CN102727355B - lifting sling - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及提升装置,尤其涉及一种提升吊索装置。The invention relates to a lifting device, in particular to a lifting sling device.
背景技术Background technique
提升吊索装置一般用于搬运病人或行动不便的人。在使用提升吊索装置中关键的问题是要防止发生意外和避免病人之间的交叉感染。最早使用的提升吊索装置采用纺织织物制成,不仅造价高昂,还易于发生交叉感染。专利CN1184628A公开了由无纺材料制成的一次性的或有限次使用的吊重装置(相当于此处的提升吊索装置)。由于无纺材料的价格是纺织材料价格的几分之一,且具有相同的承载能力,因此实现了吊重装置的专人专用,从而避免了交叉感染的风险。但由此衍生出了一个新问题,如何对丢弃的吊重装置进行处置。通常对丢弃的吊重装置进行填埋或焚化处理,焚化过程中产生的气体能污染环境,而如果吊重装置不是可生物降解的话,填埋同样会对环境造成损害。Lifting sling assemblies are generally used for carrying patients or people with reduced mobility. The key issues in using lifting sling devices are to prevent accidents and to avoid cross-infection between patients. The earliest lifting slings were made of textile fabrics, which were expensive and prone to cross-contamination. Patent CN1184628A discloses a disposable or limited use lifting device (equivalent to the lifting sling device here) made of nonwoven material. Since the price of non-woven materials is a fraction of the price of textile materials and has the same load-carrying capacity, the hoisting device can be dedicated to a specific person, thereby avoiding the risk of cross-infection. But a new problem arises from this, how to dispose of the discarded lifting devices. Discarded lifting devices are usually landfilled or incinerated. The gas generated during incineration can pollute the environment, and if the lifting device is not biodegradable, landfilling will also cause damage to the environment.
在当前常见的可生物降解的聚合物中,聚乳酸(PLA)在用于塑料和织物的可生物降解/堆肥的聚合物领域的优势在于,尽管PLA从自然的和可再生的材料中提取,但是它具有热塑性,能通过熔融挤压以生产塑料制品、纤维和织物,与基于石油合成制成的类似材料,诸如聚烯烃(聚乙烯和聚丙烯)和聚酯(聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯)相比,PLA制品具有良好的机械强度,韧性和柔软性。PLA由乳酸制成,该乳酸是从玉米、小麦、谷物或甜菜中提取的发酵副产品。当聚合形成时,乳酸形成具有以下所示的二聚体重复单元的脂肪族聚酯:Among the current common biodegradable polymers, the advantage of polylactic acid (PLA) in the field of biodegradable/compostable polymers for plastics and fabrics is that although PLA is extracted from natural and renewable materials, However, it is thermoplastic and can be melt-extruded to produce plastic products, fibers and fabrics, and similar materials based on petroleum synthesis, such as polyolefins (polyethylene and polypropylene) and polyester (polyethylene terephthalate) Compared with alcohol esters and polyethylene terephthalate), PLA products have good mechanical strength, toughness and flexibility. PLA is made from lactic acid, a by-product of fermentation extracted from corn, wheat, grains or sugar beets. When polymerized, lactic acid forms aliphatic polyesters with dimer repeat units shown below:
已发现聚(聚羟基烷基酸酯)(PHA)能通过多种作为碳源和能源的细胞内贮存材料的细菌的自然合成制得。其中P(3HB-co-4HB)的共聚酯重复单元如以下所示:It has been discovered that poly(polyhydroxyalkanoate) (PHA) can be produced by the natural synthesis of various bacteria as an intracellular storage material of carbon and energy. Wherein the copolyester repeating unit of P(3HB-co-4HB) is as follows:
聚己二酸-对苯二甲酸丁二酯(PBAT)这种可生物降解的聚合物目前无法从细菌源制得,但是可以从基于石油的产品合成制得。尽管PBAT的熔点为120℃,低于PLA的熔点,但是PBAT具有比PLA更高的弹性、优良的耐冲击强度和良好的熔体加工性能。虽然PLA具有良好熔体加工性能、强度和生物降解/堆肥性能,但是其弹性和耐冲击强度不佳。而PBAT和PLA的共混物的具有增强的弹性、柔韧性和耐冲击强度。PBAT的化学结构如以下所示:Polybutylene adipate-terephthalate (PBAT), a biodegradable polymer, cannot currently be produced from bacterial sources, but can be produced synthetically from petroleum-based products. Although the melting point of PBAT is 120°C, which is lower than that of PLA, PBAT has higher elasticity, excellent impact strength and good melt processability than PLA. While PLA has good melt processability, strength and biodegradability/compostability, it suffers from poor elasticity and impact strength. The blend of PBAT and PLA has enhanced elasticity, flexibility and impact strength. The chemical structure of PBAT is shown below:
聚丁二酸丁二醇酯(PBS)可通过乙二醇的缩聚反应合成制得。PBS的化学结构如以下所示:Polybutylene succinate (PBS) can be synthesized by polycondensation of ethylene glycol. The chemical structure of PBS is shown below:
发明内容Contents of the invention
本发明要解决的技术问题在于针对现有技术中丢弃不用的提升吊索将污染环境的缺陷,提供一种可生物降解的提升吊索装置,同时该提升吊索装置还具有相应的承载能力,且能避免病人间的交叉感染。The technical problem to be solved by the present invention is to provide a biodegradable lifting sling device in view of the defect that discarding the unused lifting sling will pollute the environment in the prior art. And can avoid cross-infection between patients.
