CN102618193A - Water-based composite adhesive - Google Patents
Water-based composite adhesive Download PDFInfo
- Publication number
- CN102618193A CN102618193A CN201210111882XA CN201210111882A CN102618193A CN 102618193 A CN102618193 A CN 102618193A CN 201210111882X A CN201210111882X A CN 201210111882XA CN 201210111882 A CN201210111882 A CN 201210111882A CN 102618193 A CN102618193 A CN 102618193A
- Authority
- CN
- China
- Prior art keywords
- monomer
- emulsion
- alkene class
- linking
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000000853 adhesive Substances 0.000 title claims abstract description 29
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 119
- 239000000839 emulsion Substances 0.000 claims abstract description 84
- -1 terpenes carboxylic acid Chemical class 0.000 claims abstract description 60
- 238000004132 cross linking Methods 0.000 claims abstract description 17
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001336 alkenes Chemical class 0.000 claims description 63
- 239000008367 deionised water Substances 0.000 claims description 33
- 229910021641 deionized water Inorganic materials 0.000 claims description 33
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 26
- 150000001875 compounds Chemical class 0.000 claims description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 238000004945 emulsification Methods 0.000 claims description 20
- 239000003995 emulsifying agent Substances 0.000 claims description 15
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 14
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 14
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 14
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 13
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 13
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 13
- 239000003999 initiator Substances 0.000 claims description 13
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 10
- 239000000080 wetting agent Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 8
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 8
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 7
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 6
- 229940077388 benzenesulfonate Drugs 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-M ethenesulfonate Chemical compound [O-]S(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-M 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 14
- 239000002904 solvent Substances 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 7
- 235000007586 terpenes Nutrition 0.000 abstract 5
- 150000003505 terpenes Chemical class 0.000 abstract 4
- 239000003431 cross linking reagent Substances 0.000 abstract 3
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000002985 plastic film Substances 0.000 abstract 1
- 229920006255 plastic film Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 39
- 238000012360 testing method Methods 0.000 description 17
- 239000013066 combination product Substances 0.000 description 14
- 229940127555 combination product Drugs 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 230000002688 persistence Effects 0.000 description 9
- 238000012856 packing Methods 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- 239000012467 final product Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 6
- 101100412856 Mus musculus Rhod gene Proteins 0.000 description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 description 6
- 235000010290 biphenyl Nutrition 0.000 description 6
- 239000004305 biphenyl Substances 0.000 description 6
- 125000006267 biphenyl group Chemical group 0.000 description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- 239000005025 cast polypropylene Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000005026 oriented polypropylene Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000863032 Trieres Species 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 238000009512 pharmaceutical packaging Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses water-based composite adhesive, which contains acrylate emulsion and a cross-linking agent, wherein the weight of the cross-linking agent is 0.1-6 percent of the weight of the acrylate emulsion; the cross-linking agent is any one or a mixture of hexamethylenediamine and adipic acid dihydrazide; and the acrylate emulsion is formed by copolymerizing a terpenes hard monomer, a terpenes soft monomer, a terpenes carboxylic acid monomer, a terpenes functional monomer, a dual-vinyl monomer and a terpenes cross-linking monomer through nuclear shells under an emulsion system. The adhesive is particularly suitable for dry-type composite adhesion between flexible package composite base materials such as a plastic film and a vacuum aluminized film which are processed through corona; has good leveling, fast drying, high transparency, capability of curing at room temperature, high initial strength, excellent peel strength, difficulty in mesh clogging and skinning, wide adaptability and low cost; and can be applied to various machine types, does not contain any organic solvent, can replace solvent adhesive at present completely, and belongs to environment friendly adhesive.
Description
Technical field
The invention belongs to the organic high molecular compound field, relate to the macromolecular compound that the carbon-to-carbon unsaturated bond reaction obtains, be specifically related to polyacrylic ester.
Background technology
The soft packaging dry type is compound to be that OPP oriented polypropylene (BOPP), SE (PVC), PS (PS), nylon (PA), Vilaterm (PE), cast polypropylene (CPP), polyester (PET), new LDPE (film grade) (LDPE), leaching membrane paper, pearly-lustre film and CPP or the base materials such as PET aluminium plating film, aluminium foil that utilize tackiness agent will pass through corona treatment are combined with each other; Thereby improved the application performance of wrapping material greatly, be widely used in food product pack, drug packaging, makeup and articles for washing packing etc.
The compound used tackiness agent of soft packaging dry type is divided into three kinds of solvent-borne type, no-solvent type and water-baseds.Solvent-based adhesive uses toluene or ETHYLE ACETATE to be solvent, and adopts isocyanic ester as solidifying agent, and big for environment pollution, safety in utilization is low; Simultaneously, in compound good finished product, dissolvent residual is arranged, be prone to infiltrate into the internal layer article, cause secondary pollution, do not meet the environmental regulation requirement of increasingly stringent.Monomer content such as no-solvent type composite gum free isocyanic ester are high, and are big for environment pollution.Aqueous composite adhesive adopts water as solvent, has the advantage of Environmental Safety, is used widely.Waterborne compound adhesive is divided into acrylate type and polyurethane-type.The composite adhered agent producing process of acrylate waterborne is simple, tack good, transparency is high, cost is low, but high temperature resistant and resistance to low temperature are relatively poor, and water-fast more bad, stripping strength passing in time can decay.Polyurethane-type waterborne compound adhesive complex manufacturing, tack is low, cost is high, but high temperature resistant good, water-fast better with resistance to low temperature.Patent of invention CN1888001 discloses a kind of dry composite water-thined adhesive in soft package of polyurethane/acrylate hydridization, but manufacture craft is comparatively complicated, and cost is higher, is difficult to suitability for industrialized production and popularization.
Summary of the invention
The technical problem that the present invention requires to solve provides a kind of waterborne compound adhesive, and this composite adhesive has the advantage that tack is good and high and low temperature resistance is good.
