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CN102650759B - LCD (Liquid crystal display) panel and manufacturing method thereof - Google Patents

LCD (Liquid crystal display) panel and manufacturing method thereof Download PDF

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Publication number
CN102650759B
CN102650759B CN201210003686.0A CN201210003686A CN102650759B CN 102650759 B CN102650759 B CN 102650759B CN 201210003686 A CN201210003686 A CN 201210003686A CN 102650759 B CN102650759 B CN 102650759B
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CN
China
Prior art keywords
liquid crystal
array base
base palte
color membrane
membrane substrates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201210003686.0A
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Chinese (zh)
Other versions
CN102650759A (en
Inventor
谷新
柳在健
姚继开
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BOE Technology Group Co Ltd
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BOE Technology Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BOE Technology Group Co Ltd filed Critical BOE Technology Group Co Ltd
Priority to CN201210003686.0A priority Critical patent/CN102650759B/en
Publication of CN102650759A publication Critical patent/CN102650759A/en
Priority to PCT/CN2012/083433 priority patent/WO2013102367A1/en
Application granted granted Critical
Publication of CN102650759B publication Critical patent/CN102650759B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/13378Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
    • G02F1/133788Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/133742Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers for homeotropic alignment
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
    • G02F1/13775Polymer-stabilized liquid crystal layers

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Liquid Crystal (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The embodiment of the invention provides a manufacturing method of an LCD (Liquid crystal display) panel, relating to the LCD panel manufacturing field. According to the invention, ultraviolet (UV) active molecules are added to liquid crystal material and the ultraviolet active molecules form a polymer film on a horizontal orientation film, so the anchoring energy between the orientation film and the liquid crystal molecules is increased and the respond speed of the liquid crystal is accelerated. The method for manufacturing the LCD panel includes the following steps: respectively coating horizontal orientation material on an array substrate and a color film substrate, and irradiating the substrates through polarized UV light for the first time to get the horizontal orientation films in a set direction on the array substrate and the color film substrate; filling the liquid crystal material blended with the UV active molecules into a liquid crystal case formed by the array substrate and the color film substrate after the array substrate and the color film substrate are encased and aligned; irradiating the array substrate and the color film substrate which are encased and aligned through polarized UV light for the second time so that the UV active molecules in the liquid crystal material can be subjected to polymerization reaction to form a thin polymer film on the horizontal orientation film. The method provided by the embodiment of the invention is used for manufacturing LCD panels.