本发明解决其技术问题所采用的技术方案是:构建一种提升吊索装置,包括吊索装置和起重装置,位于所述吊索装置中的病人通过所述起重装置提升,所述吊索装置包括用于支撑所述病人身体的主体部分,所述吊索中的织物为可生物降解的织物。The technical solution adopted by the present invention to solve the technical problem is: build a hoisting sling device, including a sling device and a lifting device, the patient in the sling device is lifted by the lifting device, and the sling device is lifted by the lifting device. The sling device includes a body portion for supporting the patient's body, and the fabric in the sling is a biodegradable fabric.
本发明中,所述吊索中的织物由热粘接的可生物降解的无定向纤维制成。In the present invention, the fabric in the sling is made of thermally bonded biodegradable random fibers.
本发明中,所述吊索中的织物由采用可生物降解的化学物粘接而成的织物制成,所述化学物包括乳胶粘合剂或粘接剂。In the present invention, the fabric in the sling is made of fabric bonded with biodegradable chemicals, and the chemicals include latex adhesives or adhesives.
本发明中,通过水刺缠结或针刺方式制备所述吊索中的可生物降解的织物。In the present invention, the biodegradable fabric in the sling is prepared by hydroentangling or needling.
本发明中,所述主体部分的织物由可生物降解的无纺聚合物材料制成,所述可生物降解的无纺聚合物材料包括聚乳酸、主要部分为聚乳酸和小部分聚羟基烷基酸酯的共混物、主要部分为聚乳酸和小部分为聚羟基烷基酸酯和聚己二酸-对苯二甲酸丁二酯的共混物、主要部分为聚乳酸和小部分为聚羟基烷基酸酯、聚己二酸-对苯二甲酸丁二酯和聚丁二酸丁二醇酯的共混物、主要部分为聚乳酸加小部分为聚己二酸-对苯二甲酸丁二酯和聚丁二酸丁二醇酯的共混物、或聚己二酸-对苯二甲酸丁二酯和聚丁二酸丁二醇酯的共混物。In the present invention, the fabric of the main body is made of a biodegradable non-woven polymer material, the biodegradable non-woven polymer material includes polylactic acid, the main part is polylactic acid and a small part of polyhydroxyalkyl A blend of esters, the main part is polylactic acid and a small part is a blend of polyhydroxyalkanoate and polybutylene adipate-terephthalate, the main part is polylactic acid and a small part is poly Hydroxyalkanoate, blend of polybutylene adipate-terephthalate and polybutylene succinate, major part polylactic acid with minor part polyadipate-terephthalic acid A blend of butylene glycol ester and polybutylene succinate, or a blend of polybutylene adipate-terephthalate and polybutylene succinate.
本发明中,将透气的或非透气的可生物降解的薄膜附着到所述吊索装置中织物的一个或多个面上。In the present invention, a breathable or non-breathable biodegradable film is attached to one or more sides of the fabric in the sling.
本发明中,将所述可生物降解的薄膜附着到所述主体部分的一侧或两侧上。In the present invention, the biodegradable film is attached to one or both sides of the body portion.
本发明中,使用可生物降解的粘接剂或可生物降解的热熔胶将所述可生物降解的薄膜粘接到所述主体部分的一侧或两侧上。In the present invention, the biodegradable film is bonded to one or both sides of the main body portion using a biodegradable adhesive or a biodegradable hot melt adhesive.
本发明中,将可生物降解的薄膜直接挤压涂层到所述主体部分的一侧或两侧上而不需要进行粘接处理。In the present invention, a biodegradable film is extrusion coated directly onto one or both sides of the body portion without an adhesive treatment.
本发明中,制成所述可生物降解的薄膜的材料包括聚己二酸-对苯二甲酸丁二酯、聚丁二酸丁二醇酯、聚己二酸-对苯二甲酸丁二酯和聚丁二酸丁二醇酯的共混物、聚己二酸-对苯二甲酸丁二酯和聚乳酸的共混物、聚丁二酸丁二醇酯和聚乳酸的共混物以及聚己二酸-对苯二甲酸丁二酯、聚乳酸和聚丁二酸丁二醇酯的共混物。In the present invention, the material for making the biodegradable film includes polybutylene adipate-terephthalate, polybutylene succinate, polybutylene adipate-terephthalate Blends with polybutylene succinate, blends of polybutylene adipate-terephthalate and polylactic acid, blends of polybutylene succinate and polylactic acid, and Blend of polybutylene adipate-terephthalate, polylactic acid and polybutylene succinate.
本发明中,在对应所述病人腿部的所述吊索装置的外侧区域中,将悬挂带缝接到所述主体部分的下端,且设置带环,以使得所述悬挂带在不使用时能向后折起并穿过所述带环。In the present invention, in the outer area of the sling device corresponding to the patient's leg, a suspending belt is sewn to the lower end of the main body part, and a belt loop is provided so that the suspending belt is not in use. Can be folded back and passed through the belt loop.
依据本发明的另一方面,构建一种用于防止在可生物降解的身体支撑吊索中提升的病人之间的交叉感染的方法,每个病人具有由可生物降解的无纺材料制成的专用吊索。According to another aspect of the present invention, a method for preventing cross-infection between patients lifted in a biodegradable body support sling is constructed, each patient has a Special sling.