In order to solve the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of waterborne compound adhesive, this composite adhesive contain acrylic ester emulsion and weight percent is the linking agent of acrylic ester emulsion weight 0.1～6%, wherein,
Described linking agent is one or both in hexanediamine and the adipic dihydrazide;
Described acrylic ester emulsion is processed by the raw material of following weight part: alkene class hard monomer 25～50, alkene class soft monomer 40～70, alkene class carboxylic acid monomer 1～3; Alkene class functional monomer 1～3; Bi-vinyl monomer 0.1～1.5, alkene class cross-linking monomer 0.5～4.5, deionized water 60.75～158.4; Emulsifying agent 1.014～7.92, initiator 0.135～0.792; Wherein said preparing acrylate emulsion method is made up of following steps:
(1) earlier 50～70w% of deionized water and 50～90w% of emulsifying agent are added dispersed with stirring mixing in the preparatory emulsification still; Add alkene class hard monomer then, alkene class soft monomer, alkene class carboxylic acid monomer; Alkene class functional monomer and bi-vinyl monomer, emulsification obtains the monomer pre-emulsion;
(2) 30～50w%, residual emulsifier, 25～50w% of initiator and the 5～15w% of the obtained monomer pre-emulsion of step (1) with deionized water adds in the reaction kettle, reacts 20～60 minutes down at 80～85 ℃;
(3) in 3～6 hours, dripping the residual monomers pre-emulsion concentration that agent is prepared with drawing of residue is 20～50w% aqueous solution;
(4) in 0.5 hour, drip alkene class cross-linking monomer,, be cooled to below 40 ℃ after 1 hour 85 ℃ of insulations, transferring pH is 6.5～8.5, and discharging is subsequent use;
In above-mentioned steps (1)～(4),
Described alkene class hard monomer is one or more in vinylbenzene, TEB 3K and the methyl acrylate;
Described alkene class soft monomer is one or more in ethyl propenoate, Bing Xisuandingzhi, Isooctyl acrylate monomer and the isodecyl methacrylate;
Described alkene class carboxylic acid monomer is a vinylformic acid, one or more in methylacrylic acid and the cis-butenedioic anhydride;
Described functional monomer is one or both in Propylene glycol monoacrylate and the Hydroxyethyl acrylate;
Described bi-vinyl monomer is one or both in ethylene glycol dimethacrylate and the Phthalic acid, diallyl ester;
Described alkene class cross-linking monomer is one or both in diacetone-acryloamide(DAA) and the AAEM;
Described emulsifying agent is one or more in vinylsulfonate, two disodium sulfonates of alkyl, allyloxy fatty alcohol polyoxyethylene ether sulfate, alcohol ether mono succinate sulfonated ester, AEO and the sodium alkyl benzene sulfonate;
Described initiator is one or both in ammonium peroxydisulfate and the Potassium Persulfate.
Waterborne compound adhesive of the present invention can also contain the skimmer that weight percent is an ACRYLIC EMULSION weight 0.02～0.1%, the wetting agent of ACRYLIC EMULSION weight 0.1～0.4% and the sanitas of ACRYLIC EMULSION weight 0.04～0.1%.Wherein, described skimmer is this area skimmer commonly used, better is silicone antifoam agent, like Degussa company's T EGO805; Described wetting agent is this area wetting agent commonly used, better is Degussa company's T EGO245; Described sanitas is this area sanitas commonly used, like the KATHON LXE of Rhom and Hass.
Waterborne compound adhesive of the present invention can prepare according to this area preparation method commonly used, is about to acrylic ester emulsion and skimmer, and sanitas, wetting agent and linking agent both mixed and get.
Polyester modification hydroxyl polyacrylic ester of the present invention compared with prior art has the following advantages:
(1) in the waterborne compound adhesive of the present invention; Introduce functional monomers such as diacetone-acryloamide(DAA) and AAEM in the acrylic ester emulsion; They have two kinds of reactive groups; On the one hand and monomer polymerization, carry out crosslinking reaction, stripping strength, high and low temperature resistance and the persistence of raising tackiness agent with hexanediamine, adipic dihydrazide during film forming on the other hand; Add the bi-vinyl monomer simultaneously, make glue-line have the interpenetrating(polymer)networks result, improve the resistant of high or low temperature and the persistence of tackiness agent.
(2) adopt the diene cross-linking monomer, promote letex polymerization to form nucleocapsid and combine, help emulsion film forming, during with emulsion film forming fast crosslinking reaction combine, help improving the initial adhesion intensity of tackiness agent.
Embodiment:
Embodiment 1
(I) acrylic ester emulsion
(a) acrylic ester emulsion prescription
Alkene class hard monomer: vinylbenzene 30.5kg
Alkene class soft monomer: Bing Xisuandingzhi 62.5kg
Alkene class carboxylic acid monomer: methylacrylic acid 2.5kg
Alkene class functional monomer: Hydroxyethyl acrylate 2.5kg,
The bi-vinyl monomer: ethylene glycol dimethacrylate 0.1kg,
Alkene class cross-linking monomer: diacetone-acryloamide(DAA) 1.9kg,
Emulsifying agent: sodium alkyl benzene sulfonate 0.3kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 0.5kg, AEO 0.375kg, alcohol ether mono succinate sulfonated ester 0.5kg,
Initiator: ammonium peroxydisulfate 0.6kg
Deionized water: 120kg
(b) preparation method
(1) with deionized water 69.9kg, sodium alkyl benzene sulfonate 0.3kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 0.5kg, AEO 0.125kg and alcohol ether mono succinate sulfonated ester 0.5kg add dispersed with stirring mixing in the preparatory emulsification still; Add vinylbenzene 30.5kg then, Bing Xisuandingzhi 62.5kg, methylacrylic acid 2.5kg, Hydroxyethyl acrylate 2.5kg, ethylene glycol dimethacrylate 0.1kg, emulsification obtains the monomer pre-emulsion;
(2) with deionized water 49.4kg, AEO 0.25kg, the monomer pre-emulsion of the above-mentioned preparation of ammonium peroxydisulfate 0.3kg and 5w% add in the reaction kettle, react 60 minutes down at 80 ℃;
(3) in 4 hours, dripping off the residual monomer pre-emulsion of remaining above-mentioned preparation and the concentration of residue ammonium peroxydisulfate preparation is the aqueous solution of 30w%;
(4) in 0.5 hour dropping diacetone-acryloamide(DAA) 1.9kg; 85 ℃ the insulation 1 hour, be cooled to then 40 the degree with the downward modulation pH be 6.5, get final product acrylic ester emulsion.
(II) waterborne compound adhesive
(a) prescription
The acrylic ester emulsion of step (I) preparation: 99.3kg
Degussa company's T EGO805:0.05kg
The KATHONLXE:0.10kg of Rhom and Hass
Degussa company's T EGO245:0.20kg
Adipic dihydrazide: 0.35kg
(b) preparation method
With acrylic ester emulsion, skimmer, sanitas, wetting agent and linking agent mix, both.
(c) performance
Viscosity: 20cps (2#/30rpm/27 ℃), solid content: 40.8%.
