CN102771516A - Disinfectant for pond water body - Google Patents
Disinfectant for pond water body Download PDFInfo
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- CN102771516A CN102771516A CN2012102894921A CN201210289492A CN102771516A CN 102771516 A CN102771516 A CN 102771516A CN 2012102894921 A CN2012102894921 A CN 2012102894921A CN 201210289492 A CN201210289492 A CN 201210289492A CN 102771516 A CN102771516 A CN 102771516A
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- disinfectant
- bodied ferric
- potassium
- water
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- 239000000645 desinfectant Substances 0.000 title claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 36
- 239000004411 aluminium Substances 0.000 claims abstract description 34
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 34
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 34
- UMPKMCDVBZFQOK-UHFFFAOYSA-N potassium;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[K+].[Fe+3] UMPKMCDVBZFQOK-UHFFFAOYSA-N 0.000 claims abstract description 22
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910001603 clinoptilolite Inorganic materials 0.000 claims abstract description 16
- 239000003643 water by type Substances 0.000 claims description 26
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 19
- 229910052700 potassium Inorganic materials 0.000 claims description 19
- 239000011591 potassium Substances 0.000 claims description 19
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 19
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 14
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 14
- 230000000694 effects Effects 0.000 abstract description 18
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 8
- 241000894006 Bacteria Species 0.000 abstract description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 4
- 241000195493 Cryptophyta Species 0.000 abstract description 4
- 241000700605 Viruses Species 0.000 abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 abstract description 4
- 239000000460 chlorine Substances 0.000 abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 150000002500 ions Chemical class 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000015271 coagulation Effects 0.000 abstract description 2
- 238000005345 coagulation Methods 0.000 abstract description 2
- 238000011161 development Methods 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 238000004042 decolorization Methods 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 239000000047 product Substances 0.000 description 9
- 241000251468 Actinopterygii Species 0.000 description 5
- 241000238557 Decapoda Species 0.000 description 5
- 230000009102 absorption Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000009360 aquaculture Methods 0.000 description 5
- 244000144974 aquaculture Species 0.000 description 5
- 238000005189 flocculation Methods 0.000 description 5
- 230000016615 flocculation Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 5
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 3
- -1 chip Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000252230 Ctenopharyngodon idella Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 230000003612 virological effect Effects 0.000 description 2
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 description 1
- 208000032843 Hemorrhage Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FSNCEEGOMTYXKY-JTQLQIEISA-N Lycoperodine 1 Natural products N1C2=CC=CC=C2C2=C1CN[C@H](C(=O)O)C2 FSNCEEGOMTYXKY-JTQLQIEISA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 241000927735 Penaeus Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 241001482311 Trionychidae Species 0.000 description 1
- 208000037386 Typhoid Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- SYKNUAWMBRIEKB-UHFFFAOYSA-N [Cl].[Br] Chemical compound [Cl].[Br] SYKNUAWMBRIEKB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000002509 fulvic acid Substances 0.000 description 1
- 229940095100 fulvic acid Drugs 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229960002415 trichloroethylene Drugs 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 201000008297 typhoid fever Diseases 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention relates to a disinfectant for a pond water body, comprising the following components in parts by weight: 10-100 parts of potassium ferrate, 100-300 parts of polymeric aluminium, 200-500 parts of polymeric ferric sulphate and 100-700 parts of clinoptilolite. Ferrate used in the invention is taken as a non-chlorine water treatment agent, bacteria, viruses and algaes in water can be rapidly killed, organic matters, inorganic matters and heavy metal ions in the water also can be removed, and the effects of disinfection, decolourization, deodorization and coagulation assistant can be realized. The disinfectant for the pond water body disclosed by the invention has reasonable components and low cost, is simple to prepare and is convenient to use, development and application curative effects are assured, toxic and side effects are small, and application range is wide.
Description
Technical field
The present invention relates to field of aquaculture industry, particularly relate to a kind of pond waters disinfectant.
Background technology
The continuous enhancing of Along with people's health care consciousness, the aquatic product quality quality is directly connected to people's health problem, thereby the aquatic products disinfectant has also been proposed requirements at the higher level.Since nineteen eighty; Selecting for use of water body disinfection from generally using bleaching powder to carry out the transition to DCCNa and TCCA sodium, bromine preparation, Operand gradually originally; Or be the composite disinfectant of main component with this type of raw material, these disinfectants can produce harm in various degree to water body environment in the process of using.
