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CN102653479A - Biological organic fertilizer prepared by using mushroom bran as raw material and preparation method thereof - Google Patents

Biological organic fertilizer prepared by using mushroom bran as raw material and preparation method thereof Download PDF

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Publication number
CN102653479A
CN102653479A CN2011100482890A CN201110048289A CN102653479A CN 102653479 A CN102653479 A CN 102653479A CN 2011100482890 A CN2011100482890 A CN 2011100482890A CN 201110048289 A CN201110048289 A CN 201110048289A CN 102653479 A CN102653479 A CN 102653479A
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organic fertilizer
fertilizer
bio
raw material
humic acid
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CN102653479B (en
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王建忠
詹德江
李广
江志阳
王颖
刘万国
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Jilin Wantong Group Shengtai Biological Technology Engineering Co ltd
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Liaoning Academy of Agricultural Sciences
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Abstract

The invention relates to a biological organic fertilizer, and particularly relates to a biological organic fertilizer prepared by using mushroom bran as a raw material and a preparation method thereof. The biological organic fertilizer is prepared by mixing mushroom bran, humic acid, raw chicken manure and a composite bacterial agent according to weight parts, and performing fermentation. On a weight basis, the ratio of the mushroom bran, humic acid, raw chicken manure and the composite bacterial agent is 1:0.08-0.1:0.08-0.1:1/300-1/400. The fertilizer of the invention can eliminate biological pollution of the mushroom bran; nutrient substances of the mushroom bran are made full use of for the production of the fertilizer; no harm is caused to the environment; and the reutilization of resources is realized.

Description

A kind of is that raw material is made biological organic fertilizer and preparation method thereof with the bacterium chaff
Technical field
The present invention relates to biological organic fertilizer, a kind of specifically is that raw material is made biological organic fertilizer and preparation method thereof with the bacterium chaff.
Background technology
The bacterium chaff is meant that with cotton seed hulls, wood sawdust, straw, corn cob and multiple kinds of crops stalk, industrial waste (vinasse etc.) be the waste residue behind the main raw material culturing edible fungus; Though wherein contain a large amount of robust fibre, xylogen and mycelium (containing rich in protein, amino acid, glucide, VITAMINs and trace element); But owing to behind the culturing edible fungus, have a big chunk bacterium chaff to can not get timely processing, kind of assorted bacterium and quantity can be geometricprogression at short notice to be increased; And the meta-bolites of these bacterium not only causes bacterium furancarboxylic acid degree higher; And also having some toxin in the meta-bolites, this not only pollutes to agroecological environment, and the edible fungus culturing after can giving brings very big hidden danger; The lighter can influence output and the quality of edible mushrooms, and is heavy then cause a large amount of breedings of disease and pest and spread.If the bacterium chaff long with storage period is applied directly in the soil, not only do not have the effect that improves edatope, and can improve soil-borne disease odds in the soil greatly.Along with improving constantly of standard of living, people are also increasing the consumers demand amount of edible mushrooms year by year, and the cultivated area of edible mushrooms also increases.How to handle and bring a large amount of bacterium chaff problems thereupon, become a very important environmental problem.
Show through test; Nutritive ingredient in the bacterium chaff is roughly following: the crude protein average content is about 8%, and crude fat average out to 0.8%, robust fibre on average are about 17%; NFE on average is about 40%, also contains trace element in the mineral substance such as abundant calcium, zinc, copper, phosphorus, iron, magnesium simultaneously.Nutritive substance contained in the bacterium chaff goes out of use for a long time, can not effectively be utilized, and very unfortunately, also be a kind of great waste.So the handling problem of bacterium chaff has in recent years obtained people's attention gradually, various treatment processs also gradually quilt invent.
Summary of the invention
The object of the invention is that the invention provides a kind of is that raw material is made biological organic fertilizer and preparation method thereof with the bacterium chaff.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is:
A kind of is that raw material is made biological organic fertilizer with the bacterium chaff: biological organic fertilizer is formed by bacterium chaff, humic acids, live chickens excrement and composite fungus agent mixed fermentation by weight; Count bacterium chaff: humic acids: live chickens excrement: composite fungus agent=1: 0.08-0.1: 0.08-0.1: 1/300-1/400 by weight.
