CN102630691A - Pesticide composition containing cyflumetofen - Google Patents
Pesticide composition containing cyflumetofen Download PDFInfo
- Publication number
- CN102630691A CN102630691A CN2012100924208A CN201210092420A CN102630691A CN 102630691 A CN102630691 A CN 102630691A CN 2012100924208 A CN2012100924208 A CN 2012100924208A CN 201210092420 A CN201210092420 A CN 201210092420A CN 102630691 A CN102630691 A CN 102630691A
- Authority
- CN
- China
- Prior art keywords
- mite
- fluorine
- fluorine mite
- ester
- mite ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000005655 Cyflumetofen Substances 0.000 title abstract description 4
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing cyflumetofen. The pesticide composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from the cyflumetofen, the active ingredient B is selected from any one of the following components: hexythiazox, clofentezine, etoxazole and flutenzine, and the weight ratio of the active ingredient A to the active ingredient B is (1:70)-(70:1). The composition disclosed by the invention can control a variety of pests on a variety of crops and has obvious synergy. Furthermore, the dosage of pesticides can be reduced, the residues of the pesticides on the crops can be reduced, and the environmental pollution can also be reduced.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of application of composition pesticide on crop pest that contains fourth fluorine mite ester.
Technical background
Fourth fluorine mite ester (Cyflumetofen) molecular formula: C
24H
24F
3NO
4The novel miticide of benzoyl acetonitrile class; Do not have cross resistance fourth fluorine mite ester with existing insecticide and stop the hatching effect of two spotted spider mite ovum lower, but its each vegetative stage is all had very high activity, especially the activity to young mite is higher; Simultaneously each plant species all there is not poisoning; All fool proof to non-target organisms such as mammal and aquatile, beneficial organism, natural enemies, metabolism rapidly, decomposition are environment amenable agricultural chemicals in soil and water.
Hexythiazox (Hexythiazox) chemical name: (4RS, 5RS)-5-(4-chlorphenyl)-N-cyclohexyl-4-methyl-2-oxo-1,3-thiazoles alkane-3 carboxylic acid amides, molecular formula: C
17H
21ClN
2O
2S.The novel miticide of thiazolidine ketone has penetrability preferably to the plant epidermis layer, but inhales conduction in not having.The various plants insect is had strong ovum extremely, kills the children if the characteristic of mite is invalid to the one-tenth mite, but the ovum that the female one-tenth mite that touches soup is produced is had the effect of inhibition hatching.This medicine belongs to non-temperature sensitive type miticide, and the effect of when high temperature or low temperature, using does not have significant difference, and the longevity of residure is long, can remain on about 50 days.
Four mite piperazine (Clofentezine) chemical names: 3, two (the 2-chlorphenyls)-1,2,4 of 6-, 5-tetrazine, molecular formula: C
14H
8Cl
2N
4The special efficacy miticide, lasting medicine.To the ovum that occurs in panonychus ulmi on fruit tree, cotton, the ornamental plants, congo red spider with if mite is effective, harmless to predation mite, natural enemy.Greenhouse rose, China pink there is slight influence.But this medicine effect is slower, 2 weeks just can reach the highest preventive effect after the general medication, should perform prediction when therefore using this medicine.
Second mite azoles (Etoxazole) molecular formula: C
21H
23F
2NO
2Belong to 2,4-diphenyl-oxazole derivatives quasi-compound is a kind of selectivity miticide.Mainly be the process of casting off a skin that suppresses the mite class, thereby mite is all had excellent tagging property from ovum, young mite to the pupa different phase.But the control efficiency to becoming mite is not fine.The mite class that Hexythiazox has been produced resistance has good control efficiency.
Fluorine mite piperazine (diflovidazin) chemical name: 3-(2-chlorphenyl)-6-(2, the 6-difluorophenyl)-1,2,4,5-tetrazine, molecular formula: C
14H
7CLF
2N
4Fluorine mite piperazine contacts the ovum and active through skin that goes out, and attracts the mite adult to get food, also prevents and treats the acarid in pupa stage.This compound effects mechanism is unique, not only ovum and one-tenth mite is had excellent activity, and makes female mite produce unsound ovum, causes destroying the evidence of mite, also can prevent insects such as pear sucker, oystershell scale, leafhopper simultaneously, and to natural enemy and Environmental security.
In the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research; Discovery is composite each other with fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine; Good synergistic effect is arranged within the specific limits; And relevant composite about fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good composition pesticide that contains fourth fluorine mite ester.
The present invention realizes through following technical scheme:
A kind of composition pesticide that contains fourth fluorine mite ester; It is characterized in that containing active components A and active component B; Active components A and active component B weight ratio are 1: 70～70: 1; Described active components A is selected from fourth fluorine mite ester, and active component B is selected from a kind of in Hexythiazox, four mite piperazines, second mite azoles, the fluorine mite piperazine.
The described composition pesticide that contains fourth fluorine mite ester is characterized in that: the weight ratio of active components A and active component B is 1: 50～50: 1.
The described composition pesticide that contains fourth fluorine mite ester is characterized in that: the weight ratio of fourth fluorine mite ester and Hexythiazox is 1: 5～20: 1.
