CN102634268A - Ultraviolet (UV) solvent-free steel tube coating and preparation method thereof - Google Patents
Ultraviolet (UV) solvent-free steel tube coating and preparation method thereof Download PDFInfo
- Publication number
- CN102634268A CN102634268A CN2012101533930A CN201210153393A CN102634268A CN 102634268 A CN102634268 A CN 102634268A CN 2012101533930 A CN2012101533930 A CN 2012101533930A CN 201210153393 A CN201210153393 A CN 201210153393A CN 102634268 A CN102634268 A CN 102634268A
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- Prior art keywords
- solvent
- coating
- steel tube
- free steel
- acrylate
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- 238000000576 coating method Methods 0.000 title claims abstract description 39
- 239000011248 coating agent Substances 0.000 title claims abstract description 38
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 37
- 239000010959 steel Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 12
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 11
- -1 polyesteracrylate Chemical compound 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 21
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 229920000728 polyester Polymers 0.000 claims description 11
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000012855 volatile organic compound Substances 0.000 abstract 2
- 238000005265 energy consumption Methods 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 4
- 239000004922 lacquer Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 239000010242 baoji Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses ultraviolet (UV) solvent-free steel tube coating and a preparation method thereof. The UV solvent-free steel tube coating is prepared by mixing urethane acrylate, polyesteracrylate, epoxy acrylate and acrylic ester monomer at a high speed, adding light inhibitor, dispersing at the high speed and adding a surfactant. The UV solvent-free steel tube coating realizes zero discharge; after the UV solvent-free steel tube coating is coated on a steel tube, the steel tube can be protected, and the surface of the steel tube is prevented from being corroded; the coating can be directly coated after being heated to be at the temperature within 50 and 60 DEG C; after the coating is coated, UV solidification is performed immediately only for 1 to 2 minutes; the production time is greatly shortened, the production efficiency is improved, energy is saved, and the energy consumption is reduced; atomized waste coating can be recycled; the content of volatile organic compounds (VOC) is almost close to zero; and the efficiency is improved completely, and the discharge is reduced.
Description
Technical field
The invention belongs to a kind of coating and preparation method, solvent-free steel pipe coating of particularly a kind of UV and preparation method.
Background technology
Along with the progress of human society, the importance to environment protection is more and more recognized in countries in the world.The low-carbon (LC) low emission is that a society field is in the major subjects of seeking and exploring always.For paint field, the direction researchdevelopment that each large enterprises of the world and manufacturer are also just containing towards the low emission height always admittedly.
The UV lacquer is to use coating more widely at present, and the UV paint film is the stereo structure structure, and hardness is big, and wear resistance is good, and transparency is good, and the product scratch resistance is bumped, rub resistance, stands the test of time.Mechanised equipment has overcome the human factor in the manual operation, makes the product aberration less, steady quality.In the making processes, the objectionable impurities in the sheet material is decomposed, and handle through the oven dry of ultraviolet photo-curing machine, product is health environment-friendly more.
Chinese patent CN102161862A discloses a kind of UV light-cured polyurethane acrylic acid resin composition; Said composition can guarantee that the UV lacquer is evenly absorbed; Increase the fullness ratio of finish paint, make paint system performance best effect, can also improve the UV lacquer and stick on the sticking power on the metal substrate.But the disclosed UV lacquer of above-mentioned patent contains organic solvent, and in the coating drying process, solvent must volatilize fully and directly be discharged in the air, damages for human body.
Summary of the invention
The objective of the invention is to overcome above-mentioned defective, solvent-free steel pipe coating of a kind of UV and preparation method are provided, it is a kind of UV steel pipe coating of zero release, and this coating can play the protection steel pipe after applying on the steel pipe, prevents the steel tube surface corrosion; As long as this coating is heated to 50 ℃-60 ℃ and can directly sprays; Can carry out UV curing and sprayed at once; Process only needs 1-2 minute, can shorten the PT greatly, enhances productivity, and save energy cuts down the consumption of energy.Discarded coating after the spraying atomizing can also reclaim repeated use.VOC content almost is close to zero; Economize efficient fully and reduce discharging; Be the quality products of a high-efficiency environment friendly fully.
