CN102661471A - Nanocomposite wear-resisting and anti-corrosion coating pipe fitting - Google Patents
Nanocomposite wear-resisting and anti-corrosion coating pipe fitting Download PDFInfo
- Publication number
- CN102661471A CN102661471A CN2012101052752A CN201210105275A CN102661471A CN 102661471 A CN102661471 A CN 102661471A CN 2012101052752 A CN2012101052752 A CN 2012101052752A CN 201210105275 A CN201210105275 A CN 201210105275A CN 102661471 A CN102661471 A CN 102661471A
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- Prior art keywords
- pipe fitting
- resisting
- corrosion
- wear
- coating
- Prior art date
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- 238000000576 coating method Methods 0.000 title claims abstract description 41
- 239000011248 coating agent Substances 0.000 title claims abstract description 40
- 238000005260 corrosion Methods 0.000 title claims abstract description 22
- 239000002114 nanocomposite Substances 0.000 title abstract 3
- -1 polyethylene Polymers 0.000 claims abstract description 14
- 229920000573 polyethylene Polymers 0.000 claims abstract description 11
- 239000004698 Polyethylene Substances 0.000 claims abstract description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 4
- 230000007797 corrosion Effects 0.000 claims description 18
- 230000002401 inhibitory effect Effects 0.000 claims description 14
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 238000009736 wetting Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 238000011282 treatment Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000006260 foam Substances 0.000 claims description 5
- 239000011858 nanopowder Substances 0.000 claims description 5
- 230000004913 activation Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 206010013786 Dry skin Diseases 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000009832 plasma treatment Methods 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 235000019157 thiamine Nutrition 0.000 claims description 3
- 150000003544 thiamines Chemical class 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 238000003851 corona treatment Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- 230000003044 adaptive effect Effects 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 239000004848 polyfunctional curative Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a nanocomposite wear-resisting and anti-corrosion coating pipe fitting which comprises a polyethylene pipe fitting and a coating which is coated on the outer wall of the pipe fitting. The coating comprises the following components by weight: 25-60 parts of epoxy resin, 1-15 parts of aluminium oxide nano-powder, 1-30 parts of diluent, 25-40 parts of amine normal temperature epoxy hardener and appropriate amount of coating additives. The nanocomposite wear-resisting and anti-corrosion coating pipe fitting is good in adhesion and significantly strengthens wear-resisting and anti-corrosion performance against the polyethylene pipe fitting, and the wear rate is reduced by more than 15%; and furthermore, the cost of raw material is low, the coating operation is convenient, the coated pipe fitting is better adaptive to the environment and has longer service life and important market value.
Description
Technical field
The present invention relates to a kind of nano combined wear-resisting, corrosion-inhibiting coating pipe fitting.
Background technique
Polyethylene pipe is one of most popular plastic tube in the world, the tenacity excellent of polyethylene pipe, shock resistance, nontoxic, and polyethylene pipe can be easy to be used widely through the molten solder assembling.At present, the pipeline that be used to feed water, buried pipeline all adopts polythene material mostly among the municipal engineering such as combustion gas.Wherein need use a large amount of electric melting pipe fittings, safe in utilization secure for guaranteeing pipeline, the performance requirement of electric melting pipe fittings is higher than the requirement of tubing, particularly the performance of wear-and corrosion-resistant aspect.Their working life of prolongation that paint spraying can be is easily and effectively carried out on the pipe fitting surface, improve their various performances.
The coating that is used for frosting must possess two primary conditions, and at first, coating must have good adhesion to plastic bottom material, and secondly, coating is the corrosion frosting too.Various its structures of different plastics are different with performance, and selectable coating variety is also different, and coating process also varies.At present, also relatively lack with the coating of wear-and corrosion-resistant and the research of application aspect with regard to polyethylene tube.
Summary of the invention
The purpose of this invention is to provide a kind of nano combined wear-resisting, corrosion-inhibiting coating pipe fitting, in order to solve defective and the deficiency that above-mentioned existing technology exists.
For realizing above-mentioned purpose, a kind of nano combined wear-resisting, corrosion-inhibiting coating pipe fitting of the present invention, the coating that it comprises polyethylene tube and is coated on the pipe fitting outer wall;
Said coating is combined by its weight ratio by following component:
Further, the lipophile aluminium sesquioxide nano-powder of said aluminium sesquioxide nano-powder for carrying out surperficial oleophylic modification via stearic acid, particle size range is 10~100nm;
Further; Described coating additive comprises more than one of wetting dispersing agent, levelling agent and foam breaker; Said wetting dispersing agent is that electroneutrality is gathered thiamines and polyester mixture wetting dispersing agent; Described levelling agent is the polyether-modified polysiloxane of non-response type, and described foam breaker is a modified polyorganosiloxane;
Further, said coating comprises 1~6 layer;
Further, during application, the polyvinyl piping materials outer wall is through surface activation treatment, because poly characteristics are that polarity is low, degree of crystallization is high, obtain the good comparison difficulty of filming of adhesion;
Said surface activation treatment is flame treatment, Corona discharge Treatment or plasma treatment;
Further, the application mode is Airless spraying, 60 ℃ of dryings of far infrared collimation method.
