CN102716808A - Flotation process for difficultly selected coal slime with high middle density substance content - Google Patents
Flotation process for difficultly selected coal slime with high middle density substance content Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000005188 flotation Methods 0.000 title abstract description 59
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- 238000007667 floating Methods 0.000 claims abstract description 16
- 238000000227 grinding Methods 0.000 claims abstract description 13
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- 238000000926 separation method Methods 0.000 claims description 17
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- 238000010494 dissociation reaction Methods 0.000 abstract description 3
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- 238000005516 engineering process Methods 0.000 description 3
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Abstract
一种高中间密度物含量难选煤泥的浮选工艺,由入浮煤泥调浆、调浆后煤泥浮选粗选、粗选精煤分级、分级后粗粒粗选精煤再磨再选、细粒粗选精煤精选五部分构成。采用浮选设备,并配合相应的浓缩分级设备与磨煤设备,组成浮选设备粗选—粗选精煤分级—粗粒粗选精煤磨煤、浮选—细粒粗选精煤单独精选工艺。入浮煤泥经过一次粗选后脱除大部分的高灰脉石矿物,减少了高灰细泥对后续煤泥磨浮过程的不利影响,通过粗选精煤粗粒级中煤和矸石连生体的解离和解离后煤泥的进一步浮选回收,解决高中间密度物含量难选煤泥分选产品质量和回收率之间的矛盾。其工艺简单,投资少,耗电量小,运行费用低。同传统分选工艺相比,分选效率高,可燃体回收率高,经济效益显著。
A kind of flotation process of refractory coal slime with high intermediate density content, including slurry adjustment of floating coal slurry, coarse selection of coal slime flotation after slurry adjustment, classification of coarse selection and clean coal, coarse coarse selection of clean coal after classification, and regrinding Re-selection, fine-grained coarse selection and clean coal selection are composed of five parts. The flotation equipment is used together with the corresponding concentration and classification equipment and coal grinding equipment to form a flotation equipment. Rough selection - rough selection of clean coal classification - coarse coarse selection of clean coal grinding, flotation - fine coarse selection of clean coal separate cleaning Choose craft. After a rough selection of the floating coal slime, most of the high-ash gangue minerals are removed, which reduces the adverse effects of the high-ash fine slime on the subsequent grinding and floating process of the coal slime. The dissociation of organisms and the further flotation recovery of coal slime after dissociation can solve the contradiction between the product quality and recovery rate of refractory coal slime with high intermediate density content. The process is simple, low investment, low power consumption, and low operating costs. Compared with the traditional sorting process, the sorting efficiency is high, the combustible body recovery rate is high, and the economic benefit is remarkable.
Description
技术领域 technical field
本发明涉及一种煤泥分选工艺,尤其是一种适用于高中间密度物含量难选煤泥的浮选工艺,属矿物分离技术领域。 The invention relates to a coal slime separation process, in particular to a flotation process suitable for refractory coal slime with high intermediate density content, and belongs to the technical field of mineral separation.
