CN102786278A - Non-asbestos fiber reinforced calcium silicate board and manufacturing method thereof - Google Patents
Non-asbestos fiber reinforced calcium silicate board and manufacturing method thereof Download PDFInfo
- Publication number
- CN102786278A CN102786278A CN2012102836752A CN201210283675A CN102786278A CN 102786278 A CN102786278 A CN 102786278A CN 2012102836752 A CN2012102836752 A CN 2012102836752A CN 201210283675 A CN201210283675 A CN 201210283675A CN 102786278 A CN102786278 A CN 102786278A
- Authority
- CN
- China
- Prior art keywords
- calcium silicate
- asbestos fiber
- silicate board
- board
- strengthens
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 36
- 239000010425 asbestos Substances 0.000 title claims abstract description 25
- 229910052895 riebeckite Inorganic materials 0.000 title claims abstract description 25
- 239000000378 calcium silicate Substances 0.000 title claims abstract description 24
- 229910052918 calcium silicate Inorganic materials 0.000 title claims abstract description 24
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000292 calcium oxide Substances 0.000 claims abstract description 10
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 8
- 238000006703 hydration reaction Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 3
- 210000001161 mammalian embryo Anatomy 0.000 claims description 3
- 238000004537 pulping Methods 0.000 claims description 3
- 238000009156 water cure Methods 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 abstract description 10
- 239000002699 waste material Substances 0.000 abstract description 7
- 239000000428 dust Substances 0.000 abstract description 4
- 238000005498 polishing Methods 0.000 abstract description 4
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 4
- 239000000391 magnesium silicate Substances 0.000 description 4
- 229910052919 magnesium silicate Inorganic materials 0.000 description 4
- 235000019792 magnesium silicate Nutrition 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 235000019739 Dicalciumphosphate Nutrition 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 1
- 229940038472 dicalcium phosphate Drugs 0.000 description 1
- 229910000390 dicalcium phosphate Inorganic materials 0.000 description 1
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229910021534 tricalcium silicate Inorganic materials 0.000 description 1
- 235000019976 tricalcium silicate Nutrition 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a non-asbestos fiber reinforced calcium silicate board and a manufacturing method thereof. The non-asbestos fiber reinforced calcium silicate board comprises the following components in percentage by weight: 15-25 percent of ceramic waste powder, 35-40 percent of cement, 20-30 percent of powdered quartz, 8-10 percent of quick lime, 7-10 percent of organic fiber, 1-2 percent of inorganic thickening agent and 0.5-1 percent of antifoaming agent. After the technical scheme is adopted, the non-asbestos fiber reinforced calcium silicate board and the manufacturing method thereof have the greatest advantages that the rigidity of the board is improved by taking glaze-containing dust (ceramic working waste), produced by grinding during polishing of ceramic veneer, as filler to participate in hydration reaction of the board, the mechanical property of the board is reinforced, so that the mechanical property of a board containing asbestos fiber is achieved.
Description
Technical field
The present invention relates to the technical field of building board, be meant that specifically a kind of non-asbestos fiber strengthens calcium silicate board and preparation method thereof.
Background technology
It is the inside and outside wallboard that the Ministry of Construction applies that non-asbestos fiber strengthens calcium silicate board.Convention in the industry; The wallboard that contains fibrous magnesium silicate (carcinogens) use that is under an embargo from June 1st, 2011; And non-asbestos fiber enhancing calcium silicate board (hereinafter to be referred as sheet material) adopts organic fibre owing to not containing fibrous magnesium silicate, and the rigidity that must strengthen sheet material just can remedy the intensity that it does not contain fibrous magnesium silicate.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, provide a kind of and utilize ceramic veneer when polishing to grind the glaze dust (waste material of Production of Ceramics process) that contains that produces to strengthen calcium silicate board and preparation method thereof with the non-asbestos fiber that improves its mechanical property as the rigidity stopping composition.
For realizing above-mentioned purpose; Each composition that its non-asbestos fiber of technical scheme provided by the present invention strengthens calcium silicate board is by following weight percent proportioning: the useless powder 15～25% of pottery, cement 35～40%, konilite 20～30%; Unslaked lime 8～10%; Organic fibre 7～10%, inorganic thickening agent 1～2%, skimmer 0.5～1%.
The major ingredient of the useless powder of said pottery is AI
2O
318-21%, SiO
267-70%, Fe
2O
31%, K
2O 6-8% and colorant.
Said konilite is 200 order konilites.
Said inorganic thickening agent is a wilkinite.