The base material compound condition:
Spread (wet glue): 5.0g/m
2(except the PET film), 6.0g/m
2(PET film)
Upper glue roller line number: 160-180 line
Oven temperature: 75 ℃-80 ℃-85 ℃
Combined temp: 55 ℃
Recombination velocity: 80m/min
Normal temperature slaking: 24 hours
Performance measurement and testing method thereof:
The test of stripping strength; Method standard is according to GB/T8808-1988 " soft composite plastics material stripping test method "; It is an amount of to materials; 50mm is respectively removed at specimen width direction two ends, and it is 15mm (must not deviation surpass 0.1mm) that broad ways is evenly got the vertical, horizontal width, each 5 on the sample of length 200mm.Compound direction is vertically.
With composite bed and base material strip off 50mm in advance, first strip off part must not have obvious damage along the specimen length direction.Survey and can the about 20mm of sample one end be immersed middle processing of solvent (vinyl acetic monomer generally commonly used, acetone) if sample is difficult for strip off,, and after treating that solvent evaporates fully, carry out the test of stripping strength again the preparatory strip off of sample.
On trier, the longitudinal axis of sample strip off part is overlapped with the last lower clamp line of centres, and degree of tightness is suitable sample strip off two ends difference clamping partly.During test, the strip off part is not the T type with draw direction.Trial speed is 300mm/min, writes down the curve of peeling off in the stripping process.
Should be noted that it is qualified that its stripping strength is judged to if composite bed can not be peeled off or composite bed when fracture.
The measuring result of table 1 embodiment 1
Remarks: 1, high temperature is 121 ℃: combination product is tested stripping strength at 121 ℃ after boiling 40 minutes, and 2, low temperature-50 ℃: combination product is tested stripping strength at-50 ℃ after following 48 hours.3, persistence: put packing material in the laminated bag and test stripping strength after 3 months.4, stripping strength unit is: N/mm.
Embodiment 2
(I) acrylic ester emulsion
(a) acrylic ester emulsion prescription
Alkene class hard monomer: TEB 3K 50kg,
Alkene class soft monomer: ethyl propenoate 40kg
Alkene class carboxylic acid monomer: vinylformic acid 3kg
Alkene class functional monomer: Propylene glycol monoacrylate 1.5kg,
The bi-vinyl monomer: Phthalic acid, diallyl ester 1.0kg,
Alkene class cross-linking monomer: diacetone-acryloamide(DAA) 4.5kg;
Emulsifying agent: alkyl diphenyl disodium sulfonate 0.5kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 1.0kg, AEO 1.25kg, alcohol ether mono succinate sulfonated ester 1.0kg,
Initiator: Potassium Persulfate 0.4kg,
Deionized water: 110kg.
(b) preparation method
(1) with deionized water 55kg, alkyl diphenyl disodium sulfonate 0.5kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 1.0kg; It is even that AEO 0.25kg, alcohol ether mono succinate sulfonated ester 1.0kg add in the preparatory emulsification still dispersed with stirring, adds TEB 3K 50kg; Ethyl propenoate 40kg, vinylformic acid 3kg, Propylene glycol monoacrylate 1.5kg; Phthalic acid, diallyl ester 1.0kg, emulsification obtains the monomer pre-emulsion;
(2) with deionized water 53.8kg, AEO 1.0kg, the monomer pre-emulsion of the above-mentioned preparation of Potassium Persulfate 0.1kg and 5w% add in the reaction kettle, react 20 minutes down at 85 ℃;
(3) in 4 hours, dripping off the residual monomers pre-emulsion is the aqueous solution of 20w% with the concentration that remains the Potassium Persulfate preparation;
(4) in 0.5 hour dropping diacetone-acryloamide(DAA) 4.5kg; 85 ℃ of insulations 1 hour, be cooled to then below 40 ℃ and add ammoniacal liquor to transfer pH be 7.5, get final product acrylic ester emulsion.
(II) waterborne compound adhesive
(a) prescription
The acrylic ester emulsion of step (I) preparation: 85kg
Degussa company's T EGO805:0.085kg
The KATHONLXE:0.05kg of Rhom and Hass
Degussa company's T EGO245:0.085kg
Adipic dihydrazide: 5.5kg
Deionized water: 9.34kg
(b) preparation method
With acrylic ester emulsion, skimmer, sanitas, wetting agent and linking agent mix, both.
(c) performance
Viscosity: 200cps (2#/30rpm/25 ℃), solid content: 38.8%.
Test condition is with embodiment 1.
The mensuration result of table 2 embodiment 2
Remarks: 1, high temperature is 121 ℃: combination product is tested stripping strength at 121 ℃ after boiling 40 minutes, and 2, low temperature-50 ℃: combination product is tested stripping strength at-50 ℃ after following 48 hours.3, persistence: put packing material in the laminated bag and test stripping strength after 3 months.4, stripping strength unit is: N/mm.
Embodiment 3
(I) acrylic ester emulsion
(a) acrylic ester emulsion prescription
Alkene class hard monomer: TEB 3K 40kg,
Alkene class soft monomer: Bing Xisuandingzhi 40kg; The different certain herbaceous plants with big flowers ester of methylacrylic acid 10kg;
Alkene class carboxylic acid monomer: cis-butenedioic anhydride 1.0kg
Alkene class functional monomer: Propylene glycol monoacrylate 1.5kg, Hydroxyethyl acrylate 1.5kg,
The bi-vinyl monomer: ethylene glycol dimethacrylate 0.5kg, Phthalic acid, diallyl ester 1.0kg,
Alkene class cross-linking monomer: acetoacetoxy ethyl methacrylate 4.5kg,
Emulsifying agent: alkyl diphenyl disodium sulfonate 1.0kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 1.5kg, AEO 3.0kg, alcohol ether mono succinate sulfonated ester 0.50kg;
Initiator: ammonium peroxydisulfate 0.1kg, Potassium Persulfate 0.1kg,
Deionized water: 100kg
(b) preparation method
(1) with deionized water 70kg, alkyl diphenyl disodium sulfonate 1.0kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 1.5kg, AEO 1.0kg, alcohol ether mono succinate sulfonated ester 0.5kg; Add preparatory emulsification stirring tank and be uniformly dispersed, add TEB 3K 40kg, Bing Xisuandingzhi BA40kg; The different certain herbaceous plants with big flowers ester of methylacrylic acid 10kg, cis-butenedioic anhydride 1.0kg, Propylene glycol monoacrylate 1.5kg; Hydroxyethyl acrylate 1.5kg; Ethylene glycol dimethacrylate 0.5kg, Phthalic acid, diallyl ester 1.0kg, emulsification obtains the monomer pre-emulsion;
(2) with deionized water 29.9kg, AEO 2.0kg, the monomer pre-emulsion of ammonium peroxydisulfate 0.1kg and the above-mentioned preparation of 10w% add in the reaction kettle, react 40 minutes down at 82 ℃;
(3) in 4 hours, drip off residual monomers pre-emulsion and Potassium Persulfate the preparation concentration be the aqueous solution of 50w%;
(4) in 0.5 hour dropping acetoacetoxy ethyl methacrylate 4.5kg; 85 ℃ of insulations 1 hour, be cooled to then and add ammoniacal liquor below 40 degree to transfer pH be 7.0, get final product acrylic ester emulsion.
