CN102775944A - Sealing joint strip and application method thereof - Google Patents
Sealing joint strip and application method thereof Download PDFInfo
- Publication number
- CN102775944A CN102775944A CN2011100331208A CN201110033120A CN102775944A CN 102775944 A CN102775944 A CN 102775944A CN 2011100331208 A CN2011100331208 A CN 2011100331208A CN 201110033120 A CN201110033120 A CN 201110033120A CN 102775944 A CN102775944 A CN 102775944A
- Authority
- CN
- China
- Prior art keywords
- joint strip
- elastomerics
- mass parts
- maleic anhydride
- thermoplastic polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention provides a sealing joint strip which is used for heat bonding of a solar battery assembly or a flat-plate solar heat collector with a border. The sealing joint strip is characterized by comprising the following components by mass: 100 parts of thermoplastic polymer elastomer and 0.1 to 10 parts of a silane coupling agent. During utilization, the sealing joint strip can be pressed at a position where the solar battery assembly or the flat-plate solar heat collector and the border joint in the assembling process of a solar module and is then laid aside or treated at a certain temperature for a period of time so as to finish heat bonding, which allows good sealing and fixing effects of the sealing joint strip to be obtained. The application method for the sealing joint strip is characteristic of simpleness, high efficiency and environment friendliness. The sealing joint strip and the application method can also be used for the flat solar heat collector.
Description
Technical field
The present invention relates to a kind of sealing material and method of use thereof; Concrete; The present invention relates to a kind of joint strip and method of use thereof; It is bonding that said joint strip and method of use thereof are used for solar module or flat-plate solar collector and frame bonded, has excellent sealing and endurance quality, simple, the efficient and environmental protection of its operating procedure.
Background technology
Solar cell is if directly be exposed in the air, and its photoelectric transformation efficiency can descend very soon, thereby, lose practical value gradually.In order to protect solar cell not receive physical abuse and environmental damage, need carry out glue envelope, lamination, frame up it, be packaged into solar module.
According to the difference of request for utilization, solar module can be divided into rigidity solar module and flexible solar battery pack.Modal in the rigidity solar module is the large-area flat-plate solar cell; Said solar module is followed successively by glass front plate, the sticking material of envelope, battery sheet (linking to each other through interconnecting strip), the sticking material of envelope, backboard from top to bottom; Make the sticking material melting and solidification of envelope through vacuum hotpressing, thus, battery sheet, glass front plate and backboard are bonded as one; Form cell panel, periphery is fixed with aluminum alloy frame again.
The gap of cell panel edge and aluminum alloy frame uses silicone adhesive to fill sealing and bonding usually.Silicone adhesive has good ageing-resistant, protection against the tide and insulating property etc.; But the shortcoming of silicone adhesive is: set time is long; Discharge objectionable impuritiess such as sour or oxime in the solidification process, need to clean cull after the curing, waste resource and increase production cost.
In addition, also there is the part solar module to adopt the double sticky tape sealing the margin.Double sticky tape is a base material with the plastics foam normally, evenly is coated with rubber-type or resin pressure sensitive adhesive on it and obtains.Common pressure sensitive adhesive has rubber, propenoate, urethane and organosilicon etc., and pressure can form bonding force through Van der Waals force between two articles a little.Compare with the silicone adhesive stick, the double sticky tape biggest advantage is to need not set time, does not need cleaning step after using.In addition, the rippability of pressure-sensitive adhesive is good, makes things convenient for the maintenance of assembly.But the shortcoming of double sticky tape is: its bonding strength is low, and quality is unstable, and environment durability difference and cost are higher.In addition, the use of double sticky tape also makes the packaging technology relative complex of solar cell.
Flat-plate solar collector also need be installed aluminum alloy frame in assembling process.Adopt at present conventional seals row culture physical seal between glass plate and the aluminum alloy frame usually, for example terpolymer EP rubber EPDM adhesive tape etc.Yet well-known, the sealing effectiveness of physical seal is limited.
In sum, common rubber-like and thermoplastic elastomer class trouble material can only play physical seal and buffered effect through compression, and sealing and endurance quality are poor, and efficient is low, not environmental protection.
Be the solar module that adapts to quick growth and the needs of plate solar collector, press for that a kind of production efficiency is high, sealing effectiveness is good, environmental-protecting performance is excellent, uses is durable, the simple edge seal material of technology and method of use accordingly thereof.
Summary of the invention
For addressing the above problem; The present invention provides a kind of and is used for solar module or is used for flat-plate solar collector and frame bonded novel seal adhesive tape; Can be at a certain temperature and solar module or flat-plate solar collector and frame heat bonding, have excellent sealing and endurance quality.Its operating procedure has simply, the characteristics of efficient and environmental protection.
Technical scheme of the present invention is following:
A kind of joint strip, mainly process by the following raw material of quality proportioning:
100 parts on thermoplastic polymer elastomerics
Silane coupling agent 0.01-10 part
According to joint strip of the present invention, preferably, said joint strip comprises the composition that the quality proportioning is following:
100 parts on thermoplastic polymer elastomerics
Silane coupling agent 0.3-1.5 part.
The thermoplastic polymer elastomerics is a kind of with rubber and thermoplastics characteristic, shows the snappiness of rubber at normal temperatures, macromolecular material that again can plasticizing forming under the high temperature.
According to joint strip of the present invention,, thereby play the sealing function of excellence because combining of thermoplastic polymer elastomerics and silane coupling agent except the characteristics that possess conventional joint strip, can be carried out thermal caking under heating condition.
According to joint strip of the present invention, said thermoplastic elastomer comprises:
Styrenic elastomerics, for example styrene-butadiene-styrene block copolymer (SBS), SIS (SIS), styrene-ethylene-butylene-styrene segmented copolymer (SEBS), styrene-ethylene-propylene-styrene segmented copolymer (SEPS) etc.;
Olefin type elastomer (POE), for example ethylene-propylene diene copolymer (EPDM), olefin copolymer elastomer etc.;
Diene class elastomerics; The polyvinyl chloride-base elastomerics;
Polyurethanes elastomerics (TPU);
Polyester elastomer (TPEE);
Polyamide-based elastomerics (TPAE);
Organic fluorine class elastomerics (TPF) and silicone based elastomerics or the like.