本发明产生的有益效果是:使用依据本发明的提升吊索装置,既能避免不同病人之间的使用而导致的交叉感染,而且因丢弃后的提升吊索装置是可生物降解的,从而不会对环境造成负面影响。The beneficial effects produced by the present invention are: the use of the lifting sling device according to the present invention can avoid the cross-infection caused by the use between different patients, and because the discarded lifting sling device is biodegradable, there is no need to can have a negative impact on the environment.
附图说明Description of drawings
下面将结合附图及实施例对本发明作进一步说明,附图中:The present invention will be further described below in conjunction with accompanying drawing and embodiment, in the accompanying drawing:
图1是依据本发明实施例的提升吊索装置和病人的侧面透视图。Figure 1 is a side perspective view of a lifting sling assembly and a patient in accordance with an embodiment of the present invention.
具体实施方式detailed description
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.
本发明涉及一种身体支撑提升吊索,其中所述提升吊索中的织物由可生物降解的聚合物材料制成,能在防止病人之间发生交叉感染的同时,还能因身体支撑提升吊索可生物降解和/或可堆肥,使得使用后丢弃的身体支撑提升吊索不会污染环境。因为吊索装置支撑病人的背部和大腿,所述病人通过诸如吊带或类似物的可拆卸悬挂件从起重悬挂。The present invention relates to a lifting sling for body support, wherein the fabric in the lifting sling is made of biodegradable polymer material, which can prevent cross infection between patients and can also improve the health of the lifting sling due to body support. The sling is biodegradable and/or compostable so that the discarded body support lifting sling does not pollute the environment after use. Because the sling arrangement supports the patient's back and thighs, the patient is suspended from the hoist by a detachable suspension such as a sling or the like.
所述吊索装置优选地为单件身体支撑吊索装置,能支撑病人的背部和大腿。要求悬挂件至少有四个点附着,其中两个位于对应肩部区域中的吊索装置的侧边,两个位于病人两个腿之间的吊索装置的底端。另外两个可选的附加悬挂件位于吊索装置的底部且在对应病人每条腿区域中吊索装置的织物外侧,而其附着点在吊索装置的每一侧上,但是优选地不会太靠近病人的腿,以免在提升过程中接触到病人的腿,使用该附加悬挂件能增强提升病人过程中的安全性,同时给予病人更强的安全感。如果病人的腿太宽,或是太过娇嫩或酸痛,不能冒任何风险与可选的外部悬挂件接触,将不会使用这两个可选悬挂件,而是将每个悬挂件向后折叠并穿入带环中。所述悬挂件优选地包括用于支撑人的身体主体部分和悬垂腿部的下端部分,所述下端部分在病人的大腿之间分别向下和向下延伸。所述吊索还具有上端的头部支撑延伸部分。该情况中,吊索还可能在头部区域具有两个另外的附着点,或可能具有一个或多个增强件,实质上延伸穿过所述延伸部分,并以一定距离超出连接吊索装置中对应肩部区域中吊索装置附着点的连线。The sling is preferably a one-piece body support sling capable of supporting the patient's back and thighs. At least four points of attachment of the suspension are required, two at the sides of the sling in the corresponding shoulder region and two at the bottom end of the sling between the patient's legs. Two additional optional additional hangers are located at the bottom of the sling and outside the fabric of the sling in the area of each of the patient's legs, with attachment points on each side of the sling, but preferably without Too close to the patient's legs, so as not to touch the patient's legs during the lifting process, the use of this additional suspension can enhance the safety of the patient's lifting process, and at the same time give the patient a stronger sense of security. If the patient's legs are too wide, or too delicate or sore, to risk any contact with the optional external suspension, the two optional external suspensions will not be used and each suspension will be folded back and thread into the belt loop. The hanger preferably includes a lower end portion for supporting the main body portion of the person and the depending legs, the lower end portions extending downwardly and downwardly respectively between the patient's thighs. The sling also has an upper head support extension. In this case, the sling may also have two further attachment points in the head area, or may have one or more reinforcements, extending substantially through The line corresponding to the attachment point of the rigging in the shoulder area.
所述吊索还设置有标枪形部分或是其它形状,以使它能在提升中能更加符合人体体型。还可在区域中进行加强和/或加垫。The sling is also provided with a javelin-shaped part or other shapes, so that it can better conform to the body shape of the human body during lifting. Reinforcement and/or padding may also be performed in areas.
图1是依据本发明实施例的提升吊索装置和病人的侧面透视图。如图1所示,图中示出了一个单件吊索装置10,包括主体部分11,所述主体部分11具有下端的悬垂腿的支撑部分12和上端的头部支撑延伸部分13。通过悬垂腿的支撑部分12在病人的两个大腿之间分别向下和向上延伸,且通过头部支撑延伸部分13支撑该病人的头部H,主体部分11支撑悬挂病人I的背部和肩部。将设置悬挂件的短延伸带14缝结在病人肩部对应的区域中,且类似地将悬挂带15缝结到悬垂腿的支撑部分12的端部上。另外,将可选的悬挂带25附着到主体部分11的下端且在病人每个腿对应的吊索装置的织物的外侧,以在绕枢轴12处确保安全。如果不使用悬挂带25,则将它们向后折起并穿过带环26。Figure 1 is a side perspective view of a lifting sling assembly and a patient in accordance with an embodiment of the present invention. As shown in FIG. 1, there is shown a one-piece sling assembly 10 comprising a main body portion 11 having a depending leg support portion 12 at a lower end and a head support extension 13 at an upper end. The support portion 12 of the hanging leg extends downward and upward respectively between the two thighs of the patient, and the head H of the patient is supported by the head support extension 13, and the main body portion 11 supports the back and shoulders of the suspended patient 1. . A short extension strap 14 providing the suspension is stitched in the corresponding area of the patient's shoulder, and a suspension strap 15 is similarly stitched to the end of the support portion 12 of the depending leg. Additionally, optional suspension straps 25 are attached to the lower end of the main body portion 11 and outside the fabric of the sling set for each of the patient's legs for safety around the pivot 12 . If the suspension straps 25 are not used, they are folded back and passed through the strap loops 26 .
