CN102617094B - Inorganic heat-storage, energy-saving and temperature-regulating wall material - Google Patents
Inorganic heat-storage, energy-saving and temperature-regulating wall material Download PDFInfo
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- CN102617094B CN102617094B CN 201210097827 CN201210097827A CN102617094B CN 102617094 B CN102617094 B CN 102617094B CN 201210097827 CN201210097827 CN 201210097827 CN 201210097827 A CN201210097827 A CN 201210097827A CN 102617094 B CN102617094 B CN 102617094B
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- 239000000463 material Substances 0.000 title claims abstract description 40
- 238000005338 heat storage Methods 0.000 title abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 22
- 239000004743 Polypropylene Substances 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 10
- -1 polypropylene Polymers 0.000 claims abstract description 10
- 229920001155 polypropylene Polymers 0.000 claims abstract description 10
- 229920002472 Starch Polymers 0.000 claims abstract description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008107 starch Substances 0.000 claims abstract description 7
- 235000019698 starch Nutrition 0.000 claims abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010425 asbestos Substances 0.000 claims abstract description 6
- 239000011324 bead Substances 0.000 claims abstract description 6
- 239000011575 calcium Substances 0.000 claims abstract description 6
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 6
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 6
- 210000002268 wool Anatomy 0.000 claims abstract description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004816 latex Substances 0.000 claims description 8
- 229920000126 latex Polymers 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 239000005871 repellent Substances 0.000 abstract description 4
- 230000002940 repellent Effects 0.000 abstract description 4
- 238000000926 separation method Methods 0.000 abstract description 4
- 239000011232 storage material Substances 0.000 abstract description 4
- 239000004570 mortar (masonry) Substances 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 239000011470 perforated brick Substances 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 abstract 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 abstract 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 abstract 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 abstract 1
- 239000012782 phase change material Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 238000010276 construction Methods 0.000 description 15
- 238000009413 insulation Methods 0.000 description 7
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- 239000010410 layer Substances 0.000 description 6
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- 238000012360 testing method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
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- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
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- 231100000252 nontoxic Toxicity 0.000 description 1
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- 230000036314 physical performance Effects 0.000 description 1
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Landscapes
- Finishing Walls (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Disclosed is an inorganic heat-storage, energy-saving and temperature-regulating wall material. The technical scheme includes that a certain quantity of high alumina cement, vitreous beads, aluminum silicate powder, bentonite, redispersible polymer powder, hydroxypropyl methyl cellulose, polypropylene fibers, starch ether 6200, gray calcium powder, water repellent or waterproofing agent, air-entraining agent and asbestos wool are mixed, and are sufficiently mixed in a cyclone separation manner and packaged to form a finished product. When heated (by heat sources such as sunlight and the like), the low-carbon heat-storage, energy-saving and automatic temperature-regulating wall material becomes liquid when reaching saturated temperature, and heat energy is stored; and when external temperature is lower than set temperature, the heat-storage material begins to release heat, after the heat is released thoroughly, the phase-change material becomes solid from the liquid, and the process runs in circle. The inorganic heat-storage, energy-saving and temperature-regulating wall material can be made into a section, a plate, mortar and a perforated brick, can absorb sound wave, is elastic, and vibrates, rebounds and reversely absorbs under sound wave impact, frequencies of the material are different, structural vibration is relieved, and the purpose of eliminating noise is achieved.
Description
Technical field
The present invention relates to a kind of natural inorganic accumulation of heat building material technical field, specifically a kind of inorganic heat-conserving energy-saving multi temperature adjustment materials for wall.
Background technology
As everyone knows, existing building is with body of wall and to keep the material that body of wall energy-saving heat preserving system adopts more single, particularly in northern China, for making the construction wall insulation, satisfy the index of country energy-conservation 50%, all taking increases thick thick polyurathamc plate or the extruded sheet of benzene plate, 80mm of one deck 110mm to wall body structure, although can play certain heat insulation effect, has easy firing and poisonous, variety of issues such as work-ing life short, the construction complicated, easily slippage, cohesive strength difference.At present, be difficult to reach energy-conservation 65% index, even if can reach, its construction is loaded down with trivial details, and difficulty is very big, brings very big difficulty for outer the decoration and thickness 110mm is above.Implement State Council's " No. [2011] 46, promulgated by the State Council " about strengthening and improve firemanic suggestion and house town and country construction portion of the Ministry of Public Security and unite " covil construction external thermal insulation system and the decoration of exterior wall fire prevention temporary provisions " issued and reduce fire failure for implementing, suddenly to wait to seek and substitute the novel material research and development.