According to joint strip of the present invention, wherein, preferably, the thermoplastic polymer elastomerics be hardness from 20A to 90A, processing temperature is from 60 ℃ to 200 ℃ thermoplastic polymer elastomerics.Wherein, more preferably, said thermoplastic polymer elastomerics be hardness from 40A to 80A, processing temperature is from 90 ℃ to 160 ℃ thermoplastic polymer elastomerics.
According to a preferred embodiment of the present invention, preferably hardness is in styrenic elastomerics and the olefin copolymer elastomer of 40A to 70A.
In the present invention, silane coupling agent comprises that all contain the silicoorganic compound of siloxane groups, and its substruction formula is Y-R-SiX
3, wherein, Y is an organo-functional group, normally vinyl, amino, epoxy group(ing), methacryloxy, sulfydryl or urea groups.R is an alkyl group, and Si is a Siliciumatom.X is chloro, methoxyl group, oxyethyl group, methoxy ethoxy, acetoxyl group etc. normally, generates silanol (Si (OH) during these group hydrolysis
3), and combine with inorganic substance, form siliconoxygen bond.
According to the present invention, silane coupling agent commonly used comprises:
γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane, γ-An Bingjisanyiyangjiguiwan; γ-An Bingjisanjiayangjiguiwan, N-β (aminoethyl)-γ-An Bingjisanyiyangjiguiwan, N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan; N-β (aminoethyl)-γ-aminopropyl methyl dimethoxysilane, N-β (aminoethyl)-γ-aminopropyl methyldiethoxysilane, phenylamino Union carbide A-162; The phenylamino methyltrimethoxy silane, aminoethyl aminoethyl aminopropyl trimethoxysilane, γ-r-chloropropyl trimethoxyl silane; Vinyl trichloro silane, vinyltriethoxysilane, γ-methacryloxypropyl trimethoxy silane; Vinyltriacetoxy silane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane or the like.Preferred examples is N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan and γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane or the like among the present invention.
In joint strip of the present invention, can also add the maleic anhydride grafted polymer component, to increase the bonding strength of joint strip.Said maleic anhydride grafted polymer comprises: maleic anhydride graft polyolefine, maleic anhydride grafted polyethylene for example, maleic anhydride inoculated polypropylene etc.; The maleic anhydride grafted ethene analog copolymer; Ethene copolymer be ethene and at least a below monomeric multipolymer: vinyl acetate, vinylformic acid C1-4 alkane ester, methylacrylic acid C1-4 alkane ester, vinylformic acid, methylacrylic acid, maleic anhydride, glycidyl acrylate, SY-Monomer G; The maleic anhydride graft styrene block copolymer, maleic anhydride graft SEBS for example, maleic anhydride graft propylene cyanogen-butylene-styrene multipolymer (AB S) or the like.The proportioning of said maleic anhydride grafted polymer is the 5-200 mass parts for the thermoplastic polymer elastomerics to 100 mass parts.
A preferred embodiment of using among the present invention is maleic anhydride graft SEBS.
In joint strip of the present invention; Can also add antioxidant component; To increase the thermal stability of joint strip, the proportioning of said antioxidant component is the 0.01-10 mass parts to the thermoplastic polymer elastomerics of 100 mass parts, preferably the 0.05-1 mass parts.Said oxidation inhibitor comprises Hinered phenols and suffocated amine antioxidant or the like.
In the preferred embodiment of using in the present invention, said oxidation inhibitor is four (methylene radical (3,5-two-(uncle)-butyl-4-hydroxyl hydrogenated cinnamate)) methane.
In joint strip of the present invention, can also add the photostabilizer component, to increase the uvioresistant stability of joint strip.The proportioning of said photostabilizer component is the 0.01-10 mass parts to the thermoplastic polymer elastomerics of 100 mass parts, preferably the 0.05-1 mass parts.Said photostabilizer comprises Hinered phenols photostabilizer, hindered amine light stabilizer, ultraviolet quenchers such as carbon black and titanium oxide or the like.
In the preferred embodiment of using in the present invention, said photostabilizer is two (2,2,6, the 6-tetramethyl-piperidyl) sebates.
At joint strip of the present invention, the thermoplastic polymer elastomerics that can also add to 100 mass parts is the 1-100 mass parts, and the tackifier component of 10-50 mass parts preferably is to increase the adhesive property of joint strip.Said tackifier comprise petroleum resin, rosin and hydrogenated wood rosin glycerol ester, terpine resin and low-melting terpene phenolic resin, coumarone-indene resin or the like.
In joint strip of the present invention, the thermoplastic polymer elastomerics that can also add to 100 mass parts is the 1-100 mass parts, and the weighting agent component of 10-50 mass parts preferably is to improve the consistency and elasticity performance of joint strip.Said weighting agent comprises Yellow Protopet 2A and NO or the like.
In joint strip of the present invention, can also comprise other additives that usually use in the polymer compsn field, for example static inhibitor, whipping agent, lubricant, softening agent, tinting material and filler or the like.
The polymer compsn that uses among the present invention can be made into the polymeric seal adhesive tape or the polymeric seal film of various cross-sectional shapes through the mode of melt extrusion processing or injection moulding processing.Wherein common cross-sectional shape such as U type or C type.
Method of use according to joint strip of the present invention; In the process of assembling solar battery module or flat-plate solar collector; Said joint strip pressure is put the junction at solar module or flat-plate solar collector and frame; Assembling solar battery module or flat-plate solar collector; Is 60 ℃-200 ℃ (wherein preferred temperature range is from 90 ℃ to 160 ℃, and the TR that is more preferably is from 110 ℃ to 150 ℃) held or thermal treatment 1 minute to 30 minutes with the solar module that assembles or flat-plate solar collector in TR, (preferably 3 minutes to 15 minutes); Said joint strip and solar module and frame are carried out heat bonding, and the TR of the heat bonding of said joint strip is 60 ℃-200 ℃.
According to the method for use of joint strip according to the invention, the TR of the heat bonding of said joint strip is 90 ℃ to 160 ℃, and the TR that is more preferably is from 110 ℃ to 150 ℃.
According to joint strip according to the invention and method of use thereof, be that a production efficient is high, sealing effectiveness is good, environmental-protecting performance is excellent, uses is durable, the simple edge seal material of technology and method of use accordingly thereof
Embodiment
Below, in conjunction with specific embodiment joint strip of the present invention is described further, but protection scope of the present invention is not limited in this.