吊索装置10优选地设置有通过滚压(压延)形成的凸起图案,以使其具有纺织织物的外观。可通过附件织物层加固吊索装置10,在所述附件织物层的区域中,将悬挂带14、15和可选的悬挂带25缝结到吊索装置上,且悬垂腿的支撑部分12可在无纺织物提升臂的两层之间具有垫子,以增加病人的舒适感。这些吊索的造价成本是纺织吊索的几分之一,如果有限次使用该吊索装置,则可设置该装置为个人专用,以防止交叉感染。The sling device 10 is preferably provided with a raised pattern formed by rolling (calendering) to give it the appearance of a woven fabric. The sling device 10 can be reinforced by an accessory fabric layer in the region of which the suspension straps 14, 15 and the optional suspension strap 25 are stitched to the sling device and the support portion 12 of the depending leg can be There is a cushion between the two layers of the non-woven lifting arm for added patient comfort. The cost of these slings is a fraction of the cost of textile slings, and if the sling device is used for a limited number of times, the device can be set for personal use to prevent cross-infection.
为了支撑所述头部支撑延伸部分13,吊索装置可以具有基板上在整个延伸部分13延伸的、且连接延伸带11上的那些位置的连线延伸一定的距离的一个或多个加强件。可以选择地,还可以有来两个悬挂带(图1中未示出)连接的头部对应的区域。To support said head support extension 13 , the sling may have one or more reinforcements on the base plate extending over the entire extension 13 and the line connecting those positions on the extension strap 11 extending for a certain distance. Optionally, there may also be an area corresponding to the head where two suspension straps (not shown in FIG. 1 ) are connected.
如图1所示,身体支撑提升吊索装置还包括起重装置20,图1示出了起重臂21的外端,吊架22通过叉形连接器连接到所述的臂上,该连接装置23装在一个轴承24内,轴承24和臂21的端部设置有一个垂直的枢轴,且在位置23a处枢轴的连接到吊架22上。即吊架22可以在臂21的外端围绕刚性的垂直轴枢纽轴地转动,且吊架22和连接器23像一个整体围绕垂直轴转动,并且吊架22在连接器23上可围绕有枢轴位置23a确定的横向水平轴枢轴的转动。As shown in Figure 1, the body support lifting sling device also includes a lifting device 20, Figure 1 shows the outer end of the lifting arm 21, the hanger 22 is connected to the arm by a fork connector, the connection The device 23 is mounted in a bearing 24, and the end of the bearing 24 and arm 21 is provided with a vertical pivot and is pivotally connected to the hanger 22 at position 23a. That is, the hanger 22 can pivot around a rigid vertical axis at the outer end of the arm 21, and the hanger 22 and the connector 23 rotate around the vertical axis as a whole, and the hanger 22 can be pivoted around the connector 23. The axis position 23a determines the rotation of the transverse horizontal axis pivot.
此处的吊索装置已经能经受50次提升250kg的重物,且再50次提升190kg的重物的试验,且已经证明无任何磨损的迹象。The sling device here has been able to withstand 50 lifts of a 250 kg load and 50 lifts of a 190 kg load without any signs of wear.
理想地是不能清洗吊索装置,这将避免重复使用。为此,设想缝结是牢固的,且悬挂带是用可解开的线连接到吊索装置,因此,如果试图清洗,吊索装置将分离。Ideally the sling arrangement cannot be washed, which would avoid re-use. For this purpose it is assumed that the stitching is secure and the suspension strap is connected to the sling with a thread that can be untied so that if cleaning is attempted the sling will detach.
本发明不限于单件提升吊索装置,也可用于其它提升吊索装置。而且,单件提升吊索装置不会总是具有支撑头部延伸部分13。The present invention is not limited to single-piece lifting sling arrangements, but may be used with other lifting sling arrangements. Also, a one-piece lifting sling arrangement will not always have a support head extension 13 .
还可将透气的或非透气的薄膜层压到吊索的生物降解无纺织物的一侧或两侧上,以能在提升和搬运过程中含住病人的任何体液。A breathable or non-breathable film may also be laminated to one or both sides of the biodegradable nonwoven fabric of the sling to be able to trap any bodily fluids of the patient during lifting and carrying.
为了使不再使用的丢弃提升吊索装置不会对环境造成负面影响,吊索装置中的织物采用可生物降解的和/或可堆肥的织物。以下将讨论上述可生物降解的和/或可堆肥的织物。本发明中所采用的可生物降解的材料既能确保吊索装置具有相应的承载能力,防止在提升中出现意外;同时也不会增加吊索装置的制造成本,从而使得病人可以承担得起专人专用的提升吊索装置,避免交叉感染的发生。In order that the discarded lifting sling that is no longer used will not have a negative impact on the environment, the fabric in the sling is biodegradable and/or compostable. The aforementioned biodegradable and/or compostable fabrics are discussed below. The biodegradable material used in the present invention can not only ensure that the sling device has a corresponding bearing capacity and prevent accidents during lifting; Special lifting sling device to avoid cross-infection.