The described composition pesticide that contains fourth fluorine mite ester is characterized in that: the weight ratio of fourth fluorine mite ester and four mite piperazines is 1: 20～15: 1.
The described composition pesticide that contains fourth fluorine mite ester is characterized in that: the weight ratio of fourth fluorine mite ester and second mite azoles is 1: 5～35: 1.
The described composition pesticide that contains fourth fluorine mite ester is characterized in that: the weight ratio of fourth fluorine mite ester and fluorine mite piperazine is 1: 10～15: 1.
The described composition pesticide that contains fourth fluorine mite ester, it is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
The described composition pesticide that contains fourth fluorine mite ester is used to prevent and treat the insect of crops, and described crops comprise cereal crops, fruit tree, vegetables, flowers, fiber crop.
Described insect comprises Tetranychus urticae, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper.
Amount of application when the content of active component depends on independent use in the present composition also depends on the mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, and the while is also relevant with target pest.Usually the weight percentage of active component is 2%～90% of a gross weight in the composition, and preferable is 5%～80%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1%～60% active substance by weight, preferably is 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, preferably is 10%～80%.
At least contain a kind of surfactant in the composition pesticide of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 2%～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The surfactant that composition pesticide of the present invention is selected for use is known in those skilled in the art: can be selected from dispersant, wetting agent, thickener or the antifoaming agent one or more.According to different dosage form, can also contain stabilizing agent known in those skilled in the art, antifreeze etc. in the preparation.
Composition pesticide of the present invention can be by the user before use through dilution or directly use.Its preparation can be by processing method known in those skilled in the art preparation, is about to active component and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, binding agent, the antifoaming agent etc. one or more again.
Composition pesticide of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
When processing wetting powder, composition comprises following component and content: active components A 1%～70%, active component B 1%～70%, dispersant 1%～12%, wetting agent 1%～8%, filler surplus.
When processing water dispersible granules, composition comprises following component and content: active components A 1%～70%, active component B1%～70%, dispersant 1%～12%, wetting agent 1%～8%, disintegrant 1%～10%, binding agent 0%～8%, filler surplus.
Comprise following component and content when composition is processed suspending agent: active components A 1%～60%, active component B1%～60%, dispersant 1%～10%, wetting agent 1%～10%, antifoaming agent 0.1%～2%, thickener 0.05%～2%, antifreeze 0%～8%, deionized water add to 100%.
Comprise following component and content when composition is processed suspension emulsion: active components A 1%～60%, active component B1%～60%, emulsifier 1%～10%, dispersant 1%～10%, solvent 0～20%, antifoaming agent 0.1%～2%, thickener 0.05%～2%, antifreeze 0%～8%, stabilizing agent 0%～3%, deionized water add to 100%.
Comprise following component and content when composition is processed aqueous emulsion: active components A 1%～60%, active component B1%～60%, solvent 1%～20%, emulsifier 1%～12%, antifreeze 0%～8%, antifoaming agent 0.1%～2%, thickener 0.05%～2%, deionized water add to 100%.
Comprise following component and content when composition is processed microemulsion: active components A 1%～60%, active component B1%～60%, emulsifier 1%～15%, solvent 1%～10%, antifreeze 0%～8%, stabilizing agent 0%～3%, antifoaming agent 0.1%～2%, deionized water add to 100%.
Comprise following component and content when composition is processed microcapsule suspending agent: active components A 1%～60%, active component B1%～60%, macromolecule cyst material 1%～10%, dispersant 2%～10%, solvent 1%～10%, emulsifier 1%～7%, pH regulator agent 0.1%～5%, antifoaming agent 0.1%～2%, deionized water add to 100%.
Composition comprises following component and content when processing microcapsule suspension-suspending agent: active components A 1%～60%, active component B1%～60%, macromolecule cyst material 1%～12%, surfactant 2%～15%, solvent 1%～15%, emulsifier 1%～8%, antifoaming agent 0.1%～2%, thickener 0.05%～2%, pH regulator agent 0.1%～5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single agent.
(2) the agricultural chemicals dosage reduces, and reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution.
(3) Tetranychus urticae on cereal crops, fruit tree, vegetables, flowers, the fiber crop, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper all there is greater activity.
Application implementation example one
The present invention is explained further that the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Instance 1 50% fourth fluorine mite ester Hexythiazox wetting powder
Fourth fluorine mite ester 40%, Hexythiazox 10%, octylphenol polyethylene oxyethylene group ether sulfate 5%, soapberry powder 4%, precipitated calcium carbonate add to 100%, and mixture carries out comminution by gas stream, make 50% fourth fluorine mite ester Hexythiazox wetting powder.
Instance 2 80% fourth fluorine mite ester Hexythiazox wetting powders
Fourth fluorine mite ester 70%, Hexythiazox 10%, polycarboxylate 4%, lauryl sodium sulfate 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 80% fourth fluorine mite ester Hexythiazox wetting powder.
Instance 3 36% fourth fluorine mite ester Hexythiazox wetting powders
Fourth fluorine mite ester 32%, Hexythiazox 4%, lignosulfonates 5.1%, Nekal BX 5%, attapulgite add to 100%, the mixed 36% fourth fluorine mite ester Hexythiazox wetting powder that gets.