(II) waterborne compound adhesive
(a) prescription
The acrylic ester emulsion of step (I) preparation: 90.0kg
Degussa company's T EGO805:0.03kg
The KATHONLXE:0.08kg of Rhom and Hass
Degussa company's T EGO245:0.30kg
Hexanediamine: 5.5kg
Deionized water 4.09kg
(b) preparation method
With acrylic ester emulsion, skimmer, sanitas, wetting agent and linking agent mix, both.
(c) performance
Viscosity: 180cps (2#/30rpm/25 ℃), solid content: 48.8%.
Test condition is with embodiment 1.
The mensuration result of table 3 embodiment 3
Remarks: 1, high temperature is 121 ℃: combination product is tested stripping strength at 121 ℃ after boiling 40 minutes, and 2, low temperature-50 ℃: combination product is tested stripping strength at-50 ℃ after following 48 hours.3, persistence: put packing material in the laminated bag and test stripping strength after 3 months.4, stripping strength unit is: N/mm.
Embodiment 4
(I) acrylic ester emulsion
(a) acrylic ester emulsion prescription
Alkene class hard monomer: TEB 3K 25kg,
Alkene class soft monomer: ethyl propenoate 70kg
Alkene class carboxylic acid monomer: cis-butenedioic anhydride 1.0kg, vinylformic acid 0.5kg;
Alkene class functional monomer: Hydroxyethyl acrylate 2.5kg,
The bi-vinyl monomer: ethylene glycol dimethacrylate 0.1kg, Phthalic acid, diallyl ester 0.1kg,
Alkene class cross-linking monomer: diacetone-acryloamide(DAA) 0.8kg,
Emulsifying agent: allyloxy fatty alcohol polyoxyethylene ether sulfate 2.5kg, AEO 2.5kg,
Initiator: ammonium peroxydisulfate 0.3kg
Deionized water: 90kg
(b) preparation method
(1) with deionized water 50kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 2.5kg, AEO 1.0kg adds in the preparatory emulsification stirring tank and is uniformly dispersed; Add methyl acrylate 25kg, ethyl propenoate 70kg, vinylformic acid 0.5kg; Cis-butenedioic anhydride 1.0kg; Hydroxyethyl acrylate 2.5kg, ethylene glycol dimethacrylate 0.1kg and Phthalic acid, diallyl ester 0.1kg, emulsification obtains the monomer pre-emulsion;
(2) with deionized water 39.2kg, AEO 2.5kg, the monomer pre-emulsion of ammonium peroxydisulfate 0.1kg and the above-mentioned preparation of 15w% add in the reaction kettle, react 30 minutes down at 84 ℃;
(3) in 6 hours, dripping off the residual monomers pre-emulsion is the aqueous solution of 20w% with the concentration that remains the ammonium peroxydisulfate preparation;
(4) in 0.5 hour dropping diacetone-acryloamide(DAA) 0.8kg; 85 ℃ of insulations 1 hour, be cooled to then below 40 ℃ and add ammoniacal liquor to transfer pH be 8.5, get final product acrylic ester emulsion.
(II) waterborne compound adhesive
(a) prescription
The acrylic ester emulsion of step (I) preparation: 95.0kg
Degussa company's T EGO805:0.019kg
The KATHONLXE:0.038kg of Rhom and Hass
Degussa company's T EGO245:0.20kg
AH: 0.50kg
Deionized water 4.24kg
(b) preparation method
With acrylic ester emulsion, skimmer, sanitas, wetting agent and linking agent mix, both.
(c) performance
Viscosity: 180cps (2#/30rpm/25 ℃), solid content: 48.8%.
Test condition is with embodiment 1.
The mensuration result of table 4 embodiment 4
Remarks: 1, high temperature is 121 ℃: combination product is tested stripping strength at 121 ℃ after boiling 40 minutes, and 2, low temperature-50 ℃: combination product is tested stripping strength at-50 ℃ after following 48 hours.3, persistence: put packing material in the laminated bag and test stripping strength after 3 months.4, stripping strength unit is: N/mm.
Embodiment 5
(I) acrylic ester emulsion
(a) acrylic ester emulsion prescription
Alkene class hard monomer: TEB 3K 15kg, vinylbenzene 10kg,
Alkene class soft monomer: Bing Xisuandingzhi 35kg, Isooctyl acrylate monomer 35kg,
Alkene class carboxylic acid monomer: vinylformic acid 0.5kg, methylacrylic acid 0.5kg,
Alkene class functional monomer: Hydroxyethyl acrylate 0.5kg, Propylene glycol monoacrylate 0.5kg,
The bi-vinyl monomer: ethylene glycol dimethacrylate 0.1kg, Phthalic acid, diallyl ester 0.1kg,
Alkene class cross-linking monomer: diacetone-acryloamide(DAA) 1.0kg, AAEM 3.5kg;
Emulsifying agent: sodium vinyl sulfonate 0.3kg, alkyl diphenyl disodium sulfonate 0.5kg, AEO 0.6kg, allyl group aliphatic acid polyethenoxy ether sodium sulfate 0.1kg,
Initiator: ammonium peroxydisulfate 0.5kg
Deionized water: 120kg
(b) preparation method
(1) with deionized water 60kg, sodium vinyl sulfonate 0.3kg, alkyl diphenyl disodium sulfonate 0.5kg; It is even that AEO 0.45kg and allyl group aliphatic acid polyethenoxy ether sodium sulfate 0.05kg add in the preparatory emulsification still dispersed with stirring, adds vinylbenzene 10.0kg, TEB 3K 15kg; Bing Xisuandingzhi 35kg, Isooctyl acrylate monomer 35kg, methylacrylic acid 0.5kg; Vinylformic acid 0.5kg; Hydroxyethyl acrylate 0.5kg, Propylene glycol monoacrylate 0.5kg and ethylene glycol dimethacrylate 0.1kg, emulsification obtains the monomer pre-emulsion;
(2) with deionized water 59.3kg, AEO 0.15kg, allyl group aliphatic acid polyethenoxy ether sodium sulfate 0.05kg, the monomer pre-emulsion of ammonium peroxydisulfate 0.2kg and the above-mentioned preparation of 5w% add in the reaction kettle, react 35 minutes down at 83 ℃;
(3) in 3 hours, dripping off the residual monomers pre-emulsion is the aqueous solution of 30w% with the concentration that remains the ammonium peroxydisulfate preparation;
(4) in 0.5 hour dropping diacetone-acryloamide(DAA) 1.0kg and AAEM 3.5kg; 85 ℃ of insulations 1 hour, be cooled to then and add ammoniacal liquor below 40 degree to transfer pH be 8.0, get final product acrylic ester emulsion.