尽管已显示P(3HB-co-4HB)产品易于在土壤、污泥和海水中生物降解,但是因水中缺乏微生物而使水中的生物降解速率非常慢(Saito,Yuji,Shigeo Nakamura,MasayaHiramitsu and Yoshiharu Doi,“Microbial Synthesis and Properties of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate),”Polymer International 39(1996),169-174)。因此P(3HB-co-4HB)产品的保存期限在诸如密封包装的干燥存储、清洁溶液等的清洁环境中应当是非常优良的。然而,当置于包含微生物的诸如土壤、河水、河泥、海水以及肥料和沙子、污泥和海水的堆肥的脏环境中时,丢弃的P(3HB-co-4HB)织物、薄膜和封装材料应当易于降解。应当注意的是,聚乳酸(PLA)在以上的脏环境中和环境温度下不易于生物降解,但是必须进行堆肥。首先,堆肥堆中的热度和湿度必须将PLA聚合物分解成更小的聚合物链,最后分解成乳酸。堆肥和土壤中的微生物将更小的聚合物片段和乳酸作为养分而消耗了它们。因此,诸如具有PLA的P(3HB-co-4HB)产品的聚羟基烷酸酯(PHA)混合物应当增强了由PHAs-PLA的共混物制成的产品的降解。另外,由PHA和PLA的共混物制成的产品应当已经增强了在清洁环境中保存期限。然而,在过去的10年,PLA的价格已经大幅度地降低到只比诸如聚丙烯和PET聚酯的合成聚合物稍高一点;与此同时,PHAs的价格继续保持比PLA的高2到3倍,该PLA可大规模地由乳酸合成。PHAs有具有特定碳源的细菌制成,且必须采用溶剂从细菌提取。因此,在商业上无法实现将超过25%的PHA与PLA混合,以熔融挤压形成产品,诸如纺织织物、针织和无纺织物、薄膜、食品包装容器等。Although P(3HB-co-4HB) products have been shown to readily biodegrade in soil, sludge and seawater, the rate of biodegradation in water is very slow due to the absence of microorganisms in water (Saito, Yuji, Shigeo Nakamura, Masaya Hiramitsu and Yoshiharu Doi , "Microbial Synthesis and Properties of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)," Polymer International 39(1996), 169-174). Therefore the shelf life of the P(3HB-co-4HB) product should be very good in clean environments such as dry storage in airtight packaging, cleaning solutions, and the like. However, discarded P(3HB-co-4HB) fabrics, films, and packaging materials, when placed in dirty environments containing microorganisms such as soil, river water, river mud, seawater, and composts of manure and sand, sludge, and seawater Should be readily degradable. It should be noted that polylactic acid (PLA) does not readily biodegrade in the above dirty environments and ambient temperatures, but must be composted. First, the heat and humidity in the compost heap must break down the PLA polymers into smaller polymer chains and finally into lactic acid. Microorganisms in the compost and soil consumed the smaller polymer fragments and lactic acid as nutrients. Therefore, polyhydroxyalkanoate (PHA) blends such as P(3HB-co-4HB) products with PLA should enhance the degradation of products made from blends of PHAs-PLA. Additionally, products made from blends of PHA and PLA should have enhanced shelf life in clean environments. However, in the past 10 years, the price of PLA has dropped drastically to be only slightly higher than that of synthetic polymers such as polypropylene and PET polyester; meanwhile, the price of PHAs continues to remain 2 to 3 times, the PLA can be synthesized from lactic acid on a large scale. PHAs are made by bacteria with a specific carbon source and must be extracted from the bacteria using a solvent. Therefore, it is commercially impossible to blend more than 25% of PHA with PLA to melt-extrude to form products such as woven fabrics, knitted and non-woven fabrics, films, food packaging containers, and the like.