Instance 4 55% fourth fluorine mite ester Hexythiazox water dispersible granules
The phonetic formaldehyde condensation products sulphate of fourth fluorine mite ester 50%, Hexythiazox 5%, alkylphenol-polyethenoxy 5%, sldium lauryl sulfate 4.5%, bentonite 3%, kaolin add to 100%, mixed 55% fourth fluorine mite ester Hexythiazox water dispersible granules.
Instance 5 35% fourth fluorine mite ester Hexythiazox water dispersible granules
Fourth fluorine mite ester 30%, Hexythiazox 5%, lignosulfonates 4.5%, wetting and penetrating agent F5%, sodium bicarbonate 3.1%, attapulgite add to 100%, the mixed 35% fourth fluorine mite ester Hexythiazox water dispersible granules that gets.
Instance 6 30% fourth fluorine mite ester Hexythiazox water dispersible granules
Fourth fluorine mite ester 20%, Hexythiazox 10%, aryl phenol polyoxyethylene succinate sulfonate 4%, neopelex 3.6%, urea 3%, attapulgite add to 100%, the mixed 30% fourth fluorine mite ester Hexythiazox water dispersible granules that gets.
Instance 7 39% fourth fluorine mite ester hexythiazox suspension agents
Fourth fluorine mite ester 36%, Hexythiazox 3%, alkylaryl APEO 5%, silkworm excrement 5%, silicone 0.11%, hydroxyethylcellulose 0.13%, deionized water add to 100%, the mixed 39% fourth fluorine mite ester hexythiazox suspension agent that gets.
Instance 8 30% fourth fluorine mite ester hexythiazox suspension agents
Fourth fluorine mite ester 25%, Hexythiazox 5%, alkylaryl APEO 5%, silkworm excrement 4%, silicone oil 0.13%, Magnesiumaluminumsilicate 0.12%, glycerine 1%, deionized water add to 100%, the mixed 30% fourth fluorine mite ester hexythiazox suspension agent that gets.
Instance 9 25% fourth fluorine mite ester hexythiazox suspension agents
Fourth fluorine mite ester 20%, Hexythiazox 5%, aliphatic alcohol polyethenoxy base ether 4%, Nekal BX 3%, capric acid 0.14%, Magnesiumaluminumsilicate 0.12%, ethylene glycol 1%, deionized water add to 100%, the mixed 25% fourth fluorine mite ester hexythiazox suspension agent that gets.
Instance 10 20% fourth fluorine mite ester Hexythiazox suspension emulsions
The phonetic formaldehyde condensation products sulphate of fourth fluorine mite ester 15%, Hexythiazox 5%, alkylphenol-polyethenoxy 4.5%, lauryl sodium sulfate 4%, 3-methyl cyclohexanol ketenes 8%, alkyl benzene calcium sulfonate 6%, capric acid 0.14%, sodium alginate 0.13%, triethylene glycol 2.5%, deionized water add to 100%, mixed 20% fourth fluorine mite ester Hexythiazox suspension emulsion.
Instance 11 30% fourth fluorine mite ester hexythiazox micro-emulsions
Fourth fluorine mite ester 5%, Hexythiazox 25%, AEO 5%, N-octylpyrrolidone 9%, propane diols 3%, silicone oil 0.12%, deionized water supply 100%, the mixed 30% fourth fluorine mite ester hexythiazox micro-emulsion that gets.
Instance 12 36% fourth fluorine mite ester Hexythiazox aqueous emulsions
Fourth fluorine mite ester 1%, Hexythiazox 35%, alkyl benzene calcium sulfonate 4%, N-pyrrolidones 9%, glycerine 5%, organosilicon 0.15%, melon glue 0.08%, deionized water supply 100%, make 36% fourth fluorine mite ester Hexythiazox aqueous emulsion.
Instance 13 51% fourth fluorine mite ester Hexythiazox microcapsule suspending agents
Fourth fluorine mite ester 50%, Hexythiazox 1%, sodium alginate 5%, polyoxyethylene carboxylate 5%, vegetable oil 8.8%, sorbitan fatty acid ester APEO 5%, PH conditioning agent hydrochloric acid and sodium hydroxide amount to 2.1%, silicone 0.14%, deionized water add to 100%, mixed 51% fourth fluorine mite ester Hexythiazox microcapsule suspending agent.
Instance 14 21% fourth fluorine mite ester Hexythiazox microcapsule suspension-suspending agents
Fourth fluorine mite ester 20%, Hexythiazox 1%, soapberry powder 4%, lignosulfonates 5%, PIC 3.9%, polyvinyl alcohol 0.11%, N-pyrrolidones 9%, phenethyl phenol polyoxy ethyl polypropylene-base ether 5%, silicone 0.12%, PH conditioning agent citric acid and sodium hydroxide 1.7%, deionized water add to 100%, the mixed 21% fourth fluorine mite ester Hexythiazox microcapsule suspension-suspending agent that gets.
Hexythiazox among the instance 1-14 is changed to four mite piperazines, second mite azoles, fluorine mite piperazine can makes novel formulation equally.
