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CN102832123A - Power electric switch device and manufacturing method thereof - Google Patents

Power electric switch device and manufacturing method thereof Download PDF

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Publication number
CN102832123A
CN102832123A CN2011101584764A CN201110158476A CN102832123A CN 102832123 A CN102832123 A CN 102832123A CN 2011101584764 A CN2011101584764 A CN 2011101584764A CN 201110158476 A CN201110158476 A CN 201110158476A CN 102832123 A CN102832123 A CN 102832123A
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Prior art keywords
gate electrode
photoresist
photoresist layer
substrate
oxide
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CN2011101584764A
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Chinese (zh)
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孙润光
刘宏宇
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Abstract

The invention discloses a manufacturing method of a high electron mobility transistor device, which comprises the following steps: (a) coating a layer of photoresist on one substrate; (b) drying the photoresist; (c) illuminating the photoresist by a beam of parallel light, wherein the parallel light beam is distributed on the cross section in the way that the light intensity in the central part is greater than that in the peripheral part; (d) developing the photoresist layer, so that a deep groove which is deep to the substrate is formed at a part of the photoresist layer, which is illuminated by the light beam central part, and a shallow groove which is shallower than the deep groove is formed at a part which is illuminated by the light beam peripheral part; (e) depositing a polycrystalline silicon gate electrode material on the photoresist layer by a chemical vapor deposition method, thereby forming a T-shaped gate electrode pattern in the deep groove and the shallow groove; and (f) removing the photoresist layer and the gate electrode material which is deposited outside the T-shaped gate electrode pattern by the plasma oxygen ashing process.

