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CN102764592B - Polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller - Google Patents

Polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller Download PDF

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Publication number
CN102764592B
CN102764592B CN201210281768.1A CN201210281768A CN102764592B CN 102764592 B CN102764592 B CN 102764592B CN 201210281768 A CN201210281768 A CN 201210281768A CN 102764592 B CN102764592 B CN 102764592B
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CN
China
Prior art keywords
ptfe
filter element
combination filter
polytetrafluoroethylene
cartridge type
Prior art date
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Expired - Fee Related
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CN201210281768.1A
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Chinese (zh)
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CN102764592A (en
Inventor
曹凤中
赵章元
杨云奇
章大明
王玉振
陈礼辉
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Zhengren Environmental Protection Technology Co Ltd
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Zhengren Environmental Protection Technology Co Ltd
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Priority to CN201210281768.1A priority Critical patent/CN102764592B/en
Publication of CN102764592A publication Critical patent/CN102764592A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Separation Using Semi-Permeable Membranes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention provides a kind of polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller, it comprises: CPVC film cylinder and Combination filter element, Combination filter element is positioned at CPVC film cylinder and CPVC film cylinder is passed at the central suction pipe two ends of Combination filter element, the PTFE hydrophobic membrane of many groups of high aperture rates and PET weave plain net and to be composited circular dull and stereotyped vacuum diaphragm assembly, the dull and stereotyped vacuum diaphragm assembly of each circle is connected into Combination filter element by a central suction pipe, CPVC film cylinder lower end is provided with inlet, upper end is provided with liquid outlet, processed liquid material enters from inlet, by circle dull and stereotyped vacuum diaphragm inter-module, Combination filter element is flooded completely, processed liquid material is discharged from liquid outlet, formation circulates, aperture on central suction pipe is the steam sucking-off of PET braiding plain net, subsequent condensation becomes product water.Polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the present invention, manufacture craft is simple, is conducive to large-scale production.

