main additive comprises:
0.5 the methylcellulose gum of~1.0 weight parts (methyl cellulose);
The alkyl glycoside of 1~6 weight part (alkyl glucoside);
0.1 the sodium polyacrylate of~1.0 weight parts (sodium polyacrylate);
The SPC-D of 5~10 weight parts (sodium percarbonate); And
The Starso of 5~10 weight parts (sodium metasilicate).
And this time additive comprises:
0.3 the carboxymethyl cellulose powder of~2 weight parts [carboxymethyl cellulose thickener (CMC-T)];
The glycerine of 3~10 weight parts (glycerol);
The dioxide peroxide that 250ppm is following; And
The neem oil of 3~10 weight parts (vegetable oil Triglyceride).
The methylcellulose gum that the present invention adds has thickening, protection and divergent function; and alkyl glycoside can be eliminated the lime in the tap water; avoid producing the calcification phenomenon; this sodium polyacrylate can be used as tenderizer and thickening material uses; and in the present invention, because this sodium polyacrylate is by vinylformic acid (CH 2CHCOOH) with sodium acrylate [CH 2CH (COONa)-] be polymerized, it can be concatenated to form polymkeric substance with negative electric charge, and it can also soften the hardening material in the tap water except the moisture content that can absorb a large amount reaches the function of moisturizing, to improve the cleaning power of sanitising agent, assist simultaneously the thickening effectiveness of methylcellulose gum.Because sodium polyacrylate has better moisture content assimilation effect, therefore, when sanitising agent is discharged into nature, also can improve the water content of arid soil, all has the effect of adjusting for farm crop and climate temperature.
In addition; synthectic detergents was owing to containing the composition of strong acid, highly basic in the past; therefore after cleaning; the skin that is in contact with it has the problems such as moisture content scatters and disappears fast, drying, accelerated deterioration; the present invention uses cooperating of alkyl glycoside and sodium polyacrylate; can in cleaning process, provide better protection effect to grease, and produce the water content more than 300 times, therefore can produce extraordinary humidity-holding effect to skin.
SPC-D of the present invention and Starso can use as SYNTHETIC OPTICAL WHITNER, and this carboxymethyl cellulose powder belongs to the additive of food grade, also be a kind of of thickening material, the glycerine that the present invention adds can improve moisturizing and the antifreezing effect of composition, and the dioxide peroxide of interpolation can improve the sterilization effect of composition.Put down in writing as can be known from scientific literature in the past, dioxide peroxide is a kind of titanium dioxide agent but not chlorizating agent, have very strong oxidation capacity, but and killing bacteria and virus, therefore dioxide peroxide is classified as high-level efficiency, A1 level the 4th generation sterilant fast by the World Health Organization (WTO).Neem oil of the present invention is called again veepa oil, and it is a kind of biodegradable and nontoxic sterilant, has simultaneously splendid humidity-holding effect, can be used to treat eczema for example, allergic etc. dermatosis.
Beneficial functional of the present invention is: utilize the saltcake of specified proportion to come the hardened surface of fast softening greasy dirt, dirt, allow simultaneously the natural series interfacial agent can go deep into smoothly grease inside and make complete cleaning, above-mentioned composition does not only for example contain: the environmentally harmful composition of formaldehyde, benzene, fluorescent agent, EDTA, nonyl phenol, heavy metal etc., can also allow biodegradable (biodegradable) ratio up to more than 95%, therefore the not only environmental protection of this cleanser compositions of the present invention also has better cleaning effect.
Embodiment
<embodiment 1 〉
The present embodiment is with the Oleum Cocois of 10 weight parts, the coconut powder of 12 weight parts, the hydrogenation castor oil of 2.3 weight parts, the methyl glycine two acetic acid trisodium salts of 1 weight part, the saltcake of 25 weight parts, the methylcellulose gum of 0.7 weight part, the alkyl glycoside of 2.5 weight parts, the sodium polyacrylate of 0.5 weight part, the SPC-D of 7 weight parts, and the yellow soda ash of the Starso of 7 weight parts, 32 weight parts mixes, and just can make cleanser compositions of the present invention.
<embodiment 2 〉
