CN102850833A - Novel light-storing coating - Google Patents
Novel light-storing coating Download PDFInfo
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- CN102850833A CN102850833A CN2012101170848A CN201210117084A CN102850833A CN 102850833 A CN102850833 A CN 102850833A CN 2012101170848 A CN2012101170848 A CN 2012101170848A CN 201210117084 A CN201210117084 A CN 201210117084A CN 102850833 A CN102850833 A CN 102850833A
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- Prior art keywords
- light
- storing
- type
- novel light
- novel
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- 239000011248 coating agent Substances 0.000 title abstract 4
- 238000000576 coating method Methods 0.000 title abstract 4
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000003973 paint Substances 0.000 claims abstract description 14
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 11
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 9
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 7
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 benzo oxygen nitrogen Chemical compound 0.000 claims description 8
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 6
- 239000004922 lacquer Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims description 4
- 229960000956 coumarin Drugs 0.000 claims description 4
- 235000001671 coumarin Nutrition 0.000 claims description 4
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 4
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 claims description 4
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims description 4
- 235000021286 stilbenes Nutrition 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229920002160 Celluloid Polymers 0.000 abstract description 2
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 229920002972 Acrylic fiber Polymers 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 229910052692 Dysprosium Inorganic materials 0.000 description 2
- 229910052691 Erbium Inorganic materials 0.000 description 2
- 229910052693 Europium Inorganic materials 0.000 description 2
- 229910052688 Gadolinium Inorganic materials 0.000 description 2
- 229910052689 Holmium Inorganic materials 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 229910052773 Promethium Inorganic materials 0.000 description 2
- 229910052772 Samarium Inorganic materials 0.000 description 2
- 229910052771 Terbium Inorganic materials 0.000 description 2
- 229910052775 Thulium Inorganic materials 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 2
- 230000005281 excited state Effects 0.000 description 2
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 2
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 2
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 2
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- ANDNPYOOQLLLIU-UHFFFAOYSA-N [Y].[Lu] Chemical compound [Y].[Lu] ANDNPYOOQLLLIU-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a novel light-storing coating, comprising a light-storing material and a celluloid paint, wherein the light-storing material comprises 7wt% of acrylic resin, 8wt% of epoxy resin, 40wt% of phosphorescent powder, 5wt% of rare earth, 25wt% of fluorescent whitening agent, and 15wt% of alcohol. According to the invention, the light-storing coating will not lose light-storing capacity because of long-time exposure outside, the light-storing coating is green and has no pollution, and the production cost is low.
Description
Technical field
The present invention relates to hold optical arena, particularly relate to a kind of novel light-storing paint.
Background technology
After material is excited, material will be in excited state, the energy of excited state can discharge by the form of light or heat, if the energy of this part is to be positioned at visible, ultraviolet or near infrared electromagnetic radiation, this process is referred to as luminescence process, luminous is exactly that material is launched unnecessary energy with the form of light outside thermal radiation, this emission process has certain time length, the material that can realize said process is called luminescent material, material inside absorbs energy in some way, and the process that converts it into optical radiation (nonequilibrium radiation) is called luminous; In actual applications, will excite by the external world and luminous solid is called luminescent material.They can powder, monocrystalline, film or the form such as noncrystal are used, and main ingredient is compound and the semiconductor material of rare earth metal, and is very close with the non-ferrous metal relation.
Light-storing paint in the market can be because long-term exposure loses the ability of holding light outside.
Summary of the invention
The technical problem that the present invention mainly solves provides a kind of novel light-storing paint, can have for a long time storing capacity.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of novel light-storing paint is provided, comprise: described light-storing paint comprises light-storing material and the clear lacquer, described light-storing material by following component according to being forming of weight percent: acrylic resin 7%, Resins, epoxy 8%, luminescent powder 40%, rare earth 5%, white dyes 25%, alcohol 15%.
In a preferred embodiment of the present invention, described light-storing material and the clear lacquer form according to the weight ratio of 1:2.
In a preferred embodiment of the present invention, described white dyes can be divided into five classes by chemical structure: Stilbene-based, coumarin type, pyrazoline type, benzo oxygen nitrogen type, Phthalimide type.
The invention has the beneficial effects as follows: light-storing paint of the present invention can not lose the ability of holding light outside because of long-term exposure, and environmental protection, and is pollution-free, at the bottom of the production cost.
Embodiment
The below is described in detail preferred embodiment of the present invention, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that protection scope of the present invention is made more explicit defining.
The invention discloses a kind of novel light-storing paint, comprise: described light-storing paint comprises light-storing material and the clear lacquer, described light-storing material by following component according to being forming of weight percent: acrylic resin 7%, Resins, epoxy 8%, luminescent powder 40%, rare earth 5%, white dyes 25%, alcohol 15%.
Preferably, described light-storing material and the clear lacquer form according to the weight ratio of 1:2.