Under the background of global financial crisis; National Development and Reform Committee has at first proposed with energy-conservation as first means that solve crisis; and China was defined as the national economy first pillar industry with construction industry (improving the basic living conditions of the people by development of real estate) in recent years; therefore, to replace the material of construction of old heat-insulating property difference be the new problem that the professional and technical personnel is concentrating on studies always to the novel heat insulation material of construction.
Summary of the invention
The purpose of this invention is to provide a kind of inorganic heat-conserving energy-saving multi temperature adjustment materials for wall that utilizes the natural inorganic mineral material to realize sunlight is stored and discharged.It is the characteristic of utilizing phase change heat storage material, all thermals source such as the solar energy of pollution-free cheapness, electric energy has directly been stored the supplemental heat source that is used as lagging material and energy-conservation.
The object of the present invention is achieved like this: it comprises following composition and parts by weight: 10 parts of 42.5 grades of high-alumina cements; glass bead 4.0-10.0 part of rate of closed hole 〉=50%; aluminium silicate powder 2.0-5.0 part; wilkinite 1.0-3.0 part; redispersable latex powder 0.12-0.35 part; Vltra tears 0.04-0.09 part; polypropylene fibre 0.12-0.20 part; starch ethers 6200 0.06-0.20 parts; ash calcium powder 0.65-2.5 part; hydrophober or water-resisting agent 0.08-0.20 part are as alkylphenol oxyethane 0.06-0.12 part of air entrapment agent, asbestos wool 0.6-1.2 part.
42.5 grades of high-alumina cements of the present invention also claim aluminosulfate cement.
The dry-mix additive series product that polypropylene fibre of the present invention selects for use Beijing Orient Fu Cheng company limited to produce for polypropylene fibre FC-05(), has cracking resistance/antiseepage/shock resistance/tension/improve workability.
Redispersion latex powder F2805 of the present invention, Vltra tears, starch ethers 6200 is as the alkylphenol oxyethane of air entrapment agent and belong to 206 organosilyl hydrophober and also all be selected from the dry-mix additive series product that Beijing Orient Fu Cheng company limited produces.
Principle of work of the present invention is: utilize natural inorganic mineral matter shale and pitchstone to select it can the expanded absorption storage of solar energy of lightweight (calorific potential), it can discharge energy again as the supplemental heat source material of regulating room temp when environment change, and is not subjected to the luminous energy that influences sun power of overcast and rainy mist directly to penetrate the complete earth surface that is radiated of atmospheric layer again to be absorbed by the mineral substance heat-storing material and store the low-carbon energy-saving heat accumulating dry powder of producing the supplemental heat source material that is applicable in the building trade again through the present invention.
Solar radiation wavelength 0.38～0.76 μ m, can be mapped to earth surface, and the rotation of the earth and around the oval-shaped orbital motion of the sun, the distance of the sun and the earth is a variable, its energy everywhere identity distance from and change, sunlight wavelength 0.3～3 μ m ray heat energy maximum, its storage heat energy of inorganic heat-conserving energy-saving multi temperature adjustment materials for wall is the highest, the corresponding radiation quantity 604W/m of sunlight
2Shared per-cent 47%(visible light), when inorganic heat-conserving energy-saving multi temperature adjustment materials for wall of the present invention be coated with touch exterior wall after the ratio of its accumulation of heat time and heat release time be a constant, be that an equivalent correction yarn is counted δ=0.33～0.266 according to test result, the inorganic heat-conserving energy-saving multi temperature adjustment of the present invention materials for wall is only measured its numerical value under steady state, and the heat conduction yarn of real phase-transition heat-storage is counted δ * λ (stationary value of phase change heat storage material), i.e. equivalent heat conduction yarn number.