Description

A kind of liquid crystal panel and manufacture method thereof
Technical field
The present invention relates to liquid crystal panel technical field, relate in particular to a kind of liquid crystal panel and manufacture method thereof.
Background technology
In recent years along with the continuous progress of science and technology, LCD (Liquid Crystal Display liquid crystal display) technology constantly perfect, it is low with energy consumption, is easy to panelized, and the advantages such as environmental protection occupy very important status, demonstration field.The narrower meeting in visual angle of LCD causes contrast to decline, when visual angle is excessive, can there is the phenomenon of gray scale and colour reversal, have a strong impact on the display quality of LCD, in order to improve the demonstration character of LCD, in prior art, there is the method for a variety of solutions visual angle problem, as in-plane switching mode (IPS), fringe field switching mode (FFS) and multidomain vertical plane pattern of rows and columns (MVA) etc.
Light alignment method during LCD manufactures, comprise light isomery, photo-crosslinking, light degradation etc., utilize polarized ultraviolet to irradiate the film that contains photosensitive group, make its film that forms orientation homogeneous, overcome the problem such as static, dust in fringe field switching mode (FFS) method for alignment rubbing.
Light alignment technique under vertical electric field pattern has had widespread use, when but the in-plane switching mode (IPS) under horizontal electric field mode, fringe field switching mode (FFS) need to adopt light alignment technique, but during because of the interior rotation of liquid crystal face, need very large anchoring energy, but do not have horizontal alignment material can form that alignment films that alignment capability is stronger provides and liquid crystal molecule between this anchoring energy, so apply and be restricted under horizontal electric field mode.
Summary of the invention
Embodiments of the invention provide a kind of liquid crystal panel and manufacture method thereof, can strengthen the alignment capability of alignment films, thereby strengthen the anchoring energy between alignment films and liquid crystal molecule.
For achieving the above object, embodiments of the invention adopt following technical scheme:
On the one hand, provide a kind of liquid crystal panel, comprise color membrane substrates and array base palte to box, between described color membrane substrates and described array base palte, be filled with liquid crystal material;
On described color membrane substrates and array base palte, be formed with alignment films, described alignment films be comprise horizontal alignment material form horizontal alignment film and the laminated film of thin polymer film; Wherein, described thin polymer film is formed by the polymerization of ultraviolet light bioactive molecule, and described thin polymer film is formed on described horizontal alignment film.
On the other hand, provide a kind of manufacture method of liquid crystal panel, comprising:
On array base palte and color membrane substrates, apply respectively horizontal alignment material, and carry out polarized ultraviolet irradiation for the first time, obtain being positioned at the horizontal alignment film on described array base palte and color membrane substrates;
The liquid crystal material that is mixed with ultraviolet light bioactive molecule is filled in the liquid crystal cell that described array base palte becomes box-like with described color membrane substrates;
To described, panel after box is carried out to polarized ultraviolet irradiation for the second time, to make the described ultraviolet light bioactive molecule polymerization reaction take place in described liquid crystal material, on described horizontal alignment film, form thin polymer film, obtain described liquid crystal panel.
The liquid crystal panel that the embodiment of the present invention provides and manufacture method thereof, on array base palte and color membrane substrates, apply respectively horizontal alignment material, carrying out polarized ultraviolet for the first time irradiates, in the box forming, add the liquid crystal material that is mixed with ultraviolet light bioactive molecule again, and again carry out polarized ultraviolet irradiation, make ultraviolet light bioactive molecule polymerization reaction take place, on horizontal alignment film, form thin polymer film.Under the acting in conjunction of thin polymer film and horizontal alignment film, between alignment films and liquid crystal molecule, there is stronger interaction, therefore increased the acting force of alignment films and liquid crystal molecule, and then strengthen the anchoring energy between alignment films and liquid crystal molecule, strengthen the stability of liquid crystal molecular orientation, accelerated the response time of liquid crystal simultaneously.
Brief description of the drawings
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, to the accompanying drawing of required use in embodiment or description of the Prior Art be briefly described below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, do not paying under the prerequisite of creative work, can also obtain according to these accompanying drawings other accompanying drawing.
A kind of liquid crystal panel structure schematic diagram that Fig. 1 provides for the embodiment of the present invention;
The LCD panel manufacturing method schematic flow sheet that Fig. 2 provides for the embodiment of the present invention;
The another liquid crystal panel structure schematic diagram that Fig. 3 provides for the embodiment of the present invention;
The liquid crystal panel structure schematic diagram again that Fig. 4 provides for the embodiment of the present invention.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtaining under creative work prerequisite, belong to the scope of protection of the invention.