(II) waterborne compound adhesive
(a) prescription
The acrylic ester emulsion of step (I) preparation: 90.0kg
Degussa company's T EGO805:0.05kg
The KATHONLXE:0.08kg of Rhom and Hass
Degussa company's T EGO245:0.36kg
Hexanediamine 3.5kg;
AH: 1.0kg
Deionized water: 5.07kg
(b) preparation method
With acrylic ester emulsion, skimmer, sanitas, wetting agent and linking agent mix, both.
(c) performance
Viscosity: 33cps (2#/30rpm/25 ℃), solid content: 41.5%.
Test condition is with embodiment 1.
The survey of table 5 embodiment 5 decide the result
Remarks: 1, high temperature is 121 ℃: combination product is tested stripping strength at 121 ℃ after boiling 40 minutes, and 2, low temperature-50 ℃: combination product is tested stripping strength at-50 ℃ after following 48 hours.3, persistence: put packing material in the laminated bag and test stripping strength after 3 months.4, stripping strength unit is: N/mm.
Embodiment 6
(I) acrylic ester emulsion
(a) acrylic ester emulsion prescription
Alkene class hard monomer: TEB 3K 30kg
Alkene class soft monomer: ethyl propenoate 55kg, Isooctyl acrylate monomer 10kg
Alkene class carboxylic acid monomer: vinylformic acid 1.5kg
Alkene class functional monomer: Hydroxyethyl acrylate 3.5kg,
The bi-vinyl monomer: ethylene glycol dimethacrylate 0.1kg,
Alkene class cross-linking monomer: diacetone-acryloamide(DAA) 1.0kg;
Emulsifying agent: sodium vinyl sulfonate 2.3kg, AEO 3.7,
Initiator: Potassium Persulfate 0.4kg
Deionized water: 90kg
(b) preparation method
(1) preparation of monomer pre-emulsion: with deionized water 50kg; It is even that sodium vinyl sulfonate 2.0kg and AEO 3.4kg add preparatory emulsification still dispersed with stirring, adds TEB 3K 30kg, ethyl propenoate 55kg; Isooctyl acrylate monomer 10kg; Vinylformic acid 0.5kg, Hydroxyethyl acrylate 3.5kg and ethylene glycol dimethacrylate 0.1kg, emulsification obtains the monomer pre-emulsion;
(2) with deionized water 39.3kg, AEO 0.3kg, sodium vinyl sulfonate 0.3kg, the monomer pre-emulsion of Potassium Persulfate 0.1kg and the above-mentioned preparation of 5w% add in the reaction kettle, react 35 minutes down at 83 ℃;
(3) in 4 hours, dripping off the residual monomers pre-emulsion is the aqueous solution of 30w% with the concentration that remains the Potassium Persulfate preparation;
(4) in 0.5 hour dropping diacetone-acryloamide(DAA) 1.0kg; 85 ℃ of insulations 1 hour, be cooled to then and add ammoniacal liquor below 40 degree to transfer pH be 7.5, get final product acrylic ester emulsion.
(II) waterborne compound adhesive
(a) prescription
The acrylic ester emulsion of step (I) preparation: 95.0kg
AH: 0.95kg
Deionized water: 4.05kg
(b) preparation method
With acrylic ester emulsion, linking agent and water mix, both.
(c) performance
Viscosity: 300cps (2#/30rpm/25 ℃), solid content: 52.6%.
Test condition is with embodiment 1.
The mensuration result of table 6 embodiment 6
Remarks: 1, high temperature is 121 ℃: combination product is tested stripping strength at 121 ℃ after boiling 40 minutes, and 2, low temperature-50 ℃: combination product is tested stripping strength at-50 ℃ after following 48 hours.3, persistence: put packing material in the laminated bag and test stripping strength after 3 months.4, stripping strength unit is: N/mm.
Embodiment 7
(I) acrylic ester emulsion
(a) acrylic ester emulsion prescription
Alkene class hard monomer: TEB 3K 20kg, vinylbenzene 5kg, methyl acrylate 5kg
Alkene class soft monomer: ethyl propenoate 40kg, Isooctyl acrylate monomer 10kg, Bing Xisuandingzhi 15kg
Alkene class carboxylic acid monomer: vinylformic acid 0.5kg, vinylformic acid 0.5kg, cis-butenedioic anhydride 0.5kg,
Alkene class functional monomer: Hydroxyethyl acrylate 3.5kg,
The bi-vinyl monomer: ethylene glycol dimethacrylate 0.1kg,
Alkene class cross-linking monomer: diacetone-acryloamide(DAA) 0.5kg;
Emulsifying agent: AEO 5.5kg,
Initiator: Potassium Persulfate 0.4kg
Deionized water: 100kg
(b) preparation method
(1) preparation of monomer pre-emulsion: it is even that deionized water 60kg and AEO 4.0kg are added in the preparatory emulsification still dispersed with stirring, adds TEB 3K 20kg, vinylbenzene 5kg; Methyl acrylate 5kg, ethyl propenoate 40kg, Isooctyl acrylate monomer 10kg; Bing Xisuandingzhi 15kg, vinylformic acid 0.5kg, vinylformic acid 0.5kg; Cis-butenedioic anhydride 0.5kg, Hydroxyethyl acrylate 3.5kg and ethylene glycol dimethacrylate 0.1kg, emulsification obtains the monomer pre-emulsion;
(2) with deionized water 39.2kg, AEO 1.5kg, the monomer pre-emulsion of Potassium Persulfate 0.2kg and the above-mentioned preparation of 5w% add in the reaction kettle, react 35 minutes down at 83 ℃;
(3) in 4 hours, dripping off the residual monomers pre-emulsion is the aqueous solution of 20w% with the concentration that remains the Potassium Persulfate preparation;
(4) in 0.5 hour dropping diacetone-acryloamide(DAA) 0.5kg; 85 ℃ of insulations 1 hour, be cooled to then and add ammoniacal liquor below 40 degree to transfer pH be 7.5, get final product acrylic ester emulsion.
