CN102643541A - Antibacterial halogen-free flame retardant nylon alloy material - Google Patents
Antibacterial halogen-free flame retardant nylon alloy material Download PDFInfo
- Publication number
- CN102643541A CN102643541A CN201210128676XA CN201210128676A CN102643541A CN 102643541 A CN102643541 A CN 102643541A CN 201210128676X A CN201210128676X A CN 201210128676XA CN 201210128676 A CN201210128676 A CN 201210128676A CN 102643541 A CN102643541 A CN 102643541A
- Authority
- CN
- China
- Prior art keywords
- parts
- alloy material
- meant
- nylon alloy
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An antibacterial halogen-free flame retardant nylon alloy material belongs to the technical field of high molecular materials. The antibacterial halogen-free flame retardant nylon alloy material comprises, by weight, the following raw materials of 60-65 parts of nylon 66 resins, 30-35 parts of nylon 1010 resins, 20-30 parts of rubbers, 0.8-1.6 parts of coupling agents, 28-35 parts of flame retardants, 1.2-2.0 parts of antibacterial agents, 0.4-0.9 part of antioxidants, 45-50 parts of chopped glass fibers and 0.3-0.8 part of surface modifiers. The antibacterial halogen-free flame retardant nylon alloy material has the advantages that the tensile strength is larger than 145MPa, the flexural strength is larger than 215MPa, the izod notched impact strength is larger than 32kj per square meter, the melt index is larger than 22g/10min, the flame retardance reaches to V-0 (UL-94-1.6mm), and the antibacterial halogen-free flame retardant nylon alloy material can resist bacteria erosion.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of antimicrobial halogen-free reinforced nylon alloy material.
Background technology
In order to give anti-flaming function, add halogen-containing fire retardant usually, but the nylon that contains the fire retardant of halogen the time is easy to generate toxic and harmful and is detrimental to health, and particularly when fire takes place, is prone to cause secondary to endanger in burning to nylon.Therefore, the use that reduces halogen in the nylon material is very favourable and have a good security to environmental protection.The technical scheme that will introduce below is based on producing under this background.
Summary of the invention
Task of the present invention is to provide a kind of due mechanical and physical performance of nylon that both can ensure, can avoid again producing toxic and harmful and using the antimicrobial halogen-free reinforced nylon alloy material that embodies environmental protection and avoid secondary pollution in when burning.
Task of the present invention is accomplished like this, a kind of antimicrobial halogen-free reinforced nylon alloy material, and its raw material by following parts by weight is formed:
60～65 parts of Nylon 66s;
30～35 parts of nylon 1010 resins;
20～30 parts of rubber;
0.8～1.6 part of coupling agent;
28～35 parts of fire retardants;
1.2～2.0 parts of antiseptic-germicides;
0.4～0.9 part in oxidation inhibitor;
45～50 parts of short glass fibers;
0.3～0.8 part of surface-modifying agent.
In a concrete embodiment of the present invention, described Nylon 66 is meant that fusing point is at 220 ℃ resin.
In another concrete embodiment of the present invention, described nylon 1010 resin is meant that melting point resin is at 230 ℃ resin.
In another concrete embodiment of the present invention, described rubber is meant acrylonitrile-butadiene-styrene copolymer.
In another concrete embodiment of the present invention, described coupling agent is meant vinyl three (β methoxyethoxy) silane.
Also have among the concrete embodiment of the present invention, described fire retardant is meant the trimeric cyanamide ammonium polyphosphate.
more of the present invention and among concrete embodiment, described antiseptic-germicide is meant the plastic antimicrobial agent of carrying silver ion.
In of the present invention and then concrete embodiment, described oxidation inhibitor is meant four [methyl-β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] pentaerythritol ester.
Of the present invention again more and among concrete embodiment, described short glass fiber is meant that length is the alkali-free short glass fiber of 3mm.
Again and then among concrete embodiment, described surface-modifying agent is meant two stearic amides in the present invention.
Antimicrobial halogen-free reinforced nylon alloy material of the present invention has following technique effect through test: tensile strength is greater than 145MPa, and flexural strength is greater than 215MPa, and the socle girder notched Izod impact strength is greater than 32kj/m
2, melting index is greater than 22g/10min, and flame retardant resistance reaches V-0 (UL-94-1.6mm), and bacterium corrodes in opposing.
