CN102627986A - Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof - Google Patents
Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof Download PDFInfo
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- CN102627986A CN102627986A CN201210098605XA CN201210098605A CN102627986A CN 102627986 A CN102627986 A CN 102627986A CN 201210098605X A CN201210098605X A CN 201210098605XA CN 201210098605 A CN201210098605 A CN 201210098605A CN 102627986 A CN102627986 A CN 102627986A
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- China
- Prior art keywords
- parts
- ferrocene
- ethanol
- liquid fuel
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 239000000446 fuel Substances 0.000 title claims abstract description 37
- 239000007788 liquid Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 57
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 34
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 3
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims abstract 8
- 239000000243 solution Substances 0.000 claims abstract 5
- 239000011259 mixed solution Substances 0.000 claims abstract 4
- 235000019264 food flavour enhancer Nutrition 0.000 claims abstract 2
- 230000007613 environmental effect Effects 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 abstract description 8
- 239000000654 additive Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000000779 smoke Substances 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 239000003245 coal Substances 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 235000009781 Myrtillocactus geometrizans Nutrition 0.000 description 1
- 240000009125 Myrtillocactus geometrizans Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
本发明公开了一种环保醇基民用液体燃料及其制备方法，原料组分及各组分的质量份数为甲醇80-95份，乙醇3-5份，二氯甲烷1-3份，二茂铁3-10份，乙硫醇0.1-1份；将二茂铁倒入部分乙醇和二氯甲烷的混合溶液中，再倒入部分甲醇溶液使二茂铁完全溶解；用剩余的甲醇和乙醇与乙硫醇配制成的混合溶液作为增味剂，将两部分溶液混合在一起，即得产品。本发明加入乙醇和二氯甲烷，改善燃料的互溶性，提高燃料的透明度，减少析出沉淀的产生。将二茂铁作为消烟节能添加剂，可以大幅度提高燃烧效率、减少烟雾、防止环境污染。本发明可在常温常压下存储、运输、使用，无需特殊工艺处理，各项成本低廉，非常适合民用。The invention discloses an environmentally friendly alcohol-based civil liquid fuel and a preparation method thereof. The raw material components and the mass parts of each component are 80-95 parts of methanol, 3-5 parts of ethanol, 1-3 parts of dichloromethane, two 3-10 parts of ferrocene, 0.1-1 part of ethanethiol; pour ferrocene into a mixed solution of part of ethanol and dichloromethane, and then pour part of methanol solution to completely dissolve ferrocene; use the remaining methanol and The mixed solution prepared by ethanol and ethanethiol is used as a flavor enhancer, and the two parts of the solution are mixed together to obtain the product. The invention adds ethanol and dichloromethane to improve the mutual solubility of the fuel, increase the transparency of the fuel, and reduce the generation of precipitation. Using ferrocene as a smoke-eliminating and energy-saving additive can greatly improve combustion efficiency, reduce smoke, and prevent environmental pollution. The invention can be stored, transported and used under normal temperature and normal pressure without special processing, and the cost is low, which is very suitable for civil use.
Description
Technical field
The invention belongs to the fuel field, be specifically related to a kind of environmental protection alcohol-based domestic liquid fuel and preparation method thereof.
Background technology
China's oil starvation, weak breath, rich coal, according to the world energy sources statistics, about 1,000,000,000,000 tons of coal retained reserve is wherein verified 1,145 hundred million tons of workable reserve, and explored coal reserves accounts for 33.8% of world's coal reserves.Verified in the fossil energy reserves in the whole nation, oil and natural gas only accounts for 6%, and all the other 94% are coal.Therefore, coal is the main energy sources of China, and this energy structure can not change in following one period.About 75% of the present output of coal of China directly is used for burning, the main energy is provided for national economy and people's lives, has also brought the serious environmental pollution simultaneously.Based on more than, the development and utilization of substitute energy just becomes the focus of research, invents a kind of environment friendly alcohol civil liquid fuel, not only alleviates the nervous situation that the energy uses, and also meets the longterm planning of country " 12 " energy development.Novel environment friendly fuel should be sanitation and hygiene, safe, cheap and easy to get and easy to use, convenient transportation.But at present, various alcohol civil fuel is arranged on the market, but all ubiquity that the cigarette amount is big, burning not thoroughly, unstable, the carbon distribution of combustion processes and etc. many defectives.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection alcohol-based domestic liquid fuel and preparation method thereof, the present invention adds ethanol and methylene dichloride, improves the mutual solubility of fuel, improves the transparency of fuel, reduces and separates out sedimentary generation.Ferrocene as the fume-eliminating energy-saving additive, can be increased substantially efficiency of combustion, reduces smog, prevents the pollution of the environment.The present invention can store at normal temperatures and pressures, transports, use, and need not special process and handles, and each item is with low cost, is fit to very much civilian.