Application purpose of the present invention provides a kind of exterior wall of novel energy-conserving lightweight, and interior wall phase-change thermal-storage material is incorporated in concrete, the mortar and can stores heat, and reaches heat preservation energy-saving 65%, reduces cost, improves operating efficiency, economical with materials thereby reach.
Advantage of the present invention:
1, the present invention is the energy-conservation theory according to Germany " three liters of rooms of BASF ", through exploration practice, now form the production technology exploitation and used a whole set of relatively rounded system, satisfied energy-conservation 65% requirement fully, the body of wall of making through the present invention, thermal conductivity is little, heat-retaining capacity is big, its physical performance index, and the center test is qualified fully after tested.
2, inorganic heat-conserving energy-saving multi temperature adjustment materials for wall adaptability is strong, cohesive strength is big, be nontoxic, tasteless, harmless natural environmental-protective material, be to belong to the lightweight float stone rock that condenses after the volcanic explosion, volcanic ash is made base-material or carrier, in producing and constructing use, can not produce the pollution to environment, thermal insulation layer has certain ventilative and phase transition temperature effect, human settlements wherein, can not produce feeling of oppression and heat winter, can not produce baking sense summer, the house reaches " cold of winter-warm syndrome summer " by heat insulating, simultaneously, lagging material of the present invention is radiationless, sound insulation is good, is of value to occupant's comfortable health.If with lagging material of the present invention by with the combination of existing building Materials science standard, alternative air-conditioning, taking full advantage of solar radiation can save energy.
3, inorganic heat-conserving energy-saving multi temperature adjustment materials for wall can use separately, and self-organizing system is made section bar, sheet material, mortar, perforated brick can absorb sound wave, has elasticity, under sonic impinging, produce and tremble, rebound, absorb reverse, be transformed into different frequency, alleviate structure quake, reach the purpose of noise elimination.
4, phase-transition heat-storage energy of the present invention is bigger, and 280j/g～160j/g is subjected to the steady heat effect when indoor, when indoor air temperature rose or descends, the wall body structure layer can absorb heat or release of heat, is beneficial to indoor maintaining constant temperature, improve indoor environmental quality, it is obvious to substitute air conditioner energy saving.
5, make insulating layer of external wall, no hollowing does not ftracture, and Wind-Pressure Resistance is shock-resistant, good weatherability; Need not establish gas cloud, avoid under the negative blast state, because of the destruction that volume of air in the thermal insulation layer expands and causes the Highrise buildings thermal insulation layer, particularly the wind suction prevention ability is strong.
6, fire performance is good, belongs to A level incombustible material, does not burn under the naked light state, has solved the requirement of buildings fire-protection rating, and no flue dust disaster is pollution-free.
7, the freeze-thaw-ability is strong, with basic unit metope bonding firmly, no hollow, sound construction avoids occurring the body of wall dewfall, anti-rain corrodes, the increase weathering resistance.The present invention can be widely used in the bonding of wall body decoration, ceramic tile, reason stone and metope, to satisfy different requirement of client.
To be described in further detail the present invention by example below, but following example only is the present invention's example wherein that do not represent the rights protection scope that the present invention limits, the scope of the present invention is as the criterion with claims.
Embodiment
Example 1:
Get 1000 kilograms of 42.5 grades of high-alumina cements successively; 700 kilograms of the glass beads of rate of closed hole 〉=50%; 420 kilograms of aluminium silicate powder; 240 kilograms of wilkinites; and 25 kilograms redispersable latex powder F2805; 7 kilograms Vltra tears; 16 kilograms polypropylene fibre (FC-05), the grey calcium powder that 15 kilograms of starch etherss are 6200,200 kilograms; 15 kilograms 206 organosilicon moisture repellents; 10 kilograms of alkylphenol oxyethane as air entrapment agent; 80 kilograms of asbestos wools join in the mixing tank for coating colors, and by behind the abundant mixing of cyclonic separation; fully after the mixing packing, namely become inorganic heat-conserving energy-saving multi temperature adjustment materials for wall finished product of the present invention.