Embodiment 1:
In mass fraction, in 100 parts of styrene-ethylene-butylene-styrene segmented copolymers (Chinese Yueyang petrochemical industry ltd), add 0.6 part of N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan (Dow corning company), and mix.Resulting composition is through melt blending, and extruded becomes continuous film or U type or C type adhesive tape.
Embodiment 2:
In mass fraction, in 100 parts of styrene-ethylene-butylene-styrene segmented copolymers (Chinese Yueyang petrochemical industry ltd), add 0.6 part of γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane (Dow corning company), and mix.Resulting composition is through melt blending, and extruded becomes continuous film or U type or C type adhesive tape.
Embodiment 3:
In mass fraction, in 100 parts of styrene-ethylene-butylene-styrene segmented copolymers (Chinese Yueyang petrochemical industry ltd), add 0.6 part of N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan (Dow corning company); Add 30 parts of maleic anhydride graft SEB S (U.S. Ke Teng Polymer Company); 0.2 part oxidation inhibitor four (methylene radical (3,5-two-(uncle)-butyl-4-hydroxyl hydrogenated cinnamate)) methane (Nanjing Ning Kang chemical industry ltd), 0.2 part of photostabilizer two (2; 2; 6, the 6-tetramethyl-piperidyl) sebate (Milan, Nanjing chemical industry ltd), and mix.Resulting composition is through melt blending, and extruded becomes continuous film or U type or C type adhesive tape.
Embodiment 4:
In mass fraction, in 100 parts of ethylene-propylene terpolymers (The Dow Chemical Co. (US) 2030 Dow Center, Abbott Road, Midland, Michigan 48640), add 1 part of N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan (Dow corning company); 0.1 part oxidation inhibitor four (methylene radical (3,5-two-(uncle)-butyl-4-hydroxyl hydrogenated cinnamate)) methane (Nanjing Ning Kang chemical industry ltd), 0.1 part of photostabilizer two (2; 2; 6, the 6-tetramethyl-piperidyl) sebate (Milan, Nanjing chemical industry ltd), and mix.Resulting composition is through melt blending, and extruded becomes continuous film or U type or C type adhesive tape.
Embodiment 5:
In mass fraction, in 100 parts of TPUEs (BASF Aktiengesellschaft), add 2 parts of N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan (Dow corning company); 0.1 part oxidation inhibitor four (methylene radical (3,5-two-(uncle)-butyl-4-hydroxyl hydrogenated cinnamate)) methane (Nanjing Ning Kang chemical industry ltd), 0.1 part of photostabilizer two (2; 2; 6, the 6-tetramethyl-piperidyl) sebate (Milan, Nanjing chemical industry ltd), and mix.Resulting composition is through melt blending, and extruded becomes continuous film or U type or C type adhesive tape.
Embodiment 6:
In mass fraction, in 100 parts of olefin copolymer elastomer (Sinopec ltd), add 0.6 part of N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan (Dow corning company); Also add 30 parts of maleic anhydride graft SEB S (U.S. Ke Teng Polymer Company); 0.2 part oxidation inhibitor four (methylene radical (3,5-two-(uncle)-butyl-4-hydroxyl hydrogenated cinnamate)) methane (Nanjing Ning Kang chemical industry ltd), 0.2 part of photostabilizer two (2; 2; 6, the 6-tetramethyl-piperidyl) sebate (Milan, Nanjing chemical industry ltd), and mix.Resulting composition is through melt blending, and extruded becomes continuous film or U type or C type adhesive tape.
Embodiment 7:
Except following difference, other make joint strip of the present invention as embodiment 1.TPUE is styrene-ethylene-propylene-styrene segmented copolymer SEPS.Add 0.3 part of silane coupling agent N-β (aminoethyl)-γ-aminopropyl methyldiethoxysilane.
Said joint strip comprises: the quality proportioning is 5 parts of maleic anhydride inoculated polypropylenes in order to the bonding strength of increase joint strip for the SEPS to 100 mass parts; 0.01 the antioxidant component of mass parts, said oxidation inhibitor comprises Hinered phenols and suffocated amine antioxidant; The photostabilizer component of 3 mass parts, the ultraviolet quencher of carbon black and titanium oxide; The tackifier hydrogenated wood rosin glycerol ester of 5 mass parts; The Yellow Protopet 2A of 1 mass parts.
Embodiment 8:
Except following difference, other make joint strip of the present invention as embodiment 1.TPUE is the polyvinyl chloride-base elastomerics; Silane coupling agent is the phenylamino Union carbide A-162 of 1.0 mass parts.Said joint strip also comprises: the quality proportioning for be 60 parts to the thermoplastic polymer elastomerics of 100 mass parts, in order to the maleic anhydride graft propylene cyanogen-butylene-styrene copolymer A B S of the bonding strength that increases joint strip; The antioxidant component of 8 mass parts, said oxidation inhibitor comprises Hinered phenols and suffocated amine antioxidant; The tackifier petroleum resin of 10 mass parts; The weighting agent component NO of 5 mass parts, and static inhibitor, the tinting material of 0.2 mass parts and the pearl filler of 20 mass parts of 0.1 mass parts.
Embodiment 9:
Except following difference, other make joint strip of the present invention as embodiment 1.Thermoplastic elastomer is polyamide-based elastomerics TPAE, and silane coupling agent is the phenylamino methyltrimethoxy silane of 1.5 mass parts.
Said joint strip also comprises: the quality proportioning for be 100 parts to the thermoplastic polymer elastomerics of 100 mass parts, in order to the maleic anhydride graft styrene block copolymer of the bonding strength that increases joint strip; Said joint strip adds the antioxidant component of 0.02 mass parts, and said oxidation inhibitor comprises the tackifier of Hinered phenols and suffocated amine antioxidant and 0.1 mass parts.
Embodiment 10:
Except following difference, other make joint strip of the present invention as embodiment 1.Thermoplastic elastomer is the phenylamino Union carbide A-162 of organic polyurethane elastomer and silicone based elastic composition (organic fluorine class elastomerics TPF80 mass parts, silicone based elastomerics 20 mass parts) and 5.0 mass parts.
Said joint strip also comprises: the thermoplastic polymer elastomerics to 100 mass parts is 150 parts of maleic anhydride grafted polymer components in order to the bonding strength of increase joint strip: maleic anhydride grafted polyethylene.
Said joint strip adds the antioxidant component of 2 mass parts, and said oxidation inhibitor comprises Hinered phenols and suffocated amine antioxidant; The weighting agent component of the tackifier of 80 mass parts and 30 mass parts, said weighting agent comprises Yellow Protopet 2A and NO.In addition, add 2 parts of whipping agents, 1 part of softening agent and 1 part of tinting material.