Said bacterium chaff is the waste residue behind the main raw material culturing edible fungus from production mushroom, cotton seed hulls, wood sawdust, straw, corn cob and multiple kinds of crops stalk, industrial waste vinasse; Contain humic acids total amount >=40% in the humic acids, ph value<7.0, humic acids is 50 orders; Chicken manure is without the chicken manure that becomes thoroughly decomposed.
With the bacterium chaff is the preparation method that raw material is made biological organic fertilizer: with bacterium chaff, humic acids, live chickens excrement and composite fungus agent by weight 1: 0.08-0.1: 0.08-0.1: 1/300-1/400 mixes; Mixing the back evenly stirs; Regulate about water cut to 50% C: N=20-30: 1; Treat to carry out overturning when temperature rises to more than 50 ℃, ventilating fermentation 5-7 days, promptly obtain biological organic fertilizer.
Said gained biological organic fertilizer is through drying, but makes the fertilizer water cut reach granulation below 20% or pack obtains the refined biometric fertilizer.Said bacterium chaff piles high 500mm-700mm when fermenting, wide 1.5m, and long 20m's is trapezoidal.
The present invention has the following advantages:
1. the present invention processes biological organic fertilizer with the bacterium chaff through the biological bacteria fermentation; Can improve the utilization ratio of agricultural crop straw, cotton seed hulls and wood sawdust etc.; Not only fundamentally avoid the topsoil that brings because of crop straw burning; Can also improve the utilization ratio of this type waste, turn waste into wealth, elongate the industrial chain of mushroom industry.The present invention is to the quality examination of bacterium chaff; And, add the nutritive substance of suitable proportion according to concrete detection data, comprise and regulate pH value, the material of moisture and the mineral substance of some rich trace elements; And with this as carrier; Adding is to the useful vinelandii of soil, phosphate solubilizing bacteria, potassium bacterium and to stimulate the fungi etc. of the disease-resistant function of plant growth be the active bio source of core, under the prerequisite of realization to the harmless treatment of bacterium chaff, by detection means; Find out the optimum producting condition of bacterium furfuryl group matter, various active bios source and crop growth, produce biological organic fertilizer.Also can suit measures to local conditions to carry out working condition and change, produce all kinds of bio-organic fertilizer specials according to the different soils situation.
2. the present invention adopts the edible mushrooms health can change the rural area because of the long-term heap of the bacterium chaff situation smelly, the addle crossing current of rotting, and fundamentally finds the approach of a science recycle bacterium chaff.
3. adopt biological organic fertilizer of the present invention can reduce the use of a few kiloton inorganic fertilizers; Increase soil aggregate, make loosing soil, help water conservation, protect fertilizer, ventilate and promote root system development; For farm crop provide comfortable growing environment, for the rural ecological environmental improvement provides technical support.
4. the present invention further explores the symbiotic top condition in active bio source (comprising bacterium, fungi and actinomycetes), top condition that works out each step in the bacterium chaff fermenting process and the active bio source best life condition in bacterium furfuryl group body; Guarantee the ideal effect of biological organic fertilizer after use produced; Thereby change the mushroom farming and the bacterium chaff is abandoned or directly uses custom in the soil (because the acidity of bacterium chaff is stronger; And hazardous and noxious substances is more, directly uses and can cause the underproduction or total crop failure to some farm crop).
Embodiment
Embodiment 1
Fertilizer: be biological organic fertilizer after 50 kilograms of humic acidss, 50 kilogram of raw chicken manures, 1.5 kilograms of composite fungus agents and the mixed fermentations of 500 kilograms of bacterium chaffs.
The above-mentioned materials source is:
Composite fungus agent is produced by green source, Shenyang City biotechnology research, the agent of trade(brand)name organic material composting.The bacterial classification technical indicator is living bacteria count (every kind of quantity) 0.01 hundred million/gram; Moisture content≤35%; Assorted bacterium rate≤30%; PH value 5-8.