Instance 15 40% fourth fluorine mite ester clofentezine wettable powders
The phonetic formaldehyde condensation products sulphate of fourth fluorine mite ester 15%, four mite piperazines 25%, alkylphenol-polyethenoxy 5%, wetting and penetrating agent F3%, kaolin add to 100%, and mixture carries out comminution by gas stream, makes 40% fourth fluorine mite ester clofentezine wettable powder.
Instance 16 60% fourth fluorine mite ester clofentezine wettable powders
Fourth fluorine mite ester 50%, four mite piperazines 10%, alkylnaphthalene sulfonate 4.5%, neopelex 3%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 60% fourth fluorine mite ester clofentezine wettable powder.
Instance 17 45% fourth fluorine mite ester clofentezine wettable powders
Fourth fluorine mite ester 15%, four mite piperazines 30%, polycarboxylate 5%, soapberry powder 4%, white carbon add to 100%, and mixture carries out comminution by gas stream, makes 45% fourth fluorine mite ester clofentezine wettable powder.
Instance 18 70% fourth fluorine mite ester clofentezine water dispersible granules
Fourth fluorine mite ester 30%, four mite piperazines 40%, octylphenol polyethylene oxyethylene group ether sulfate 4.5%, spaonin powder 5%, ammonium sulfate 3%, white carbon add to 100%, mixed 70% fourth fluorine mite ester clofentezine water dispersible granule.
Instance 19 80% fourth fluorine mite ester clofentezine water dispersible granules
Fourth fluorine mite ester 40%, four mite piperazines 40%, alkyl benzene sulfonate calcium salt 5%, spaonin powder 3%, starch add to 100%, mixed 80% fourth fluorine mite ester clofentezine water dispersible granule.
Instance 20 40% fourth fluorine mite ester clofentezine water dispersible granules
Fourth fluorine mite ester 5%, four mite piperazines 35%, aliphatic amine polyoxyethylene are phonetic 4%, sldium lauryl sulfate 4.5%, glucose 2%, bentonite add to 100%, mixed 40% fourth fluorine mite ester clofentezine water dispersible granule.
Instance 21 45% fourth fluorine mite ester clofentezine suspension agents
Fourth fluorine mite ester 25%, four mite piperazines 20%, polyoxyethylene carboxylate 4%, tea are withered 3.5%, silicone 0.1%, xanthans 0.13%, deionized water add to 100%, mixed 45% fourth fluorine mite ester clofentezine suspension agent.
Instance 22 33% fourth fluorine mite ester clofentezine suspension agents
Fourth fluorine mite ester 3%, four mite piperazines 30%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 4.2%, lauryl sodium sulfate 5%, silicone 0.12%, gum Arabic 0.12%, deionized water add to 100%, mixed 33% fourth fluorine mite ester clofentezine suspension agent.
Instance 23 50% fourth fluorine mite ester clofentezine suspension agents
Fourth fluorine mite ester 20%, four mite piperazines 30%, lignosulfonates 4.6%, tea are withered 5%, silicone 0.12%, gelatin 0.12%, deionized water add to 100%, mixed 50% fourth fluorine mite ester clofentezine suspension agent.
Instance 24 16% fourth fluorine mite esters four mite piperazine suspension emulsions
Fourth fluorine mite ester 1%, four mite piperazines 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, Nekal BX 4%, N, dinethylformamide 8.9%, phenyl phenol polyoxy ethyl ether phosphate 5%, C
8～10Aliphatic alcohols 0.12%, gum Arabic 0.05%, glycerine 1.8%, deionized water add to 100%, mixed 16% fourth fluorine mite ester, the four mite piperazine suspension emulsions that get.
Instance 25 11% fourth fluorine mite esters four mite piperazine microemulsions
Fourth fluorine mite ester 10%, four mite piperazines 1%, castor oil polyoxyethylene ether 5.3%, polyethylene glycol 4.1%, acetone 9%, capric acid 0.15%, deionized water supply 100%, make 11% fourth fluorine mite ester, four mite piperazine microemulsions.
Instance 26 16% fourth fluorine mite esters four mite piperazine aqueous emulsions
Fourth fluorine mite ester 15%, four mite piperazines 1%, alkylphenol-formaldehyde resin polyoxy ethyl ether 5%, EGME 9.6%, methylcellulose 0.15%, propane diols 3%, silicone oil 0.15%, deionized water supply 100%, make 16% fourth fluorine mite ester, four mite piperazine aqueous emulsions.
Instance 27 42% fourth fluorine mite esters four mite piperazine microcapsule suspending agents
Fourth fluorine mite ester 2%, four mite piperazines 40%, alkylphenol-polyethenoxy are phonetic 3%, polyfunctional group acyl halide polyamines 4.5%, butyl ether 8%, alkylaryl polyoxyethylene poly-oxygen propylene aether 5%, PH conditioning agent sodium hydroxide and citric acid amount to 1.9%, organosilicon 0.08%, deionized water add to 100%, mixed 42% fourth fluorine mite ester, four mite piperazine microcapsule suspending agents.