Embodiment 11:
Except following difference, other make joint strip of the present invention as embodiment 1.TPUE is styrene-ethylene-propylene-styrene segmented copolymer SEPS.Silane coupling agent is the aminoethyl aminoethyl aminopropyl trimethoxysilane of 6.0 mass parts.In addition, also add the antioxidant component and the photostabilizer component of 0.01 mass parts, said oxidation inhibitor comprises Hinered phenols and suffocated amine antioxidant.Said photostabilizer is selected from the ultraviolet quencher of Hinered phenols photostabilizer, hindered amine light stabilizer, carbon black and titanium oxide.
Add the tackifier of 5 mass parts and the weighting agent component of 20 mass parts, said weighting agent comprises Yellow Protopet 2A and NO.
Embodiment 12:
Except following difference, other make joint strip of the present invention as embodiment 1.The aminoethyl aminoethyl aminopropyl trimethoxysilane of 10 mass parts, the antioxidant component of 2 mass parts and photostabilizer component, said oxidation inhibitor comprises Hinered phenols and suffocated amine antioxidant.Said photostabilizer is selected from the ultraviolet quencher of Hinered phenols photostabilizer, hindered amine light stabilizer, carbon black and titanium oxide.
Also add the tackifier of 5 mass parts and the weighting agent component of 20 mass parts, said weighting agent comprises Yellow Protopet 2A and NO.
According to peeling off experimental requirements, the plateholder of 0.5 mm thick 130 ℃ of hot pressing 5 minutes, makes and peels off specimen, in order to the stripping strength of test film and matrix in the middle of the matrix of two needs tests.Application requiring according to bonding solar components and frame; Gained film and glass among the embodiment 1 to 5, solar cell backboard (are example with the backboard based on PVDF (PVDF) material among the present invention; But being not limited to this, also can be that pvdf (PVF) or materials such as polyethylene terephthalate (PET) or polyamide (PA) are the backboard of matrix) and the stripping strength of aluminum alloy frame test.
Comparative Examples 1:
Select the widely used silicone sealant of area of solar cell frame seal aspect example as a comparison for use.Silicone sealant and glass, solar cell backboard (are example with the backboard based on PVDF (PVDF) material among the present invention; But being not limited to this, also can be that pvdf (PVF) or materials such as polyethylene terephthalate (PET) or polyamide (PA) are the backboard of matrix) and the stripping strength of aluminum alloy frame test.Silicone sealant (Tianshan Mountains tackiness agent company) is filled in the middle of the matrix of two needs tests, compresses, and the room temperature held was tested after the completely solidified in 48 hours.
Comparative Examples 2:
Select the widely used double sticky tape of area of solar cell frame seal aspect example as a comparison for use.Double sticky tape and glass, solar cell backboard (are example with the backboard based on PVDF (PVDF) material among the present invention; But being not limited to this, also can be that pvdf (PVF) or materials such as polyethylene terephthalate (PET) or polyamide (PA) are the backboard of matrix) and the stripping strength of aluminum alloy frame test.Double sticky tape (Luo Man adhesive tape ltd) is placed in the middle of the matrix of two needs tests, compresses, and the room temperature held was tested after 24 hours.
With the sample among the embodiment 1 to 5 is example.Double sticky tape in silicone sealant, the Comparative Examples 2 in gained film, the Comparative Examples 1 among the embodiment 1 to 5, its tensile strength, hardness, the initial bonding strength of itself and glass, backboard and aluminum alloy frame; (85 ℃ of stripping strengths behind the hydrothermal aging; 85% humidity, 1000 hours), the result is listed in the table 1.
The performance of table 1 embodiment and Comparative Examples
Though the front shows to preferred implementation and has described the present invention, it will be understood by those skilled in the art that and under the prerequisite that does not break away from the scope of the invention that limits in claims, can make variations and modifications.
Claims (16)
1. a joint strip is used for solar module or flat-plate solar collector and combines with the heat bonding of frame, comprises the thermoplastic polymer elastomerics, it is characterized in that said joint strip comprises the composition that the quality proportioning is following:
100 parts on thermoplastic polymer elastomerics
Silane coupling agent 0.01-10 part.
2. joint strip as claimed in claim 1 is characterized in that, said joint strip comprises the composition that the quality proportioning is following:
100 parts on thermoplastic polymer elastomerics
Silane coupling agent 0.3-1.5 part.
3. according to claim 1 or claim 2 joint strip is characterized in that said thermoplastic elastomer is selected from following elastomerics:
Styrenic elastomerics like styrene-butadiene-styrene block copolymer SBS, SIS SIS, styrene-ethylene-butylene-styrene segmented copolymer SEBS;
Styrene-ethylene-propylene-styrene segmented copolymer SEPS;
Olefin type elastomer POE like ethylene-propylene diene copolymer EPDM, olefin copolymer elastomer;
Diene class elastomerics;
The polyvinyl chloride-base elastomerics;
The polyurethanes elastomer;
Polyester elastomer TPEE;
Polyamide-based elastomerics TPAE;
Organic fluorine class elastomerics TPF and silicone based elastomerics.
4. joint strip as claimed in claim 3 is characterized in that, the hardness of said thermoplastic elastomer is the 20A-90A scope, and processing temperature is 60 ℃-200 ℃.
5. joint strip as claimed in claim 3 is characterized in that, the hardness of said thermoplastic elastomer is the 40A-80A scope, and processing temperature is 90 ℃-160 ℃.
6. joint strip as claimed in claim 3 is characterized in that, said thermoplastic elastomer be styrenic elastomerics, olefin type elastomer or the polyurethane elastomer of hardness 40A-80A scope.
7. joint strip as claimed in claim 1 is characterized in that,
Said silane coupling agent comprises the silicoorganic compound that contain siloxane groups, and its substruction formula is Y-R-SiX
3, wherein, Y is the organo-functional group that is selected from vinyl, amino, epoxy group(ing), methacryloxy, sulfydryl or urea groups; R is an alkyl group, and Si is a Siliciumatom, and X is selected from chloro, methoxyl group, oxyethyl group, methoxy ethoxy, acetoxyl group,
Generate silanol Si (OH) during above-mentioned these group hydrolysis
3, combine to form siliconoxygen bond with inorganic substance.