Contain total humic acid amount >=40% among the humic acids HA, derive from brown coal (weathered coal), ph value<7.0.
The chicken manure chicken manure of making a living.Contain crude protein 25.00%-27.00%, crude fat 1.40%, NFE 26.60%, robust fibre 12.70%, coarse ash 27.09% approximately, and a large amount of trace elements.
The bacterium chaff is the waste residue behind the main raw material culturing edible fungus from production mushroom, cotton seed hulls, wood sawdust, straw, corn cob and multiple kinds of crops stalk, industrial waste vinasse; Be that bacterium bacterium chaff is by the substratum behind the ordinary method production edible mushrooms; Producing the substratum of edible mushrooms is made up of major ingredient and auxiliary material; Content meter by weight, wherein major ingredient accounts for 92-98%, and auxiliary material accounts for 2-8%; Major ingredient is by cotton seed hulls, wood sawdust, straw, corn cob, bagasse, corn stalk powder, soya bean stem meal, wheat bran, rice chaff, rice husk, cotton straw powder, wheat straw, weeds, and bagasse, vinasse, vinegar are poor, 2~4 kinds of mixtures in xylose residue, rapeseed cake, pig manure, chicken manure, horsehit, cow dung, human excrement, pigsty fertilizer and the pond sludge soil are formed; Auxiliary material is made up of the 3-6 kind mixture in soybean cake powder, cotton seed cake, wheat bran, urea, composite fertilizer, superphosphate of lime, fused(calcium magnesium)phosphate, lime powder, terra alba, lime carbonate, plant ash, potassium primary phosphate, sucrose, brown sugar, ammoniacal liquor, dried silkworm chrysalis meal, glucose and the VITMAIN B1; The edible fungus bran mycelia is pure white, the material agllutination is real, nothing is gone mouldy and rotten composition the C of bacterium chaff: N=20-35: 1, and C: P=120-270: 1, through exsiccant bacterium chaff water cut 10-25%, the bacterium chaff particle diameter 0.2-1.0cm of pulverizing.
With above-mentioned fertilizer through detecting its living bacteria count (cfu)>=0.2 hundred million/g; Organic (in butt)>=25.0%; Moisture≤30%; PH value 5.5-8.5; Excrement colibacillus group number≤100/g; Induced worm egg death rate>=95%; Arsenic and compound thereof (in arsenic)≤75mg/kg; Cadmium and compound thereof (in cadmium)≤10mg/kg; Lead and compound thereof (in lead)≤100mg/kg; Chromium and compound thereof (in chromium)≤150mg/kg; Mercury and compound thereof (in mercury)≤5mg/kg, detected result shows that it meets the product technology requirement of NY 884-2004 biological organic fertilizer standard code.
Preparation:
50 kilograms of humic acidss, 50 kilogram of raw chicken manures, 1.5 kilograms of composite fungus agents are mixed with 500 kilograms of bacterium chaffs, mix the back and evenly stir, regulate about water cut to 50% C: N=20-30: 1; Treat to carry out overturning when temperature rises to more than 50 ℃, ventilating fermentation 5-7 days, promptly obtain biological organic fertilizer.
Use:
Experimental field soil is brown earth, and preceding crop is a cucumber.Nearly 1.0 mu of area (comprise spacing track, observe road and isolation strip) experimental field.
Confession studies thing: tomato, and kind: powder is precious, and transplant and field planting the back of growing seedlings.