背景技术 Background technique
当煤泥中密度在1.4g/cm3-1.8g/cm3之间的物料重量占总物料的比重超过30%时,其可以被称为高中间密度物煤泥。当中间密度物含量高时,煤同矸石连生的颗粒多,通过浮选无法将煤同矸石实现有效分离,造成煤损失在尾煤中,或者矸石夹带在精煤中;当中间密度物含量低时,纯煤和纯矸石颗粒含量高,通过简单的浮选即可有效分离出煤和矸石。随着我国采煤机械化程度的提高、资源地质条件的恶化、选煤厂大型化建设及重介旋流器的广泛应用,煤泥比例急剧增加,特别是当-0.074mm微细粒煤泥含量高、粗颗粒煤泥中间密度物含量高、灰分高时,煤泥呈现易浮难选现象,可选性差。而选煤厂为了确保精煤灰分,往往通过控制浮选药剂用量、粗选精煤再选等工艺技术手段来保证精煤灰分合格,而使煤泥中的中间密度物最终进入浮选尾煤中,且细粒级煤泥也不能得到有效分选,浪费了资源、降低了选煤厂的经济效益。这对于我国优质稀缺肥焦煤资源来讲,更是一种极大的浪费。随着优质稀缺肥焦煤资源储量的不断减少,作为不可再生资源,对高中间密度物含量的难选煤泥进行高效分选显得尤为迫切。 When the weight of materials with a density between 1.4g/cm 3 and 1.8g/cm 3 in the slime accounts for more than 30% of the total material, it can be called high intermediate density slime. When the content of intermediate density is high, there are many particles of coal and gangue, and the coal and gangue cannot be effectively separated by flotation, resulting in coal loss in tailing coal, or gangue entrained in clean coal; when the content of intermediate density When it is low, the content of pure coal and pure gangue particles is high, and the coal and gangue can be effectively separated by simple flotation. With the improvement of my country's coal mining mechanization, the deterioration of resource geological conditions, the large-scale construction of coal preparation plants and the wide application of dense medium cyclones, the proportion of coal slime has increased sharply, especially when the content of -0.074mm fine-grained coal slime is high 1. When the intermediate density of coarse-grained coal slime is high and the ash content is high, the coal slime is easy to float and difficult to select, and the selectivity is poor. In order to ensure the ash content of clean coal, the coal preparation plant often controls the dosage of flotation agents, roughing and re-selecting clean coal to ensure that the ash content of clean coal is qualified, so that the intermediate density in the coal slime finally enters the flotation tailings. In addition, the fine-grained coal slime cannot be effectively sorted, which wastes resources and reduces the economic benefits of the coal preparation plant. This is a great waste for my country's high-quality and scarce fertilizer coking coal resources. With the continuous reduction of high-quality scarce fertile coking coal resource reserves, as a non-renewable resource, it is particularly urgent to efficiently sort the refractory coal slime with high intermediate density content.
常规的浮选工艺流程是将浮选入料经调浆处理后送入浮选柱(或浮选机),浮选柱(或浮选机)分选出精煤和尾矿,并进入各自的后续产品处理作业。该工艺主要用于常规易选煤泥的分选,并在我国应用多年,积累了丰富的经验,是我国目前煤泥浮选应用最广泛的浮选工艺。对于高中间密度物难选煤泥分选来说,该工艺普遍存在产品回收率和生产效率低的缺陷,严重制约了最终精煤产品质量。开发高中间密度物难选煤泥高效分选的关键技术已成为煤炭资源高效洁净利用过程中亟需解决的一个难题。 The conventional flotation process is to send the flotation feed material to the flotation column (or flotation machine) after pulping treatment, and the flotation column (or flotation machine) to separate clean coal and tailings, and enter the respective Subsequent product processing operations. This process is mainly used for the separation of conventional easy-to-select coal slime, and has been used in my country for many years, and has accumulated rich experience. It is currently the most widely used flotation process for coal slime flotation in my country. For the separation of high-intermediate-density refractory coal slime, the process generally has the defects of low product recovery and production efficiency, which seriously restricts the quality of the final clean coal product. The development of key technologies for efficient separation of high-intermediate density and difficult-to-separate coal slimes has become a problem that needs to be solved urgently in the process of efficient and clean utilization of coal resources.
发明内容 Contents of the invention
技术问题:本发明的目的在于克服已有技术中的不足,提供一种低成本、工艺简单、投资少、分选效率高、经济效益显著的高中间密度物含量难选煤泥分选的工艺方法。 Technical problem: the object of the present invention is to overcome the deficiencies in the prior art, and provide a low-cost, simple process, low investment, high sorting efficiency, significant economic benefits, and a process for sorting refractory coal slime with high intermediate density content method.