The liquid crystal panel that the embodiment of the present invention provides, as shown in Figure 1, comprising:
Color membrane substrates 11 to box and array base palte 12.
Wherein, the alignment films on color membrane substrates 11 is horizontal alignment film 131 and the laminated film of thin polymer film 151, and thin polymer film is formed on horizontal alignment film 131, contacts with liquid crystal molecule 14.
Alignment films on array base palte 12 is also horizontal alignment film 132 and the laminated film of thin polymer film 152, and thin polymer film is formed on horizontal alignment film 132, contacts with liquid crystal molecule 14.
Further, color membrane substrates 11 is 3.6 μ m with array base palte 12 to maintaining box after box thick, above-mentioned thin polymer film the 151, the 152nd, by containing in the liquid crystal material of filling in box, 15 polymerizations of ultraviolet light bioactive molecule form, wherein, the manufacture process of thin polymer film 151,152 will describe in detail in following embodiment of the method, no longer launch at this.
The liquid crystal panel that the embodiment of the present invention provides, the alignment films forming on substrate includes horizontal alignment film and thin polymer film.Between the alignment films that thin polymer film and horizontal alignment film are compounded to form and liquid crystal molecule, have stronger interaction, can provide and liquid crystal between larger anchoring energy, thereby strengthened the stability of liquid crystal aligning, accelerated the response time of liquid crystal.
The manufacture method of the liquid crystal panel that the embodiment of the present invention provides, as shown in Figure 2, comprising:
S201, on array base palte and color membrane substrates, apply respectively horizontal alignment material, and carry out polarized ultraviolet for the first time and irradiate, obtain being positioned at the horizontal alignment film on array base palte and color membrane substrates.
Exemplary, on pair array substrate and color membrane substrates, apply respectively after horizontal alignment material, horizontal alignment material can be Coumarins material, cinnamate derivative material, polyvinylpyridine class material, one or more of the materials such as polyvinyl benzopyrrole ketone, can use wavelength for 254nm, luminous energy be 0.1~10J/cm 2polarized ultraviolet it is irradiated, wherein most preferred luminous energy is 1J/cm 2, through irradiating, horizontal alignment material can direction as required form horizontal alignment film, and the present embodiment is given an example with the alignment films that forms horizontal direction, but does not do any restriction with this.
S202, the liquid crystal material that is mixed with ultraviolet light bioactive molecule is filled in the liquid crystal cell that array base palte becomes box-like with color membrane substrates.
Further, ultraviolet light bioactive molecule can be vinyl benzene ring, one or both mixing in vinylpyridine.
Concrete, as shown in Figure 3, can be that the liquid crystal material that is 0.1%~5% containing ultraviolet light bioactive molecule 15 mass percent concentrations mixing is dropped on the color membrane substrates 11 that has formed horizontal alignment film 131 in S201, sealed plastic box is coated on the array base palte 12 that has formed horizontal alignment film 132 in S201;
Or, the liquid crystal material that ultraviolet light bioactive molecule 15 mass percent concentrations are 0.1%~5% that contains mixing is dropped on the array base palte that has formed horizontal alignment film 132 in S201, sealed plastic box is coated on the color membrane substrates that has formed horizontal alignment film 131 in S201.In the present embodiment, color membrane substrates 11 and array base palte 12 are to after box, and maintaining box thick is for example 3.6 μ m.
S203, the panel to after box is carried out for the second time to polarized ultraviolet irradiate, to make the ultraviolet light bioactive molecule polymerization reaction take place in liquid crystal material, on horizontal alignment film, form thin polymer film, obtain liquid crystal panel.
Exemplary, as shown in Figure 3, irradiating the good panel of box being carried out to ultraviolet polarisation for the second time, light source can adopt 310nm, and energy is 5~50mJ/cm 2, to make the ultraviolet light bioactive molecule polymerization reaction take place in liquid crystal material, on horizontal alignment film 131, form on thin polymer film 151 and horizontal alignment film 132 and form thin polymer film 152 respectively.
Now, because liquid crystal molecule can unifiedly be orientated under the effect of horizontal alignment film, irradiate by this secondary polarized ultraviolet, the ultraviolet light bioactive molecule polymerization reaction take place in liquid crystal molecule forms thin polymer film on horizontal alignment film.Like this, between the thin polymer film 151,152 obtaining and liquid crystal molecule, there is strong interaction, increase the interaction between alignment films and the liquid crystal molecule that thin polymer film and horizontal alignment film be compounded to form, can make the anchoring energy between alignment films and liquid crystal molecule increase, thereby strengthen the stability of liquid crystal molecular orientation, accelerated the response time of liquid crystal.
The above; be only the specific embodiment of the present invention, but protection scope of the present invention is not limited to this, any be familiar with those skilled in the art the present invention disclose technical scope in; can expect easily changing or replacing, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of described claim.