(II) waterborne compound adhesive
(a) prescription
The acrylic ester emulsion of step (I) preparation: 90.0kg
Hexanediamine 3.4kg;
AH: 2.0kg
Deionized water: 4.6kg
(b) preparation method
Acrylic ester emulsion, linking agent and water are mixed, both.
(c) performance
Viscosity: 160cps (2#/30rpm/25 ℃), solid content: 50.4%.
Test condition is with embodiment 1.
The mensuration result of table 7 embodiment 7
Remarks: 1, high temperature is 121 ℃: combination product is tested stripping strength at 121 ℃ after boiling 40 minutes, and 2, low temperature-50 ℃: combination product is tested stripping strength at-50 ℃ after following 48 hours.3, persistence: put packing material in the laminated bag and test stripping strength after 3 months.4, stripping strength unit is: N/mm.
Claims (2)
1. waterborne compound adhesive, this composite adhesive contains acrylic ester emulsion and weight percent is the linking agent of acrylic ester emulsion weight 0.1～6%, wherein,
Described linking agent is one or both in hexanediamine and the adipic dihydrazide;
Described acrylic ester emulsion is processed by the raw material of following weight part: alkene class hard monomer 25～50, alkene class soft monomer 40～70, alkene class carboxylic acid monomer 1～3; Alkene class functional monomer 1～3; Bi-vinyl monomer 0.1～1.5, alkene class cross-linking monomer 0.5～4.5, deionized water 60.75～158.4; Emulsifying agent 1.014～7.92, initiator 0.135～0.792; Wherein said preparing acrylate emulsion method is made up of following steps:
(1) earlier 50～70w% of deionized water and 50～90w% of emulsifying agent are added dispersed with stirring mixing in the preparatory emulsification still; Add alkene class hard monomer then, alkene class soft monomer, alkene class carboxylic acid monomer; Alkene class functional monomer and bi-vinyl monomer, emulsification obtains the monomer pre-emulsion;
(2) 30～50w%, residual emulsifier, 25～50w% of initiator and the 5～15w% of the obtained monomer pre-emulsion of step (1) with deionized water adds in the reaction kettle, reacts 20～60 minutes down at 80～85 ℃;
(3) in 3～6 hours, dripping the residual monomers pre-emulsion concentration that agent is prepared with drawing of residue is 20～50w% aqueous solution;
(4) in 0.5 hour, drip alkene class cross-linking monomer,, be cooled to below 40 ℃ after 1 hour 85 ℃ of insulations, transferring pH is 6.5～8.5, and discharging is subsequent use;
In above-mentioned steps (1)～(4),
Described alkene class hard monomer is one or more in vinylbenzene, TEB 3K and the methyl acrylate;
Described alkene class soft monomer is one or more in ethyl propenoate, Bing Xisuandingzhi, Isooctyl acrylate monomer and the isodecyl methacrylate;
Described alkene class carboxylic acid monomer is a vinylformic acid, one or more in methylacrylic acid and the cis-butenedioic anhydride;
Described functional monomer is one or both in Propylene glycol monoacrylate and the Hydroxyethyl acrylate;
Described bi-vinyl monomer is one or both in ethylene glycol dimethacrylate and the Phthalic acid, diallyl ester;
Described alkene class cross-linking monomer is one or both in diacetone-acryloamide(DAA) and the AAEM;
Described emulsifying agent is one or more in vinylsulfonate, two disodium sulfonates of alkyl, allyloxy fatty alcohol polyoxyethylene ether sulfate, alcohol ether mono succinate sulfonated ester, AEO and the sodium alkyl benzene sulfonate;
Described initiator is one or both in ammonium peroxydisulfate and the Potassium Persulfate.
2. the described a kind of waterborne compound adhesive of claim 1; It is characterized in that, also contain the skimmer that weight percent is an ACRYLIC EMULSION weight 0.02～0.1%, the wetting agent of ACRYLIC EMULSION weight 0.1～0.4% and the sanitas of ACRYLIC EMULSION weight 0.04～0.1% in this composite adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210111882XA CN102618193A (en) | 2012-04-16 | 2012-04-16 | Water-based composite adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210111882XA CN102618193A (en) | 2012-04-16 | 2012-04-16 | Water-based composite adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102618193A true CN102618193A (en) | 2012-08-01 |
Family
ID=46558411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210111882XA Pending CN102618193A (en) | 2012-04-16 | 2012-04-16 | Water-based composite adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102618193A (en) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103770419A (en) * | 2014-01-07 | 2014-05-07 | 无锡三帝特种高分子材料有限公司 | PE/BOPET (Polyethylene/Biaxially Oriented Poly(Ethylene Terephthalate)) composite packaging film and preparation method thereof |
| CN104497920A (en) * | 2014-11-27 | 2015-04-08 | 广东多正化工科技有限公司 | Water-based laminating adhesive and preparation method |
| CN105017912A (en) * | 2015-07-29 | 2015-11-04 | 苏州荣昌复合材料有限公司 | Acrylic emulsion coat |
| CN105062389A (en) * | 2015-08-26 | 2015-11-18 | 界首市天鸿新材料股份有限公司 | Adhesive for package paper |
| CN105531340A (en) * | 2013-09-23 | 2016-04-27 | Lg化学株式会社 | Acrylic emulsion adhesive, and production method for same |
| CN105555896A (en) * | 2013-09-26 | 2016-05-04 | 株式会社Lg化学 | Adhesive composition for polypropylene film and preparation method thereof |
| CN105969265A (en) * | 2016-05-26 | 2016-09-28 | 江阴市江泰高分子新材料有限公司 | High-performance waterborne pressure-sensitive adhesive and preparation method thereof and PE protective film |
| CN106147672A (en) * | 2015-04-07 | 2016-11-23 | 宏峰行化工(深圳)有限公司 | A kind of for moulding/mould compound aqueous polyurethane acrylate binding agent and preparation method thereof |