Instance 28 51% fourth fluorine mite esters four mite piperazine microcapsule suspension-suspending agents
Fourth fluorine mite ester 1%, four mite piperazines 50%, alkylaryl APEO 4%, tea are withered 5%, formaldehyde 4%, CMC 0.1%, propyl alcohol 9%, phenethyl fluosite polyoxy ethyl ether 3.5%, organosilicon 0.1%, PH conditioning agent sodium hydroxide and hydrochloric acid amount to 1.8%, deionized water adds to 100%, mixed 51% fourth fluorine mite ester, four mite piperazine microcapsule suspension-suspending agents.
Four mite piperazines among the instance 15-28 are changed to Hexythiazox, second mite azoles, fluorine mite piperazine can make novel formulation equally.
Instance 29 36% fourth fluorine mite ester second mite azoles wetting powders
Fourth fluorine mite ester 35%, second mite azoles 1%, naphthalene sulfonic acid-formaldehyde condensation product 4%, spaonin powder 5%, bentonite add to 100%, the mixed 36% fourth fluorine mite ester second mite azoles wetting powder that gets.
Instance 30 71% fourth fluorine mite ester second mite azoles water dispersible granules
Fourth fluorine mite ester 70%, second mite azoles 1%, polycarboxylate 4%, tea are withered 5%, bentonite 3%, starch add to 100%, mixed 71% fourth fluorine mite ester second mite azoles water dispersible granules.
Instance 31 30% fourth fluorine mite ester second mite azoles water dispersible granules
Fourth fluorine mite ester 25%, second mite azoles 5%, lignosulfonates 4.5%, wetting and penetrating agent F5%, sodium bicarbonate 3.1%, precipitated calcium carbonate add to 100%, the mixed 30% fourth fluorine mite ester second mite azoles water dispersible granules that gets.
Instance 32 40% fourth fluorine mite ester second mite azole suspending agents
Fourth fluorine mite ester 35%, second mite azoles 5%, ester polyoxyethylene are phonetic 3.3%, soapberry powder 4%, C
8～10Aliphatic alcohols 0.12%, hydroxyethylcellulose 0.15%, deionized water add to 100%, the mixed 40% fourth fluorine mite ester second mite azole suspending agent that gets.
Instance 33 33% fourth fluorine mite ester second mite azoles suspension emulsions
Fourth fluorine mite ester 30%, second mite azoles 3%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5.3%, lauryl sodium sulfate 4%, 3-methyl cyclohexanol ketenes 8%, alkyl benzene calcium sulfonate 5%, silicone oil 0.11%, gelatin 0.12%, ethylene glycol 2.4%, deionized water add to 100%, the mixed 33% fourth fluorine mite ester second mite azoles suspension emulsion that gets.
Instance 34 35% fourth fluorine mite ester second mite azoles microemulsions
Fourth fluorine mite ester 30%, second mite azoles 5%, alkylaryl polyoxyethylene polyoxypropylene ether 4%, glycerine 4.3%, cyclohexanone 5%, C
10～20Saturated fat acids 0.11%, deionized water supply 100%, make 35% fourth fluorine mite ester second mite azoles microemulsion.
Instance 35 45% fourth fluorine mite ester second mite azole microcapsule suspension agent
Fourth fluorine mite ester 40%, second mite azoles 5%, polyfunctional group acyl halide dihydroxylic alcohols 4%, aliphatic amine polyoxyethylene are phonetic 5%, ethyl acetate 7%, C
10～20Saturated fat acids 0.11%, sorbitan monostearate 5%, PH conditioning agent sorbic acid and sodium hydroxide amount to 2.3%, deionized water adds to 100%, mixed 45% fourth fluorine mite ester second mite azole microcapsule suspension agent.
Second mite azoles among the instance 29-35 is changed to four mite piperazines, Hexythiazox, fluorine mite piperazine can makes novel formulation equally.
Instance 36 71% fourth fluorine mite ester fluorine mite piperazine wetting powders
Fourth fluorine mite ester 1%, fluorine mite piperazine 70%, alkylphenol-polyethenoxy are phonetic 5.2%, spaonin powder 5%, diatomite add to 100%, mixed 71% fourth fluorine mite ester fluorine mite piperazine wetting powder.
Instance 37 50% fourth fluorine mite ester fluorine mite piperazine wetting powders
The phonetic formaldehyde condensation products sulphate of fourth fluorine mite ester 25%, fluorine mite piperazine 25%, alkylphenol-polyethenoxy 4%, wetting and penetrating agent F5%, kaolin add to 100%, and mixture carries out comminution by gas stream, makes 50% fourth fluorine mite ester fluorine mite piperazine wetting powder.
Instance 38 30% fourth fluorine mite ester fluorine mite piperazine water dispersible granules
Fourth fluorine mite ester 20%, fluorine mite piperazine 10%, aliphatic alcohol polyethenoxy base ether 5%, neopelex 4%, ammonium sulfate 4%, kaolin add to 100%, the mixed 30% fourth fluorine mite ester fluorine mite piperazine water dispersible granules that gets.