A kind of nano combined wear-resisting, corrosion-inhibiting coating pipe fitting provided by the invention, coating adhesion is good, has had significantly for the wear-and corrosion-resistant performance of polyethylene tube and has strengthened; Wear rate reduces more than 15%; And cost of material is cheap, and application is convenient, and the pipe fitting environmental suitability after the application is better; Longer service life has important market value.
Embodiment
Embodiment 1
A kind of nano combined wear-resisting, corrosion-inhibiting coating pipe fitting provided by the invention, it comprises polyethylene tube and the coating that is coated on the pipe fitting outer wall;
Said coating is combined by its weight ratio by following component:
Further, said aluminium sesquioxide nano-powder Mean particle diameter is 60nm;
Further, described coating additive comprises that the wetting dispersing agent electroneutrality gathers thiamines and polyester mixture wetting dispersing agent, and described levelling agent is the polyether-modified polysiloxane of non-response type, and described foam breaker is a modified polyorganosiloxane;
Further, said coating is 3 layers;
Further, during application, the polyvinyl piping materials outer wall is through plasma treatment;
Further, the application mode is Airless spraying, 60 ℃ of dryings of far infrared collimation method.
Embodiment 2
Said coating is combined by its weight ratio by following component:
Other conditions are with embodiment 1.
Claims (8)
2. according to said a kind of nano combined wear-resisting, the corrosion-inhibiting coating pipe fitting of claim 1, it is characterized in that the lipophile aluminium sesquioxide nano-powder of said aluminium sesquioxide nano-powder for carrying out surperficial oleophylic modification via stearic acid.
3. according to said a kind of nano combined wear-resisting, the corrosion-inhibiting coating pipe fitting of claim 1, it is characterized in that said aluminium sesquioxide particle diameter of nanometer powder scope is 10~100nm.
4. according to arbitrary said a kind of nano combined wear-resisting, the corrosion-inhibiting coating pipe fitting of claim 1~3; It is characterized in that described coating additive comprises more than one of wetting dispersing agent, levelling agent and foam breaker; Said wetting dispersing agent is that electroneutrality is gathered thiamines and polyester mixture wetting dispersing agent; Described levelling agent is the polyether-modified polysiloxane of non-response type, and described foam breaker is a modified polyorganosiloxane.
5. according to said a kind of nano combined wear-resisting, the corrosion-inhibiting coating pipe fitting of claim 4, it is characterized in that said coating comprises 1~6 layer.
6. according to said a kind of nano combined wear-resisting, the corrosion-inhibiting coating pipe fitting of claim 4, when it is characterized in that application, the polyvinyl piping materials outer wall is earlier through surface activation treatment.
7. according to said a kind of nano combined wear-resisting, the corrosion-inhibiting coating pipe fitting of claim 6, it is characterized in that said surface activation treatment is flame treatment, Corona discharge Treatment or plasma treatment.