Fertilising scheme: the fertilization principle of taking to wait nutrition
The embodiment of the invention provides fertilizer: 358 kilograms/mu
Compound organic and inorganic fertilizer: 204 kilograms/mu (wherein NPK is 25 kilograms, 179 kilograms of biological organic fertilizers)
NPK: 50 kilograms/mu (N: P: K is 15: 15: 15)
Conventional fertilizer application: 50 kilograms (N: P: K is 13: 17: 15)
The fertilizer of all different proportionings is base fertilizer at the field planting previous crops all; Disposable ditch applies in the corresponding district, and by randomized block design, 3 processing are established in test altogether; 3 repetitions are established in each processing; Be respectively the fertilizer that the bacterium chaff is produced, compound organic and inorganic fertilizer and NPK compare (also can think 4 processing) with the conventional fertilizer application of locality.Tomato was grown seedlings in early Febuary, 2009, and early March is transplanted in Nursery, and April 11 is in the pilot region field planting; June 4 began to gather, the completion of gathering July 6, experimental plot; Long 5.2 meters, 1.0 meters of every row spacings, every ridge plants two row; 0.5 meter of line-spacing, 0.25 meter of spacing in the rows is all established two row guard rows on every side.About 21 strains of every row are carried out field management by routine.
The influence of different fertilization to output calculated in results backs, can know referring to table 1, uses the output of biological organic fertilizer, compound organic and inorganic fertilizer and NPK and do not have significant difference, but between their threes and conventional fertilizer application utmost point significant difference is arranged.The MV of output after the various fertilizer treatment; The rate ratio of using biological organic fertilizer and compound organic and inorganic fertilizer is used respectively low 6.62% and 4.93% of NPK; This maybe be because the biological organic fertilizer nutrient discharges slowly relevant; The output of conventional fertilizer application is starkly lower than the output of using biological organic fertilizer, compound organic and inorganic fertilizer and NPK, maybe be improper relevant with the nutrient proportioning of the used fertilizer of conventional fertilizer application.
Different fertilization is to the influence of Tomato Quality; Can know from table 2; After using different fertilizer, each content of handling solubility total reducing sugar, soluble solid, vitamins C and the nitrate salt of back tomato does not all have significant difference, and this possibly receive the higher influence of soil background nutrient content; Also possibly be that manure trial is only carried out this time, the influence that different fertilizer is handled aspect Tomato Quality does not also thoroughly manifest.But MV from each Q factor; Solubility total reducing sugar, soluble solid and the Vitamin C content of tomato of using biological organic fertilizer is higher slightly than the content of using compound organic and inorganic fertilizer, NPK and conventional fertilizer application; And the content of nitrate salt will hang down a bit slightly, can reflect that biological organic fertilizer helps improve the trend of Tomato Quality in this manure trial.
Different fertilization is to the influence of soil physical and chemical property; Can know referring to table 3; Use the embodiment of the invention soil weight and the porosity of fertilizer and compound organic and inorganic fertilizer is provided and use NPK and conventional fertilizer application there were significant differences; Use the embodiment of the invention and provide before unit weight and porosity and the fertilising of fertilizer, compound organic and inorganic fertilizer, NPK and conventional fertilizer application also there were significant differences; There were significant differences with using compound organic and inorganic fertilizer, NPK and conventional fertilizer application to use the soil organic matter content that the embodiment of the invention provides fertilizer; Use before organic content that the embodiment of the invention provides fertilizer, compound organic and inorganic fertilizer, NPK and conventional fertilizer application and the fertilising also there were significant differences; The content of the fast nitrogen of 5 kinds of soil, fast phosphorus and fast potassium does not have significant difference; But using the embodiment of the invention provides the soil speed nitrogen content of fertilizer higher slightly; Use higher slightly before than fertilising of soil speed phosphorus that the embodiment of the invention provides fertilizer, compound organic and inorganic fertilizer, NPK and conventional fertilizer application, using the embodiment of the invention, to provide the fast potassium ratio of fertilizer and compound organic and inorganic fertilizer soil to use before NPK, conventional fertilizer application and the fertilising higher slightly.
To sum up, from analytical results, the embodiment of the invention provides fertilizer really can improve Soil structure, increases the ventilation property of soil, has explained that also the embodiment of the invention provides the nutrient release to birth ratio of fertilizer slower, is fit to tomato to the nutrient absorbing characteristics.Provide fertilizer for improving the soil it is thus clear that use the embodiment of the invention, there is significant effect the supply mode aspect that changes soil nutrient, helps improvement of soil fertility, realizes sustainable using of land resources.