The making method that non-asbestos fiber according to the invention strengthens calcium silicate board is following:
1) the component proportioning that, described non-asbestos fiber is strengthened calcium silicate board adds 75%～80% water and processes and contain solid-state 25～28% slip; At first the organic fibre water is mixed; Under whipped state, add unslaked lime, cement, the useless powder of pottery, konilite, inorganic thickening agent then; Wherein, Unslaked lime was given water cure earlier and is handled before feeding intake, can produce bubble at pulping process because organic fibre reacts, so add skimmer to stablize slip;
2), with above-mentioned 1) in the slip that obtains inject laminator and process the soft board embryo through 60 ℃ ± 2 ℃ warm and humid maintenances, under the condition of 175～185 ℃ of 0.8～1Mpa pressure and temperature, process hard plate material then through 8 hours hydration reaction.
The hard plate material of processing is at density 1.1g/cm
3State under, the folding strength>=10Mpa of its oven-dried condition meets the using strength of sheet material fully.
The present invention is after adopting above technical scheme; Its great advantage is that the present invention grinds the glaze dust (potter makes waste) that contains that produces to make the hydration reaction that stopping composition is participated in sheet material when utilizing the ceramic veneer polishing; Improve the rigidity of sheet material; To strengthen its mechanical property, make it reach the mechanical property of the sheet material that contains fibrous magnesium silicate.
Embodiment
Below in conjunction with specific embodiment the present invention is further specified.
The described non-asbestos fiber of present embodiment strengthens calcium silicate board, and its each composition is by following weight percent proportioning: the useless powder 15～25% of pottery, cement 35～40%; Konilite 20～30%, unslaked lime 8～10%, organic fibre 7～10%; Inorganic thickening agent 1～2%, skimmer 0.5～1%; Wherein, the first-selected wilkinite of the described inorganic thickening agent of present embodiment, skimmer is commercially available finished product, konilite is 200 order konilites.In addition, the major ingredient of the useless powder of the said pottery of present embodiment is the multiple glaze hybrid fine particles of glass crystallization, mullite crystallization, is specially AI
2O
318-21%, SiO
267-70%, Fe
2O
31%, K
2O 6-8% and colorant etc. (oven dry metering) are a kind of rigidity materials, its SIO
2And AI
2O
3Major ingredient and cement (Dicalcium Phosphate (Feed Grade) and tricalcium silicate) be good bond material.1), component proportioning that above-mentioned non-asbestos fiber is strengthened calcium silicate board adds 75%～80% water and process and contain solid-state 25～28% slip below strengthens the concrete making method of calcium silicate board: for the above-mentioned non-asbestos fiber of present embodiment; Its concrete operations are: at first organic fibre is mixed by above-mentioned weight proportion water; Under whipped state, add the useless powder of unslaked lime, cement, pottery, konilite, inorganic thickening agent then by above-mentioned weight proportion; Wherein, Unslaked lime was given the water cure processing earlier before feeding intake just can carry out slurrying; And in pulping process because organic fibre reaction can produce bubble, so the skimmer that will add above-mentioned weight proportion is to stablize slip; 2), with 1) in the slip that obtains inject laminator and process the soft board embryo through 60 ℃ ± 2 ℃ warm and humid maintenances; Then under the condition of 175～185 ℃ of 0.8～1Mpa pressure and temperature; Process hard plate material-non-asbestos fiber through 8 hours hydration reaction and strengthen calcium silicate board; Wherein, the hard plate material of processing is at density 1.1g/cm
3State under, the folding strength>=10Mpa of its oven-dried condition meets the using strength of sheet material fully.In a word; After adopting above scheme; The present invention be utilize ceramic veneer when polishing to grind to produce contain glaze dust (waste material of Production of Ceramics process) as the rigidity stopping composition to improve its mechanical property, when adopting ceramic waste material to produce hard plate material, realized the second stage employ of resource; Thereby reduced the environmental pollution of ceramic industry waste widely, be worthy to be popularized.
The embodiment of the above only is the present invention's preferred embodiment, is not to limit practical range of the present invention with this, so the variation that all shapes according to the present invention, principle are done all should be encompassed in protection scope of the present invention.
Claims (6)
1. a non-asbestos fiber strengthens calcium silicate board; It is characterized in that: each composition that said non-asbestos fiber strengthens calcium silicate board is by following weight percent proportioning: the useless powder 15～25% of pottery, cement 35～40%, konilite 20～30%; Unslaked lime 8～10%; Organic fibre 7～10%, inorganic thickening agent 1～2%, skimmer 0.5～1%.
2. a kind of non-asbestos fiber according to claim 1 strengthens calcium silicate board, it is characterized in that: the major ingredient of the useless powder of said pottery is AI
2O
318-21%, SiO
267-70%, Fe
2O
31%, K
2O 6-8% and colorant.
3. a kind of non-asbestos fiber according to claim 1 strengthens calcium silicate board, and it is characterized in that: said konilite is 200 order konilites.