8. joint strip as claimed in claim 7 is characterized in that,
Said silane coupling agent is selected from: γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane, γ-An Bingjisanyiyangjiguiwan; γ-An Bingjisanjiayangjiguiwan, N-β (aminoethyl)-γ-An Bingjisanyiyangjiguiwan, N-β (aminoethyl)-γ-An Bingjisanjiayangjiguiwan; N-β (aminoethyl)-γ-aminopropyl methyl dimethoxysilane, N-β (aminoethyl)-γ-aminopropyl methyldiethoxysilane, phenylamino Union carbide A-162; The phenylamino methyltrimethoxy silane, aminoethyl aminoethyl aminopropyl trimethoxysilane, γ-r-chloropropyl trimethoxyl silane; Vinyl trichloro silane, vinyltriethoxysilane, γ-methacryloxypropyl trimethoxy silane; Vinyltriacetoxy silane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane.
9. joint strip as claimed in claim 1; It is characterized in that; Said joint strip comprise the quality proportioning for be 5-200 part to the thermoplastic polymer elastomerics of 100 mass parts, in order to the maleic anhydride grafted polymer component of the bonding strength that increases joint strip, said maleic anhydride grafted polymer is selected from following:
Like maleic anhydride grafted polyethylene, the maleic anhydride graft polyolefine of maleic anhydride inoculated polypropylene;
The maleic anhydride grafted ethene analog copolymer; Said ethene copolymer be ethene and at least a below monomeric multipolymer: vinyl acetate, vinylformic acid C1-4 alkane ester, methylacrylic acid C1-4 alkane ester, vinylformic acid, methylacrylic acid, maleic anhydride, glycidyl acrylate, SY-Monomer G;
Like maleic anhydride graft SEBS, the maleic anhydride graft styrene block copolymer of maleic anhydride graft propylene cyanogen-butylene-styrene copolymer A BS.
11. joint strip according to claim 1 or claim 2; It is characterized in that; Described joint strip comprises that the thermoplastic polymer elastomerics to 100 mass parts is the antioxidant component of 0.01-10 mass parts, and said oxidation inhibitor comprises Hinered phenols and suffocated amine antioxidant.
12. joint strip according to claim 1 or claim 2; It is characterized in that; Described joint strip comprises that the thermoplastic polymer elastomerics to 100 mass parts in order to the uvioresistant stability that increases joint strip is the photostabilizer component of 0.01-10 mass parts, and said photostabilizer is selected from the ultraviolet quencher of Hinered phenols photostabilizer, hindered amine light stabilizer, carbon black and titanium oxide.
13. joint strip according to claim 1 or claim 2; It is characterized in that; The thermoplastic polymer elastomerics to 100 mass parts that said joint strip comprises in order to the adhesive property that increases joint strip is the tackifier component of 1-100 mass parts, and said tackifier are selected from petroleum resin, rosin and hydrogenated wood rosin glycerol ester; Terpine resin and low-melting terpene phenolic resin, coumarone-indene resin.
14. joint strip according to claim 1 or claim 2; It is characterized in that; The thermoplastic polymer elastomerics to 100 mass parts that said joint strip comprises in order to the consistency and elasticity performance of improving joint strip is the weighting agent component of 1-100 mass parts, and said weighting agent comprises Yellow Protopet 2A and NO.
15. joint strip according to claim 1 or claim 2 is characterized in that, said joint strip comprises other additives like static inhibitor, whipping agent, lubricant, softening agent, tinting material and filler.
16. the method for use of the said joint strip of claim 1; It is characterized in that; In the process of assembling solar battery module or flat-plate solar collector; Said joint strip pressed put in the junction of solar module or flat-plate solar collector and frame, assembling solar battery module or flat-plate solar collector are 60 ℃ of-200 ℃ of held or thermal treatment 1 minute to 30 minutes with the solar module that assembles or flat-plate solar collector in TR; Said joint strip and solar module and frame are carried out heat bonding, and the TR of the heat bonding of said joint strip is 60 ℃-200 ℃.
17. the method for use like the said joint strip of claim 16 is characterized in that, the TR of the heat bonding of said joint strip is 90 ℃ to 160 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100331208A CN102775944A (en) | 2011-01-30 | 2011-01-30 | Sealing joint strip and application method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100331208A CN102775944A (en) | 2011-01-30 | 2011-01-30 | Sealing joint strip and application method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102775944A true CN102775944A (en) | 2012-11-14 |
Family
ID=47121058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100331208A Pending CN102775944A (en) | 2011-01-30 | 2011-01-30 | Sealing joint strip and application method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102775944A (en) |
Cited By (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173180A (en) * | 2013-03-23 | 2013-06-26 | 广东新展化工新材料有限公司 | Thermoplastic adhesive and preparation method thereof |
| CN103205210A (en) * | 2013-03-19 | 2013-07-17 | 江苏鹿山光伏科技有限公司 | High-temperature-resistant hot melt adhesive membrane for aluminum honeycomb boards, and preparation method thereof |
| CN103554823A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Heat-resistant and corrosion-resistant insulating material for wire harnesses of refrigerator |