Table 1 different fertilization is to the influence of tomato ultimate production
Figure BDA0000048367360000051
Table 2 different fertilization is to influence (the tomato sampling time: 2009.06.22) of Tomato Quality
Figure BDA0000048367360000052
Table 3 different fertilization is to the influence of soil physical and chemical property
Figure BDA0000048367360000061
Embodiment 2
Fertilizer: be biological organic fertilizer after 40 kilograms of humic acidss, 40 kilogram of raw chicken manures, 1.5 kilograms of composite fungus agents and the mixed fermentations of 500 kilograms of bacterium chaffs.
Preparation: 540 kilograms of humic acidss, 40 kilogram of raw chicken manures, 1.5 kilograms of composite fungus agents are mixed with 500 kilograms of bacterium chaffs, mix the back and evenly stir, regulate about water cut to 50% C: N=20-30: 1; Treat to carry out overturning when temperature rises to more than 50 ℃, ventilating fermentation 5-7 days, promptly obtain biological organic fertilizer.
Use:
Above-mentioned materials is applied to 1 mu of ground, the plantation Chinese cabbage, yield increased group (mu is used 1000 kilograms of bacterium chaffs) output increases by 8.4%.
Embodiment 3
Fertilizer: bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.08: 0.1 by weight: 1/300, be biological organic fertilizer after the mixed fermentation.
Preparation: with bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.08: 0.1 by weight: 1/300 mixes, and mixes the back and evenly stirs, and regulates about water cut to 50% C: N=20-30: 1; Treat to carry out overturning when temperature rises to more than 50 ℃, ventilating fermentation 5-7 days, promptly obtain biological organic fertilizer.
Embodiment 4
Fertilizer: bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.1: 0.08 by weight: 1/400, be biological organic fertilizer after the mixed fermentation.
Preparation: with bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.1: 0.08 by weight: 1/400 mixes, and mixes the back and evenly stirs, and regulates about water cut to 50% C: N=20-30: 1; Treat to carry out overturning when temperature rises to more than 50 ℃, ventilating fermentation 5-7 days, promptly obtain biological organic fertilizer.
Embodiment 5
Fertilizer: bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.09: 0.1 by weight: 1/300, be biological organic fertilizer after the mixed fermentation.
Preparation: with bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.09: 0.1 by weight: 1/300 mixes, and mixes the back and evenly stirs, and regulates about water cut to 50% C: N=20-30: 1; Treat to carry out overturning when temperature rises to more than 50 ℃, ventilating fermentation 5-7 days, promptly obtain biological organic fertilizer.
Embodiment 6
Fertilizer: bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.09: 0.09 by weight: 1/400, be biological organic fertilizer after the mixed fermentation.
Preparation: with bacterium chaff, humic acids, live chickens excrement and composite fungus agent 1: 0.09: 0.09 by weight: 1/400 mixes, and mixes the back and evenly stirs, and regulates about water cut to 50% C: N=20-30: 1; Treat to carry out overturning when temperature rises to more than 50 ℃, ventilating fermentation 5-7 days, promptly obtain biological organic fertilizer.