Some organochlorine compound is highly stable in environment, like Polychlorinated biphenyls (PCD), DDT and hexachlorcyclohexane etc., stops certainly producing so far, in water body, bed mud and organism, still can detect higher residue; Some is chloride, the disinfectant of bromine can produce organic carcinogens such as chloroform, bromofom in use; Produce a large amount of haloform (THMs) simultaneously; It not only influences water quality, and aquatic livestock is had strong impulse and carcinogenesis, and directly the physical and mental health to the people constitutes a threat to.Use if these disinfectants are long-term, can cause antibody-resistant bacterium and virus variation to strengthen, make people be difficult to control more culture diseases.
Therefore, providing that a kind of reasonable recipe, preparation are simple, efficient, low toxicity, green be applied to pond waters disinfectant and preparation method thereof, is one of this field scientific research technical staff major issue of being badly in need of solving.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, a kind of pond waters disinfectant is provided.
To achieve these goals, technical scheme of the present invention is:
A kind of pond waters disinfectant; Form by potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite, by its parts by weight: 10～100 parts of potassium ferrates, 100～300 parts of aluminium polychlorides, 200～500 parts of bodied ferric sulfates, 100～700 parts of clinoptilolites.
Preferably, above-mentioned pond waters disinfectant is by its parts by weight: 50～100 parts of potassium ferrates, 100～200 parts of aluminium polychlorides, 200～250 parts of bodied ferric sulfates, 300～700 parts of clinoptilolites
Preferably, above-mentioned pond waters disinfectant is by its parts by weight: 100 parts of potassium ferrates, 100 parts of aluminium polychlorides, 200 parts of bodied ferric sulfates, 700 parts of clinoptilolites.
Preferably, above-mentioned pond waters disinfectant is by its parts by weight: 50 parts of potassium ferrates, 200 parts of aluminium polychlorides, 250 parts of bodied ferric sulfates, 500 parts of clinoptilolites.
Preferably, above-mentioned pond waters disinfectant is by its parts by weight: 50 parts of potassium ferrates, 200 parts of aluminium polychlorides, 300 parts of bodied ferric sulfates, 450 parts of clinoptilolites.
Preferably, above-mentioned pond waters disinfectant is by its parts by weight: 100 parts of potassium ferrates, 100 parts of aluminium polychlorides, 500 parts of bodied ferric sulfates, 300 parts of clinoptilolites.
Preferably, above-mentioned pond waters disinfectant is by its parts by weight: 10 parts of potassium ferrates, 300 parts of aluminium polychlorides, 400 parts of bodied ferric sulfates, 100 parts of clinoptilolites.
During preparation, above-mentioned each component mixed according to ratio range get final product.
During use, be used for the consumption in 3～5 mu in the pond of 1 meter of the depth of water according to every 1kg product of the present invention, with product of the present invention with the ratio dissolving and dilution of pond water with 1:2000 after, full pool spilling head.
Beneficial effect of the present invention is:
(1) performance synergy between each composition of product of the present invention, kill virus and bacterium wider, and also disinfection force is not influenced by water hardness, acid-base value.This product property is stable in addition, and prolong effective time greatly.After the use, to the natural bait of fish, shrimp, crab in the water body---propagation and the growth of phytoplankton do not have influence yet, not the more important thing is and can develop immunity to drugs, can be not residual in animal body yet, belong to the safe green disinfectant products.
(2) ferrate is as the water treatment agent of non-chlorine type; Can not only kill bacterium, virus and algae in the water fast; But also can remove organic matter, inorganic matter and the heavy metal ion in the water; Playing sterilization, decolouring, deodorizing, help the effect of coagulating, is a kind of novel, multifunctional water disinfectant efficiently.
(3) reasonable recipe of the present invention, preparation is simple, and with low cost, easy to use, the Application and Development curative effect is certain, and toxic and side effect is little, and applied range.In shrimp aquaculture, use, the shrimp survival rate significantly improves, and becomes the shrimp aquaculture specification to strengthen; Use at aspects such as grass carp toxicity hemorrhage, the mad trip disease of eel, soft-shelled turtle viral disease and grass carp nurture of fish fingerlings, its protective rate is apparently higher than chlorinated products such as bromine chlorine.Obvious application effect has vast market prospect.
