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CN102717579B - Method utilizing expanded perlite to produce vacuum insulated plate - Google Patents

Method utilizing expanded perlite to produce vacuum insulated plate Download PDF

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Publication number
CN102717579B
CN102717579B CN201210187116.1A CN201210187116A CN102717579B CN 102717579 B CN102717579 B CN 102717579B CN 201210187116 A CN201210187116 A CN 201210187116A CN 102717579 B CN102717579 B CN 102717579B
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film
expanded perlite
core
mold
board
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CN102717579A (en
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何奕
侯钦鹏
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Anhui Keruike Insulation Material Co ltd
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ANHUI KERUIKE THERMAL INSULATION MATERIAL Co Ltd
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Abstract

一种利用膨胀珍珠岩生产真空绝热板的方法,制作工艺的步骤是:配料:将所述材料投入混合机进行充分混合;烘干:将搅拌均匀的混合料进行烘干;芯料成型:将烘干好的物料和吸气剂投入模具中,将模具放入压制机中加压成型;包裹:将压制成型的芯板从模具中取出,并在芯板的外围包裹一层无纺布,即得到建筑用真空绝热板芯板;将芯板置入高阻气膜袋内抽真空,真空度为0.02-20Pa,然后封口。本发明的优点是:膨胀珍珠岩吸音性好,自身导热系数低,传统保温板使用有机物发泡或者使用岩棉,易燃或者导热系数较高,研发出的以珍珠岩作为心裁主要成分的保温板能达到较低的导热系数,又是无机材料,不易燃烧。

A method for producing a vacuum insulation board by using expanded perlite. The steps of the manufacturing process are: batching: put the materials into a mixer for thorough mixing; drying: dry the evenly stirred mixture; forming the core material: put The dried material and getter are put into the mold, and the mold is put into the pressing machine to form it under pressure; wrapping: take the pressed core board out of the mold, and wrap a layer of non-woven fabric around the core board, That is, the core board of the vacuum insulation board for building is obtained; the core board is placed in a high-barrier gas film bag for vacuuming, and the vacuum degree is 0.02-20Pa, and then sealed. The advantages of the invention are: expanded perlite has good sound absorption and low thermal conductivity. The traditional thermal insulation board uses organic foam or rock wool, which is flammable or has a high thermal conductivity. The developed perlite is the main component of the thermal insulation board. The board can achieve a low thermal conductivity, and it is an inorganic material, which is not easy to burn.

Description

利用膨胀珍珠岩生产真空绝热板的方法Method for producing vacuum insulation panels using expanded perlite

技术领域 technical field

本发明涉及一种利用膨胀珍珠岩生产真空绝热板的方法,用于生产真空绝热板,该真空绝热板用作建筑或工业保温用材。 The invention relates to a method for producing a vacuum heat insulation board by using expanded perlite, which is used for producing a vacuum heat insulation board, and the vacuum heat insulation board is used as a building or industrial heat preservation material.

背景技术 Background technique

现有真空绝热板主要由内部隔热芯材和外覆高阻气薄膜构成,其中隔热芯材一般采用常规保温材料(如发泡塑料)、玻璃纤维或/和气凝胶等材料制成,其缺点是材料成本高,能耗高,不环保。 Existing vacuum insulation panels are mainly composed of internal heat-insulating core material and outer high-barrier film, in which the heat-insulation core material is generally made of conventional thermal insulation materials (such as foamed plastics), glass fiber or/and airgel, etc. Its disadvantages are high material cost, high energy consumption and not environmental protection.

发明内容 Contents of the invention

本发明旨在提供一种利用膨胀珍珠岩生产真空绝热板的方法,以解决现有技术存在的材料成本高,能耗高,不环保的问题。  The present invention aims to provide a method for producing vacuum insulation panels by using expanded perlite, so as to solve the problems of high material cost, high energy consumption and environmental protection in the prior art. the

本发明的技术方案是:一种利用膨胀珍珠岩生产真空绝热板的方法,将芯材装入高阻气膜袋内,抽真空后封口,其特征在于,所述的芯材成分和重量份数为:膨胀珍珠岩60-90,纤维 10-20,真空活性稳定剂 3-6; The technical solution of the present invention is: a method for producing a vacuum insulation panel by using expanded perlite. The core material is put into a high-resistance gas film bag, and sealed after vacuuming. It is characterized in that the core material composition and parts by weight The number is: expanded perlite 60-90, fiber 10-20, vacuum active stabilizer 3-6;