8. according to said a kind of nano combined wear-resisting, the corrosion-inhibiting coating pipe fitting of claim 4, it is characterized in that the application mode is Airless spraying, 60 ℃ of dryings of far infrared collimation method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2012101052752A CN102661471A (en) | 2012-04-11 | 2012-04-11 | Nanocomposite wear-resisting and anti-corrosion coating pipe fitting |
Applications Claiming Priority (1)
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CN2012101052752A CN102661471A (en) | 2012-04-11 | 2012-04-11 | Nanocomposite wear-resisting and anti-corrosion coating pipe fitting |
Publications (1)
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CN102661471A true CN102661471A (en) | 2012-09-12 |
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CN2012101052752A Pending CN102661471A (en) | 2012-04-11 | 2012-04-11 | Nanocomposite wear-resisting and anti-corrosion coating pipe fitting |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103694849A (en) * | 2013-12-05 | 2014-04-02 | 江苏金波新材料科技有限公司 | Corrosion-resistant and wear-resistant pipe coating and preparation method thereof |
CN103725157A (en) * | 2013-12-05 | 2014-04-16 | 江苏金波新材料科技有限公司 | Anti-corrosion abrasion-proof polyethylene pipe |
CN104031521A (en) * | 2013-12-25 | 2014-09-10 | 广西宾阳县荣良新材料科技有限公司 | Wood composite coating |
CN105564001A (en) * | 2016-01-27 | 2016-05-11 | 招金矿业股份有限公司蚕庄金矿 | Method for pasting abrasion-resistant layer on surface of meltable non-metallic material and product treated through method |
CN106905748A (en) * | 2017-04-06 | 2017-06-30 | 广德瑞邦涂料有限公司 | A kind of transparent aluminum alloy electrophoresis paint |
CN114231151A (en) * | 2021-12-22 | 2022-03-25 | 天信管业科技集团有限公司 | Wear-resistant coating agent for oil pipe and preparation method of coating layer of wear-resistant coating agent |
CN114716714A (en) * | 2022-04-26 | 2022-07-08 | 广东中讯通讯设备实业有限公司 | High-strength PE power conduit and preparation method thereof |
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EP1152181A1 (en) * | 2000-05-05 | 2001-11-07 | Nupi S.p.A. | Multilayer plastic pipe with improved resistance to crack propagation |
CN1556162A (en) * | 2004-01-09 | 2004-12-22 | 南京工业大学 | Nano transparent wear-resistant composite coating |
US20070051418A1 (en) * | 2005-09-02 | 2007-03-08 | Rowles Brian A | Multilayer tubes |
CN1978699A (en) * | 2006-11-30 | 2007-06-13 | 浙江大学 | Method and apparatus for modifyig polymer high-molecular material surface |
CN101914358A (en) * | 2010-08-19 | 2010-12-15 | 四川德源石油天然气工程有限公司 | Epoxy viscose for manufacturing pipeline-crossing wear-resistant protective layer and preparation method thereof |
CN102391762A (en) * | 2011-09-23 | 2012-03-28 | 北京国泰瑞华硅藻应用科技有限公司 | Epoxy abrasion-resisting anticorrosive paint |
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2012
- 2012-04-11 CN CN2012101052752A patent/CN102661471A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1152181A1 (en) * | 2000-05-05 | 2001-11-07 | Nupi S.p.A. | Multilayer plastic pipe with improved resistance to crack propagation |
CN1556162A (en) * | 2004-01-09 | 2004-12-22 | 南京工业大学 | Nano transparent wear-resistant composite coating |
US20070051418A1 (en) * | 2005-09-02 | 2007-03-08 | Rowles Brian A | Multilayer tubes |
CN1978699A (en) * | 2006-11-30 | 2007-06-13 | 浙江大学 | Method and apparatus for modifyig polymer high-molecular material surface |
CN101914358A (en) * | 2010-08-19 | 2010-12-15 | 四川德源石油天然气工程有限公司 | Epoxy viscose for manufacturing pipeline-crossing wear-resistant protective layer and preparation method thereof |
CN102391762A (en) * | 2011-09-23 | 2012-03-28 | 北京国泰瑞华硅藻应用科技有限公司 | Epoxy abrasion-resisting anticorrosive paint |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103694849A (en) * | 2013-12-05 | 2014-04-02 | 江苏金波新材料科技有限公司 | Corrosion-resistant and wear-resistant pipe coating and preparation method thereof |
CN103725157A (en) * | 2013-12-05 | 2014-04-16 | 江苏金波新材料科技有限公司 | Anti-corrosion abrasion-proof polyethylene pipe |
CN103694849B (en) * | 2013-12-05 | 2016-04-27 | 江苏金波新材料科技有限公司 | Pipe coatings of a kind of anticorrosion antiwear and preparation method thereof |
CN103725157B (en) * | 2013-12-05 | 2016-08-17 | 江苏金波新材料科技有限公司 | A kind of polyethylene tube of anticorrosion antiwear |
CN104031521A (en) * | 2013-12-25 | 2014-09-10 | 广西宾阳县荣良新材料科技有限公司 | Wood composite coating |
CN105564001A (en) * | 2016-01-27 | 2016-05-11 | 招金矿业股份有限公司蚕庄金矿 | Method for pasting abrasion-resistant layer on surface of meltable non-metallic material and product treated through method |
CN106905748A (en) * | 2017-04-06 | 2017-06-30 | 广德瑞邦涂料有限公司 | A kind of transparent aluminum alloy electrophoresis paint |
CN114231151A (en) * | 2021-12-22 | 2022-03-25 | 天信管业科技集团有限公司 | Wear-resistant coating agent for oil pipe and preparation method of coating layer of wear-resistant coating agent |
CN114716714A (en) * | 2022-04-26 | 2022-07-08 | 广东中讯通讯设备实业有限公司 | High-strength PE power conduit and preparation method thereof |
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Application publication date: 20120912 |