表1中示出了生物降解无纺织物、生物降解薄膜和无纺织物与生物降解薄膜的层压结构。从中国的供应商可获得具有9微米(μm)的纯PBAT薄膜和具有20%的碳酸钙的9μm的PBAT薄膜。从美国的Biax-Fiberfilm公司可获得包含20%的聚丙烯(PP)(非生物降解的)的熔喷(MB)(非生物降解的)。可从德国的Saxon Textile研究结构获得通常质量为80g/m2的具有碳黑的黑色纺粘(SB)PLA。在分别的试验中,使用5-13g/m2的热熔粘接剂将纯PBAT薄膜和具有20%的碳酸钙的PBAT薄膜层压到包含20%PP的Vistamaxx MB和黑色SB PLA上。通常应当使用0.5-12g/m2的热熔粘和优选的1-7g/m2的热熔粘。另外,使用熔融粘接剂层压和粘连两层SB PLA。图1中示出了对所有的原材料和层压结构所测试的重量、厚度、韧性、断裂伸长率、撕裂强度、顶破强度、透水蒸汽速率(MVT)和水头(hydrohead)。应当注意的是这些只是本发明的不同实施例的一些示例,且使用熔融应用将以下材料的不同层粘连到一起:PBAT薄膜或其它可生物降解/堆肥的薄膜,能够通过挤压涂层直接应用的衬底上而不需要粘接剂。能通过但不限于热点压延、整体压延或超声波焊接将层压结构连接或粘接到一起。另外,取代熔融粘接剂,已能使用以胶或水或溶剂为基础的粘接剂或乳胶来将层压结构粘接到一起。Table 1 shows biodegradable nonwoven fabrics, biodegradable films, and laminated structures of nonwoven fabrics and biodegradable films. Pure PBAT films with 9 micrometers ([mu]m) and 9 [mu]m PBAT films with 20% calcium carbonate are available from suppliers in China. Meltblown (MB) containing 20% polypropylene (PP) (non-biodegradable) is available from Biax-Fiberfilm, USA (non-biodegradable). Black spunbond (SB) PLA with carbon black is available in a typical mass of 80 g /m2 from Saxon Textile Research Institute in Germany. In separate tests, neat PBAT films and PBAT films with 20% calcium carbonate were laminated to Vistamaxx MB and black SB PLA containing 20% PP using 5-13 g /m2 hot melt adhesive. Typically 0.5-12 g/ m2 of hot melt and preferably 1-7 g/ m2 of hot melt should be used. Alternatively, two layers of SB PLA were laminated and bonded using a fusion adhesive. The weight, thickness, tenacity, elongation at break, tear strength, burst strength, water vapor transmission rate (MVT) and hydrohead tested for all raw materials and laminated structures are shown in FIG. 1 . It should be noted that these are just a few examples of different embodiments of the invention and that melt application is used to bond together different layers of: PBAT film or other biodegradable/compostable film that can be applied directly by extrusion coating substrate without the need for adhesives. The laminated structures can be joined or bonded together by, but not limited to, hot spot calendering, bulk calendering, or ultrasonic welding. Additionally, instead of melt adhesives, glue or water or solvent based adhesives or latexes have been used to bond laminated structures together.
表1聚合物的强度和阻隔属性Table 1 Strength and barrier properties of polymers
*DSN:表示由于高弹性而没有被顶破*DSN: Indicates that it has not been broken due to high elasticity
如表1所示,9μm的纯(100%)PBAT薄膜(样品1)在MD方向具有良好的伸长率且在CD方向上的断裂伸长率高达300%以上。不能对样品1到5执行顶破强度测试,因为所有的这些薄膜和层压结构的弹性的非常好,在测试过程中不会断裂且在测试后也不会表现出变形。样品1的透水蒸汽速率相当好,为每24小时3380g/m2的,同时静压头为549mm。具有20%碳酸钙(CaCO3)的PBAT薄膜(样品2)具有与样品1类似的数据,其中WVTR和水头都相对更低。预计与样品1和2类似的且具有6μm或以下更小厚度的PBAT薄膜也具有良好的伸长率和更高的WVTR,尽管水头可能更低。熔喷样品3包含80%的(基于Vistamaxx聚烯烃的聚合物具有高弹性且通过ExxonMobil制成)和20%的PP,因为该织物是适度开放的,因此具有约300%的MD和CD伸长率以及每24小时8816g/m2的高WVTR。尽管MB Vistamaxx织物不是生物降解的,但是它是有可能从生物降解聚合物制成的一种弹性无纺材料的示例,所述生物降解聚合物诸如具有非常高伸长率和形变恢复能力的PBAT和其它生物降解聚合物。样品3的水头相当高,为1043mm,表明其具有良好的阻隔性能。应当注意的是,将20%的PP添加到Vistamaxx聚合物颗粒,并且在共混物喂入MB挤压机之前进行物理混合,且进行熔融以使得Vistamaxx MB织物不会太黏。如果熔喷100%的Vistamaxx,则将非常黏,且可能在滚压中结块,且难于在后续的层压或使用中展开(un-wind)。As shown in Table 1, a 9 μm pure (100%) PBAT film (Sample 1) has good elongation in MD direction and a high elongation at break of more than 300% in CD direction. Burst strength testing could not be performed on samples 1 to 5 because all of these films and laminate structures were very elastic, did not break during the test and did not exhibit deformation after the test. The water vapor transmission rate of sample 1 is quite good at 3380 g/m2 per 24 hours with a static head of 549 mm. The PBAT film with 20% calcium carbonate (CaCO3) (Sample 2 ) had similar data to Sample 1, with relatively lower WVTR and water head. PBAT films similar to Samples 1 and 2 and having a smaller thickness of 6 μm or less are also expected to have good elongation and higher WVTR, although the water head may be lower. Melt blown sample 3 contained 80% of (Vistamaxx polyolefin based polymer with high elasticity and made by ExxonMobil) and 20% PP, since the fabric is moderately open, it has about 300% MD and CD elongation and 8816 g/m per 24 hours High WVTR of 2 . Although MB Vistamaxx fabric is not biodegradable, it is an example of a type of elastic nonwoven material that is possible to make from biodegradable polymers such as PBAT which has very high elongation and deformation recovery capabilities. and other biodegradable polymers. Sample 3 had a fairly high head of 1043 mm, indicating good barrier properties. It should be noted that 20% PP was added to the Vistamaxx polymer pellets and the blend was physically mixed and melted before the blend was fed into the MB extruder so that the Vistamaxx MB fabric was not too sticky. If 100% Vistamaxx is melt blown, it will be very sticky and may clump during rolling and be difficult to un-wind for subsequent lamination or use.