制作工艺包括如下步骤: The manufacturing process includes the following steps:

(1)配料:将所述材料投入混合机进行充分混合; (1) Ingredients: put the materials into the mixer for full mixing;

(2)烘干:将搅拌均匀的混合料进行烘干; (2) Drying: Dry the evenly stirred mixture;

(3)芯料成型:将烘干后的物料投入模具中,表面刮平; (3) Core molding: Put the dried material into the mold and scrape the surface;

(4)压制成型:将模具放入压制机中压制成型; (4) Compression molding: Put the mold into the pressing machine and press molding;

(5)包裹:将压制成型的芯板从模具中取出,在芯板的外围包裹一层无纺布,得到保温芯板; (5) Wrapping: Take out the pressed core board from the mold, and wrap a layer of non-woven fabric around the core board to get the insulation core board;

(6)将保温芯板置入高阻气膜袋内抽真空,真空度为0.02-20Pa,然后 (6) Put the insulation core board into the high-resistance air film bag to vacuumize, the vacuum degree is 0.02-20Pa, and then

封口。 seal.

步骤(2)的烘干温度为100-120℃,烘干过程中每隔8分钟测定一次混合料的含水率,直至混合料的含水率达到0.5%以下,停止烘干。 The drying temperature in step (2) is 100-120°C. During the drying process, measure the moisture content of the mixture every 8 minutes until the moisture content of the mixture reaches below 0.5%, and then stop drying.

步骤(4)中压制机的下降速度控制为3-7 cm/s,压力控制在20-80T/m2In step (4), the descending speed of the pressing machine is controlled at 3-7 cm/s, and the pressure is controlled at 20-80 T/m 2 .

步骤(2)的烘干过程在步骤(1)的过程中同时进行。 The drying process of step (2) is carried out simultaneously during the process of step (1).

步骤(5)中所用无纺布为阻燃型无纺布,单位面积质量为35-100g/m2The non-woven fabric used in step (5) is a flame-retardant non-woven fabric with a mass per unit area of 35-100 g/m 2 .

所述的纤维包括岩棉、玻纤、木质素纤维和玻璃陶瓷纤维中的一种以上,以任意比例混合,所述的纤维长度为3-12mm,直径为0.2-13微米。 The fibers include more than one of rock wool, glass fibers, lignin fibers and glass ceramic fibers mixed in any proportion, the length of the fibers is 3-12 mm, and the diameter is 0.2-13 microns.

所述的高阻气膜袋由外侧的防护层与内侧的密封层复合组成。 The high-barrier gas film bag is composed of an outer protective layer and an inner sealing layer.

所述的密封层包括铝箔、聚酯薄膜、尼龙薄膜、聚乙烯薄膜、聚氯乙烯薄膜、聚苯乙烯薄膜、聚偏二氯乙烯、聚乙烯醇薄膜、乙烯-醋酸乙烯共聚物薄膜、聚乙烯醇薄膜、尼龙薄膜、乙烯/乙烯醇共聚物薄膜、聚碳酸酯薄膜、聚丙烯的一种或一种以上复合而成;所述高阻气膜袋最外侧的保护层由玻纤布、无纺布、碳纤维织布、玄武岩纤维布、陶瓷纤维布的一种或一种以上复合而成。  The sealing layer includes aluminum foil, polyester film, nylon film, polyethylene film, polyvinyl chloride film, polystyrene film, polyvinylidene chloride, polyvinyl alcohol film, ethylene-vinyl acetate copolymer film, polyethylene One or more of alcohol film, nylon film, ethylene/vinyl alcohol copolymer film, polycarbonate film, polypropylene; the outermost protective layer of the high resistance air film bag is made of glass fiber cloth, no One or more composites of woven fabrics, carbon fiber woven fabrics, basalt fiber fabrics, and ceramic fiber fabrics. the

在所述的高阻气膜袋的两端设有封边,该封边设在该高阻气膜袋的两端的相对的一边,在与该封边相对的另一边设有与该封边吻合的咬合槽。 Both ends of the high-barrier air-resistance film bag are provided with edge seals, which are arranged on the opposite side of the two ends of the high-barrier air-barrier film bag, and on the other side opposite to the edge seal. Anastomotic occlusal groove.