| CN103669161A (en) * | 2013-12-30 | 2014-03-26 | 上海浦东路桥建设股份有限公司 | Telescopic strip for inhibiting pedestrian crossing crack generation as well as application method and purpose of telescopic strip |
| CN103821445A (en) * | 2014-03-05 | 2014-05-28 | 天津中财型材有限责任公司 | Sealing rubber strip and preparation method thereof |
| CN104072859A (en) * | 2014-07-16 | 2014-10-01 | 苏州新区华士达工程塑胶有限公司 | Improved POE |
| CN104194283A (en) * | 2014-09-02 | 2014-12-10 | 安特普工程塑料（苏州）有限公司 | High-performance thermoplastic elastomer and processing method thereof |
| CN104327488A (en) * | 2014-11-06 | 2015-02-04 | 苏州佰格斯电子科技有限公司 | Acid and alkali-resistant polyurethane sealing strip |
| CN104356631A (en) * | 2014-11-06 | 2015-02-18 | 苏州佰格斯电子科技有限公司 | Durable polyurethane sealant |
| CN104356633A (en) * | 2014-11-06 | 2015-02-18 | 苏州佰格斯电子科技有限公司 | High-performance polyurethane sealant |
| CN104387748A (en) * | 2014-11-06 | 2015-03-04 | 苏州佰格斯电子科技有限公司 | High-quality polyurethane sealing strip |
| CN104387749A (en) * | 2014-11-06 | 2015-03-04 | 苏州佰格斯电子科技有限公司 | High-strength foamed polyurethane sealing strip |
| CN104387676A (en) * | 2014-10-29 | 2015-03-04 | 苏州新区枫盛塑料制品厂 | Thermoplastic elastomer formula |
| CN104848571A (en) * | 2014-02-17 | 2015-08-19 | 萨沃-太阳能有限公司 | Solar thermal absorber element |
| CN105367735A (en) * | 2015-11-23 | 2016-03-02 | 苏州盖德精细材料有限公司 | Polyurethane adhesive used for shoes and preparation method thereof |
| CN105694334A (en) * | 2016-03-08 | 2016-06-22 | 安徽韧达高分子材料有限公司 | TPE (thermal plastic elastomer) material for coating nylon and preparation method of TPE material |
| CN106281064A (en) * | 2016-08-22 | 2017-01-04 | 广西南宁荣威德新能源科技有限公司 | A kind of novel environment friendly solar-energy photo-voltaic cell encapsulating material |
| CN106520006A (en) * | 2016-11-26 | 2017-03-22 | 马益元 | Small-size surface protective film for mobile phone lens |
| CN107987780A (en) * | 2017-12-12 | 2018-05-04 | 东莞市雄林新材料科技股份有限公司 | A kind of environment-friendly type organosilicon modified TPU hot melt adhesive and preparation method thereof |
| CN108285577A (en) * | 2018-01-31 | 2018-07-17 | 河北贵航鸿图汽车零部件有限公司 | A kind of TPEE modified thermoplastic elastomers weather strip for automobile |
| CN108517079A (en) * | 2018-04-20 | 2018-09-11 | 裴文韬 | A kind of preparation method of water-proof sealing rubber strip |
| CN109651642A (en) * | 2018-10-24 | 2019-04-19 | 诺博橡胶制品有限公司 | Sealing sponge sizing material and preparation method thereof and sealing strip and preparation method and automobile |
| CN109897331A (en) * | 2019-02-28 | 2019-06-18 | 金发科技股份有限公司 | A kind of highly polar Flameproof styrenic class composition, preparation method and applications |
| CN110003825A (en) * | 2019-04-10 | 2019-07-12 | 广东绿洲化工有限公司 | A kind of silane coupler modified SBS adhesive of aluminium bonding and preparation method thereof |
| CN110655874A (en) * | 2019-08-29 | 2020-01-07 | 苏州德圣辉新能源科技有限公司 | A kind of glue for solar cell back sheet film composite and preparation method thereof |
| CN110854225A (en) * | 2018-07-25 | 2020-02-28 | 比亚迪股份有限公司 | A double glass photovoltaic module |
| CN112226177A (en) * | 2020-09-18 | 2021-01-15 | 苏州赛伍应用技术股份有限公司 | Welding strip carrier film, welding strip composite body and battery piece composite body |
| CN112226169A (en) * | 2020-09-25 | 2021-01-15 | 苏州赛伍应用技术股份有限公司 | A welding tape carrier film, its preparation method, welding tape composite body, and battery sheet composite body |
| CN112852311A (en) * | 2021-01-15 | 2021-05-28 | 江苏鹿山新材料有限公司 | Photovoltaic packaging adhesive film, preparation method thereof and photovoltaic module |
| TWI750548B (en) * | 2018-12-06 | 2021-12-21 | 台橡股份有限公司 | Polymer composition, foam and method thereof |
| CN114539965A (en) * | 2022-03-03 | 2022-05-27 | 东莞市华盛新材料有限公司 | Hot-melt adhesive capable of hot-pressing and water-splashing-preventing treatment and made of nylon material and preparation process of hot-melt adhesive |
| CN114634778A (en) * | 2021-11-03 | 2022-06-17 | 张家港康得新光电材料有限公司 | Adhesive resin composition and self-adhesive protective film |
| CN115895534A (en) * | 2022-03-11 | 2023-04-04 | 上海启梦胶粘制品有限公司 | A kind of removable glue and preparation method thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007094445A1 (en) * | 2006-02-17 | 2007-08-23 | Du Pont-Mitsui Polychemicals Co. Ltd. | Solar battery sealing material |
| CN101353563A (en) * | 2008-09-11 | 2009-01-28 | 成都硅宝科技股份有限公司 | Single-component silicone fluid sealant for solar energy cell assembly and manufacturing method thereof |
| WO2009101369A1 (en) * | 2008-02-13 | 2009-08-20 | Arkema France | Binder based on carboxylic acid vinyl ethylene ester copolymer and polyolefin containing a functional monomer |
| CN101626039A (en) * | 2009-07-27 | 2010-01-13 | 江阴爱康太阳能器材有限公司 | Solar cell packaging EVA adhesive film capable of resisting heat, humidity, ultraviolet light and aging |
| CN101735744A (en) * | 2008-11-24 | 2010-06-16 | 李彪 | EVA hot melt adhesive sheet for solar battery |
| CN101870854A (en) * | 2009-04-27 | 2010-10-27 | 诸暨市枫华光伏材料有限公司 | Fast cure EVA solar cell adhesive film |
| CN101935504A (en) * | 2010-09-02 | 2011-01-05 | 上海天洋热熔胶有限公司 | A kind of high-efficiency anti-ultraviolet solar cell encapsulation EVA adhesive film and preparation method thereof |
| CN102115642A (en) * | 2010-12-31 | 2011-07-06 | 广州鹿山新材料股份有限公司 | EVA (ethylene vinyl-acetate copolymer) adhesive film capable of simplifying packaging structure of solar battery |
| CN102115643A (en) * | 2010-12-31 | 2011-07-06 | 广州鹿山新材料股份有限公司 | Novel solar cell packaging adhesive film |