与仅有Vistamaxx相比,使用热熔粘接剂且具有Vistamaxx的纯PBAT和包含20%的CaCO3的PBAT的层压结构显著增加了MD和CD韧性。该样品还具有非常高的MD伸长率和尤其高的CD伸长率(样品4为390%,样品5为542%)。样品4和样品5还具有显著高的MVTR值,分别为每24小时1671和1189g/m2,且具有高水头,分别为339和926mm水。再次应当注意的是,PBAT薄膜已经能直接挤压涂层到MB 100%Vistamaxx上或具有一些PP的MBVistamaxx上且使用或没有使用热熔粘接剂,并且挤压涂层已经允许使用更薄规格的PBAT薄膜,低至4或5μm,由此具有更高的MVTR,但是可能具有更低的水头。Laminations of pure PBAT with Vistamaxx and PBAT containing 20 % CaCO3 using hot-melt adhesives significantly increased MD and CD toughness compared to Vistamaxx alone. The samples also had very high MD elongation and especially high CD elongation (390% for sample 4 and 542% for sample 5). Samples 4 and 5 also had significantly high MVTR values of 1671 and 1189 g/m2 per 24 hours, respectively, and high water heads of 339 and 926 mm water, respectively. Again it should be noted that PBAT films have been extrusion coated directly onto MB 100% Vistamaxx or MBVistamaxx with some PP with or without hot melt adhesive and extrusion coating has allowed thinner gauges PBAT films, down to 4 or 5 μm, thus have higher MVTR, but possibly lower water head.
黑色SB PLA的目标重量是80g/m2,MD韧性为104N且CD韧性为31N,但是具有更低的MD断裂伸长率,为3.6%,而具有高CD伸长率,为30.7%。顶破强度为177KN/m2且WVTR相当高,为每24小时8322g/m2,且水头相当明显,为109mm。采用熔热粘接剂层压到纯PBAT上的80gsm的黑色SB PLA的MD和CD韧性分别比单纯的SB PLA高,其分别为107和39N,但是CD伸长率仅为9.8%。但是层压了SB PLA的PBAT具有更高的顶破强度,为220KN/m2。但是透气性仍然保持优良,WVTR为每24小时2459g/m2,且具有非常高的水头,为3115mm水。层压了包含20%CaCO3的PBAT的SB PLA具有与样品8类似的属性,除了水头比较低,尽管仍高达2600mm水。具有更薄PBAT薄膜以及特别具有通过挤压涂层沉积形成的更薄PBAT薄膜的SBPLA层压结构,可生产用于具有高MVTR的医学、工业或体育应用的防护服,因其能穿着舒适且具有高净水头以用于屏障防护。能通过在薄膜的层压之前或之后,要么在PBAT薄膜侧要么在任一侧上的SB PLA上应用整理剂(氟硅或其它类型的整理剂),来进一步增强屏障防护。还可通过在薄膜的层压之前或之后将MB PLA与SB PLA层压结合来增强屏障防护。还可能将整理剂添加到用于制备例如PBAT薄膜、SB或MB PLA的聚合物熔体中。The black SB PLA had a target weight of 80 g/m 2 , a MD toughness of 104N and a CD toughness of 31N, but had a lower MD elongation at break of 3.6% and a high CD elongation of 30.7%. The burst strength was 177KN/m 2 and the WVTR was quite high at 8322g/m 2 per 24 hours and the water head was quite significant at 109mm. The MD and CD toughness of 80 gsm black SB PLA laminated to pure PBAT with hot melt adhesive is higher than pure SB PLA, which are 107 and 39 N, respectively, but the CD elongation is only 9.8%. But the PBAT laminated with SB PLA has a higher burst strength of 220KN/m 2 . But the air permeability is still excellent, the WVTR is 2459g/m 2 per 24 hours, and it has a very high water head, which is 3115mm of water. SB PLA laminated with PBAT containing 20 % CaCO3 had similar properties to sample 8, except for a lower hydraulic head, although still as high as 2600 mm water. SBPLA laminate structures with thinner PBAT films and especially with thinner PBAT films deposited by extrusion coating, can produce protective clothing for medical, industrial or sports applications with high MVTR, because they can be worn comfortably and Has a high net head for barrier protection. Barrier protection can be further enhanced by applying a finish (fluorosilicone or other type of finish) either on the PBAT film side or on the SB PLA on either side, before or after lamination of the film. Barrier protection can also be enhanced by laminating MB PLA with SB PLA either before or after lamination of the film. It is also possible to add finishing agents to the polymer melts used to make eg PBAT films, SB or MB PLA.