本发明的优点是:本发明以珍珠岩作为芯材主要成分的真空保温板能达到较低的导热系数,又是无机材料,不易燃烧,可满足国家六五节能规划的需要。原料价格低廉,保证一定的低导热系数,降低原料成本;减少了对环境的污染。纤维与珍珠岩混合增加了保温板的强度,并可在珍珠岩的颗粒之间形成隔热层,进一步提高保温性能。 The advantages of the invention are: the vacuum insulation board with perlite as the main component of the core material can achieve low thermal conductivity, is an inorganic material, is not easy to burn, and can meet the needs of the National Sixth Five-Year Energy Saving Plan. The price of raw materials is low, which ensures a certain low thermal conductivity, reduces the cost of raw materials, and reduces the pollution to the environment. The mixing of fiber and perlite increases the strength of the insulation board, and can form an insulation layer between the particles of perlite, further improving the insulation performance.

附图说明 Description of drawings

图1是本发明一个实施例的侧面结构示意图; Fig. 1 is a side structure schematic diagram of an embodiment of the present invention;

图2是本发明的另一实施例侧面结构示意图; Fig. 2 is a schematic view of the side structure of another embodiment of the present invention;

图3是图1的俯视图; Fig. 3 is the top view of Fig. 1;

图4是本发明应用时的对接示意图。 Fig. 4 is a schematic diagram of docking when the present invention is applied.

具体实施方式 Detailed ways

本发明一种利用膨胀珍珠岩生产真空绝热板的方法,将芯材装入高阻气膜袋内,抽真空后封口,其特征在于,所述的芯材成分和重量份数为:膨胀珍珠岩60-90,纤维 10-20,真空活性稳定剂 3-6。真空活性稳定剂由活性炭,钡锂合金活化物,氧化钙,氧化镁,硅胶中的一种或一种以上混合物(任意比例)构成。所述的纤维包括岩棉、玻纤、木质素纤维和玻璃陶瓷纤维中的一种,或以任意比例混合的两种以上的上述纤维。所述的纤维长度为3-12mm,直径为0.2-13微米。 The invention discloses a method for producing a vacuum insulation panel by using expanded perlite. The core material is put into a high-barrier gas film bag and sealed after vacuuming. It is characterized in that the composition and parts by weight of the core material are: expanded pearl Rock 60-90, fiber 10-20, vacuum active stabilizer 3-6. The vacuum active stabilizer is composed of one or more mixtures (in any proportion) of activated carbon, barium-lithium alloy activator, calcium oxide, magnesium oxide, and silica gel. The fibers include one of rock wool, glass fiber, lignin fiber and glass ceramic fiber, or two or more of the above fibers mixed in any proportion. The fiber length is 3-12 mm, and the diameter is 0.2-13 microns.

制作工艺包括如下步骤: The manufacturing process includes the following steps:

(1)配料:将所述材料投入混合机进行充分混合; (1) Ingredients: put the materials into the mixer for full mixing;

(2)烘干:将搅拌均匀的混合料进行烘干;烘干温度为100-120℃,烘干过程中每隔8分钟测定一次混合料的含水率,直至混合料的含水率达到0.5%以下,停止烘干。 (2) Drying: Dry the evenly stirred mixture; the drying temperature is 100-120°C, and measure the moisture content of the mixture every 8 minutes during the drying process until the moisture content of the mixture reaches 0.5% Next, stop drying.

(3)芯料成型:将烘干后的物料投入模具中,表面刮平; (3) Core molding: Put the dried material into the mold and scrape the surface;

(4)压制成型:将模具放入压制机中压制成型;压制机的下降速度控制为3-7 cm/s,压力控制在20-80T/m2(4) Compression molding: put the mold into a press machine and press it; the descending speed of the press machine is controlled at 3-7 cm/s, and the pressure is controlled at 20-80T/m 2 .

(5)包裹:将压制成型的芯板从模具中取出,在芯板的外围包裹一层无纺布,得到保温芯板;所用无纺布为阻燃型无纺布,单位面积质量为35-100g/m2(5) Wrapping: Take out the pressed core board from the mold, and wrap a layer of non-woven fabric around the core board to obtain a thermal insulation core board; the non-woven fabric used is a flame-retardant non-woven fabric with a mass per unit area of 35 -100g/m 2 .

(6)将保温芯板置入高阻气膜袋内抽真空,真空度为0.02-20Pa,然后 (6) Put the insulation core board into the high-resistance air film bag to vacuumize, the vacuum degree is 0.02-20Pa, and then

封口。 seal.

步骤(2)的烘干过程也可以在步骤(1)的过程中同时进行。 The drying process of step (2) can also be carried out simultaneously during the process of step (1).

所述的高阻气膜袋由外侧的防护层与内侧的密封层复合组成。 The high-barrier gas film bag is composed of an outer protective layer and an inner sealing layer.