Description

A kind of power electronic switching device and manufacturing approach thereof
Technical field
The present invention relates to a kind of HEMT (High Electron Mobility Transistor; Be HEMT) device and manufacture method; Particularly gate material is made up of conducting inorganic material, device and manufacturing approach thereof that T type gate electrode adopts photoresist of coating and single exposure photoetching process to accomplish.
Background technology
HEMT (HEMT) has fast, the withstand voltage height of speed, ends advantages such as high frequency is high, environmental stability is good.Along with the raising with frequency that reduces of device size, T type gate electrode structure is widely used in the HEMT device.
A kind of method of the T type gate electrode structure manufacture method of prior art is to adopt three layers of different photobehavior photoresist of coating and electron beam exposure method to form the first half 12, transition portion 13 and the latter half 11 of T type gate electrode, and Fig. 1 is the grid groove structural representation of this manufacture method.Plated metal grid again, the unwanted part of stripping photoresist and gate electrode forms T type gate electrode.
The another kind of method of prior art is to be coated with one deck photoresist earlier; Adopt the latter half 11 of the method making T type gate electrode of X ray; Then be coated with one deck photoresist, adopt optical lithography method to make the first half 12 of T type gate electrode, Fig. 2 is the grid groove structural representation of this manufacture method.Deposit the grid metal again, the unwanted part of stripping photoresist and gate electrode forms T type gate electrode.
Above-mentioned these methods need repeatedly be coated with photoresist; Increased processing step; And liquid flux and ultrasonic method that lift-off technology adopts be easy to have influence on T type gate electrode the first half in the process of peeling off T type gate electrode the latter half photoresist, and the HEMT device is in high pressure, high frequency, hot operation in addition, and the metal material of gate electrode is easy to be diffused into following semiconductor layer; Influence the performance of device, even lost efficacy.
Fig. 1 is the grid groove structural representation of first kind of manufacture method of prior art, and wherein 1 is substrate, and 11 is T type gate electrode the latter half, and 12 is T type gate electrode the first half, and 13 is T type gate electrode transition portion.These three parts are formed by three layer photoetching glue respectively.
Fig. 2 is the grid groove structural representation of second kind of manufacture method of prior art, and wherein 1 is substrate, and 11 is T type gate electrode the latter half, and 12 is T type gate electrode the first half.These two parts are formed by two layer photoetching glue respectively.
Summary of the invention
It is simple to the purpose of this invention is to provide a kind of manufacture craft, HEMT device and manufacturing approach that production efficiency is high.
Another object of the present invention provides a kind of HEMT device and manufacturing approach of stable work in work.
For realizing above-mentioned one or more purpose, the present invention provides a kind of manufacture method of HEMT devices, comprises the following steps:
(a) coating one deck photoresist on a substrate;
(b) dry this layer photoetching glue;
(c) with a branch of this layer photoetching glue of directional light irradiation, wherein this bundle directional light distribution on its cross section is: the light intensity of its core is greater than the light intensity of periphery;
(d) above-mentioned photoresist layer is given development treatment, photoresist layer receives deep trouth that is deep to substrate of position formation that said beam center partly shines thus, forms the shallow slot of a degree of depth less than said deep trouth and receive said light beam periphery irradiated site;
(e) with chemical vapor deposition method to said photoresist layer deposit spathic silicon gate material, in said deep trouth and shallow slot, form " T " shape gate electrode figure thus;
(f) utilize plasma oxygen cineration technics to remove above-mentioned photoresist layer and be deposited on the gate material outside said " T " shape gate electrode figure.
Of the present invention have a following beneficial effect:
In device of the present invention, gate material is made up of conducting inorganic material, and the metal material of having avoided in the existing technology constituting gate electrode is easy to be diffused into the shortcoming of following semiconductor conducting layer, has improved stability, the reliability of device work.
In manufacture method of the present invention, T type gate electrode adopts photoresist of coating and single exposure photoetching process to accomplish, and manufacture craft is simple, can reduce the unit interval of device preparation effectively, enhances productivity.
In manufacture method of the present invention, adopt oxygen ashing (O 2Ashing) method is removed photoresist and the unwanted part of gate electrode figure, can avoid liquid flux and ultrasonic method has influence on T type gate electrode the first half easily in the process of peeling off T type gate electrode the latter half photoresist the shortcoming of the lift-off technology employing of existing technology.Simultaneously, if oxygen ashing (O 2Ashing) in CVD that makes gate material or pvd chamber body, carry out, can reduce the unit interval of device preparation effectively, enhance productivity.
Description of drawings
Fig. 1 is the grid groove structural representation of first kind of manufacture method of prior art.
Fig. 2 is the grid groove structural representation of second kind of manufacture method of prior art.
Fig. 3 is the grid groove structural representation according to first kind of execution mode of the present invention.
Fig. 4 is the manufacture method sketch map according to second kind of execution mode of the present invention.
Embodiment
Below in conjunction with accompanying drawing embodiment of the present invention is described.
Execution mode one
The manufacture craft of substrate 1 comprises: the heterojunction of the method that adopts metal oxide chemical vapor deposition growing gallium nitride aluminium and gallium nitride on (0001) of sapphire substrate face; The heterojunction concrete structure from bottom to top is followed successively by: 2 microns undoped gallium nitride epitaxial loayers; 5 nanometer undoped gallium nitride aluminium separators; 12 nano-silicon doped gallium nitride aluminium laminations, 5 nanometer undoped gallium nitride aluminium cap layers.
Fig. 3 is the manufacture craft structure chart according to the HEMT device of a kind of execution mode of present embodiment.
The manufacturing process of the HEMT of present embodiment:
(101) coating one deck photoresist AZ1500 (being used to form the latter half 11 and the first half 12) on substrate 1, thickness is 3 microns, baking 50 seconds (i.e. oven dry) on hot plate.Adopt the semi-transparent part 21 of half transmitance reticle (Half tone mask); Through exposure and development; Make the first half 12 of T type gate electrode photoresist figure, make the latter half 11 of T type gate electrode photoresist figure simultaneously through the full impregnated light part 22 of above reticle, developer solution is the tetramethyl-ammonium hydroxide solution of concentration 2.38%; Developing time 30 seconds is seen Fig. 3 (1).
(102) Fig. 3 (2) is a grid groove structural representation, comprising: substrate 1, T type gate electrode the latter half 11, T type gate electrode the first half 12.
(103) make heavily doped polygate electrodes material 21 through chemical vapor deposition method; Because the first half 12 of T type gate electrode photoresist figure is an inverted trapezoidal structure; The heavily doped polysilicon gate material is discontinuous at the edge of this inverted trapezoidal structure, shown in Fig. 3 (3).