The objective of the invention is to realize through following technical scheme: the solvent-free steel pipe coating of a kind of UV, it is characterized in that: it comprises following component: (weight part)
1. urethane acrylate 10-15
2. polyester acrylate 5-10
3. epoxy acrylate 25-30
4. acrylate monomer 40-50
5. light trigger 5-10
6. surperficial auxiliary agent 3-5.
Said light trigger is the basic ketone of 1-hydroxyl-hexamethylene.
Said surperficial auxiliary agent is the fluorine carbon leveling auxiliary agent.
The preparation method of the solvent-free steel pipe coating of a kind of UV, it is characterized in that: it may further comprise the steps:
1, urethane acrylate, polyester acrylate, epoxy acrylate, acrylate monomer are formed according to above-mentioned parts by weight put into stirrer, with 1200 rev/mins of mixed at high speed of stirrer 15 minutes;
2, add light trigger, 1200 rev/mins of high speed dispersion of stirrer 20 minutes, production process is added a cover lucifuge;
3, add surperficial auxiliary agent, stirrer mixed 5 minutes for 1000 rev/mins;
4,200 orders filter the back packing.
Advantage of the present invention and beneficial effect are:
1, a kind of UV steel pipe coating of zero release, this coating can play the protection steel pipe after applying on the steel pipe, prevent the steel tube surface corrosion;
As long as 2, this coating is heated to 50 ℃-60 ℃ and can directly sprays, can carry out UV at once and solidify and sprayed, process only needs 1-2 minute, can shorten the PT greatly, enhances productivity, and save energy cuts down the consumption of energy;
3, the discarded coating after the spraying atomizing can also reclaim repeated use, and VOC content almost is close to zero; Economize efficient fully and reduce discharging; Be the quality products of a high-efficiency environment friendly fully.
Embodiment
The present invention explains through embodiment, but they are not that the present invention is done any restriction.
The urethane acrylate that the present invention uses is that the special company of U.S.'s cyanogen produces; Polyester acrylate is that U.S. Sha Mate company produces; Epoxy acrylate is that the Tianjin Tianjiao Chemical Industry Co., Ltd produces, and fluorine carbon leveling auxiliary agent FC-171 is the commercially available prod for 3M company produces.
The solvent-free steel pipe coating of a kind of UV of the present invention, it comprises following component: (weight part)
1. urethane acrylate 10-15
2. polyester acrylate 5-10
3. epoxy acrylate 25-30
4. acrylate monomer 40-50
5. light trigger 5-10
6. surperficial auxiliary agent 3-5;
The preparation method of the solvent-free steel pipe coating of a kind of UV, it is characterized in that: it may further comprise the steps:
1, urethane acrylate, polyester acrylate, epoxy acrylate, acrylate monomer are formed according to above-mentioned parts by weight put into stirrer, with 1200 rev/mins of mixed at high speed of stirrer 15 minutes;
2, add light trigger, 1200 rev/mins of high speed dispersion of stirrer 20 minutes, production process is added a cover lucifuge;
3, add surperficial auxiliary agent, stirrer mixed 5 minutes for 1000 rev/mins;
4,200 orders filter the back packing.
Through concrete embodiment the present invention is described further below, understanding the present invention better, but following embodiment does not limit the scope of the invention.
Embodiment 1: the solvent-free steel pipe coating of a kind of UV of the present invention, it comprises following component: (weight part)
1. urethane acrylate 10
2. polyester acrylate 10
3. epoxy acrylate 30
4. acrylate monomer 50
5. the basic ketone 10 of 1-hydroxyl-hexamethylene
6. fluorine carbon leveling auxiliary agent FC-171 5;
The preparation method of the solvent-free steel pipe coating of a kind of UV, it is characterized in that: it may further comprise the steps:
1, urethane acrylate, polyester acrylate, epoxy acrylate, acrylate monomer are formed according to above-mentioned parts by weight put into stirrer, with 1200 rev/mins of mixed at high speed of stirrer 15 minutes;
2, add the basic ketone of light trigger 1-hydroxyl-hexamethylene, 1200 rev/mins of high speed dispersion of stirrer 20 minutes, production process is added a cover lucifuge;
3, add surperficial auxiliary agent FC-171, stirrer mixed 5 minutes for 1000 rev/mins;
4,200 orders filter the back packing.