Description

Polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller
Technical field
The present invention relates to technical field of water treatment equipment, particularly a kind of polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller.
Background technology
Membrane Materials is a kind of employing dewatering microporous film, the membrane separating process being mass transfer driving force with film both sides steam pressure difference.Under the driving of the steam pressure difference of microporous hydrophobic membrane both sides, water vapour is condensed into liquid separation process again after being passed hydrophobic membrane by the Yuan Shui side of heating.Due to the hydrophobicity of film, only have water vapour can through fenestra, former water and the Nonvolatile solute be dissolved in wherein cannot pass fenestra, so Membrane Materials procedural theory can realize 100% remove to ion, large molecule, colloid, cell and other non-volatile matter.Microporous hydrophobic membrane plays the support shielding action between two-phase in Membrane Materials process.In the process of Membrane Materials, heat and mass transfer two kinds of processes occur, temperature difference polarization also can produce with temperature difference polarization phenomena simultaneously simultaneously, thus produces adverse influence to the process of Membrane Materials.The operating temperature of Membrane Materials process is lower than traditional still-process, and operating pressure is lower than traditional membrane separating process; Lower to the mechanical property requirements of film; Compared with traditional still-process, the vapor space significantly reduces.The assembly of Membrane Materials can be designed to recovery of latent heat form, and has the flexibility being formed large-scale production system with efficient small-sized membrane module.This process can the high fortified aqueous of concentration for the treatment of, if solute is the material of easy crystallization, solution can be concentrated to hypersaturated state and realize Membrane Materials crystallization, it is the membrane process uniquely directly isolating crystallized product at present from solution, as long as and film both sides maintain the suitable temperature difference, this process just can be carried out, and can utilize the cheap energy such as solar energy, underground heat, hot spring, waste heat of plant and warm industrial wastewater.It is low that film distillation technology has operating pressure, have the salt rejection rate that can obtain 99. 99 % and under excellent operation condition higher than the water flux of counter-infiltration, show it and substitute (extensive pure water preparation) or supplementary technology as reverse osmosis technology.
Current Membrane Materials device mainly contains board-like dull and stereotyped Membrane Materials device, cartridge type film silk group distiller, submerged film silk group distiller.And board-like dull and stereotyped Membrane Materials device needs shaper, the large Heavy Weight of volume, structure is stacked inconvenience repair and replacement, be difficult to meet industrialization use, cartridge type film silk group distiller is very high to hydrophobic membrane silk throughput requirements used, can only accomplish now that the aperture rate flux of 50% is too little and film silk makes not easily volume production, there is such problem in submerged film silk group distiller too.
Summary of the invention
The present invention proposes a kind of polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller, and manufacture craft is simple, is conducive to large-scale production.The technical solution adopted in the present invention is specifically achieved in that
The invention provides a kind of polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller, it comprises: CPVC film cylinder (1) and Combination filter element (6), described Combination filter element (6) is positioned at described CPVC film cylinder (1) and described CPVC film cylinder (1) is passed at central suction pipe (8) two ends of described Combination filter element (6), the PTFE hydrophobic membrane (3) of many groups of high aperture rates and PET fibrage plain net (4) are composited circular dull and stereotyped vacuum diaphragm assembly, each described circle dull and stereotyped vacuum diaphragm assembly is connected into described Combination filter element (6) by a described central suction pipe (8), described CPVC film cylinder (1) lower end is provided with inlet (2), upper end is provided with liquid outlet (7), processed liquid material enters from described inlet (2), by circle dull and stereotyped vacuum diaphragm inter-module (5), described Combination filter element (6) is flooded completely, processed liquid material is discharged from described liquid outlet (7), formation circulates, aperture (9) on described central suction pipe (8) is the steam sucking-off of described PET fibrage plain net (4), subsequent condensation becomes product water.
Preferably, described circle dull and stereotyped vacuum diaphragm assembly adopts described PET fibrage plain net (4) as support substrate, at the upper application of adhesive of described PET fibrage plain net (4), described PTFE hydrophobic membrane (3) is compounded in described PET braiding plain net (4) and dries.
Preferably, the temperature of described oven dry is 90-130 DEG C, and the time is 15s.
Preferably, described adhesive comprise mass fraction be 75% terpolymer first and mass fraction be 25% terpolymer second.
Preferably, described terpolymer first is the thermoplasticity terpolymer of difluoroethylene, tetrafluoroethene and hexafluoropropene.
Preferably, described terpolymer second is the cruel terpolymer of glycidyl methyacrylate, ethene and acrylic acid.
Preferably, described PET fibrage plain net (4) mesh wire diameter is 0.5mm.
Preferably, the aperture of described PTFE hydrophobic membrane is O. 2 μm, and porosity is 90%, and thickness is O. 2 mm.
Polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the present invention, develop the advantage that board-like dull and stereotyped Membrane Materials device flux is large and cartridge type film silk group distiller volume is little, improve the flaw of submerged film silk group Membrane Materials mode part simultaneously, achieve volume primary flux large, manufacture craft is simple, be conducive to large-scale production, use for industrialization and started new opening a little.
Accompanying drawing explanation
Fig. 1 is the structural representation of the polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the embodiment of the present invention;
Fig. 2 is the side view of the polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the embodiment of the present invention.
Detailed description of the invention
For enabling above-mentioned purpose of the present invention, feature and advantage become apparent more, are described in detail the specific embodiment of the present invention below in conjunction with accompanying drawing, make above-mentioned and other object of the present invention, Characteristics and advantages will be more clear.Reference numeral identical in whole accompanying drawing indicates identical part.Deliberately do not draw accompanying drawing in proportion, focus on purport of the present invention is shown.
Below in conjunction with accompanying drawing, polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller specific embodiment of the present invention is described in detail.
Fig. 1 is the overall structure schematic diagram of the polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the embodiment of the present invention, Fig. 2 is the side view of the polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the embodiment of the present invention, as depicted in figs. 1 and 2, the polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the embodiment of the present invention, it comprises: CPVC(Chlorinated poly vinyl chloride, chliorinated polyvinyl chloride) film cylinder 1 and Combination filter element 6, wherein Combination filter element 6 can have many groups as required, CPVC film cylinder 1 also can make all size as required, Combination filter element 6 is positioned at CPVC film cylinder 1 and CPVC film cylinder 1 is passed at central suction pipe 8 two ends of Combination filter element 6, the PTFE(Poly tetra fluoro ethylene ptfe of many groups of high aperture rates, polytetrafluoroethylene (PTFE)) hydrophobic membrane 3 and PET (polyethylene terephthalate, PETG) fibrage plain net 4 is composited circular dull and stereotyped vacuum diaphragm assembly, the dull and stereotyped vacuum diaphragm assembly of each circle is connected into Combination filter element 6 by a central suction pipe 8, CPVC film cylinder 1 lower end is provided with inlet 2, upper end is provided with liquid outlet 7, processed liquid material enters from inlet 2, by circle dull and stereotyped vacuum diaphragm inter-module 5, Combination filter element 6 is flooded completely, processed liquid material is discharged from liquid outlet 7, formation circulates, aperture 9 on central suction pipe 8 is the steam sucking-off of PET fibrage plain net 4, subsequent condensation becomes product water.
In the present invention, circular dull and stereotyped vacuum diaphragm assembly adopts PET fibrage plain net 4 as support substrate, application of adhesive on PET fibrage plain net 4, PTFE hydrophobic membrane 3 is compounded on PET braiding plain net 4 and dries, the temperature of drying is 90-130 DEG C, time is 15s, simultaneously, adhesive comprise mass fraction be 75% terpolymer first and mass fraction be 25% terpolymer second, terpolymer first is difluoroethylene, the thermoplasticity terpolymer of tetrafluoroethene and hexafluoropropene, terpolymer second is glycidyl methyacrylate, ethene and the cruel terpolymer of acrylic acid, this adhesive is the one of the embodiment of the present invention, but be not limited to this kind of adhesive, the present invention also can use other adhesives.
The polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the embodiment of the present invention, PET fibrage plain net (4) mesh wire diameter is the aperture of 0.5mm, PTFE hydrophobic membrane is O. 2 μm, and porosity is 90%, and thickness is O. 2 mm.
Polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller of the present invention, develop the advantage that board-like dull and stereotyped Membrane Materials device flux is large and cartridge type film silk group distiller volume is little, improve the flaw of submerged film silk group Membrane Materials mode part simultaneously, achieve volume primary flux large, manufacture craft is simple, be conducive to large-scale production, use for industrialization and started new opening a little.
Set forth a lot of detail in the above description so that fully understand the present invention.But above description is only preferred embodiment of the present invention, the present invention can be much different from alternate manner described here to implement, and therefore the present invention is not by the disclosed concrete restriction implemented above.Any those skilled in the art are not departing under technical solution of the present invention ambit simultaneously, the Method and Technology content of above-mentioned announcement all can be utilized to make many possible variations and modification to technical solution of the present invention, or be revised as the Equivalent embodiments of equivalent variations.Every content not departing from technical solution of the present invention, according to technical spirit of the present invention to any simple modification made for any of the above embodiments, equivalent variations and modification, all still belongs in the scope of technical solution of the present invention protection.