Instance 39 30% fourth fluorine mite ester fluorine mite piperazine suspending agents
Fourth fluorine mite ester 15%, fluorine mite piperazine 15%, alkylaryl APEO 4%, lauryl sodium sulfate 5%, C
10～20Saturated fat acids 0.1%, sodium phosphate trimer 0.15%, deionized water add to 100%, the mixed 30% fourth fluorine mite ester fluorine mite piperazine suspending agent that gets.
Instance 40 50% fourth fluorine mite ester fluorine mite piperazine suspension emulsions
Fourth fluorine mite ester 30%, fluorine mite piperazine 20%, alkylnaphthalene sulfonate 4%, soapberry powder 3%, toluene 4%, NPE phosphate 4%, C
10～20Saturated fat acids 0.14%, phenolic resins 0.11%, diethylene glycol (DEG) 2.4%, deionized water add to 100%, the mixed 50% fourth fluorine mite ester fluorine mite piperazine suspension emulsion that gets.
Instance 41 25% fourth fluorine mite ester fluorine mite piperazine microemulsions
Fourth fluorine mite ester 20%, fluorine mite piperazine 5%, phenyl phenol polyoxy ethyl ether phosphate 3.5%, propyl alcohol 4%, cyclohexanone 5%, C
10～20Saturated fat acids 0.12%, deionized water supply 100%, make 25% fourth fluorine mite ester fluorine mite piperazine microemulsion.
Fluorine mite piperazine among the instance 36-41 is changed to four mite piperazines, Hexythiazox, second mite azoles can makes novel formulation equally.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places beaker subsequent use respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament is soaked taking-up behind the 5s, dries naturally in the soup that configures, put into insect box; Connect then and supply the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times; Every to repeat used examination borer population be 50, establishes blank simultaneously, checks dead borer population in 72h; Calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is regarded as invalid test greater than 10%.Computing formula is following:
The insect corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula is (with fourth fluorine mite ester is the standard medicament, and its toxicity index is 100) as follows:
TI * the P of the theoretical toxicity index (TTI) of M=fourth fluorine mite ester
Fourth fluorine mite esterTI * P of+effective active composition B
Effective active composition B
In the formula: M is the mixture of different proportionings
P
Effective active composition BBe effective active composition B shared ratio in composition
P
Fourth fluorine mite esterBe fourth fluorine mite ester shared ratio in composition
B is selected from a kind of in Hexythiazox, four mite piperazines, second mite azoles, the fluorine mite piperazine.
Application implementation example two:
Supply the examination insect: the apple Tetranychus urticae.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester and the former medicine of Hexythiazox and the two different proportioning mixture through preliminary experiment.
Toxicity test result
The composite toxicity test analysis of results table of table 1 fourth fluorine mite ester and Hexythiazox to the apple Tetranychus urticae
Can know by table 1; The proportioning of fourth fluorine mite ester and the composite control apple of Hexythiazox Tetranychus urticae was at 1: 70～70: 1 o'clock; Co-toxicity coefficient is all greater than 120, explains that both were mixed in the scope at 1: 70～70: 1 all to show synergistic effect, when the proportioning of fourth fluorine mite ester and Hexythiazox during at 1: 5～20: 1; Synergistic effect is obviously outstanding, and especially fourth fluorine mite ester and Hexythiazox weight ratio are that 4: 1 o'clock co-toxicity coefficients are maximum.Test is simultaneously found; When the proportioning of fourth fluorine mite ester and Hexythiazox is 20: 1,15: 1,14: 1,13: 1,12: 1,11: 1,10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5; Control to Tetranychus urticae, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper all has obvious synergistic effect, and co-toxicity coefficient is more than 210.
Application implementation example three:
Supply the examination insect: panonychus citri.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester and the former medicine of four mite piperazines and the two different proportioning mixture through preliminary experiment.
Toxicity test result
The composite toxicity test analysis of results table of table 2 fourth fluorine mite ester and four mite piperazines to panonychus citri
Can know by table 2; The proportioning of fourth fluorine mite ester and the composite control panonychus citri of four mite piperazines was at 1: 70～70: 1 o'clock; Co-toxicity coefficient is all greater than 120, explains that both were mixed in the scope at 1: 70～70: 1 all to show synergistic effect, when the proportioning of fourth fluorine mite ester and four mite piperazines during at 1: 20～15: 1; Synergistic effect is obviously outstanding, and especially fourth fluorine mite ester and four mite piperazine weight ratios are that 3: 4 o'clock co-toxicity coefficients are maximum.Test is simultaneously found; When fourth fluorine mite ester and four mite piperazine proportionings are 15: 1,10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,3: 4,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 20; Control to Tetranychus urticae, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper all has obvious synergistic effect, and co-toxicity coefficient is more than 200.
Application implementation example four:
Supply the examination insect: cotton red spider.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester and the former medicine of second mite azoles and the two different proportioning mixture through preliminary experiment.