| CN106147659A (en) * | 2015-04-09 | 2016-11-23 | 宏峰行化工(深圳)有限公司 | A kind of for moulding/mould compound phosphoric acrylic ester binding agent and preparation method thereof |
| CN106221623A (en) * | 2016-08-25 | 2016-12-14 | 广东佰合新材料科技股份有限公司 | Flexible package aqueous moulds composite glue and preparation method thereof |
| CN106433299A (en) * | 2016-09-27 | 2017-02-22 | 广东佰合新材料科技股份有限公司 | Flexible packaging gravure-printing water-based ink vehicle and method for preparing same |
| CN106496368A (en) * | 2016-09-27 | 2017-03-15 | 威远翰林科技有限公司 | Aqueouss seal the post-processing approach of latex solution |
| CN106833451A (en) * | 2017-03-01 | 2017-06-13 | 芜湖海螺新材料有限公司 | A kind of ASA co-extrusion section bars privacy protection film and preparation method |
| CN106833450A (en) * | 2017-02-14 | 2017-06-13 | 东莞市创纬胶粘剂科技有限公司 | A kind of environmentally friendly latex and preparation method thereof |
| CN107474766A (en) * | 2017-07-13 | 2017-12-15 | 无锡海特新材料研究院有限公司 | A kind of peeling force low growth pressure-sensitive polyacrylate emulsion glue and its preparation method and application |
| CN108350140A (en) * | 2015-11-06 | 2018-07-31 | 巴斯夫欧洲公司 | The method for preparing aqueous binder |
| CN109153899A (en) * | 2016-11-07 | 2019-01-04 | 赛登化学株式会社 | The aqueous adhesive composition and releasable bonding sheet of releasable |
| CN109536086A (en) * | 2018-11-14 | 2019-03-29 | 南通高盟新材料有限公司 | Bi-component waterborne styrene-acrylic emulsion adhesive and preparation method thereof for boiling packaging |
| WO2019075037A1 (en) * | 2017-10-12 | 2019-04-18 | Miwon North America Incorporated | Acrylic emulsions modified with functional (meth)acrylates to enable crosslinking |
| CN110078524A (en) * | 2019-03-11 | 2019-08-02 | 山东天汇研磨耐磨技术开发有限公司 | A kind of dedicated latent dispersing agent of ceramic grinding and its manufacturing method |
| CN110527012A (en) * | 2019-06-06 | 2019-12-03 | 广西民族大学 | A kind of modified acrylate emulsion pressure sensitive adhesive preparation method and application |
| CN113249063A (en) * | 2021-05-20 | 2021-08-13 | 东莞市冠力胶业有限公司 | Water-based plastic substitute and preparation method thereof |
| CN113562284A (en) * | 2021-07-23 | 2021-10-29 | 上海紫丹食品包装印刷有限公司 | Food-grade packaging paper barrel |
| WO2022051884A1 (en) * | 2020-09-08 | 2022-03-17 | Dow Global Technologies Llc | Aqueous curable adhesive composition and laminated article thereof |
| CN115181467A (en) * | 2021-09-02 | 2022-10-14 | 佛山市三水新联邦化工有限公司 | Water-based anti-counterfeiting fragile paper acrylic resin coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008127543A (en) * | 2006-11-24 | 2008-06-05 | Asahi Kasei Chemicals Corp | Method for producing copolymer latex and coating composition |
| CN101864024A (en) * | 2010-06-13 | 2010-10-20 | 浙江大学 | Polyacrylate coating latex and preparation method thereof |
| CN102060954A (en) * | 2010-11-23 | 2011-05-18 | 广州慧谷化学有限公司 | Acrylic emulsion as well as preparation method and application thereof |
-
2012
- 2012-04-16 CN CN201210111882XA patent/CN102618193A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008127543A (en) * | 2006-11-24 | 2008-06-05 | Asahi Kasei Chemicals Corp | Method for producing copolymer latex and coating composition |
| CN101864024A (en) * | 2010-06-13 | 2010-10-20 | 浙江大学 | Polyacrylate coating latex and preparation method thereof |
| CN102060954A (en) * | 2010-11-23 | 2011-05-18 | 广州慧谷化学有限公司 | Acrylic emulsion as well as preparation method and application thereof |
Cited By (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105531340B (en) * | 2013-09-23 | 2018-09-18 | Lg化学株式会社 | Acrylate emulsion adhesive and preparation method thereof |
| CN105531340A (en) * | 2013-09-23 | 2016-04-27 | Lg化学株式会社 | Acrylic emulsion adhesive, and production method for same |
| CN105555896A (en) * | 2013-09-26 | 2016-05-04 | 株式会社Lg化学 | Adhesive composition for polypropylene film and preparation method thereof |
| CN103770419A (en) * | 2014-01-07 | 2014-05-07 | 无锡三帝特种高分子材料有限公司 | PE/BOPET (Polyethylene/Biaxially Oriented Poly(Ethylene Terephthalate)) composite packaging film and preparation method thereof |
| CN104497920B (en) * | 2014-11-27 | 2017-01-25 | 广东多正化工科技有限公司 | Water-based laminating adhesive and preparation method |
| CN104497920A (en) * | 2014-11-27 | 2015-04-08 | 广东多正化工科技有限公司 | Water-based laminating adhesive and preparation method |
| CN106147672B (en) * | 2015-04-07 | 2018-06-19 | 宏峰行化工(深圳)有限公司 | It is a kind of to be used to moulding/moulding compound aqueous polyurethane acrylate adhesive and preparation method thereof |
| CN106147672A (en) * | 2015-04-07 | 2016-11-23 | 宏峰行化工(深圳)有限公司 | A kind of for moulding/mould compound aqueous polyurethane acrylate binding agent and preparation method thereof |
| CN106147659B (en) * | 2015-04-09 | 2018-06-19 | 宏峰行化工(深圳)有限公司 | It is a kind of to be used to moulding/moulding compound phosphoric acrylic ester adhesive and preparation method thereof |
| CN106147659A (en) * | 2015-04-09 | 2016-11-23 | 宏峰行化工(深圳)有限公司 | A kind of for moulding/mould compound phosphoric acrylic ester binding agent and preparation method thereof |
| CN105017912A (en) * | 2015-07-29 | 2015-11-04 | 苏州荣昌复合材料有限公司 | Acrylic emulsion coat |
| CN105062389A (en) * | 2015-08-26 | 2015-11-18 | 界首市天鸿新材料股份有限公司 | Adhesive for package paper |
| CN108350140B (en) * | 2015-11-06 | 2021-03-05 | 巴斯夫欧洲公司 | Method for producing aqueous adhesives |
| CN108350140A (en) * | 2015-11-06 | 2018-07-31 | 巴斯夫欧洲公司 | The method for preparing aqueous binder |