所述的密封层包括铝箔、聚酯薄膜、尼龙薄膜、聚乙烯薄膜、聚氯乙烯薄膜、聚苯乙烯薄膜、聚偏二氯乙烯、聚乙烯醇薄膜、乙烯-醋酸乙烯共聚物薄膜、聚乙烯醇薄膜、尼龙薄膜、乙烯/乙烯醇共聚物薄膜、聚碳酸酯薄膜、聚丙烯的一种或一种以上复合而成。 The sealing layer includes aluminum foil, polyester film, nylon film, polyethylene film, polyvinyl chloride film, polystyrene film, polyvinylidene chloride, polyvinyl alcohol film, ethylene-vinyl acetate copolymer film, polyethylene Alcohol film, nylon film, ethylene/vinyl alcohol copolymer film, polycarbonate film, polypropylene film or more than one compound.

所述高阻气膜袋最外侧的保护层由玻纤布、无纺布、碳纤维织布、玄武岩纤维布、陶瓷纤维布的一种或一种以上复合而成。  The outermost protective layer of the high-barrier gas film bag is composed of one or more of glass fiber cloth, non-woven fabric, carbon fiber woven cloth, basalt fiber cloth, and ceramic fiber cloth. the

所述高阻气膜袋也可采用任何现有常规的材料制成。吸气剂也是常规材料,采用分散设置或采用层结构设置在芯板的表面。 The high gas barrier film bag can also be made of any conventional material. The getter is also a conventional material, and is arranged on the surface of the core plate in a dispersed arrangement or in a layered structure.

参见图1-图4,本发明制成的真空绝热板外形结构可以是常规的形状,在高阻气膜袋1的两端设有密封边3(参见图1)。也可将高阻气膜袋1两端的密封边3设在该高阻气膜袋1的两端的相对的一边,在与该密封边3相对的另一边设有与该封边吻合的咬合槽4。在施工时将相邻的两块保温板A1与A2封边3放置在对方的咬合槽4内(如图4所示),减小了相邻两块保温板之间的热桥厚度,提高了保温效果和施工效率。 Referring to Fig. 1-Fig. 4, the outer structure of the vacuum insulation panel made by the present invention can be a conventional shape, and the two ends of the high gas barrier film bag 1 are provided with sealing edges 3 (see Fig. 1). It is also possible to set the sealing edge 3 at both ends of the high-barrier gas film bag 1 on the opposite side of the two ends of the high-barrier gas film bag 1, and the other side opposite to the sealing edge 3 is provided with a occlusal groove matching the edge sealing 4. During construction, two adjacent insulation boards A1 and A2 are placed in the occlusal groove 4 of the other side (as shown in Figure 4), which reduces the thickness of the thermal bridge between the two adjacent insulation boards and improves Improve the insulation effect and construction efficiency.

Claims (6)