Toxicity test result
The composite toxicity test analysis of results table of table 3 fourth fluorine mite ester and second mite azoles to cotton red spider
Can know by table 3; The proportioning of fourth fluorine mite ester and the composite control cotton red spider of second mite azoles was at 1: 70～70: 1 o'clock; Co-toxicity coefficient is all greater than 120, explains that both were mixed in the scope at 1: 70～70: 1 all to show synergistic effect, when the proportioning of fourth fluorine mite ester and second mite azoles during at 1: 5～35: 1; Synergistic effect is more obviously outstanding, and especially fourth fluorine mite ester and second mite azoles weight ratio are that 7: 1 o'clock co-toxicity coefficients are maximum.Test is simultaneously found; When fourth fluorine mite ester and second mite azoles proportioning are 35: 1,30: 1,25: 1,20: 1,15: 1,14: 1,13: 1,12: 1,11: 1,10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 5; Control to Tetranychus urticae, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper all has obvious synergistic effect, and co-toxicity coefficient is more than 200.
Application implementation example five:
Supply the examination insect: the oranges and tangerines blister mite.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester and the former medicine of fluorine mite piperazine and the two different proportioning mixture through preliminary experiment.
Toxicity test result
The composite toxicity test analysis of results table of table 4 fourth fluorine mite ester and fluorine mite piperazine to the oranges and tangerines blister mite
Can know by table 4; The proportioning of fourth fluorine mite ester and the composite control oranges and tangerines of fluorine mite piperazine blister mite was at 1: 70～70: 1 o'clock; Co-toxicity coefficient is all greater than 120, explains that both were mixed in the scope at 1: 70～70: 1 all to show synergistic effect, when the proportioning of fourth fluorine mite ester and fluorine mite piperazine during at 1: 10～15: 1; Synergistic effect is more obviously outstanding, and especially fourth fluorine mite ester and fluorine mite piperazine weight ratio are that 3: 2 o'clock co-toxicity coefficients are maximum.Test is simultaneously found; When fourth fluorine mite ester and fluorine mite piperazine proportioning are 15: 1,10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,3: 2,1: 1,2: 3,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10; Control to Tetranychus urticae, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper all has obvious synergistic effect, and co-toxicity coefficient is more than 200.
Application implementation example six fourth fluorine mite esters and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control citrus red mite test of pesticide effectiveness thereof
This test arrangement is Hanzhong City in Shaanxi Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 5% Hexythiazox wetting powder (commercial), 20% clofentezine suspension agent (commercial), 110g/L second mite azole suspending agent (autogamy), 10% fluorine mite piperazine suspending agent (autogamy).
Investigation citrus red mite insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 60 days after the dispenser and is calculated preventive effect.Result of the test is as follows:
Table 5 fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control citrus red mite test of pesticide effectiveness thereof
Can find out that by table 5 can effectively prevent and treat citrus red mite after fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine are composite, control efficiency all is superior to the preventive effect of single agent, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example seven fourth fluorine mite esters and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control cotton Tetranychus cinnabarinus test of pesticide effectiveness thereof
This test arrangement is the Weinan City Dali County in Shaanxi Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 5% Hexythiazox wetting powder (commercial), 20% clofentezine suspension agent (commercial), 110g/L second mite azole suspending agent (autogamy), 10% fluorine mite piperazine suspending agent (autogamy).
Investigation cotton Tetranychus cinnabarinus insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and is calculated preventive effect before the medicine.Result of the test is as follows:
Table 6 fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control cotton Tetranychus cinnabarinus test of pesticide effectiveness thereof
Can find out that by table 6 can effectively prevent and treat the cotton Tetranychus cinnabarinus after fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine are composite, control efficiency all is superior to the preventive effect of single agent, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example eight fourth fluorine mite esters and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control apple tetranychus test of pesticide effectiveness thereof
This test arrangement is in the Xianyang, Shanxi province city; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 5% Hexythiazox wetting powder (commercial), 20% clofentezine suspension agent (commercial), 110g/L second mite azole suspending agent (autogamy), 10% fluorine mite piperazine suspending agent (autogamy).
Investigation apple tetranychus insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 60 days after the dispenser and is calculated preventive effect.Result of the test is as follows:
Table 7 fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control apple tetranychus test of pesticide effectiveness thereof
Can find out that by table 7 can effectively prevent and treat apple tetranychus after fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine are composite, control efficiency all is superior to the preventive effect of single agent, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example nine fourth fluorine mite esters and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control tea tree tealeaves mite test of pesticide effectiveness thereof
This test arrangement is in the Ya'an, Sichuan Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 5% Hexythiazox wetting powder (commercial), 20% clofentezine suspension agent (commercial), 110g/L second mite azole suspending agent (autogamy), 10% fluorine mite piperazine suspending agent (autogamy).
Investigation tea tree tealeaves acarid evil index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and is calculated preventive effect before the medicine.Result of the test is as follows:
Table 8 fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control tea tree tealeaves mite test of pesticide effectiveness thereof
Can find out that by table 8 can effectively prevent and treat tea tree tealeaves mite after fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine are composite, control efficiency all is superior to the preventive effect of single agent, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example ten fourth fluorine mite esters and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control oranges and tangerines beginning tetranychid test of pesticide effectiveness thereof
This test arrangement is Hanzhong City in Shaanxi Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 5% Hexythiazox wetting powder (commercial), 20% clofentezine suspension agent (commercial), 110g/L second mite azole suspending agent (autogamy), 10% fluorine mite piperazine suspending agent (autogamy).