Embodiment 2: the solvent-free steel pipe coating of a kind of UV of the present invention, it comprises following component: (weight part)
1. urethane acrylate 15
2. polyester acrylate 5
3. epoxy acrylate 25
4. acrylate monomer 40
5. light trigger 5
6. fluorine carbon leveling auxiliary agent FC-171 3;
Concrete preparation method is identical with embodiment 1.
Embodiment 3: the solvent-free steel pipe coating of a kind of UV of the present invention, it comprises following component: (weight part)
1. urethane acrylate 12
2. polyester acrylate 8
3. epoxy acrylate 28
4. acrylate monomer 45
5. the basic ketone 7 of 1-hydroxyl-hexamethylene
6. fluorine carbon leveling auxiliary agent FC-171 4.
Concrete preparation method is identical with embodiment 1.
Below be the present invention and solvent based coating performance comparison:
Solvent based coating UV solventless coatings
VOC content 40-50% does not have
Surface drying time 20-30min-
Do solid work time 12-24h 5-10s
0 grade 0 grade of sticking power
Allotment adds thinner and directly sprays
The steel pipe enterprise that domestic a few family is large-scale, the Tianjin Seamless steel pipe, the Shanghai Baoshan Iron and Steel Company, enterprises such as Ma'an Mountain's iron and steel, Baoji steel pipe have all bought the automatic spraying equipment that Zhejiang University produces in succession, adopt such environmental protection coating material that the outlet steel pipe is sprayed.This product has carried out the detection of each item index through mark coating inspection center of Qingdao section of the authoritative feeler mechanism of domestic third party.Specific targets attached (examining report).
Attach each item index result:
| Sequence number | The Interventions Requested title | Unit | The method of inspection | Detected result | Remarks |
| 1 | Solids content | % | GB/T 1725 | 92.7 | / |
| 2 | Density | g/cm 3 | GB/T 6750 | 1.15 | / |
| 3 | Acid number | MgKOH/g | GB/T 2895 | 0.10 | / |
| 4 | Flash-point | ℃ | DIN EN ISO 2719 | 107.5 | / |
| 5 | Gloss | Gloss unit | DIN EN ISO 67530 | 2.6 | 60° |
| 6 | Sticking power | Level | DIN EN ISO 2409 | 0 | / |
| 7 | Impelling strength | Kg·cm | ASTM D 2794 | 40 | / |
| 8 | Snappiness | mm | ? | 3 | / |
| 9 | Pencil hardness | Level | DIN EN ISO 15184 | 3H | / |
| 10 | Water tolerance | / | GB/T 1733 | No abnormal | 72h |
| 11 | Salt fog resistance | / | DIN EN ISO 9227 | No abnormal | 220h |
| 12 | Petrol-resistance | / | GB/T 1734 | No abnormal | 120#, 24 hours |
| 13 | Anti-solvent wiping property | / | GB/T 23989 | No abnormal | MEK, load 1kg, 50 times |
Claims (4)
1. solvent-free steel pipe coating of UV, it is characterized in that: it comprises following component: (parts by weight)
Urethane acrylate 10-15
Polyester acrylate 5-10
Epoxy acrylate 25-30
Acrylate monomer 40-50
Light trigger 5-10
Surface auxiliary agent 3-5.
2. the solvent-free steel pipe coating of a kind of UV as claimed in claim 1 is characterized in that: said light trigger is the basic ketone of 1-hydroxyl-hexamethylene.