Claims (5)

1.一种以菌糠为原料制造生物有机肥,其特征在于:生物有机肥由菌糠、腐植酸、生鸡粪和复合菌剂按重量份数混合发酵而成;按重量份数计,菌糠∶腐植酸∶生鸡粪∶复合菌剂=1∶0.08-0.1∶0.08-0.1∶1/300-1/400。1. a kind of bio-organic fertilizer is manufactured as raw material with bacterium chaff, it is characterized in that: bio-organic fertilizer is formed by the mixed fermentation of bacterium chaff, humic acid, raw chicken manure and compound bacterial agent by weight; Bacteria bran: humic acid: raw chicken manure: composite bacterial agent = 1: 0.08-0.1: 0.08-0.1: 1/300-1/400. 2.按权利要求1所述的以菌糠为原料制造生物有机肥,其特征在于:所述菌糠来自生产蘑菇、棉籽壳、锯木屑、稻草、玉米芯及多种农作物秸秆、工业废料酒糟为主要原料栽培食用菌后的废渣;腐植酸中含腐植酸总量≥40%,ph值<7.0,腐植酸为50目;鸡粪为未经腐熟的鸡粪。2. According to claim 1, the bio-organic fertilizer is produced with fungus chaff as raw material, characterized in that: said fungus chaff comes from the production of mushrooms, cottonseed hulls, sawdust, straw, corncobs, various crop straws, and industrial waste distiller's grains The waste residue after cultivating edible fungi as the main raw material; the total amount of humic acid contained in humic acid is ≥ 40%, the pH value is less than 7.0, and the humic acid is 50 mesh; chicken manure is unripe chicken manure. 3.一种以菌糠为原料制造生物有机肥的制备方法,其特征在于:将菌糠、腐植酸、生鸡粪和复合菌剂按重量份数1∶0.08-0.1∶0.08-0.1∶1/300-1/400混合,混合后均匀搅拌,调节含水量至50%左右,C∶N=20-30∶1;待温度上升至50℃以上时进行翻倒,通风发酵5-7天,即得到生物有机肥。3. A preparation method for producing bio-organic fertilizer with fungus chaff as raw material, characterized in that: the fungus chaff, humic acid, raw chicken manure and composite bacterial agent are in parts by weight 1: 0.08-0.1: 0.08-0.1: 1 /300-1/400 mix, stir evenly after mixing, adjust the water content to about 50%, C:N=20-30:1; when the temperature rises above 50°C, turn it over, ventilate and ferment for 5-7 days, That is, bio-organic fertilizer is obtained. 4.按权利要求3所述的以菌糠为原料制造生物有机肥的制备方法,其特征在于:所述所得生物有机肥经干燥,使肥料含水量达到20%以下可造粒或装袋得到成品生物有机肥。4. The method for preparing bio-organic fertilizer with fungus chaff according to claim 3, characterized in that: the obtained bio-organic fertilizer is dried so that the water content of the fertilizer reaches below 20% and can be obtained by granulation or bagging Finished bio organic fertilizer. 5.按权利要求3所述的以菌糠为原料制造生物有机肥的制备方法,其特征在于:所述菌糠发酵时堆成高500mm-700mm,宽1.5m,长20m的梯形。5. The preparation method for producing bio-organic fertilizer by using fungus chaff as raw material according to claim 3, characterized in that: the fungus chaff is piled into a trapezoid with a height of 500mm-700mm, a width of 1.5m and a length of 20m during fermentation.
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CN106631546A (en) * 2016-09-08 2017-05-10 西北农林科技大学 Bio-organic fertilizer and preparation method thereof
CN106747713A (en) * 2016-11-30 2017-05-31 河池市金城江区科学技术情报研究所 A kind of mulberry tree base manure
CN107793182A (en) * 2017-11-01 2018-03-13 广西博白县润百种养专业合作社 A kind of passion fruit implantation methods based on new-type fertilizer
CN107801578A (en) * 2017-11-01 2018-03-16 广西博白县润百种养专业合作社 A kind of passion fruit implantation methods based on fermentation fertilizer
CN108083947A (en) * 2017-12-26 2018-05-29 福建农林大学 A kind of special organic-inorganic compound fertilizer for tomato
CN108218554A (en) * 2017-12-07 2018-06-29 常州市瑞泰物资有限公司 A kind of method that fertilizer is prepared using edible fungus bran
CN108812064A (en) * 2018-05-30 2018-11-16 江苏圣福来生态农业有限公司 A kind of method of cultured mushroom
CN109169167A (en) * 2018-10-10 2019-01-11 中国科学院沈阳应用生态研究所 One kind manufacturing forestry seedling medium and preparation method thereof by raw material of mushroom bran
CN110845258A (en) * 2019-12-11 2020-02-28 吉林农业大学 Environment-friendly bio-organic fertilizer and preparation method thereof
CN111635266A (en) * 2020-06-04 2020-09-08 贵州省化工研究院 Organic fertilizer for planting hollow plums prepared by using waste edible fungus sticks and preparation method thereof
CN114180996A (en) * 2021-11-29 2022-03-15 温州大学 Liquid organic fertilizer and preparation method and application thereof

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