Investigation oranges and tangerines beginning tetranychid insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 60 days after the dispenser and is calculated preventive effect.Result of the test is as follows:
Table 9 fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control oranges and tangerines beginning tetranychid test of pesticide effectiveness thereof
Can find out that by table 9 can effectively prevent and treat oranges and tangerines beginning tetranychid after fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine are composite, control efficiency all is superior to the preventive effect of single agent, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example 11 fourth fluorine mite esters and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control tomato goitre mite test of pesticide effectiveness thereof
This test arrangement is suburban area in the Xian District, Shanxi Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 5% Hexythiazox wetting powder (commercial), 20% clofentezine suspension agent (commercial), 110g/L second mite azole suspending agent (autogamy), 10% fluorine mite piperazine suspending agent (autogamy).
Investigation tomato goitre acarid evil index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and is calculated preventive effect before the medicine.Result of the test is as follows:
Table 10 fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and the composite control tomato goitre mite test of pesticide effectiveness thereof
Can find out that by table 10 can effectively prevent and treat tomato goitre mite after fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine are composite, control efficiency all is superior to the preventive effect of single agent, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
After draw through not comprovincial test throughout the country; Fourth fluorine mite ester and Hexythiazox, four mite piperazines, second mite azoles, fluorine mite piperazine and composite preventive effect to common insects such as Tetranychus urticae, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper thereof are all more than 95%; Be superior to single agent preventive effect, synergistic effect is obvious.
Claims (9)
1. composition pesticide that contains fourth fluorine mite ester; It is characterized in that containing active components A and active component B; Active components A and active component B weight ratio are 1: 70～70: 1; Described active components A is selected from fourth fluorine mite ester, and active component B is selected from a kind of in Hexythiazox, four mite piperazines, second mite azoles, the fluorine mite piperazine.
2. the composition pesticide that contains fourth fluorine mite ester according to claim 1 is characterized in that: the weight ratio of active components A and active component B is 1: 50～50: 1.
3. the composition pesticide that contains fourth fluorine mite ester according to claim 2 is characterized in that: the weight ratio of fourth fluorine mite ester and Hexythiazox is 1: 5～20: 1.
4. the composition pesticide that contains fourth fluorine mite ester according to claim 2 is characterized in that: the weight ratio of fourth fluorine mite ester and four mite piperazines is 1: 20～15: 1.
5. the composition pesticide that contains fourth fluorine mite ester according to claim 2 is characterized in that: the weight ratio of fourth fluorine mite ester and second mite azoles is 1: 5～35: 1.
6. the composition pesticide that contains fourth fluorine mite ester according to claim 2 is characterized in that: the weight ratio of fourth fluorine mite ester and fluorine mite piperazine is 1: 10～15: 1.
7. according to each described composition pesticide that contains fourth fluorine mite ester in the claim 1 to 6, it is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
8. the composition pesticide that contains fourth fluorine mite ester according to claim 7 is used to prevent and treat the application of crop pests.
9. application according to claim 8 is characterized in that: described insect comprises Tetranychus urticae, tetranychus viennensis, Panonychus citri, two spotted spider mite, beginning tetranychid, citrus red mite, tetranychus telarius, full pawl tetranychid, Tetranychus cinnabarinus, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, tealeaves mite, tomato goitre mite, pear sucker, oystershell scale, leafhopper.
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| CN102726419A (en) * | 2012-06-09 | 2012-10-17 | 广东中迅农科股份有限公司 | Synergistic acaricidal composition containing etoxazole and cyflumetofen |
| CN102726419B (en) * | 2012-06-09 | 2016-04-27 | 广东中迅农科股份有限公司 | A kind of Synergistic mite killing composition containing second mite azoles and cyflumetofen |
| CN103416409A (en) * | 2012-12-15 | 2013-12-04 | 海利尔药业集团股份有限公司 | Disinsection composition containing flutenzine and methoxyfenozide |
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| CN103271042A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-hexythiazox miticide composition |
| CN103271042B (en) * | 2013-04-10 | 2017-07-18 | 湖南农大海特农化有限公司 | Etoxazole-hexythiazomiticide miticide composition |
| CN104285971A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Acaricidal composition containing etoxazole and flutenzine |
| CN104542606A (en) * | 2014-12-24 | 2015-04-29 | 江西中迅农化有限公司 | Synergetic acaricidal composition containing cyenopyrafen and cyflumetofen |
| CN106305732A (en) * | 2015-06-18 | 2017-01-11 | 沈阳中化农药化工研发有限公司 | Flutenzine-containing insecticidal acaricidal composition |
| CN106305732B (en) * | 2015-06-18 | 2019-03-19 | 沈阳中化农药化工研发有限公司 | A kind of insecticide acaricide composition containing flufenzine |
| CN105123710A (en) * | 2015-09-28 | 2015-12-09 | 陕西先农生物科技有限公司 | Pesticide composition containing flufenzine and preparation method thereof |
| CN111771897A (en) * | 2019-04-04 | 2020-10-16 | 浙江省化工研究院有限公司 | A kind of acaricidal composition containing fenfenpyr and hexythifen |
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