(104) under the situation of not destroying the chemical vapor depsotition equipment vacuum, aerating oxygen (O 2), utilize plasma to carry out oxygen ashing (O 2Ashing) technology is removed photoresist and the unwanted part of gate electrode figure, shown in Fig. 3 (4).
Execution mode two
The manufacture craft of substrate is with embodiment one.
(201) coating one deck photoresist AZ1500 (being used to form the latter half 11 and the first half 12) on substrate, thickness is 3 microns, baking is 50 seconds on hot plate.Adopt the semi-transparent part 21 of half transmitance reticle (Half tone mask); Make the first half 12 of T type gate electrode photoresist figure through the method for exposure and development; The first half 12 is an inverted trapezoidal structure, makes the latter half 11 of T type gate electrode photoresist figure simultaneously through the full impregnated light part 22 of above reticle, and developer solution is the tetramethyl-ammonium hydroxide solution of concentration 2.38%; Developing time 30 seconds is seen Fig. 3 (1).
(202) Fig. 3 (2) is a grid groove structural representation, comprising: substrate 1, T type gate electrode the latter half 11, T type gate electrode the first half 12.
(203) make zinc oxide (ZnO) gate material 21 through sputter (Sputter) technology; Because the first half 12 of T type gate electrode photoresist figure is an inverted trapezoidal structure; The zinc oxide gate material is discontinuous at the edge of this inverted trapezoidal structure, shown in Fig. 3 (3).
(204) under the situation of not destroying Sputter equipment vacuum, aerating oxygen (O 2), utilize plasma to carry out oxygen ashing (O 2Ashing) technology is removed photoresist and the unwanted part of gate electrode figure, shown in Fig. 3 (4).
Execution mode three
The manufacture craft of substrate is with embodiment one.
(301) coating one deck photoresist AZ1500 (being used to form the latter half 11 and the first half 12) on substrate, thickness is 3 microns, baking is 50 seconds on hot plate.Adopt the cut blocks for printing interference fringe gray scale part 21 of (Gray tone mask) of interference fringe gray-level light; Make the first half 12 of T type gate electrode photoresist figure through the method for photoetching and development; The first half 12 is an inverted trapezoidal structure, makes the latter half 11 of T type gate electrode photoresist figure simultaneously through the full impregnated light part 22 of above reticle, and developer solution is the tetramethyl-ammonium hydroxide solution of concentration 2.38%; Developing time 30 seconds is seen Fig. 4 (1).
(302) Fig. 4 (2) is a grid groove structural representation, comprising: substrate 1, T type gate electrode the latter half 11, T type gate electrode the first half 12.
(303) make zinc oxide (ZnO) gate material 21 through sputter (Sputter) skill; Because the first half 12 of T type gate electrode photoresist figure is an inverted trapezoidal structure; The zinc oxide gate material is discontinuous at the edge of this inverted trapezoidal structure, shown in Fig. 4 (3).
(304) under the situation of not destroying Sputter equipment vacuum, aerating oxygen (O 2), utilize plasma to carry out oxygen ashing (O 2Ashing) technology is removed photoresist and the unwanted part of gate electrode figure, shown in Fig. 4 (4).
Embodiment four
The manufacture craft of substrate is with embodiment one.
(401) coating one deck photoresist AZ1500 (being used to form the latter half 11 and the first half 12) on substrate, thickness is 3 microns, baking is 50 seconds on hot plate.Adopt the cut blocks for printing interference fringe gray scale part 21 of (Gray tone mask) of interference fringe gray-level light; Make the first half 12 of T type gate electrode photoresist figure through the method for photoetching and development; Make the latter half 11 of T type gate electrode photoresist figure simultaneously through the full impregnated light part 22 of above reticle; Developer solution is the tetramethyl-ammonium hydroxide solution of concentration 2.38%, and developing time 30 seconds is seen Fig. 4 (1).
(402) Fig. 4 (2) is a grid groove structural representation, comprising: substrate 1, T type gate electrode the latter half 11, T type gate electrode the first half 12.
(403) make heavily doped polygate electrodes material 21 through chemical vapor deposition method, because the first half 12 of T type gate electrode photoresist figure is an inverted trapezoidal structure, the heavily doped polysilicon gate material is discontinuous at the edge of this inverted trapezoidal structure.
The device that (404) will deposit gate material is immersed in the stripper, removes unwanted metal and all photoresists, and stripper is the N-methyl pyrrolidone, adopts acetone and ethanol to clean afterwards.
Embodiment five
The manufacture craft of substrate is with embodiment one.
(501) coating one deck photoresist AZ1500 (being used to form the latter half 11 and the first half 12) on substrate, thickness is 3 microns, baking is 50 seconds on hot plate.Adopt the cut blocks for printing interference fringe gray scale part 21 of (Gray tone mask) of interference fringe gray-level light; Make the first half 12 of T type gate electrode photoresist figure through the method for photoetching and development; Make the latter half 11 of T type gate electrode photoresist figure simultaneously through the full impregnated light part 22 of above reticle; Developer solution is the tetramethyl-ammonium hydroxide solution of concentration 2.38%, and developing time 30 seconds is seen Fig. 4 (1).
(502) Fig. 4 (2) is a grid groove structural representation, comprising: substrate 1, T type gate electrode the latter half 11, T type gate electrode the first half 12.
(503) make the gate material 21 of heavily doped nickel and golden double-level-metal (thickness is respectively 30 nanometers and 200 nanometers) through chemical vapor deposition method, shown in Fig. 4 (3).
The device that (504) will deposit gate material is immersed in the stripper, removes unwanted metal and all photoresists, and stripper is the N-methyl pyrrolidone, adopts acetone and ethanol to clean afterwards, shown in Fig. 4 (3).
Through said embodiment and accompanying drawing, generally speaking, the present invention provides a kind of manufacture method of HEMT devices, comprises the following steps:
(a) coating one deck photoresist (for example, photoresist AZ1500) on a substrate;
(b) dry this layer photoetching glue (for example through 50 seconds time of baking);
(c) with a branch of this layer photoetching glue of directional light irradiation, wherein this bundle directional light distribution on its cross section is: the light intensity of its core is greater than the light intensity of periphery;
(d) above-mentioned photoresist layer (is for example given development treatment; Developer solution is the tetramethyl-ammonium hydroxide solution of concentration 2.38%; Developing time 30 seconds); Photoresist layer receives deep trouth that is deep to substrate of position formation that said beam center partly shines thus, forms the shallow slot of a degree of depth less than said deep trouth and receive said light beam periphery irradiated site;
(e) with chemical vapor deposition method to said photoresist layer deposit spathic silicon gate material, like tin oxide (In 2O 3), antimony oxide (SbO), zinc oxide (ZnO), (GaO) etc. sowed in oxidation, and the oxide of above-mentioned alloy such as tin indium oxide (ITO), indium oxide are sowed zinc (IGZO) etc., inorganic conductive materials such as heavily doped polysilicon, germanium.In said deep trouth and shallow slot, form " T " shape gate electrode figure thus; With
(f) utilize plasma oxygen cineration technics to remove above-mentioned photoresist layer and be deposited on the gate material outside said " T " shape gate electrode figure.
Best, the intensity distributions of said collimated light beam is through the realization of cutting blocks for printing of semi-transparent rate photolithography plate or interference fringe gray-level light.
More than be described to preferred implementation of the present invention, it should be appreciated by those skilled in the art that not breaking away from the scope basis of spirit of the present invention and claims and can carry out variations and modifications.