| CN102134450A (en) * | 2010-12-14 | 2011-07-27 | 上海天洋热熔胶有限公司 | High-adhesive-strength ethylene vinyl acetate adhesive film for packaging solar cells and preparation method thereof |
| CN102153958A (en) * | 2011-01-11 | 2011-08-17 | 广州市宝力达电气材料有限公司 | EVA (ethylene-vinyl acetate) adhesive film for heat-resistant solar battery, and preparation method and application thereof |
-
2011
- 2011-01-30 CN CN2011100331208A patent/CN102775944A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007094445A1 (en) * | 2006-02-17 | 2007-08-23 | Du Pont-Mitsui Polychemicals Co. Ltd. | Solar battery sealing material |
| WO2009101369A1 (en) * | 2008-02-13 | 2009-08-20 | Arkema France | Binder based on carboxylic acid vinyl ethylene ester copolymer and polyolefin containing a functional monomer |
| CN101353563A (en) * | 2008-09-11 | 2009-01-28 | 成都硅宝科技股份有限公司 | Single-component silicone fluid sealant for solar energy cell assembly and manufacturing method thereof |
| CN101735744A (en) * | 2008-11-24 | 2010-06-16 | 李彪 | EVA hot melt adhesive sheet for solar battery |
| CN101870854A (en) * | 2009-04-27 | 2010-10-27 | 诸暨市枫华光伏材料有限公司 | Fast cure EVA solar cell adhesive film |
| CN101626039A (en) * | 2009-07-27 | 2010-01-13 | 江阴爱康太阳能器材有限公司 | Solar cell packaging EVA adhesive film capable of resisting heat, humidity, ultraviolet light and aging |
| CN101935504A (en) * | 2010-09-02 | 2011-01-05 | 上海天洋热熔胶有限公司 | A kind of high-efficiency anti-ultraviolet solar cell encapsulation EVA adhesive film and preparation method thereof |
| CN102134450A (en) * | 2010-12-14 | 2011-07-27 | 上海天洋热熔胶有限公司 | High-adhesive-strength ethylene vinyl acetate adhesive film for packaging solar cells and preparation method thereof |
| CN102115642A (en) * | 2010-12-31 | 2011-07-06 | 广州鹿山新材料股份有限公司 | EVA (ethylene vinyl-acetate copolymer) adhesive film capable of simplifying packaging structure of solar battery |
| CN102115643A (en) * | 2010-12-31 | 2011-07-06 | 广州鹿山新材料股份有限公司 | Novel solar cell packaging adhesive film |
| CN102153958A (en) * | 2011-01-11 | 2011-08-17 | 广州市宝力达电气材料有限公司 | EVA (ethylene-vinyl acetate) adhesive film for heat-resistant solar battery, and preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| (印)鲍米克(BHOWMICK, A.K.)、(美)斯蒂芬思(STEPHENS, H.L.): "《弹性体手册（第二版）》", 31 January 2005, 中国石化出版社 * |
| 李广宇等: "《胶黏剂原材料手册》", 31 August 2004, 国防工业出版社 * |
| 王玉忠: "《高分子科学导论》", 31 December 2010, 科学出版社 * |
Cited By (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205210B (en) * | 2013-03-19 | 2015-04-01 | 江苏鹿山光伏科技有限公司 | High-temperature-resistant hot melt adhesive membrane for aluminum honeycomb boards, and preparation method thereof |
| CN103205210A (en) * | 2013-03-19 | 2013-07-17 | 江苏鹿山光伏科技有限公司 | High-temperature-resistant hot melt adhesive membrane for aluminum honeycomb boards, and preparation method thereof |
| CN103173180A (en) * | 2013-03-23 | 2013-06-26 | 广东新展化工新材料有限公司 | Thermoplastic adhesive and preparation method thereof |
| CN103173180B (en) * | 2013-03-23 | 2015-06-24 | 广东新展化工新材料有限公司 | Thermoplastic adhesive and preparation method thereof |
| CN103554823A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Heat-resistant and corrosion-resistant insulating material for wire harnesses of refrigerator |
| CN103669161A (en) * | 2013-12-30 | 2014-03-26 | 上海浦东路桥建设股份有限公司 | Telescopic strip for inhibiting pedestrian crossing crack generation as well as application method and purpose of telescopic strip |
| CN103669161B (en) * | 2013-12-30 | 2018-01-02 | 上海浦东路桥建设股份有限公司 | One kind suppresses expansion strip and its application process and purposes caused by crossing crackle |
| US10598408B2 (en) | 2014-02-17 | 2020-03-24 | Savo-Solar Oy | Solar thermal absorber element |
| CN104848571A (en) * | 2014-02-17 | 2015-08-19 | 萨沃-太阳能有限公司 | Solar thermal absorber element |
| CN103821445A (en) * | 2014-03-05 | 2014-05-28 | 天津中财型材有限责任公司 | Sealing rubber strip and preparation method thereof |
| CN104072859A (en) * | 2014-07-16 | 2014-10-01 | 苏州新区华士达工程塑胶有限公司 | Improved POE |
| CN104194283A (en) * | 2014-09-02 | 2014-12-10 | 安特普工程塑料（苏州）有限公司 | High-performance thermoplastic elastomer and processing method thereof |
| CN104387676A (en) * | 2014-10-29 | 2015-03-04 | 苏州新区枫盛塑料制品厂 | Thermoplastic elastomer formula |
| CN104387749A (en) * | 2014-11-06 | 2015-03-04 | 苏州佰格斯电子科技有限公司 | High-strength foamed polyurethane sealing strip |
| CN104387748A (en) * | 2014-11-06 | 2015-03-04 | 苏州佰格斯电子科技有限公司 | High-quality polyurethane sealing strip |
| CN104356633A (en) * | 2014-11-06 | 2015-02-18 | 苏州佰格斯电子科技有限公司 | High-performance polyurethane sealant |
| CN104356631A (en) * | 2014-11-06 | 2015-02-18 | 苏州佰格斯电子科技有限公司 | Durable polyurethane sealant |
| CN104327488A (en) * | 2014-11-06 | 2015-02-04 | 苏州佰格斯电子科技有限公司 | Acid and alkali-resistant polyurethane sealing strip |
| CN105367735A (en) * | 2015-11-23 | 2016-03-02 | 苏州盖德精细材料有限公司 | Polyurethane adhesive used for shoes and preparation method thereof |
| CN105694334A (en) * | 2016-03-08 | 2016-06-22 | 安徽韧达高分子材料有限公司 | TPE (thermal plastic elastomer) material for coating nylon and preparation method of TPE material |
| CN106281064B (en) * | 2016-08-22 | 2018-05-25 | 南京万源千纳纳米科技有限公司 | A kind of novel environment friendly solar-energy photo-voltaic cell encapsulating material |
| CN106281064A (en) * | 2016-08-22 | 2017-01-04 | 广西南宁荣威德新能源科技有限公司 | A kind of novel environment friendly solar-energy photo-voltaic cell encapsulating material |
| CN106520006A (en) * | 2016-11-26 | 2017-03-22 | 马益元 | Small-size surface protective film for mobile phone lens |
| CN106520006B (en) * | 2016-11-26 | 2019-03-26 | 广州德鑫电子科技有限公司 | A kind of mobile lens small size surface protection film |