当将两层SB PLA熔粘接结合在一起而形成样品9时,MD和CD韧性和顶破强度实质上是一层结构的样品6的两倍。对应从110g/m2SB PP产生的病人提升吊索的断裂伸长率(%伸长率)的目标MD和CD韧性分别至少每5cm为200和140N,MD和CD中的伸长率值至少都为40%。如表1所示,两个粘接结合的SB PLA层的MD韧性为215N,但CD韧性仅为所需级别的50%。而且MD和CD的断裂伸长率比40%的所需最小值要低得多。能通过在SB织物挤压之前将PLA与5到60%的PBAT或优选地20到50%的PBAT共混,以增强SB PLA的MD和CD伸长率。另外,可将PBAT和PBS与PLA共混以获得具有所需MD和CD韧性和伸长率值以及热暴露后稳定性的织物。另外,可通过非热点压延的工艺粘接SB长丝网,以获得更大的多方向强度和伸长率以包含水刺缠结式和针刺式。能生成110g/m2和更大重量的针刺SB PLA而不需要将两个或多个SB PLA织物层压或粘接结合在一起以获得所需的强度和伸长率值。When two layers of SB PLA were melt-bonded together to form Sample 9, the MD and CD toughness and burst strength were substantially double those of Sample 6, which was a one-layer construction. Target MD and CD tenacities corresponding to elongation at break (% elongation) of patient lifting slings produced from 110 g/m 2 SB PP are at least 200 and 140 N per 5 cm, respectively, with elongation values in MD and CD of at least Both are 40%. As shown in Table 1, the MD toughness of two adhesively bonded SB PLA layers was 215N, but the CD toughness was only 50% of the required grade. Also the elongation at break in MD and CD is much lower than the required minimum of 40%. The MD and CD elongation of SB PLA can be enhanced by blending PLA with 5 to 60% PBAT or preferably 20 to 50% PBAT prior to SB fabric extrusion. Additionally, PBAT and PBS can be blended with PLA to obtain fabrics with desired MD and CD tenacity and elongation values and stability after heat exposure. In addition, the SB filament web can be bonded by non-hot spot calendering to obtain greater multi-directional strength and elongation to include hydroentangling and needle punching. Needlepunched SB PLA of 110 g/ m2 and greater can be produced without the need to laminate or bond two or more SB PLA fabrics together to obtain the desired strength and elongation values.
还显示由诸如PLA的可生物降解/堆肥的织物制成的吊索,从原材料阶段到工厂的聚合物形成,所产生诸如二氧化碳的温室气体排放要低得多。例如,生产PLA聚合物中,每千克聚合物产生1.3千克的二氧化碳,相应的,生产每千克PP将产生1.9千克的二氧化碳以及生产每千克PET将产生3.4千克的二氧化碳。而且从原料阶段到聚合物工厂的生产中,PLA使用更少的非可再生能量,生产Ingeo牌PLA中,每公斤聚合物使用42兆焦耳的非可再生能量,与之相比的PP生产中,每公斤聚合物使用77兆焦耳的非可再生能量,PET生产中,每公斤聚合物使用87兆焦耳的非可再生能量(“The IngeoTM Journey,Nature Works LLC BrochureCopyright 2009)。It has also been shown that slings made from biodegradable/compostable fabrics such as PLA produce much lower greenhouse gas emissions such as carbon dioxide from the raw material stage to polymer formation in factories. For example, the production of PLA polymer produces 1.3 kg of CO2 per kg of polymer, correspondingly, the production of PP produces 1.9 kg of CO2 and the production of PET produces 3.4 kg of CO2. And PLA uses less non-renewable energy in production from the raw material stage to the polymer plant, producing Ingeo brand PLA uses 42 megajoules of non-renewable energy per kilogram of polymer compared to PP production , using 77 MJ of non-renewable energy per kilogram of polymer, and 87 MJ of non-renewable energy per kilogram of polymer used in PET production (“The Ingeo TM Journey, Nature Works LLC BrochureCopyright 2009).
所述吊索装置由无纺的可生物降解/堆肥的材料制成,典型的为PLA、或主要部分为PLA加少量的PHA的共混物、或主要部分为PLA加少量的PHA和PBAT的共混物、或主要部分为PLA加少量的PHA、PBAT和PBS的共混物、或主要部分为PLA加少量的PBAT和PBS的共混物、或PBAT和PBS的共混物。将吊索裁剪成更加符合病人I的体型,为使病人更觉舒适,在吊索10中还设置有标枪形部分16。The sling is made of a non-woven biodegradable/compostable material, typically PLA, or a blend of major PLA with a small amount of PHA, or a major PLA with minor amounts of PHA and PBAT A blend, or a blend of PLA plus a small amount of PHA, PBAT and PBS, or a blend of PLA plus a small amount of PBAT and PBS, or a blend of PBAT and PBS. The sling is cut to conform to the body shape of the patient 1 more, and for making the patient feel more comfortable, a javelin-shaped part 16 is also provided with in the sling 10.
典型地,通过热粘接随机取向的生物降解/堆肥的聚合物纤维制成所述吊索,但是也可通过干法成网、化学粘接(采用生物降解粘接剂)的织物制成,或由干法成网或水刺(水刺缠结)织物制成。该材料通常是具有透气性(除非有非透气的生物降解薄膜粘附在上面)但不能穿过水,且可能需要在吊索中设置穿孔,以用于降低病人进入到浴池中。Typically, the slings are made by thermobonding randomly oriented biodegradable/compostable polymer fibers, but can also be made from dry-laid, chemically bonded (with biodegradable adhesives) fabrics, Or made from dry-laid or spunlace (spunlace entangled) fabrics. The material is usually breathable (unless a non-breathable biodegradable film is adhered to it) but impermeable to water and may require perforations in the sling for lowering the patient's access to the bath.
应当理解的是,对本领域普通技术人员来说,可以根据上述说明加以改进或变换,而所有这些改进和变换都应属于本发明所附权利要求的保护范围。It should be understood that those skilled in the art can make improvements or changes based on the above description, and all these improvements and changes should fall within the protection scope of the appended claims of the present invention.
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