Embodiment
Embodiment 1:
By weight: to get Nylon 66 and be fusing point be fusing point at 230 ℃ 30.4 parts of resins, rubber at 220 ℃ 60.2 parts of resins, nylon 1010 resin is that 20.3 parts of acrylonitrile-butadiene-styrene copolymers, coupling agent are that 0.8 part in vinyl three (β methoxyethoxy) silane, fire retardant are that 28.1 parts of trimeric cyanamide ammonium polyphosphates, antiseptic-germicide are that promptly four [methyl-β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] 0.4 part of pentaerythritol ester, length are 0.4 part of 45 parts of alkali-free short glass fibers and the promptly two stearic amide of surface-modifying agent of 3mm for 1.2 parts of the plastic antimicrobial agents, oxidation inhibitor of carrying silver ion.
Embodiment 2:
By weight: to get Nylon 66 and be fusing point be fusing point at 230 ℃ 32.2 parts of resins, rubber at 220 ℃ 62.5 parts of resins, nylon 1010 resin is that 25.2 parts of acrylonitrile-butadiene-styrene copolymers, coupling agent are that 1.3 parts in vinyl three (β methoxyethoxy) silane, fire retardant are that 30.5 parts of trimeric cyanamide ammonium polyphosphates, antiseptic-germicide are that promptly four [methyl-β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] 0.5 part of pentaerythritol ester, length are 0.6 part of 47.2 parts of alkali-free short glass fibers and the promptly two stearic amide of surface-modifying agent of 3mm for 1.6 parts of the plastic antimicrobial agents, oxidation inhibitor of carrying silver ion.
Embodiment 3:
By weight: to get Nylon 66 and be fusing point be fusing point at 230 ℃ 34.5 parts of resins, rubber at 220 ℃ 64.2 parts of resins, nylon 1010 resin is that 28.3 parts of acrylonitrile-butadiene-styrene copolymers, coupling agent are that 1.4 parts in vinyl three (β methoxyethoxy) silane, fire retardant are that 33.2 parts of trimeric cyanamide ammonium polyphosphates, antiseptic-germicide are that promptly four [methyl-β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] 0.7 part of pentaerythritol ester, length are 0.8 part of 48.8 parts of alkali-free short glass fibers and the promptly two stearic amide of surface-modifying agent of 3mm for 1.8 parts of the plastic antimicrobial agents, oxidation inhibitor of carrying silver ion.
Embodiment 4:
By weight: to get Nylon 66 and be fusing point be fusing point at 230 ℃ 35 parts of resins, rubber at 220 ℃ 65 parts of resins, nylon 1010 resin is that 29.8 parts of acrylonitrile-butadiene-styrene copolymers, coupling agent are that 1.6 parts in vinyl three (β methoxyethoxy) silane, fire retardant are that 34.8 parts of trimeric cyanamide ammonium polyphosphates, antiseptic-germicide are that promptly four [methyl-β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] 0.9 part of pentaerythritol ester, length are 0.9 part of 49.9 parts of alkali-free short glass fibers and the promptly two stearic amide of surface-modifying agent of 3mm for 2.0 parts of the plastic antimicrobial agents, oxidation inhibitor of carrying silver ion.
The antimicrobial halogen-free reinforced nylon alloy material that is obtained by the foregoing description 1 to 4 has the technique effect shown in the following table.
Claims (10)
1.
A kind of antimicrobial halogen-free reinforced nylon alloy material is characterized in that its raw material by following parts by weight forms:
60～65 parts of Nylon 66s;
30～35 parts of nylon 1010 resins;
20～30 parts of rubber;
0.8～1.6 part of coupling agent;
28～35 parts of fire retardants;
1.2～2.0 parts of antiseptic-germicides;
0.4～0.9 part in oxidation inhibitor;
45～50 parts of short glass fibers;
0.3～0.8 part of
surface-modifying agent.
2.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described Nylon 66 is meant that fusing point is at 220 ℃ resin.
3.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described nylon 1010 resin is meant that melting point resin is at 230 ℃ resin.
4.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described rubber is meant acrylonitrile-butadiene-styrene copolymer.
5.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described coupling agent is meant vinyl three (β methoxyethoxy) silane.
6.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described fire retardant is meant the trimeric cyanamide ammonium polyphosphate.