The cleanser compositions of the present embodiment is except comprising: the Oleum Cocois of 10 weight parts, the coconut powder of 10 weight parts, 1.3 the hydrogenation castor oil of weight part, the methyl glycine two acetic acid trisodium salts of 1 weight part, the saltcake of 30 weight parts, 0.5 the methylcellulose gum of weight part, the alkyl glycoside of 2 weight parts, 0.2 the sodium polyacrylate of weight part, the SPC-D of 6 weight parts, and the Starso of 6 weight parts, outside the yellow soda ash of 22 weight parts, also further comprise: the carboxymethyl cellulose powder of 1 weight part, the glycerine of 5 weight parts, the neem oil of 5 weight parts, and the dioxide peroxide of 150ppm.
<embodiment 3 〉
The cleanser compositions of the embodiment of the invention 3 is similar to Example 2, and different places is that the usage quantity of saltcake is heightened 35 weight parts.
<comparative example 〉
Composition is similar to embodiment 2, but the ratio of saltcake is reduced to 20 weight parts, and adjusts the composition of coconut powder, Oleum Cocois and yellow soda ash.
The composition deck watch of<embodiment and comparative example 〉
Figure BDA0000075836500000041
Figure BDA0000075836500000051
<cleaning effect explanation 〉
<oil stain decomposition test 〉
The interior greasy dirt of sewage treatment tank in dining room is taked first in this test, and be placed on equally respectively in two test tanks, then the cleanser compositions of equivalent being made by embodiment 1 is poured in one of them test tank, and the composition that equivalent is made by comparative example is poured in another test tank, then leave standstill after 1 hour and find, as long as the saltcake in cleanser compositions is higher than 25 weight parts, the complete emulsification of the greasy dirt that just can allow the dining room be difficult to clean, but when the usage quantity of saltcake is lower than 25 weight part, still have the greasy dirt of part to suspend, therefore the poor effect of the degreasing of comparative example.
<cleaning leather test 〉
This test is to test with embodiment 2 and comparative example, the object of wiping is a chair that speckles with greasy dirt, shown by the wiping result, when the saltcake content in the cleanser compositions is lower than 25 weight part, chair after the wiping still has obvious greasy dirt, but when the saltcake addition of cleanser compositions during at 30 weight part, the light that just chair that attach greasy dirt originally can be wiped is therefore cleanser compositions of the present invention has better wiping effect really.
<cleaning ironware test 〉
Still take embodiment 2 as example, this test is that the cleanser compositions that utilizes embodiment 2 allotments to form comes wipe surfaces to have the metal tube of iron rust, test-results shows, the metal tube that is stained with iron rust becomes bright after the wiping via embodiment 2, therefore, this cleanser compositions of the present invention can also be used to the clean metal pipe fitting except cleaning the leather.
<cleaning cloth test 〉
This test is for comparative example and each embodiment, the object of test is cloth, at first cloth is immersed in the liquid that is mixed by 10cc soy sauce and 10cc salad oil, and be 4 times of volumes with the sanitising agent dilution then, washed by rubbing with the hands through 30 seconds, again the cleaning performance of the sanitising agent of each embodiment and comparative example relatively.Confirmed by test-results, the fabric color that utilizes comparative example to clean is deep, and namely soy sauce and edible oil go deep in the fiber, therefore unclean after cleaning.Review the sanitising agent of various embodiments of the present invention, can effectively remove the dirt on the cloth, and saltcake content when higher cleaning effect better, its cleaning effect almost can make the color and luster of cloth return to untainted situation.
By above various cleaning effect test results as can be known, the present invention utilizes the saltcake of specified proportion to come the hardened surface of fast softening greasy dirt, dirt, allow simultaneously the natural series interfacial agent can go deep into smoothly grease inside and make complete cleaning, above-mentioned composition does not only for example contain: the environmentally harmful composition of formaldehyde, benzene, fluorescent agent, EDTA, nonyl phenol, heavy metal etc., can also allow the biodegradable ratio up to more than 95%, therefore the not only environmental protection of this cleanser compositions of the present invention also has better cleaning effect.