| CN107987780A (en) * | 2017-12-12 | 2018-05-04 | 东莞市雄林新材料科技股份有限公司 | A kind of environment-friendly type organosilicon modified TPU hot melt adhesive and preparation method thereof |
| CN108285577A (en) * | 2018-01-31 | 2018-07-17 | 河北贵航鸿图汽车零部件有限公司 | A kind of TPEE modified thermoplastic elastomers weather strip for automobile |
| CN108517079A (en) * | 2018-04-20 | 2018-09-11 | 裴文韬 | A kind of preparation method of water-proof sealing rubber strip |
| CN110854225A (en) * | 2018-07-25 | 2020-02-28 | 比亚迪股份有限公司 | A double glass photovoltaic module |
| CN109651642A (en) * | 2018-10-24 | 2019-04-19 | 诺博橡胶制品有限公司 | Sealing sponge sizing material and preparation method thereof and sealing strip and preparation method and automobile |
| CN109651642B (en) * | 2018-10-24 | 2021-12-24 | 诺博橡胶制品有限公司 | Sealing strip, preparation method thereof and automobile |
| US11746226B2 (en) | 2018-12-06 | 2023-09-05 | Tsrc Corporation | Polymer composition, foam and method thereof |
| TWI750548B (en) * | 2018-12-06 | 2021-12-21 | 台橡股份有限公司 | Polymer composition, foam and method thereof |
| CN109897331A (en) * | 2019-02-28 | 2019-06-18 | 金发科技股份有限公司 | A kind of highly polar Flameproof styrenic class composition, preparation method and applications |
| WO2020173490A1 (en) * | 2019-02-28 | 2020-09-03 | 金发科技股份有限公司 | High-polarity flame-retardant styrene composition, preparation method for same, and applications thereof |
| CN110003825A (en) * | 2019-04-10 | 2019-07-12 | 广东绿洲化工有限公司 | A kind of silane coupler modified SBS adhesive of aluminium bonding and preparation method thereof |
| CN110655874A (en) * | 2019-08-29 | 2020-01-07 | 苏州德圣辉新能源科技有限公司 | A kind of glue for solar cell back sheet film composite and preparation method thereof |
| CN112226177A (en) * | 2020-09-18 | 2021-01-15 | 苏州赛伍应用技术股份有限公司 | Welding strip carrier film, welding strip composite body and battery piece composite body |
| CN112226169A (en) * | 2020-09-25 | 2021-01-15 | 苏州赛伍应用技术股份有限公司 | A welding tape carrier film, its preparation method, welding tape composite body, and battery sheet composite body |
| CN112852311A (en) * | 2021-01-15 | 2021-05-28 | 江苏鹿山新材料有限公司 | Photovoltaic packaging adhesive film, preparation method thereof and photovoltaic module |
| CN112852311B (en) * | 2021-01-15 | 2022-10-18 | 江苏鹿山新材料有限公司 | Photovoltaic encapsulation film and preparation method thereof, and photovoltaic module |
| CN114634778A (en) * | 2021-11-03 | 2022-06-17 | 张家港康得新光电材料有限公司 | Adhesive resin composition and self-adhesive protective film |
| CN114634778B (en) * | 2021-11-03 | 2023-09-22 | 张家港康得新光电材料有限公司 | Adhesive resin composition and self-adhesive protective film |
| CN114539965A (en) * | 2022-03-03 | 2022-05-27 | 东莞市华盛新材料有限公司 | Hot-melt adhesive capable of hot-pressing and water-splashing-preventing treatment and made of nylon material and preparation process of hot-melt adhesive |
| CN115895534A (en) * | 2022-03-11 | 2023-04-04 | 上海启梦胶粘制品有限公司 | A kind of removable glue and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102775944A (en) | Sealing joint strip and application method thereof | |
| US8597447B2 (en) | Adhesive tape, particularly for bonding photovoltaic modules | |
| EP2638111B1 (en) | Fluid applied silicone air&water barrier system and process thereof | |
| JP4924780B2 (en) | Easy adhesive for solar cell back surface protective sheet, solar cell back surface protective sheet, and solar cell module | |
| US20100000604A1 (en) | Framed device, seal, and method for manufacturing same | |
| JP4690329B2 (en) | Reactive hot melt resin composition and reactive hot melt adhesive | |
| US20080039576A1 (en) | Vulcanizate composition | |
| JPH0955530A (en) | Solar cell module and manufacturing method thereof | |
| CN102051149A (en) | Preparation methods of hot melt pressure-sensitive adhesive and protective film as well as hot melt pressure-sensitive adhesive | |
| WO2009017552A1 (en) | Encapsulant materials and associated devices | |
| JP6157502B2 (en) | High performance hot melt window sealant | |
| CN101292007A (en) | Pressure-sensitive adhesive composition | |
| US9404004B2 (en) | High performance hotmelt window sealant | |
| CN102676092A (en) | Adhesive, adhesive sheet and electronic device | |
| CN106753059A (en) | A kind of pair of glass photovoltaic module hot melt butyl sealant and preparation method | |
| US20140329074A1 (en) | Reactive polyolefin hot-melt adhesive having low viscosity and use thereof for textile laminations | |
| US20080038549A1 (en) | Composite structure | |
| WO2011109605A1 (en) | Thermally resistant reactive silane functional poly-alpha-olefin hot melt adhesive composition, methods of using the same, and solar panel assembly including the same | |
| JP2010166032A (en) | Reactive hot-melt sealing composition for solar cell | |
| CN117025112A (en) | Protective film applied to solar photovoltaic panel and preparation process thereof | |
| CA3116911A1 (en) | Moisture curable hot melt sealant composition including silane functional polyurethane | |
| JP5729292B2 (en) | Easy adhesive for solar cell back surface protective sheet, solar cell back surface protective sheet, and solar cell module | |
| CN113528046A (en) | High-adhesion high-weather-resistance coating type solar cell backboard and preparation method thereof | |
| CN113956826B (en) | Bonding composition, protective film and application thereof | |
| JP6069988B2 (en) | Resin composition and liquid crystal display panel sealant containing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121114 |