7.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described antiseptic-germicide is meant the plastic antimicrobial agent of carrying silver ion.
8.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described oxidation inhibitor is meant four [methyl-β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] pentaerythritol ester.
9.
a kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described short glass fiber is meant that length is the alkali-free short glass fiber of 3 ㎜.
10.
A kind of antimicrobial halogen-free reinforced nylon alloy material according to claim 1 is characterized in that described surface-modifying agent is meant two stearic amides
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210128676 CN102643541B (en) | 2012-04-27 | 2012-04-27 | Antibacterial halogen-free flame retardant nylon alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210128676 CN102643541B (en) | 2012-04-27 | 2012-04-27 | Antibacterial halogen-free flame retardant nylon alloy material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102643541A true CN102643541A (en) | 2012-08-22 |
| CN102643541B CN102643541B (en) | 2013-09-25 |
Family
ID=46656630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210128676 Expired - Fee Related CN102643541B (en) | 2012-04-27 | 2012-04-27 | Antibacterial halogen-free flame retardant nylon alloy material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102643541B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205118A (en) * | 2013-04-16 | 2013-07-17 | 常熟市凯力达蜂窝包装材料有限公司 | Method for preparing black halogen-free polyamide composite material with high performance |
| CN103205121A (en) * | 2013-04-16 | 2013-07-17 | 常熟市凯力达蜂窝包装材料有限公司 | High-performance black halogen-free polyamide composite material |
| CN103304952A (en) * | 2013-06-24 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | ABS (acrylonitrile butadiene styrene)/PA (polyamide) composite antibacterial pipe and preparation method thereof |
| CN103333492A (en) * | 2013-07-22 | 2013-10-02 | 深圳市兴盛迪新材料有限公司 | Halogen-free flame retardant nylon resin composition |
| CN111892808A (en) * | 2019-05-05 | 2020-11-06 | 上海术博新材料技术有限公司 | Flame-retardant nylon for preparing battery bracket of electric automobile and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100318012A1 (en) * | 2009-06-16 | 2010-12-16 | Arkema France | Bacteriostatic textile based on polyamide 11 |
| US20100331461A1 (en) * | 2008-01-31 | 2010-12-30 | Basf Se | Fiber-Reinforced Polyamide[5,10] Molding Compounds |
| CN102040828A (en) * | 2009-10-26 | 2011-05-04 | 杜邦兴达（无锡）单丝有限公司 | Antibacterial composition, antibacterial brush filament and preparation method thereof |
| CN102321362A (en) * | 2011-08-05 | 2012-01-18 | 四川大学 | High-retardant polyamide |
-
2012
- 2012-04-27 CN CN 201210128676 patent/CN102643541B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100331461A1 (en) * | 2008-01-31 | 2010-12-30 | Basf Se | Fiber-Reinforced Polyamide[5,10] Molding Compounds |
| US20100318012A1 (en) * | 2009-06-16 | 2010-12-16 | Arkema France | Bacteriostatic textile based on polyamide 11 |
| CN102040828A (en) * | 2009-10-26 | 2011-05-04 | 杜邦兴达（无锡）单丝有限公司 | Antibacterial composition, antibacterial brush filament and preparation method thereof |
| CN102321362A (en) * | 2011-08-05 | 2012-01-18 | 四川大学 | High-retardant polyamide |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205118A (en) * | 2013-04-16 | 2013-07-17 | 常熟市凯力达蜂窝包装材料有限公司 | Method for preparing black halogen-free polyamide composite material with high performance |
| CN103205121A (en) * | 2013-04-16 | 2013-07-17 | 常熟市凯力达蜂窝包装材料有限公司 | High-performance black halogen-free polyamide composite material |
| CN103304952A (en) * | 2013-06-24 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | ABS (acrylonitrile butadiene styrene)/PA (polyamide) composite antibacterial pipe and preparation method thereof |
| CN103304952B (en) * | 2013-06-24 | 2015-07-01 | 苏州新区佳合塑胶有限公司 | ABS (acrylonitrile butadiene styrene)/PA (polyamide) composite antibacterial pipe and preparation method thereof |
| CN103333492A (en) * | 2013-07-22 | 2013-10-02 | 深圳市兴盛迪新材料有限公司 | Halogen-free flame retardant nylon resin composition |