1.一种利用膨胀珍珠岩生产真空绝热板的方法,将芯材装入高阻气膜袋内,抽真空后封口,其特征在于,所述的芯材成分和重量份数为:膨胀珍珠岩60-90份、纤维 10-20份、真空活性稳定剂 3-6份,制作工艺包括如下步骤: 1. A method of utilizing expanded perlite to produce a vacuum insulation panel. The core material is packed into a high-barrier gas film bag and sealed after vacuuming. It is characterized in that the core material composition and parts by weight are: expanded pearl 60-90 parts of rock, 10-20 parts of fiber, 3-6 parts of vacuum active stabilizer, the production process includes the following steps: (1)配料:将所述材料投入混合机进行充分混合; (1) Ingredients: put the materials into the mixer for full mixing; (2)烘干:将搅拌均匀的混合料进行烘干,烘干温度为100-120℃,烘干过程中每隔8 分钟测定一次混合料的含水率,直至混合料的含水率达到0.5% 以下,停止烘干; (2) Drying: Dry the evenly stirred mixture at a temperature of 100-120°C. During the drying process, measure the moisture content of the mixture every 8 minutes until the moisture content of the mixture reaches 0.5%. Below, stop drying; (3)芯料成型:将烘干后的物料投入模具中,表面刮平; (3) Core molding: Put the dried material into the mold and scrape the surface; (4)压制成型:将模具放入压制机中压制成型,压制机的下降速度控制为3-7 cm/s,压力控制在20-80T/m2(4) Compression molding: Put the mold into a press machine and press it into a molding machine. The descending speed of the press machine is controlled at 3-7 cm/s, and the pressure is controlled at 20-80T/m 2 ; (5)包裹:将压制成型的芯板从模具中取出,在芯板的外围包裹一层无纺布,得到保温芯板; (5) Wrapping: Take out the pressed core board from the mold, and wrap a layer of non-woven fabric around the core board to get the insulation core board; (6)将保温芯板置入高阻气膜袋内抽真空,真空度为0.02-20Pa,然后封口; (6) Put the insulation core board into the high-resistance gas film bag to vacuumize, the vacuum degree is 0.02-20Pa, and then seal; 所述的纤维包括岩棉、玻纤、木质素纤维和玻璃陶瓷纤维中的一种以上以任意比例混合,所述的纤维长度为3-12mm,直径为0.2-13 微米; The fibers include more than one of rock wool, glass fibers, lignin fibers and glass ceramic fibers mixed in any proportion, the length of the fibers is 3-12 mm, and the diameter is 0.2-13 microns;     所述的真空活性稳定剂为活性炭、钡锂合金活化物、氧化钙、氧化镁、硅胶中的一种以上以任意比例混合的混合物。 The vacuum active stabilizer is a mixture of activated carbon, barium-lithium alloy activator, calcium oxide, magnesium oxide, and silica gel mixed in any proportion. 2.根据权利要求1 所述利用膨胀珍珠岩生产真空绝热板的方法,其特征在于:步骤(2)的烘干过程在步骤(1)的过程中同时进行。 2. The method for producing vacuum insulation panels using expanded perlite according to claim 1, characterized in that: the drying process of step (2) is carried out simultaneously in the process of step (1). 3.根据权利要求1 所述利用膨胀珍珠岩生产真空绝热板的方法,其特征在于:步骤(5)中所用无纺布为阻燃型无纺布,单位面积质量为35-100g/m23. The method for producing vacuum insulation panels using expanded perlite according to claim 1, characterized in that: the non-woven fabric used in step (5) is a flame-retardant non-woven fabric, and the mass per unit area is 35-100g/m 2 . 4.根据权利要求1 所述的利用膨胀珍珠岩生产真空绝热板的方法,其特征在于,所述的高阻气膜袋由外侧的防护层与内侧的密封层复合组成。 4. The method for producing vacuum insulation panels using expanded perlite according to claim 1, characterized in that, the high-barrier gas film bag is composed of an outer protective layer and an inner sealing layer. 5.根据权利要求4所述的利用膨胀珍珠岩生产真空绝热板的方法,其特征在于:所述的密封层包括铝箔、聚酯薄膜、尼龙薄膜、聚乙烯薄膜、聚氯乙烯薄膜、聚苯乙烯薄膜、聚偏二氯乙烯、聚乙烯醇薄膜、乙烯- 醋酸乙烯共聚物薄膜、乙烯/ 乙烯醇共聚物薄膜、聚碳酸酯薄膜、聚丙烯的一种以上复合而成;所述高阻气膜袋最外侧的保护层由玻纤布、无纺布、碳纤维织布、玄武岩纤维布、陶瓷纤维布的一种以上复合而成。 5. The method for producing vacuum insulation panels using expanded perlite according to claim 4, characterized in that: said sealing layer comprises aluminum foil, polyester film, nylon film, polyethylene film, polyvinyl chloride film, polystyrene It is composed of one or more of ethylene film, polyvinylidene chloride, polyvinyl alcohol film, ethylene-vinyl acetate copolymer film, ethylene/vinyl alcohol copolymer film, polycarbonate film, and polypropylene; the high gas barrier The outermost protective layer of the film bag is composed of more than one kind of glass fiber cloth, non-woven fabric, carbon fiber woven cloth, basalt fiber cloth and ceramic fiber cloth. 6.根据权利要求1 所述的利用膨胀珍珠岩生产真空绝热板的方法,其特征在于:在所述的高阻气膜袋的两端设有封边,该封边设在该高阻气膜袋的两端的相对的一边,在与该封边相对的另一边设有与该封边吻合的咬合槽。 6. The method of utilizing expanded perlite to produce vacuum insulation panels according to claim 1, characterized in that: edge seals are provided at both ends of the high-barrier gas film bag, and the edge seals are located on the high-barrier gas film bag. On the opposite side of the two ends of the film bag, the other side opposite to the sealing edge is provided with an engaging groove matching the sealing edge.
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CN105333266A (en) * 2015-12-01 2016-02-17 太仓清宇特种塑料有限公司 Thermal insulation composite material
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