CN102669154B - 一种灭蝇组合物及其应用 - Google Patents
一种灭蝇组合物及其应用 Download PDFInfo
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- CN102669154B CN102669154B CN201210154000.8A CN201210154000A CN102669154B CN 102669154 B CN102669154 B CN 102669154B CN 201210154000 A CN201210154000 A CN 201210154000A CN 102669154 B CN102669154 B CN 102669154B
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- fipronil
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- flour
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- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 230000002147 killing effect Effects 0.000 title claims abstract description 15
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 claims abstract description 90
- 239000005899 Fipronil Substances 0.000 claims abstract description 90
- 229940013764 fipronil Drugs 0.000 claims abstract description 90
- 239000003814 drug Substances 0.000 claims abstract description 20
- 229940079593 drug Drugs 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims description 53
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical group CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 22
- 235000013312 flour Nutrition 0.000 claims description 22
- 239000008267 milk Substances 0.000 claims description 22
- 210000004080 milk Anatomy 0.000 claims description 22
- 239000005946 Cypermethrin Substances 0.000 claims description 21
- 229960005424 cypermethrin Drugs 0.000 claims description 21
- 235000013336 milk Nutrition 0.000 claims description 21
- 235000015895 biscuits Nutrition 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 15
- 150000001241 acetals Chemical class 0.000 claims description 15
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 12
- 235000013339 cereals Nutrition 0.000 claims description 11
- 239000005909 Kieselgur Substances 0.000 claims description 10
- 241000257159 Musca domestica Species 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims description 6
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims description 6
- 235000019733 Fish meal Nutrition 0.000 claims description 5
- 244000068988 Glycine max Species 0.000 claims description 5
- 235000010469 Glycine max Nutrition 0.000 claims description 5
- 239000004467 fishmeal Substances 0.000 claims description 5
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 5
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- 244000291564 Allium cepa Species 0.000 claims description 4
- 235000002732 Allium cepa var. cepa Nutrition 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229930091371 Fructose Natural products 0.000 claims description 4
- 239000005715 Fructose Substances 0.000 claims description 4
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 4
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000008103 glucose Substances 0.000 claims description 4
- 235000015167 meat floss Nutrition 0.000 claims description 4
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 claims description 4
- 239000003016 pheromone Substances 0.000 claims description 4
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 239000004375 Dextrin Substances 0.000 claims description 3
- 229920001353 Dextrin Polymers 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 3
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- 229960000892 attapulgite Drugs 0.000 claims description 3
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 235000019991 rice wine Nutrition 0.000 claims description 3
- 235000000346 sugar Nutrition 0.000 claims description 3
- NIWFIJFHALTBRN-UHFFFAOYSA-N 2-methyl-5-propan-2-ylidenecyclopentan-1-one Chemical compound CC1CCC(=C(C)C)C1=O NIWFIJFHALTBRN-UHFFFAOYSA-N 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 235000019483 Peanut oil Nutrition 0.000 claims description 2
- 239000006004 Quartz sand Substances 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 2