Preferably, described white dyes can be divided into five classes by chemical structure: Stilbene-based, coumarin type, the pyrazoline type, benzo oxygen nitrogen type, the Phthalimide type, Stilbene-based, be used for cotton fibre and some synthon, papermaking, the industry such as soapmaking, has blue-fluorescence, coumarin type, has coumarone basic structure, be used for xylonite, igelites etc. have stronger blue-fluorescence, the pyrazoline type, be used for wool, polymeric amide, the fibers such as acrylic fibers, have green glimmering look, benzo oxygen nitrogen type is used for fiber and the polyvinyl chloride such as acrylic fibers, the plastics such as polystyrene, has red fluorescence, the Phthalimide type is used for terylene, acrylic fibers, the fibers such as polyamide fibre have blue-fluorescence.
Preferably, rare earth element is to find successively since last years of a century in 18th century, and people often called soil to water-fast soild oxide at that time, and rare earth is generally separated with the oxide compound state, and is very rare again, thereby must be called rare earth.Usually lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium are called light rare earths or cerium group rare-earth; Gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium yttrium are called heavy rare earths or yttrium group rare-earth, similarity and the otherness according to the rare earth element physicochemical property that also have, except scandium (what have incorporates scandium into rare and scatter element), be divided into three groups, namely the light rare earths group is lanthanum, cerium, praseodymium, neodymium, promethium; The middle-weight rare earths group is samarium, europium, gadolinium, terbium, dysprosium; The heavy rare earths group is holmium, erbium, thulium, ytterbium, lutetium, yttrium.
Preferably, the luminescent powder people utilize the long-time luminous characteristic of luminescent powder in real life, make the weak illumination light source, in military service special use is arranged, this material is coated in various switch signs on instrument, clock and watch, window, the machine, the handle of door etc. is located, and also available various light-passing plastic is pressed into various symbols, parts, articles for use (such as power switch, socket, fishhook etc.) together.These luminous components get up behind night or during accidental power failure, the lightning etc. that it is still continuing luminously after rayed, make people can distinguish peripheral direction, for work and life bring convenience.The noctilucent material ultrafine particle is mixed in the textiles, make color more bright-coloured, child puts on the textiles of noctilucence, can reduce traffic accident.
Preferably, acrylic resin is the resin of being made by esters of acrylic acid and methyl acrylic ester and other olefinic type monomers copolymerization, by selecting different resin structures, different prescription, production technique and solvent composition, can synthesize the acrylic resin of dissimilar, different performance and different application occasion, acrylic resin can be divided into thermoplastic acrylic resin and thermosetting acrylic resin again according to the difference of structure and membrane formation mechanism.
Claims (3)
1. novel light-storing paint, it is characterized in that, comprise: described light-storing paint comprises light-storing material and the clear lacquer, described light-storing material by following component according to being forming of weight percent: acrylic resin 7%, Resins, epoxy 8%, luminescent powder 40%, rare earth 5%, white dyes 25%, alcohol 15%.
2. novel light-storing paint according to claim 1 is characterized in that, described light-storing material and the clear lacquer form according to the weight ratio of 1:2.
3. novel light-storing paint according to claim 1 is characterized in that, described white dyes can be divided into five classes by chemical structure: Stilbene-based, coumarin type, pyrazoline type, benzo oxygen nitrogen type, Phthalimide type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101170848A CN102850833A (en) | 2012-04-20 | 2012-04-20 | Novel light-storing coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101170848A CN102850833A (en) | 2012-04-20 | 2012-04-20 | Novel light-storing coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102850833A true CN102850833A (en) | 2013-01-02 |
Family
ID=47397832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101170848A Pending CN102850833A (en) | 2012-04-20 | 2012-04-20 | Novel light-storing coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102850833A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322778A (en) * | 2001-05-30 | 2001-11-21 | 大连明辰振邦氟涂料股份有限公司 | Coating phosphor and its prepn and long-afterglow fluorescent aqueous paint containing the phosphor |
| CN1434848A (en) * | 2000-02-18 | 2003-08-06 | 奥赖恩21A.D.有限公司 | Luminescent gel coats and moldable resins |
| CN1434088A (en) * | 2003-02-13 | 2003-08-06 | 海洋化工研究院 | Energy storage water-borne luminous coating |
-
2012
- 2012-04-20 CN CN2012101170848A patent/CN102850833A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1434848A (en) * | 2000-02-18 | 2003-08-06 | 奥赖恩21A.D.有限公司 | Luminescent gel coats and moldable resins |
| CN1322778A (en) * | 2001-05-30 | 2001-11-21 | 大连明辰振邦氟涂料股份有限公司 | Coating phosphor and its prepn and long-afterglow fluorescent aqueous paint containing the phosphor |
| CN1434088A (en) * | 2003-02-13 | 2003-08-06 | 海洋化工研究院 | Energy storage water-borne luminous coating |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130102 |