CN102718569A - Lead-free red wear-resistant frit for ceramics preparation - Google Patents
Lead-free red wear-resistant frit for ceramics preparation Download PDFInfo
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- CN102718569A CN102718569A CN2012101914928A CN201210191492A CN102718569A CN 102718569 A CN102718569 A CN 102718569A CN 2012101914928 A CN2012101914928 A CN 2012101914928A CN 201210191492 A CN201210191492 A CN 201210191492A CN 102718569 A CN102718569 A CN 102718569A
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- lead
- frit
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- wear resistance
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Abstract
The invention discloses lead-free red wear-resistant frit for ceramics preparation, which is prepared from the following raw materials in part by weight: 30-50 parts of SiO2, 10-20 parts of Al2O3, 1-5 parts of CuO, 1-5 parts of Fe2O3, 10-20 parts of CaO, 10-20 parts of MgO and 10-20 parts of B2O3 and 10-20 parts of alkali metal. The lead-free red wear-resistant frit for ceramics preparation disclosed by the invention has the advantages of bright red, good wear resistance, and good attractiveness, and especially has uniform color distribution, no lead and environment friendliness, and wide application scope.
Description
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Technical field
The present invention relates to a kind of frit for preparing ceramic usefulness, be specifically related to the frit that a kind of potting of wear resistance of the lead-free redness of the skin or complexion for preparing ceramic usefulness is used.
Background technology
Along with rapid economy development and people to the improving constantly of standard of living, ceramic has been widely used in fields such as daily necessities, material of construction, artwork.But the frit that the general potting of prior art is used exists wear resistance not enough; And color is more single mostly for the pottery of prior art, can not meet the bright-coloured high demand of people's multicolour, and the glaze distribution of color is inhomogeneous; And be added with heavy metal lead, feature of environmental protection property is relatively poor more.Therefore, necessary on the basis of prior art, the frit that the potting of the wear resistance of a kind of lead-free redness of the skin or complexion of research and development design is used.
Summary of the invention
Goal of the invention: technical problem to be solved by this invention is the deficiency that overcomes prior art; Provide that a kind of redness of the skin or complexion is bright-coloured, wear resistance good, the glaze distribution of color is even; And do not add metallic lead, the frit that the potting of the wear resistance of safety and environmental protection, lead-free redness of the skin or complexion is used.
Technical scheme: for solving above technical problem, the present invention takes following technical scheme:
The frit that a kind of potting of wear resistance of lead-free redness of the skin or complexion is used, it is processed by the raw material of following parts by weight:
SiO
230 ~ 50 parts, Al
2O
310 ~ 20 parts, Fe
2O
35 ~ 15 parts, NiO20 ~ 30 part, 10 ~ 20 parts of ZnO, 10 ~ 20 parts of MgO, B
2O
310 ~ 20 parts of 10 ~ 20 parts, basic metal.
As preferred version, the frit that the potting of the wear resistance of above-described lead-free redness of the skin or complexion is used, it is processed by the raw material of following parts by weight:
SiO
240 ~ 50 parts, Al
2O
310 ~ 15 parts, Fe
2O
35 ~ 10 parts, NiO10 ~ 20 part, ZnO10 ~ 15 part, 10 ~ 15 parts of MgO, B
2O
310 ~ 15 parts of 10 ~ 15 parts, basic metal.
As more preferably scheme, the frit that the potting of the wear resistance of above-described lead-free redness of the skin or complexion is used, it is processed by the raw material of following parts by weight:
SiO
245 parts, Al
2O
315 parts, Fe
2O
310 parts, 15 parts of NiO, 15 parts of ZnO,, 15 parts of MgO, B
2O
315 parts of 15 parts, basic metal.
As preferred version, the frit that the potting of the wear resistance of above-described lead-free redness of the skin or complexion is used, described Alkali-Metal Na
2O or K
2O.
The present invention is according to the specification of quality of potting with coloured frit; Confirm the ratio of the composition and the each component of the frit that the potting of the wear resistance of lead-free redness of the skin or complexion is used through a large amount of experiments; The frit that the potting of the wear resistance of lead-free redness of the skin or complexion provided by the invention is used, redness of the skin or complexion is bright-coloured, wear resistance good, especially distribution of color is even, and glossiness is good; Can satisfy the standard of people's high request, the frit specific product parameter that the potting of the wear resistance of this lead-free redness of the skin or complexion uses is:
Thermal expansivity 70, change point (degree) 550, expansion softening temperature (degree) 650, sintering point (degree) 690, softening temperature (degree) 780, ball point (degree) 950, hemisphere point (degree) 1000, each item character meets the requirements, Functionality, quality and appealing design.
Beneficial effect: the frit that the potting of the wear resistance of lead-free redness of the skin or complexion provided by the invention is used is compared with prior art has following advantage:
The frit that the potting of the wear resistance of the lead-free redness of the skin or complexion of the ceramic usefulness of preparation provided by the invention is used; The best according to the preferred frit of a large amount of experiments is formed and proportioning, and redness of the skin or complexion is bright-coloured, wear resistance good, especially distribution of color is even, and glossiness is good; Good visual effect; Aesthetics is high, and does not add the metal lead, environmental protection, safety.