4. a kind of non-asbestos fiber according to claim 1 strengthens calcium silicate board, and it is characterized in that: said inorganic thickening agent is a wilkinite.
5. the described non-asbestos fiber of a claim 1 strengthens the making method of calcium silicate board, and it is characterized in that: this making method is following:
1) the component proportioning that, described non-asbestos fiber is strengthened calcium silicate board adds 75%～80% water and processes and contain solid-state 25～28% slip; At first the organic fibre water is mixed; Under whipped state, add unslaked lime, cement, the useless powder of pottery, konilite, inorganic thickening agent then; Wherein, Unslaked lime was given water cure earlier and is handled before feeding intake, can produce bubble at pulping process because organic fibre reacts, so add skimmer to stablize slip;
2), with above-mentioned 1) in the slip that obtains inject laminator and process 60 ℃ ± 2 ℃ warm and humid maintenances of soft board embryo low temperature, under the condition of 175～185 ℃ of 0.8～1Mpa pressure and temperature, process hard plate material then through 8 hours hydration reaction.
6. a kind of non-asbestos fiber according to claim 5 strengthens the making method of calcium silicate board, and it is characterized in that: the hard plate material of processing is at density 1.1g/cm
3State under, the folding strength>=10Mpa of its oven-dried condition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102836752A CN102786278A (en) | 2012-08-10 | 2012-08-10 | Non-asbestos fiber reinforced calcium silicate board and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102836752A CN102786278A (en) | 2012-08-10 | 2012-08-10 | Non-asbestos fiber reinforced calcium silicate board and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102786278A true CN102786278A (en) | 2012-11-21 |
Family
ID=47151888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102836752A Pending CN102786278A (en) | 2012-08-10 | 2012-08-10 | Non-asbestos fiber reinforced calcium silicate board and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102786278A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105732078A (en) * | 2014-12-10 | 2016-07-06 | 辽宁利永盛新材料有限公司 | Preparation method for colored foamed ceramic sheet material by utilizing polished waste slag |
| CN110423080A (en) * | 2019-06-24 | 2019-11-08 | 武汉建筑材料工业设计研究院有限公司 | A kind of calcium silicate board or fibre cement board assembly line waste material reuse method |
| CN112176132A (en) * | 2020-09-25 | 2021-01-05 | 新疆互力佳源环保科技有限公司 | Resource utilization process for utilizing steelmaking production in cooperation with waste asbestos |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1205315A (en) * | 1997-07-10 | 1999-01-20 | 李瑜琳 | Non-asbest china clay calcium silicate plate and its prodn. method |
| CN101905962A (en) * | 2010-07-13 | 2010-12-08 | 石磊 | Modified inorganic powder composite material and preparation method thereof |
| CN101948285A (en) * | 2010-10-09 | 2011-01-19 | 南京明裕恒材料科技有限公司 | Calcium silicate material prepared from waste ceramic powder and preparation method thereof |
| CN102173855A (en) * | 2011-02-24 | 2011-09-07 | 董正根 | Calcium-silicon composite thermal insulating product |
-
2012
- 2012-08-10 CN CN2012102836752A patent/CN102786278A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1205315A (en) * | 1997-07-10 | 1999-01-20 | 李瑜琳 | Non-asbest china clay calcium silicate plate and its prodn. method |
| CN101905962A (en) * | 2010-07-13 | 2010-12-08 | 石磊 | Modified inorganic powder composite material and preparation method thereof |
| CN101948285A (en) * | 2010-10-09 | 2011-01-19 | 南京明裕恒材料科技有限公司 | Calcium silicate material prepared from waste ceramic powder and preparation method thereof |
| CN102173855A (en) * | 2011-02-24 | 2011-09-07 | 董正根 | Calcium-silicon composite thermal insulating product |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105732078A (en) * | 2014-12-10 | 2016-07-06 | 辽宁利永盛新材料有限公司 | Preparation method for colored foamed ceramic sheet material by utilizing polished waste slag |
| CN110423080A (en) * | 2019-06-24 | 2019-11-08 | 武汉建筑材料工业设计研究院有限公司 | A kind of calcium silicate board or fibre cement board assembly line waste material reuse method |
| CN112176132A (en) * | 2020-09-25 | 2021-01-05 | 新疆互力佳源环保科技有限公司 | Resource utilization process for utilizing steelmaking production in cooperation with waste asbestos |
| CN112176132B (en) * | 2020-09-25 | 2022-06-21 | 新疆互力佳源环保科技有限公司 | Resource utilization process for utilizing steelmaking production in cooperation with waste asbestos |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C12 | Rejection of a patent application after its publication | ||
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Application publication date: 20121121 |