| CN111892808A (en) * | 2019-05-05 | 2020-11-06 | 上海术博新材料技术有限公司 | Flame-retardant nylon for preparing battery bracket of electric automobile and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102643541B (en) | 2013-09-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102643541B (en) | Antibacterial halogen-free flame retardant nylon alloy material | |
| CN102634207B (en) | Preparation method of antibacterial halogen-free flame-retardant nylon alloy material | |
| CN103421240A (en) | Square single-wall corrugated pipe material for electric power | |
| CN103396607A (en) | Flame-retardant and reinforced antistatic PP composite material and preparation method thereof | |
| CN101050290A (en) | Dynamic sulfurated retardant composite material of polypropylene without halogen, and preparation method | |
| CN102061077B (en) | Halogen-free inflaming retarding PC/ABS (Polycarbonate/Acrylonitrile Butadiene Styrene) alloy | |
| CN104327462A (en) | Phosphorus-based synergistically flame-retardant PET/PBS alloy material and preparation method thereof | |
| CN102627850B (en) | Antibacterial fire-resistant nylon composite material | |
| CN103483690B (en) | A kind of modified polypropylene composite material | |
| CN104098886A (en) | Water-proof heat-proof inflaming retarding cable sheath material | |
| CN107418197B (en) | Heat-conducting nylon engineering plastic and preparation method thereof | |
| CN102993740A (en) | Preparation method of glass fiber reinforced flame-retardant nylon alloy material | |
| CN103421294A (en) | Halogen-free flame-retardant enhanced PC/ABS alloy and preparation method thereof | |
| CN109553874A (en) | A kind of low temperature resistant, light aging resisting material flame retardant polystyrene composite, preparation method and applications | |
| MX2019009938A (en) | Flame-retardant, moisture-cured wire and cable constructions with improved glancing impact performance. | |
| CN102732009B (en) | Flame retardant electroconductive nylon composite material | |
| CN103214837A (en) | Fiberglass reinforced black halogen-free flame-retardant polyamide alloy material | |
| CN102746650A (en) | Calcium sulfate whisker filled halogen-free flame retardant nylon alloy material | |
| CN103214836A (en) | Environmental-friendly black nylon material | |
| EP1777261A4 (en) | Flame-retardant polyolefin resin composition | |
| CN105199219A (en) | Stretch-proof polypropylene composite material | |
| CN103304900A (en) | Flame-retardant whisker-enhanced polypropylene alloy material | |
| CN102850787A (en) | Halogen-free flame-retarding nylon composite material | |
| CN105885337A (en) | Carbon nanotube toughened modified ABS material | |
| CN103205108A (en) | Black glass fiber enhanced flame retardant polyamide composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: CHANGSHU KAILIDA HONEYCOMB PACKAGE MATERIAL CO., L Free format text: FORMER OWNER: CHANGSHU CITY FADONG PLASTIC INDUSTRY CO., LTD. Effective date: 20130715 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 215553 SUZHOU, JIANGSU PROVINCE TO: 215515 SUZHOU, JIANGSU PROVINCE |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20130715 Address after: 215515 Jiangsu city of Suzhou province Changshou City ancient town miaoquan Industrial Park Applicant after: Changshu Kailida Honeycomb Package Material Co., Ltd. Address before: Shang Hu Zhen Wang Xin Cun shoyama Suzhou city of Jiangsu province Changshou City 215553 Applicant before: Changshu City Fadong Plastic Industry Co., Ltd. |
|
| ASS | Succession or assignment of patent right |
Owner name: CHANGSHA YEMEI MODEL CLOTHES RACK CO., LTD. Free format text: FORMER OWNER: CHANGSHU KAILIDA HONEYCOMB PACKAGE MATERIAL CO., LTD. Effective date: 20130807 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 215515 SUZHOU, JIANGSU PROVINCE TO: 215551 SUZHOU, JIANGSU PROVINCE |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20130807 Address after: Suzhou City, Jiangsu Province, 215551 Changshou City Shang Hu Zhen Liantang Chang Xing Cun Applicant after: Changshu Yamei Mannequins Co., Ltd. Address before: 215515 Jiangsu city of Suzhou province Changshou City ancient town miaoquan Industrial Park Applicant before: Changshu Kailida Honeycomb Package Material Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130925 Termination date: 20150427 |
|
| EXPY | Termination of patent right or utility model |