Embodiment
Below in conjunction with specific embodiment; Further illustrate the present invention; Should understand these embodiment only be used to the present invention is described and be not used in the restriction scope of the present invention; After having read the present invention, those skilled in the art all fall within the application's accompanying claims institute restricted portion to the modification of the various equivalent form of values of the present invention.
Embodiment 1
The frit that a kind of potting of wear resistance of lead-free redness of the skin or complexion is used, it is processed by the raw material of following parts by weight:
SiO
250 parts, Al
2O
320 parts, Fe
2O
315 parts, 30 parts of NiO, 20 parts of ZnO, 20 parts of MgO, B
2O
320 parts, Na
2O20 part.
Embodiment 2
The frit that a kind of potting of wear resistance of lead-free redness of the skin or complexion is used, it is processed by the raw material of following parts by weight:
SiO
230 parts, Al
2O
310 parts, Fe
2O
35 parts, NiO20 part, 10 parts of ZnO, 10 parts of MgO, B
2O
310 parts of 10 parts, basic metal
The above only is a preferred implementation of the present invention; Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; Can also make some improvement and retouching, these improvement and retouching also should be regarded as protection scope of the present invention.
Claims (4)
1. the frit used of the potting of the wear resistance of a lead-free redness of the skin or complexion is characterized in that it is processed by the raw material of following parts by weight:
SiO
230 ~ 50 parts, Al
2O
310 ~ 20 parts, Fe
2O
35 ~ 15 parts, NiO20 ~ 30 part, 10 ~ 20 parts of ZnO, 10 ~ 20 parts of MgO, B
2O
310 ~ 20 parts of 10 ~ 20 parts, basic metal.
2. the frit used of the potting of the wear resistance of lead-free redness of the skin or complexion according to claim 1 is characterized in that it is processed by the raw material of following parts by weight:
SiO
240 ~ 50 parts, Al
2O
310 ~ 15 parts, Fe
2O
35 ~ 10 parts, NiO10 ~ 20 part, ZnO10 ~ 15 part, 10 ~ 15 parts of MgO, B
2O
310 ~ 15 parts of 10 ~ 15 parts, basic metal.
3. the frit used of the potting of the wear resistance of lead-free redness of the skin or complexion according to claim 1 is characterized in that it is processed by the raw material of following parts by weight:
SiO
245 parts, Al
2O
315 parts, Fe
2O
310 parts, 15 parts of NiO, 15 parts of ZnO,, 15 parts of MgO, B
2O
315 parts of 15 parts, basic metal.
4. the frit of using according to the potting of the wear resistance of each described lead-free redness of the skin or complexion of claim 1 to 3 is characterized in that described basic metal is Na
2O or K
2O.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101914928A CN102718569A (en) | 2012-06-12 | 2012-06-12 | Lead-free red wear-resistant frit for ceramics preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101914928A CN102718569A (en) | 2012-06-12 | 2012-06-12 | Lead-free red wear-resistant frit for ceramics preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102718569A true CN102718569A (en) | 2012-10-10 |
Family
ID=46944476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101914928A Pending CN102718569A (en) | 2012-06-12 | 2012-06-12 | Lead-free red wear-resistant frit for ceramics preparation |
Country Status (1)
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| CN (1) | CN102718569A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107698237A (en) * | 2016-12-01 | 2018-02-16 | 张晓辉 | Silicide additive, silicon protect stone series of plates and its processing technology |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693291A (en) * | 2005-05-11 | 2005-11-09 | 刘锡军 | Low temp. red glaze for ceramics and mfg. method thereof |
| CN1884212A (en) * | 2006-07-12 | 2006-12-27 | 上海师范大学 | High-temperature reparation glaze composition and process for preparing same and application thereof |
| CN101050060A (en) * | 2007-05-15 | 2007-10-10 | 淄博华为颜料有限公司 | Low temperature ceramic color without lead on glaze, and preparation method |
| CN101768016A (en) * | 2009-12-29 | 2010-07-07 | 深圳市永丰源实业有限公司 | Enamel color ceramic glaze and production process and application thereof |
-
2012
- 2012-06-12 CN CN2012101914928A patent/CN102718569A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693291A (en) * | 2005-05-11 | 2005-11-09 | 刘锡军 | Low temp. red glaze for ceramics and mfg. method thereof |
| CN1884212A (en) * | 2006-07-12 | 2006-12-27 | 上海师范大学 | High-temperature reparation glaze composition and process for preparing same and application thereof |
| CN101050060A (en) * | 2007-05-15 | 2007-10-10 | 淄博华为颜料有限公司 | Low temperature ceramic color without lead on glaze, and preparation method |
| CN101768016A (en) * | 2009-12-29 | 2010-07-07 | 深圳市永丰源实业有限公司 | Enamel color ceramic glaze and production process and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107698237A (en) * | 2016-12-01 | 2018-02-16 | 张晓辉 | Silicide additive, silicon protect stone series of plates and its processing technology |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121010 |