- RHDGNLCLDBVESU-UHFFFAOYSA-N but-3-en-4-olide Chemical compound O=C1CC=CO1 RHDGNLCLDBVESU-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 235000005822 corn Nutrition 0.000 claims description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 235000021552 granulated sugar Nutrition 0.000 claims description 2
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000312 peanut oil Substances 0.000 claims description 2
- 229940100595 phenylacetaldehyde Drugs 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000008159 sesame oil Substances 0.000 claims description 2
- 235000011803 sesame oil Nutrition 0.000 claims description 2
- 235000013555 soy sauce Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
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- 239000000052 vinegar Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 2
- 241000779819 Syncarpia glomulifera Species 0.000 claims 1
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- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 abstract description 3
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- 238000013329 compounding Methods 0.000 description 15
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- 229930006000 Sucrose Natural products 0.000 description 13
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 11
- 229960005199 tetramethrin Drugs 0.000 description 11
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 8
- 239000005874 Bifenthrin Substances 0.000 description 8
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 8
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- 241000257226 Muscidae Species 0.000 description 6
- QQODLKZGRKWIFG-RUTXASTPSA-N [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-RUTXASTPSA-N 0.000 description 6
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
实施例编号 | 氟虫腈(g) | 氯氰菊酯(g) | 复配比例 |
1 | 0.0136g | 0.1364g | 1:10 |
2 | 0.025g | 0.125g | 1:5 |
3 | 0.075g | 0.075g | 1:1 |
4 | 0.125g | 0.025g | 5:1 |
5 | 0.0071g | 0.1429g | 1:20 |
6 | 0.1429g | 0.0071g | 20:1 |
7 | 0.1364g | 0.0136g | 10:1 |
组分A | 组分B | 组分A比例(%) | 组分B比例(%) | A:B比例 | 理论毒性指数 |
氟虫腈 | 氯氰菊酯 | 16.67% | 83.33% | 1:5 | 16.796 |
氟虫腈 | 氯氰菊酯 | 9.09% | 90.91% | 1:10 | 9.213 |
氟虫腈 | 氯氰菊酯 | 4.76% | 95.24% | 1:20 | 4.905 |
氟虫腈 | 氯氰菊酯 | 50% | 50% | 1:1 | 50.076 |
氟虫腈 | 氯氰菊酯 | 83.33% | 16.67% | 5:1 | 83.355 |
氟虫腈 | 氯氰菊酯 | 90.91% | 9.09% | 10:1 | 80.924 |
氟虫腈 | 氯氰菊酯 | 95.24% | 4.76% | 20:1 | 95.247 |
组分A | 组分B | A:B比例 | 共毒系数 | 组分A | 组分B | A:B比例 | 共毒系数 |
氟虫腈 | 高效氯氰菊酯 | 1:5 | 195 | 氟虫腈 | 功夫菊酯 | 1:5 | 183 |
氟虫腈 | 氟氯氰菊酯 | 1:5 | 154 | 氟虫腈 | 苯氰菊酯 | 1:5 | 165 |
氟虫腈 | 高效氟氯氰菊酯 | 1:5 | 168 | 氟虫腈 | 苯醚菊酯 | 1:5 | 174 |
氟虫腈 | 四溴菊酯 | 1:5 | 179 | 氟虫腈 | 溴氰菊酯 | 1:5 | 186 |
氟虫腈 | 四氟苯菊酯 | 1:5 | 214 | 氟虫腈 | 联苯菊酯 | 1:5 | 159 |
氟虫腈 | 氯氟醚菊酯 | 1:5 | 226 | - | - | - | - |
Claims (6)
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CN201210154000.8A CN102669154B (zh) | 2012-05-17 | 2012-05-17 | 一种灭蝇组合物及其应用 |
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CN201210154000.8A CN102669154B (zh) | 2012-05-17 | 2012-05-17 | 一种灭蝇组合物及其应用 |
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CN102669154A CN102669154A (zh) | 2012-09-19 |
CN102669154B true CN102669154B (zh) | 2014-05-28 |
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CN105685083A (zh) * | 2014-11-24 | 2016-06-22 | 江苏扬农化工股份有限公司 | 含有氯氟醚菊酯与氟虫腈的卫生杀虫组合物 |
JP6679972B2 (ja) | 2016-02-16 | 2020-04-15 | 住友化学株式会社 | 被覆農薬粒剤 |
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CN106665563A (zh) * | 2016-12-28 | 2017-05-17 | 武汉朗克环境科技有限公司 | 灭蝇剂及其制备方法 |
CN107258809A (zh) * | 2017-07-21 | 2017-10-20 | 无锡市林业总站 | 桔小实蝇食物引诱剂与化学药剂的协同防治方法 |
CN107751231A (zh) * | 2017-09-11 | 2018-03-06 | 开平市达豪日化科技有限公司 | 一种安全高效灭蝇药物 |
MX2018008741A (es) * | 2018-07-16 | 2020-01-17 | Arturo Echeverria Ortega Sergio | Composicion insecticida a base de cipermetrina y sus mezclas con compuestos con y sin gluten. |
CN112931521A (zh) * | 2021-02-24 | 2021-06-11 | 党惠才 | 一种诱虫剂配方及其制备方法 |
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