技术方案:本发明的高中间密度物含量难选煤泥的浮选工艺,包括用Ⅰ调浆设备对添加Ⅰ浮选药剂的入浮煤泥进行调浆;将调浆好的Ⅰ煤泥水送入Ⅰ浮选设备进行粗选作业,得到Ⅰ浮选精煤和Ⅰ浮选尾煤;还包括如下步骤: Technical solution: The flotation process of refractory coal slime with high intermediate density content of the present invention includes using I slurry mixing equipment to adjust the slurry of the floating coal slurry added with I flotation agent; sending the adjusted I slurry to Put into I flotation equipment for roughing operation to obtain I flotation clean coal and I flotation tailing coal; also include the following steps:
a.将Ⅰ浮选设备浮选出的Ⅰ浮选精煤送入浓缩设备进行浓缩处理,得到底流产品和溢流产品; a. Send the I flotation clean coal from the I flotation equipment to the concentration equipment for concentration treatment to obtain underflow products and overflow products;
b.将底流产品送入分级设备分级,得到筛上产物和筛下产物; b. The underflow product is sent to the classification equipment for classification, and the above-sieve product and the under-sieve product are obtained;
c.将筛上产物送入磨煤设备磨矿,得到磨后产品; c. The screened product is sent to the coal grinding equipment for grinding to obtain the ground product;
d.将添加Ⅱ浮选药剂的磨后产品送入Ⅱ调浆设备调浆,得到调浆好的Ⅱ煤泥水; d. Send the milled product added with II flotation agent to II pulping equipment for pulping to obtain the well-blended II coal slime water;
e.将Ⅱ煤泥水送入Ⅱ浮选设备进行分选,得到Ⅱ浮选精煤和Ⅱ浮选尾煤; e. Send the II coal slime water to the II flotation equipment for separation to obtain II flotation clean coal and II flotation tailing coal;
f.将溢流产品和筛下产物送入到Ⅲ调浆设备,添加Ⅲ浮选药剂进行调浆,得到调浆好的Ⅲ煤泥水; f. The overflow product and the under-screen product are sent to the III slurry mixing equipment, and the III flotation agent is added for slurry adjustment to obtain the well adjusted III coal slime water;
g.将Ⅲ煤泥水送入Ⅲ浮选设备进行分选,得到Ⅲ浮选精煤和Ⅲ浮选尾煤。 g. The III coal slime water is sent to the III flotation equipment for separation, and the III flotation clean coal and the III flotation tailing coal are obtained.
所述的分级设备采用分级粒度为0.125mm或0.15mm的分级旋流器或筛网旋流器;所述Ⅱ浮选设备分选出的Ⅱ浮选尾煤灰分高于40%时,作为最终尾煤产品;所述Ⅱ浮选设备分选出的Ⅱ浮选尾煤的灰分低于40%时,返回Ⅰ调浆设备再次调浆分选。 The classification equipment adopts a classification cyclone or a screen cyclone with a classification particle size of 0.125mm or 0.15mm; when the ash content of the tailings of the II flotation coal sorted by the II flotation equipment is higher than 40%, it is used as the final tailing coal product; when the ash content of the tailing coal of II flotation sorted by the II flotation equipment is lower than 40%, it is returned to the I slurry conditioning equipment for slurry conditioning and separation again.
有益效果:本发明是一种基于难选煤泥分选的实用技术,是对一种高中间密度物含量的难选煤泥进行高效分选的工艺流程。本发明首先利用浮选技术对高中间密度物含量的难选煤泥进行粗选作业,然后将得到的粗选粗精煤浓缩分级,分级后粗粒粗精煤再磨再选,细粒粗精煤单独精选,从而实现高中间密度物含量难选煤泥的高效分选。入浮煤泥经过一次粗选后脱除大部分的高灰脉石矿物,减少了高灰细泥对后续煤泥磨浮过程的不利影响,通过粗选精煤粗粒级中煤和矸石连生体的解离和解离后煤泥的进一步浮选回收,解决了高中间密度物含量难选煤泥分选产品质量和回收率之间的矛盾。本发明的优点在于:工艺简单,投资少,耗电量小,运行费用低。同传统分选工艺相比,分选效率高,经济效益显著。 Beneficial effects: the present invention is a practical technology based on the separation of refractory coal slime, and is a technological process for efficiently sorting refractory coal slime with high intermediate density content. In the present invention, firstly, the flotation technology is used to roughen the difficult-to-separate coal slime with high intermediate density content, and then the obtained coarsely-separated coarse-cleaned coal is concentrated and classified, and the coarse-grained coarse-cleaned coal is re-grinded and re-selected after classification, and the fine-grained coarse-grained coal The clean coal is selected separately, so as to realize the efficient separation of refractory coal slime with high intermediate density content. After a rough selection of the floating coal slime, most of the high-ash gangue minerals are removed, which reduces the adverse effects of the high-ash fine slime on the subsequent grinding and floating process of the coal slime. The dissociation of organisms and the further flotation recovery of the dissociated coal slime solve the contradiction between the product quality and recovery rate of the refractory coal slime with high intermediate density content. The invention has the advantages of simple process, low investment, low power consumption and low operating cost. Compared with the traditional sorting process, the sorting efficiency is high and the economic benefit is remarkable.