For realizing above-mentioned purpose, the present invention adopts following technical scheme:
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are methyl alcohol 80-95 part, ethanol 3-5 part, methylene dichloride 1-3 part, ferrocene 3-10 part, sulfur alcohol 0.1-1 part.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
Remarkable advantage of the present invention is:
(1) in the environmental protection alcohol-based domestic liquid fuel, adds ethanol, methylene dichloride mutual solvent, can improve the mutual solubility of liquid like this, improve clarity of liquor, reduce and separate out sedimentary generation.
(2) ferrocene is a kind of organometallics, also is ferrocene.It is as the fume-eliminating energy-saving additive in the present invention; Add uniform dissolution in the liquid fuel with less mass ratio; Can increase substantially efficiency of combustion, reduce smog, the positive effect that prevented the pollution of the environment, and the production cost of ferrocene is lower, be fit to extensive the use.
(3) the present invention is to be raw material with the thick methyl alcohol of cheapness, according to certain processing condition synthetic cleaning, environmental protection, high heating value liquid fuel, can store at normal temperatures and pressures, transports, use, and need not special process and handles, and each item is with low cost, is fit to very much civilian.
Embodiment
Embodiment 1
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are 80 parts of methyl alcohol, 5 parts of ethanol, 3 parts of methylene dichloride, 10 parts of ferrocene, 1 part of sulfur alcohol.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
Embodiment 2
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are 95 parts of methyl alcohol, 3 parts of ethanol, 1 part of methylene dichloride, 3 parts of ferrocene, 0.1 part of sulfur alcohol.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
Embodiment 3
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are 85 parts of methyl alcohol, 4 parts of ethanol, 2 parts of methylene dichloride, 5 parts of ferrocene, 0.5 part of sulfur alcohol.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
A kind of environmental protection alcohol-based domestic liquid fuel effect of combustion:
1. owing to fuel self structure characteristics, consume oxygen is less during burning, and fuel combustion is abundant, presents blue flame during stable burning, does not contain solid particulate in the flue gas, and products of combustion is mainly carbonic acid gas and water;
2. fuel bound nitrogen, sulphur content are very low, and nitride in the flue gas after the fuel combustion, that sulfide generates concentration is also extremely low, can obviously reduce emission of harmful substances.
3. this fuel is compared with liquefied gas stove with diesel oil, the expense that can cut down the consumption of energy, and alleviate pollution to environment.Its thermo-efficiency can reach about 60%.
The above is merely preferred embodiment of the present invention, and all equalizations of doing according to claim of the present invention change and modify, and all should belong to covering scope of the present invention.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210098605XA CN102627986A (en) | 2012-04-06 | 2012-04-06 | Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210098605XA CN102627986A (en) | 2012-04-06 | 2012-04-06 | Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102627986A true CN102627986A (en) | 2012-08-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210098605XA Pending CN102627986A (en) | 2012-04-06 | 2012-04-06 | Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102627986A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103980957A (en) * | 2014-04-04 | 2014-08-13 | 黄利 | Novel alcohol-based liquid fuel and preparation method thereof |
| CN106010676A (en) * | 2016-05-30 | 2016-10-12 | 贵州绿能燃料科技有限公司 | Preparation method for environment-friendly alcohol-based liquid fuel and prepared fuel |
| CN106190357A (en) * | 2016-08-25 | 2016-12-07 | 桂林浩新科技服务有限公司 | A kind of efficient environment protective fuel additive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050160662A1 (en) * | 2002-06-11 | 2005-07-28 | Oryxe Energy International, Inc. | Method and composition for using stabilized beta-carotene as cetane improver in hydrocarbonaceous diesel fuels |
| CN1818037A (en) * | 2006-03-07 | 2006-08-16 | 路俊杰 | Synthetic environmental-protective methanol fuel |
| CN101144037A (en) * | 2006-09-14 | 2008-03-19 | 蒋维均 | Nano composite alcohol group fuel |
| CN101619250A (en) * | 2009-07-15 | 2010-01-06 | 占小玲 | Methanol gasoline heat value agent |
-
2012
- 2012-04-06 CN CN201210098605XA patent/CN102627986A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050160662A1 (en) * | 2002-06-11 | 2005-07-28 | Oryxe Energy International, Inc. | Method and composition for using stabilized beta-carotene as cetane improver in hydrocarbonaceous diesel fuels |
| CN1818037A (en) * | 2006-03-07 | 2006-08-16 | 路俊杰 | Synthetic environmental-protective methanol fuel |
| CN101144037A (en) * | 2006-09-14 | 2008-03-19 | 蒋维均 | Nano composite alcohol group fuel |
| CN101619250A (en) * | 2009-07-15 | 2010-01-06 | 占小玲 | Methanol gasoline heat value agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103980957A (en) * | 2014-04-04 | 2014-08-13 | 黄利 | Novel alcohol-based liquid fuel and preparation method thereof |
| CN106010676A (en) * | 2016-05-30 | 2016-10-12 | 贵州绿能燃料科技有限公司 | Preparation method for environment-friendly alcohol-based liquid fuel and prepared fuel |
| CN106190357A (en) * | 2016-08-25 | 2016-12-07 | 桂林浩新科技服务有限公司 | A kind of efficient environment protective fuel additive and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120808 |