Claims (3)

1. the manufacture method of a HEMT devices comprises the following steps:
(a) coating one deck photoresist on a substrate;
(b) dry this layer photoetching glue;
(c) with a branch of this layer photoetching glue of directional light irradiation, wherein this bundle directional light distribution on its cross section is: the light intensity of its core is greater than the light intensity of periphery;
(d) above-mentioned photoresist layer is given development treatment, photoresist layer receives deep trouth that is deep to substrate of position formation that said beam center partly shines thus, forms the shallow slot of a degree of depth less than said deep trouth and receive said light beam periphery irradiated site;
(e) with chemical vapor deposition method to said photoresist layer deposit spathic silicon gate material, in said deep trouth and shallow slot, form " T " shape gate electrode figure thus;
(f) utilize plasma oxygen cineration technics to remove above-mentioned photoresist layer and be deposited on the gate material outside said " T " shape gate electrode figure.
2. method as claimed in claim 1 is characterized in that, said gate material comprises: conducting metal oxide, and like tin oxide (In 2O 3), antimony oxide (SbO), zinc oxide (ZnO), (GaO) etc. sowed in oxidation, and the oxide of above-mentioned alloy such as tin indium oxide (ITO), indium oxide are sowed zinc (IGZO) etc., inorganic conductive materials such as heavily doped polysilicon, germanium.
3. like the method for claim 1 or 2, it is characterized in that the intensity distributions of said collimated light beam is through the realization of cutting blocks for printing of semi-transparent rate reticle or interference fringe gray-level light.
CN2011101584764A 2011-06-14 2011-06-14 Power electric switch device and manufacturing method thereof Pending CN102832123A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011101584764A CN102832123A (en) 2011-06-14 2011-06-14 Power electric switch device and manufacturing method thereof

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Application Number Priority Date Filing Date Title
CN2011101584764A CN102832123A (en) 2011-06-14 2011-06-14 Power electric switch device and manufacturing method thereof

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Publication Number Publication Date
CN102832123A true CN102832123A (en) 2012-12-19

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5543253A (en) * 1994-08-08 1996-08-06 Electronics & Telecommunications Research Inst. Photomask for t-gate formation and process for fabricating the same
CN1700418A (en) * 2004-05-19 2005-11-23 上海宏力半导体制造有限公司 Method for manufacturing T-shaped polysilicon gate using dual damascene process
CN101330010A (en) * 2007-06-20 2008-12-24 中国科学院微电子研究所 A method of making T-type HBT emitter/HEMT grid

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5543253A (en) * 1994-08-08 1996-08-06 Electronics & Telecommunications Research Inst. Photomask for t-gate formation and process for fabricating the same
CN1700418A (en) * 2004-05-19 2005-11-23 上海宏力半导体制造有限公司 Method for manufacturing T-shaped polysilicon gate using dual damascene process
CN101330010A (en) * 2007-06-20 2008-12-24 中国科学院微电子研究所 A method of making T-type HBT emitter/HEMT grid

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Application publication date: 20121219