Claims (8)

1. a liquid crystal panel, comprises color membrane substrates and array base palte to box, between described color membrane substrates and described array base palte, is filled with liquid crystal material, it is characterized in that,
On described color membrane substrates and array base palte, be formed with alignment films, described alignment films be comprise horizontal alignment material form horizontal alignment film and the laminated film of thin polymer film; Wherein, described thin polymer film is formed by the polymerization of ultraviolet light bioactive molecule, and described thin polymer film is formed on described horizontal alignment film, and described ultraviolet light bioactive molecule is one or both mixing in vinyl phenyl ring or vinylpyridine.
2. liquid crystal panel according to claim 1, is characterized in that, described horizontal alignment material is one or more mixing in Coumarins material, cinnamate derivative material, polyvinylpyridine class material or polyvinyl benzopyrrole ketone material.
3. a manufacture method for liquid crystal panel, is characterized in that, comprising:
On array base palte and color membrane substrates, apply respectively horizontal alignment material, and carry out polarized ultraviolet irradiation for the first time, obtain being positioned at the horizontal alignment film on described array base palte and color membrane substrates;
The liquid crystal material that is mixed with ultraviolet light bioactive molecule is filled in the liquid crystal cell that described array base palte becomes box-like with described color membrane substrates, and described ultraviolet light bioactive molecule is one or both mixing in vinyl phenyl ring or vinylpyridine;
To described, panel after box is carried out to polarized ultraviolet irradiation for the second time, to make the described ultraviolet light bioactive molecule polymerization reaction take place in described liquid crystal material, on described horizontal alignment film, form thin polymer film, obtain described liquid crystal panel.
4. method according to claim 3, is characterized in that, the liquid crystal material that is mixed with ultraviolet light bioactive molecule is filled into described array base palte and comprises with the liquid crystal cell that described color membrane substrates becomes box-like:
The liquid crystal material that is mixed with ultraviolet light bioactive molecule is dropped on described array base palte, sealed plastic box is coated on described color membrane substrates;
Maybe the liquid crystal material that is mixed with ultraviolet light bioactive molecule is dropped on described color membrane substrates, sealed plastic box is coated on described array base palte;
Again described array base palte is become to described liquid crystal cell with described color membrane substrates to box-like.
5. method according to claim 3, is characterized in that, the wavelength that described polarized ultraviolet for the first time irradiates is that 254nm, luminous energy are 0.1~10J/cm 2.
6. according to the arbitrary described method of claim 3 to 5, it is characterized in that, described array base palte and described color membrane substrates are during to box, and box is thick is 3.6 μ m.
7. method according to claim 3, is characterized in that, described in be mixed with in the liquid crystal material of ultraviolet light bioactive molecule, the mass percent concentration of described ultraviolet light bioactive molecule is 0.1%~5%.
8. method according to claim 3, is characterized in that, the wavelength that described polarized ultraviolet for the second time irradiates is 310nm, and luminous energy is 5~50mJ/cm 2.
CN201210003686.0A 2012-01-06 2012-01-06 LCD (Liquid crystal display) panel and manufacturing method thereof Expired - Fee Related CN102650759B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201210003686.0A CN102650759B (en) 2012-01-06 2012-01-06 LCD (Liquid crystal display) panel and manufacturing method thereof
PCT/CN2012/083433 WO2013102367A1 (en) 2012-01-06 2012-10-24 Liquid crystal alignment film, liquid crystal panel and manufacturing method thereof

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CN102650759B true CN102650759B (en) 2014-11-05

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CN102650759B (en) * 2012-01-06 2014-11-05 京东方科技集团股份有限公司 LCD (Liquid crystal display) panel and manufacturing method thereof
CN104020609A (en) * 2014-05-16 2014-09-03 京东方科技集团股份有限公司 Liquid crystal coating method and display panel manufacturing method
CN104777675B (en) * 2015-04-29 2018-09-21 厦门大学 A method of control cholesteric liquid crystal grating orientation
CN104765213B (en) * 2015-04-29 2018-09-04 京东方科技集团股份有限公司 The preparation method of display base plate, the preparation method of display panel, display device
CN104777651B (en) * 2015-04-29 2018-02-27 厦门大学 A kind of cholesteric liquid crystal grating pattern polymerization
CN107402477B (en) * 2017-09-22 2020-11-24 京东方科技集团股份有限公司 Display panel, preparation method thereof and display device
CN110687721A (en) * 2019-09-16 2020-01-14 南京中电熊猫平板显示科技有限公司 Liquid crystal display panel and manufacturing method thereof

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CN102127458A (en) * 2010-12-31 2011-07-20 北京科技大学 Binary synergistic photosensitive liquid crystal orientation agent for disc liquid crystal orientation and preparation method

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WO2013102367A1 (en) 2013-07-11

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