Claims (5)

1.一种清洁剂组合物,包含:11~45重量份的天然系界面活性剂、10~40重量份的碳酸钠、0.1~5重量份的甲基甘胺酸二醋酸三钠盐,以及清洁助剂;1. A cleanser composition comprising: 11 to 45 parts by weight of natural surfactants, 10 to 40 parts by weight of sodium carbonate, 0.1 to 5 parts by weight of trisodium methylglycine diacetate, and cleaning aids; 其特征在于:该清洁剂组合物还包含25~35重量份的芒硝,所述清洁助剂和天然系界面活性剂、碳酸钠、甲基甘胺酸二醋酸三钠盐以及芒硝的合计量是100重量份。It is characterized in that: the cleaning agent composition also contains 25-35 parts by weight of Glauber's salt, and the total amount of the cleaning aid, natural surfactant, sodium carbonate, trisodium methylglycine diacetate and Glauber's salt is 100 parts by weight. 2.如权利要求1所述的清洁剂组合物,其特征在于:该天然系界面活性剂是选自于至少一种椰子油、椰子粉、氢化篦麻油,或它们的组合。2. The cleaning agent composition according to claim 1, wherein the natural surfactant is selected from at least one coconut oil, coconut flour, hydrogenated castor oil, or a combination thereof. 3.如权利要求2所述的清洁剂组合物,其特征在于:该天然系界面活性剂包含5~20重量份的椰子油、5~20重量份的椰子粉,以及1~5重量份的氢化篦麻油。3. The cleanser composition according to claim 2, characterized in that: the natural surfactant comprises 5 to 20 parts by weight of coconut oil, 5 to 20 parts by weight of coconut powder, and 1 to 5 parts by weight of Hydrogenated castor oil. 4.如权利要求1或3所述的清洁剂组合物,其特征在于:该清洁助剂包含:4. The cleaning agent composition according to claim 1 or 3, wherein the cleaning aid comprises: 0.5~1.0重量份的甲基纤维素;0.5~1.0 parts by weight of methylcellulose; 1~6重量份的烷基糖苷;1 to 6 parts by weight of alkyl glycosides; 0.1~1.0重量份的聚丙烯酸钠;0.1~1.0 parts by weight of sodium polyacrylate; 5~10重量份的过碳酸钠;及5-10 parts by weight of sodium percarbonate; and 5~10重量份的偏硅酸钠。5-10 parts by weight of sodium metasilicate. 5.如权利要求4所述的清洁剂组合物,其特征在于:该清洁助剂还包含:5. The cleaning agent composition according to claim 4, wherein the cleaning aid also comprises: 0.3~2重量份的羧甲基纤维素粉;0.3~2 parts by weight of carboxymethylcellulose powder; 3~10重量份的甘油;3-10 parts by weight of glycerol; 250ppm以下的二氧化氯;以及Chlorine dioxide below 250ppm; and 3~10重量份的苦楝油。3-10 parts by weight of neem oil.
CN2011101971875A 2011-07-14 2011-07-14 cleaning composition Pending CN102876468A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104450225A (en) * 2014-11-03 2015-03-25 唐翊珲 Pesticide residue scavenging agent and preparation method thereof
CN105862205A (en) * 2016-05-20 2016-08-17 长兴宏泰纺织有限公司 Preparation method of ultraviolet-proof covering yarn
CN106118892A (en) * 2016-06-30 2016-11-16 江绍玫 A kind of omnipotent food stage cleaning agent and preparation method thereof
CN106118893A (en) * 2016-06-30 2016-11-16 江绍玫 A kind of gentleness, green cleaning agent and preparation method thereof
CN112266830A (en) * 2020-11-20 2021-01-26 广州元美盛化妆品有限公司 Low-carbon multifunctional sanitary ware element for tableware and other articles

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1220306A (en) * 1997-12-19 1999-06-23 巫松虎 Concentrated detergent powder
CN1240227A (en) * 1999-07-23 2000-01-05 李志军 Multi-function washing powder and productive process
CN101165151A (en) * 2007-09-29 2008-04-23 上海特地旺农业科技有限公司 Natural, mild and green cleaning agent
CN101809134A (en) * 2007-08-03 2010-08-18 美国消毒者公司 Biodegradable detergent concentrate for medical instruments and equipment
CN101896593A (en) * 2008-01-04 2010-11-24 埃科莱布有限公司 Use the solidification matrix of aminocarboxylate
CN102046769A (en) * 2008-05-30 2011-05-04 美国消毒者公司 Biodegradable scale control composition for use in highly concentrated alkaline detergents

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1220306A (en) * 1997-12-19 1999-06-23 巫松虎 Concentrated detergent powder
CN1240227A (en) * 1999-07-23 2000-01-05 李志军 Multi-function washing powder and productive process
CN101809134A (en) * 2007-08-03 2010-08-18 美国消毒者公司 Biodegradable detergent concentrate for medical instruments and equipment
CN101165151A (en) * 2007-09-29 2008-04-23 上海特地旺农业科技有限公司 Natural, mild and green cleaning agent
CN101896593A (en) * 2008-01-04 2010-11-24 埃科莱布有限公司 Use the solidification matrix of aminocarboxylate
CN102046769A (en) * 2008-05-30 2011-05-04 美国消毒者公司 Biodegradable scale control composition for use in highly concentrated alkaline detergents

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104450225A (en) * 2014-11-03 2015-03-25 唐翊珲 Pesticide residue scavenging agent and preparation method thereof
CN105862205A (en) * 2016-05-20 2016-08-17 长兴宏泰纺织有限公司 Preparation method of ultraviolet-proof covering yarn
CN106118892A (en) * 2016-06-30 2016-11-16 江绍玫 A kind of omnipotent food stage cleaning agent and preparation method thereof
CN106118893A (en) * 2016-06-30 2016-11-16 江绍玫 A kind of gentleness, green cleaning agent and preparation method thereof
CN112266830A (en) * 2020-11-20 2021-01-26 广州元美盛化妆品有限公司 Low-carbon multifunctional sanitary ware element for tableware and other articles

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Application publication date: 20130116