| CN105969265A (en) * | 2016-05-26 | 2016-09-28 | 江阴市江泰高分子新材料有限公司 | High-performance waterborne pressure-sensitive adhesive and preparation method thereof and PE protective film |
| CN106221623A (en) * | 2016-08-25 | 2016-12-14 | 广东佰合新材料科技股份有限公司 | Flexible package aqueous moulds composite glue and preparation method thereof |
| CN106496368A (en) * | 2016-09-27 | 2017-03-15 | 威远翰林科技有限公司 | Aqueouss seal the post-processing approach of latex solution |
| CN106433299A (en) * | 2016-09-27 | 2017-02-22 | 广东佰合新材料科技股份有限公司 | Flexible packaging gravure-printing water-based ink vehicle and method for preparing same |
| CN109153899A (en) * | 2016-11-07 | 2019-01-04 | 赛登化学株式会社 | The aqueous adhesive composition and releasable bonding sheet of releasable |
| CN106833450A (en) * | 2017-02-14 | 2017-06-13 | 东莞市创纬胶粘剂科技有限公司 | A kind of environmentally friendly latex and preparation method thereof |
| CN106833451A (en) * | 2017-03-01 | 2017-06-13 | 芜湖海螺新材料有限公司 | A kind of ASA co-extrusion section bars privacy protection film and preparation method |
| CN107474766A (en) * | 2017-07-13 | 2017-12-15 | 无锡海特新材料研究院有限公司 | A kind of peeling force low growth pressure-sensitive polyacrylate emulsion glue and its preparation method and application |
| WO2019075037A1 (en) * | 2017-10-12 | 2019-04-18 | Miwon North America Incorporated | Acrylic emulsions modified with functional (meth)acrylates to enable crosslinking |
| CN109536086A (en) * | 2018-11-14 | 2019-03-29 | 南通高盟新材料有限公司 | Bi-component waterborne styrene-acrylic emulsion adhesive and preparation method thereof for boiling packaging |
| CN110078524A (en) * | 2019-03-11 | 2019-08-02 | 山东天汇研磨耐磨技术开发有限公司 | A kind of dedicated latent dispersing agent of ceramic grinding and its manufacturing method |
| CN110527012A (en) * | 2019-06-06 | 2019-12-03 | 广西民族大学 | A kind of modified acrylate emulsion pressure sensitive adhesive preparation method and application |
| WO2022051884A1 (en) * | 2020-09-08 | 2022-03-17 | Dow Global Technologies Llc | Aqueous curable adhesive composition and laminated article thereof |
| CN116057137A (en) * | 2020-09-08 | 2023-05-02 | 陶氏环球技术有限责任公司 | Aqueous curable adhesive composition and its laminate |
| EP4211196A4 (en) * | 2020-09-08 | 2024-05-29 | Dow Global Technologies LLC | Aqueous curable adhesive composition and laminated article thereof |
| CN113249063A (en) * | 2021-05-20 | 2021-08-13 | 东莞市冠力胶业有限公司 | Water-based plastic substitute and preparation method thereof |
| CN113249063B (en) * | 2021-05-20 | 2022-11-04 | 东莞市冠力胶业有限公司 | Water-based plastic substitute and preparation method thereof |
| CN113562284A (en) * | 2021-07-23 | 2021-10-29 | 上海紫丹食品包装印刷有限公司 | Food-grade packaging paper barrel |
| CN115181467A (en) * | 2021-09-02 | 2022-10-14 | 佛山市三水新联邦化工有限公司 | Water-based anti-counterfeiting fragile paper acrylic resin coating and preparation method thereof |
| CN115181467B (en) * | 2021-09-02 | 2023-05-23 | 佛山市三水新联邦化工有限公司 | Acrylic resin coating of water-based anti-counterfeiting fragile paper and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102618193A (en) | Water-based composite adhesive | |
| CN101372607B (en) | Emulsion pressure-sensitive adhesive for soft PVC electric adhesive tape and preparation thereof | |
| CN106085309B (en) | Automobile floor leather melt pressure sensitive glue composition and preparation method thereof | |
| CN113004494B (en) | Modified epoxy resin, preparation method and emulsion preparation method thereof, and application of waterproof coating | |
| CN107189732B (en) | A kind of high durable thermoplastic polyolefin water-proof coiled material hot-fusible pressure-sensitive adhesive and preparation method thereof | |
| CN103725231B (en) | Adhesive material for adhesive tapes and preparation method thereof | |
| CN100358960C (en) | Thermosetting adhesive tape or sheet, and manufacturing method thereof | |
| CN103059784A (en) | Water-based plastic-plastic composite adhesive for food and drug flexible packaging and preparation method thereof | |
| CN101168650A (en) | Single-component self-crosslinking emulsion adhesive for dry-type composite membrane and preparation method thereof | |
| CN103031090A (en) | Acid-free OCA and adhesive belt and fabrication method of acid-free OCA and adhesive belt | |
| CN101418194A (en) | Double-sided pressure-sensitive adhesive sheet and method for producing the same | |
| CN101225271A (en) | Water-based all-purpose adhesive and method for preparing same | |
| CN102399501A (en) | Re-peelable adhesive sheet | |
| CN112391131B (en) | Environment-friendly water-soluble acrylate pressure-sensitive adhesive, adhesive tape and preparation method and application thereof | |
| KR20190003486A (en) | Self-adhesive layer | |
| CN102212317A (en) | Adhesive agent of polaroid and preparation method for polaroid by using adhesive agent | |
| CN111363504A (en) | Moisture-absorption curing type acrylate pressure-sensitive adhesive and preparation method thereof | |
| CN102477264A (en) | Double-sided adhesive tape | |
| CN107987737A (en) | A kind of UV pressure-sensitive adhesives mixture and its preparation method and application | |
| CN116018384A (en) | How to separate the junction | |
| CN1036600C (en) | Hot-melt adhesive | |
| KR20190003485A (en) | Self-adhesive layer | |
| CN107903353A (en) | Printing in textiles table glue and preparation method thereof | |
| CN102732192A (en) | Emulsion acrylate pressure-sensitive adhesive, preparation method and application thereof | |
| CN107254270B (en) | A kind of high adhesion force aqueous laminating adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120801 |