Embodiment
Below in conjunction with specific embodiment, the present invention is carried out detailed description.
Embodiment 1
A kind of pond waters disinfectant makes after being mixed by potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite, by its parts by weight: 100 parts of potassium ferrates, 100 parts of aluminium polychlorides, 200 parts of bodied ferric sulfates, 700 parts of clinoptilolites.
Embodiment 2
A kind of pond waters disinfectant makes after being mixed by potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite, by its parts by weight: 50 parts of potassium ferrates, 200 parts of aluminium polychlorides, 250 parts of bodied ferric sulfates, 500 parts of clinoptilolites.
Embodiment 3
A kind of pond waters disinfectant makes after being mixed by potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite, by its parts by weight: 50 parts of potassium ferrates, 200 parts of aluminium polychlorides, 300 parts of bodied ferric sulfates, 450 parts of clinoptilolites.
Embodiment 4
A kind of pond waters disinfectant makes after being mixed by potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite, by its parts by weight: 100 parts of potassium ferrates, 100 parts of aluminium polychlorides, 500 parts of bodied ferric sulfates, 300 parts of clinoptilolites.
Embodiment 5
A kind of pond waters disinfectant makes after being mixed by potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite, by its parts by weight: 10 parts of potassium ferrates, 300 parts of aluminium polychlorides, 400 parts of bodied ferric sulfates, 100 parts of clinoptilolites.
Each component characteristic that the present invention adopts is following:
Potassium ferrate (K
2FeO
4) be to contain FeO
4 2-A kind of compound, its central atom Fe exists with sexavalence, therefore; No matter at acid condition, or ferrate all has extremely strong oxidisability under the alkali condition, is a kind of oxidant also stronger than the oxidability of potassium permanganate, ozone and chlorine; Applicable pH value scope is wide; Have disinfective action efficiently, can remove organic and inorganic pollution, especially hardly degraded organic substance is had special efficacy.For example: potassium ferrate has good removal effect for the BOD in the water body, COD, lead, cadmium, sulphur etc.; The BOD of the potassium ferrate oxidation 96% of 10mg-20mg/L, the ammonia nitrogen of removal 86% and 75% phosphorus, PH was at 5.5 o'clock; Raw water turbidity is under 28 degree (heavy back the is surplus turbid) condition; The potassium ferrate of 30mg/L can remove 85.6% with trichloro-ethylene in the water, and the clearance of naphthalene reaches 100%; PH was at 6～6.5 o'clock, and every premium on currency adds potassium ferrate 6mg～10mg, and it is more than 99.5%～99.95% that normal temperature can be killed pathogenic bacteria in the water body, Escherichia coli, typhoid bacillus and viral clearance in following 30 minutes.
Potassium ferrate mainly is the effect of in the water treatment of fish pond aquaculture class, playing sterilization, sterilization, purification in the present invention; Increase the dissolved oxygen amount of water body; Ammonia nitrogen, nitrite, algae class in the water body are had good removal effect, be used for removing water fulvic acid, suspension; The effect unique of potassium ferrate in water body purification is to bring into play the synergy of oxidation, absorption, flocculation, deposition, sterilization, sterilization, decolouring, deodorizing simultaneously, do not produce any poisonous, harmful material.In addition, potassium ferrate in water with the process of pollutant effect in, through series reaction, and progressively be reduced into Fe (III) with absorption preferably and effect of flocculant, pond waters is had good flocculation.
Aluminium polychloride is an inorganic macromolecule compound, is between AlCI
3And Al (OH)
3Between product, through the polymerization of hydroxyl bridge formation, have quantity in the molecule and do not wait hydroxyl, its chemical general formula is [AI
2(OH) NCI
6-N]
MThat color is is yellow or faint yellow, dark brown, Dark grey resin-like solid.Alumina content is more than 29% in the solid product, and basicity 65～85% mainly is applicable to the purification of industry or domestic water.Mainly be to be used for materials such as absorption, flocculation organic matter, chip, impurity in the present invention.