Claims (4)

1. a polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller, it is characterized in that, it comprises: CPVC film cylinder (1) and Combination filter element (6), described Combination filter element (6) is positioned at described CPVC film cylinder (1) and described CPVC film cylinder (1) is passed at central suction pipe (8) two ends of described Combination filter element (6), described Combination filter element is many groups, the PTFE hydrophobic membrane (3) of many groups of high aperture rates and PET fibrage plain net (4) are composited circular dull and stereotyped vacuum diaphragm assembly, each described circle dull and stereotyped vacuum diaphragm assembly is connected into described Combination filter element (6) by a described central suction pipe (8), described CPVC film cylinder (1) lower end is provided with inlet (2), upper end is provided with liquid outlet (7), processed liquid material enters from described inlet (2), by circle dull and stereotyped vacuum diaphragm inter-module (5), described Combination filter element (6) is flooded completely, processed liquid material is discharged from described liquid outlet (7), formation circulates, aperture (9) on described central suction pipe (8) is the steam sucking-off of described PET fibrage plain net (4), subsequent condensation becomes product water, described circle dull and stereotyped vacuum diaphragm assembly adopts described PET fibrage plain net (4) as support substrate, at the upper application of adhesive of described PET fibrage plain net (4), described PTFE hydrophobic membrane (3) is compounded in described PET braiding plain net (4) and dries, described PET fibrage plain net (4) mesh wire diameter is 0.5 mm, the aperture of described PTFE hydrophobic membrane is 0.2 μm, porosity is 90%, thickness is 0.2 mm.
2. polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller according to claim 1, is characterized in that, the temperature of described oven dry is 90-130 DEG C, and the time is 15s.
3. polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller according to claim 1, is characterized in that, described adhesive comprise mass fraction be 75% terpolymer first and mass fraction be 25% terpolymer second.
4. polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller according to claim 3, is characterized in that, described terpolymer first is the thermoplasticity terpolymer of difluoroethylene, tetrafluoroethene and hexafluoropropene.
CN201210281768.1A 2012-08-09 2012-08-09 Polytetrafluoroethylene (PTFE) cartridge type Flat Membrane distiller Expired - Fee Related CN102764592B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201578994U (en) * 2010-01-22 2010-09-15 苏州膜华材料科技有限公司 A Submerged Flat Plate Membrane Separator
CN102125806A (en) * 2010-01-20 2011-07-20 中国科学院生态环境研究中心 Method for applying spiral membrane assembly to vacuum membrane distillation
CN102284251A (en) * 2011-08-01 2011-12-21 浙江东大环境工程有限公司 Method for manufacturing polytetrafluoroethylene hollow fibrous membrane
CN202803119U (en) * 2012-08-09 2013-03-20 正仁环保科技股份有限公司 Polytetrafluoroethylene (PTFE) cylinder type plate membrane distiller

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004051671A1 (en) * 2004-10-22 2006-04-27 Microdyn-Nadir Gmbh Device for filtering substances from liquids

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102125806A (en) * 2010-01-20 2011-07-20 中国科学院生态环境研究中心 Method for applying spiral membrane assembly to vacuum membrane distillation
CN201578994U (en) * 2010-01-22 2010-09-15 苏州膜华材料科技有限公司 A Submerged Flat Plate Membrane Separator
CN102284251A (en) * 2011-08-01 2011-12-21 浙江东大环境工程有限公司 Method for manufacturing polytetrafluoroethylene hollow fibrous membrane
CN202803119U (en) * 2012-08-09 2013-03-20 正仁环保科技股份有限公司 Polytetrafluoroethylene (PTFE) cylinder type plate membrane distiller

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