3. the solvent-free steel pipe coating of a kind of UV as claimed in claim 1 is characterized in that: said surperficial auxiliary agent is the fluorine carbon leveling auxiliary agent.
4. the preparation method of the solvent-free steel pipe coating of the described a kind of UV of claim 1, it is characterized in that: it may further comprise the steps:
(1), urethane acrylate, polyester acrylate, epoxy acrylate and acrylate monomer are put into stirrer, with 1200 rev/mins of mixed at high speed of stirrer 15 minutes;
(2), add light trigger, 1200 rev/mins of high speed dispersion of stirrer 20 minutes, production process is added a cover lucifuge;
(3), add surperficial auxiliary agent, 1000 rev/mins of mixing of stirrer 5 minutes;
(4), 200 orders filter the back packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101533930A CN102634268A (en) | 2012-05-17 | 2012-05-17 | Ultraviolet (UV) solvent-free steel tube coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101533930A CN102634268A (en) | 2012-05-17 | 2012-05-17 | Ultraviolet (UV) solvent-free steel tube coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102634268A true CN102634268A (en) | 2012-08-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101533930A Pending CN102634268A (en) | 2012-05-17 | 2012-05-17 | Ultraviolet (UV) solvent-free steel tube coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102634268A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045050A (en) * | 2013-01-17 | 2013-04-17 | 浙江佑谦特种材料有限公司 | Antirust coating for metal pipeline |
| CN104031446A (en) * | 2014-05-28 | 2014-09-10 | 江苏巨珩新材料科技有限公司 | Solvent-free UV (ultraviolet) base coating material for mirror board surfaces and preparation method thereof |
| CN105505020A (en) * | 2016-01-04 | 2016-04-20 | 惠州圣源恒工艺品有限公司 | Environment-friendly ceramic simulating coating and spraying method thereof |
| CN107335597A (en) * | 2017-09-07 | 2017-11-10 | 阜南县柳祥工艺品有限公司 | A kind of metal handicrafts rust preventive paint method |
| CN114672228A (en) * | 2022-03-23 | 2022-06-28 | 山东沃丰新材料有限公司 | Environment-friendly color steel plate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
| CN101979449A (en) * | 2010-11-30 | 2011-02-23 | 中国乐凯胶片集团公司 | A kind of ultraviolet curing coating for whiteboard |
-
2012
- 2012-05-17 CN CN2012101533930A patent/CN102634268A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
| CN101979449A (en) * | 2010-11-30 | 2011-02-23 | 中国乐凯胶片集团公司 | A kind of ultraviolet curing coating for whiteboard |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045050A (en) * | 2013-01-17 | 2013-04-17 | 浙江佑谦特种材料有限公司 | Antirust coating for metal pipeline |
| CN103045050B (en) * | 2013-01-17 | 2016-09-14 | 浙江佑谦特种材料有限公司 | A kind of antirusting paint for metallic conduit |
| CN104031446A (en) * | 2014-05-28 | 2014-09-10 | 江苏巨珩新材料科技有限公司 | Solvent-free UV (ultraviolet) base coating material for mirror board surfaces and preparation method thereof |
| CN105505020A (en) * | 2016-01-04 | 2016-04-20 | 惠州圣源恒工艺品有限公司 | Environment-friendly ceramic simulating coating and spraying method thereof |
| CN107335597A (en) * | 2017-09-07 | 2017-11-10 | 阜南县柳祥工艺品有限公司 | A kind of metal handicrafts rust preventive paint method |
| CN107335597B (en) * | 2017-09-07 | 2020-09-08 | 阜南县柳祥工艺品有限公司 | Metal artware rust-proof paint spraying method |
| CN114672228A (en) * | 2022-03-23 | 2022-06-28 | 山东沃丰新材料有限公司 | Environment-friendly color steel plate and preparation method thereof |
| CN114672228B (en) * | 2022-03-23 | 2023-02-28 | 山东沃丰新材料有限公司 | Environment-friendly color steel plate and preparation method thereof |
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Application publication date: 20120815 |