附图说明 Description of drawings
图1是本发明分选工艺流程框图。 Fig. 1 is a block diagram of the separation process of the present invention.
图2是本发明分选工艺设备系统图。 Fig. 2 is a system diagram of the separation process equipment of the present invention.
图中:A—Ⅰ调浆设备、B—Ⅰ浮选设备、C—浓缩设备、D—分级设备、E—磨煤设备、F—Ⅱ调浆设备、G—Ⅱ浮选设备、H—Ⅲ调浆设备、I—Ⅲ浮选设备。 In the picture: A—Ⅰ slurry mixing equipment, B—Ⅰ flotation equipment, C—concentrating equipment, D—classification equipment, E—coal grinding equipment, F—Ⅱ slurry mixing equipment, G—Ⅱ flotation equipment, H—Ⅲ Slurry equipment, I-III flotation equipment.
具体实施方式 Detailed ways
下面结合附图对本发明的一个实施作进一步的描述: An implementation of the present invention will be further described below in conjunction with accompanying drawing:
本发明的高中间密度物含量难选煤泥的浮选工艺,采用调浆设备、浮选设备B、浓缩设备C、分级设备D、磨煤设备E,其工艺步骤如下: The flotation process of the refractory coal slime with high intermediate density content of the present invention adopts slurry adjustment equipment, flotation equipment B, concentration equipment C, classification equipment D, and coal grinding equipment E, and its process steps are as follows:
a.将添加了Ⅰ浮选药剂1的入浮煤泥2送入Ⅰ调浆设备A,通过Ⅰ调浆设备A对添加Ⅰ浮选药剂1的入浮煤泥2进行调浆,得到调浆好的煤泥水3;
a. The floating
b.将调浆好的Ⅰ煤泥水3送入Ⅰ浮选设备B进行粗选作业,得到Ⅰ浮选精煤4和Ⅰ浮选尾煤5;
b. Slurry prepared I
c.将Ⅰ浮选设备B浮选出的Ⅰ浮选精煤4送入浓缩设备C进行浓缩处理,得到底流产品6和溢流产品7;
c. Send the I flotation
d.将底流产品6送入分级设备D分级,得到筛上产物8和筛下产物9;所述的分级设备采用分级粒度为0.125mm或0.15mm的分级旋流器或筛网旋流器。
d. The
e.将筛上产物8送入磨煤设备E磨矿,得到磨后产品10;
e. The
f.将添加Ⅱ浮选药剂11的磨后产品10送入Ⅱ调浆设备F调浆,得到调浆好的Ⅱ煤泥水12;
f. Send the milled
g.将Ⅱ煤泥水12送入Ⅱ浮选设备G进行分选,得到Ⅱ浮选精煤13和Ⅱ浮选尾煤14;
g. Send the II
h.将溢流产品7和筛下产物9送入到Ⅲ调浆设备H,添加Ⅲ浮选药剂15进行搅拌调浆,得到调浆好的Ⅲ煤泥水16;
h. The
i.将Ⅲ煤泥水16送入Ⅲ浮选设备I进行分选,得到Ⅲ浮选精煤17和Ⅲ浮选尾煤18;
i. Sending III
当Ⅱ浮选设备G的浮选出的Ⅱ浮选尾煤14灰分高于40%时,作为最终尾煤产品;
When the ash content of II
当Ⅱ浮选设备G的浮选出的Ⅱ浮选尾煤14灰分低于40%时,返回Ⅰ调浆设备A再次调浆分选。
When the ash content of
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CN103028486A (en) * | 2012-12-21 | 2013-04-10 | 中国矿业大学 | High and medium density coarse slime separation process |
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CN104741211A (en) * | 2015-03-02 | 2015-07-01 | 中国矿业大学 | Grading size mixing and bulk flotation separation process |
CN104815748A (en) * | 2015-04-26 | 2015-08-05 | 中国矿业大学 | Two-stage crushing and grinding flotation technology for coking medium coal |
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