The bodied ferric sulfate molecular formula is [Fe2 (OH) n (SO4) 3-n/2] m): coagulation performance is good, and flocculation rate is fast, and the alumization of formation is closely knit, and floc settlement speed is fast; Purifying water effect is good, and effluent quality is good, does not contain Al
3+, harmful substances such as chlorine and heavy metal, the water that does not also have iron ion shifts, and is nontoxic, safe and reliable; To little pollution, contain algae and the former water purification obvious processing effect of low-temperature and low turbidity, high turbidity purificating raw water is had better effect; Dosage is few, and is easy to use.Mainly be to be used for materials such as absorption, flocculation organic matter, chip, impurity in the present invention.
Using natural clinoptilolite is the aluminium silicate mineral of a kind of alkali metal containing or alkaline earth metal, and what be used for aquaculture mainly is the clinoptilolite powder, and it is big to have specific surface area, and absorption property is good, and ion-exchange capacity is strong, characteristics such as stable chemical performance.It can remove the ammonia nitrogen in all kinds of water effectively, and clearance can reach more than 90%.Its effective fluorine and phosphorus in the adsorbed water simultaneously; And heavy metal ion such as cadmium, arsenic, chromium, zinc, lead, mercury, copper; Remove the turbidity, colourity of low water etc., handling life of urban resident sewage, industrial sewage, improving and have bigger effect in the environment for human survival.
Effect is given an example:
The Ninghe, Tianjin mainly cultivates fresh water fishes and Penaeus Vannmei, and two fishes and shrimps are raised together with the pond and carried out the medication contrast, and pond waters disinfectant of the present invention was regularly used through per 7 days in the medication pond, and incidence of disease comparison is low by 10% according to the pond, and feed coefficient has reduced by 5～8%.
Above-mentioned detailed description of this pond waters disinfectant being carried out with reference to embodiment; Be illustrative rather than determinate; Can enumerate out several embodiment according to institute's limited range,, should belong within protection scope of the present invention therefore in the variation and the modification that do not break away under the general plotting of the present invention.
Claims (7)
1. pond waters disinfectant; It is characterized in that it is made up of potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite; By its parts by weight: 10～100 parts of potassium ferrates; 100～300 parts of aluminium polychlorides, 200～500 parts of bodied ferric sulfates, 100～700 parts of clinoptilolites.
2. a kind of pond waters disinfectant according to claim 1 is characterized in that the parts by weight of said potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite are respectively: 50～100 parts of potassium ferrates, 100～200 parts of aluminium polychlorides, 200～250 parts of bodied ferric sulfates, 300～700 parts of clinoptilolites.
3. a kind of pond waters disinfectant according to claim 1 is characterized in that the parts by weight of said potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite are respectively: 100 parts of potassium ferrates, 100 parts of aluminium polychlorides, 200 parts of bodied ferric sulfates, 700 parts of clinoptilolites.
4. a kind of pond waters disinfectant according to claim 1 is characterized in that the parts by weight of said potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite are respectively: 50 parts of potassium ferrates, 200 parts of aluminium polychlorides, 250 parts of bodied ferric sulfates, 500 parts of clinoptilolites.
5. a kind of pond waters disinfectant according to claim 1 is characterized in that the parts by weight of said potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite are respectively: 50 parts of potassium ferrates, 200 parts of aluminium polychlorides, 300 parts of bodied ferric sulfates, 450 parts of clinoptilolites.
6. a kind of pond waters disinfectant according to claim 1 is characterized in that the parts by weight of said potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite are respectively: 100 parts of potassium ferrates, 100 parts of aluminium polychlorides, 500 parts of bodied ferric sulfates, 300 parts of clinoptilolites.
7. a kind of pond waters disinfectant according to claim 1 is characterized in that the parts by weight of said potassium ferrate, aluminium polychloride, bodied ferric sulfate and clinoptilolite are respectively: 10 parts of potassium ferrates, 300 parts of aluminium polychlorides, 400 parts of bodied ferric sulfates, 100 parts of clinoptilolites.
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| CN108184904A (en) * | 2017-12-29 | 2018-06-22 | 兰溪市哥特生物技术有限公司 | Culture of ornamental fish water body improves the preparation method of liquid |
| CN108479350A (en) * | 2018-05-02 | 2018-09-04 | 安徽浩悦环境科技有限责任公司 | A kind of deodorant and its application method of the disposition waste peculiar smell of organic amine containing pesticide |
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Application publication date: 20121114 |