Using method: after becoming packed fortune to put the building site product of the present invention, need not add any material, only need add an amount of water back that stirs and directly go up external wall construction (replacing lime mortar or sand-cement slurry), once floating, thickness sets up on their own as required, mainly be to change according to on-site temperature in four seasons, generally in 15～30 millimeters scopes; Curing need not health voluntarily, labor and material saving, and its surface, construction back is the nature canescence.The present invention is equally applicable to the indoor wall construction, is beneficial to decoration, whitewashes, adorns ceramic tile etc.
Detect through national building materials test center, its physical and mechanical property index is qualified, sees Table one and table two.
Example 2:
Get 1000 kilograms of 42.5 grades of high-alumina cements successively; 550 kilograms of the glass beads of rate of closed hole 〉=50%; 450 kilograms of aluminium silicate powder; 200 kilograms of wilkinites; and 20 kilograms redispersable latex powder F2805; 8 kilograms Vltra tears; 15 kilograms polypropylene fibre (FC-05), the grey calcium powder that 10 kilograms of starch etherss are 6200,150 kilograms; 15 kilograms 206 organosilicon moisture repellents; 11 kilograms of alkylphenol oxyethane as air entrapment agent; the double centner asbestos wool joins in the mixing tank for coating colors, and by behind the abundant mixing of cyclonic separation; fully after the mixing packing, namely become inorganic heat-conserving energy-saving multi temperature adjustment materials for wall finished product of the present invention.
Using method: after becoming packed fortune to put the building site product of the present invention, need not add any material, only need add an amount of water back that stirs and directly go up external wall construction (replacing lime mortar or sand-cement slurry), once floating, thickness sets up on their own as required, mainly be to change according to on-site temperature in four seasons, generally in 15～30 millimeters scopes; Curing need not health voluntarily, labor and material saving, and its surface, construction back is the nature canescence.The present invention is equally applicable to the indoor wall construction, is beneficial to decoration, whitewashes, adorns ceramic tile etc.
After testing, its physical and mechanical property index is also all in table one and table two scope.
Example 3:
Get 1000 kilograms of 42.5 grades of high-alumina cements successively; 800 kilograms of the glass beads of rate of closed hole 〉=50%; 300 kilograms of aluminium silicate powder; 150 kilograms of wilkinites; and 25 kilograms redispersable latex powder F2805; 5 kilograms Vltra tears, 13 kilograms polypropylene fibre (FC-05), 18 kilograms of starch etherss 6200; the grey calcium powder of double centner; 16 kilograms 206 organosilicon moisture repellents, 8 kilograms of alkylphenol oxyethane as air entrapment agent, 110 kilograms of asbestos wools; join in the mixing tank for coating colors; and by behind the abundant mixing of cyclonic separation, fully after the mixing packing, namely become inorganic heat-conserving energy-saving multi temperature adjustment materials for wall finished product of the present invention.
Using method of the present invention and range of application are identical with example 1.
After testing, its physical and mechanical property index is also all in table one and table two scope.
The inorganic heat-conserving energy-saving multi temperature adjustment of table one materials for wall technical indicator
Physical and mechanical property after the inorganic heat-conserving energy-saving multi thermal control material sclerosis of table two
Annotate: invaded bubble in the water 24 hours, if the water regain of system that only has float coat and have whole protective layers is less than 500g/m
2The time, can not detect freeze-thaw resistance.
Claims (3)
1. inorganic heat-conserving energy-saving multi temperature adjustment materials for wall; it comprises following composition and parts by weight: 10 parts of 42.5 grades of high-alumina cements; glass bead 4.0-10.0 part of rate of closed hole 〉=50%; aluminium silicate powder 2.0-5.0 part; wilkinite 1.0-3.0 part; redispersable latex powder 0.12-0.35 part; Vltra tears 0.04-0.09 part; polypropylene fibre 0.12-0.20 part; starch ethers 6200 0.06-0.20 parts, grey calcium powder 0.65-2.5 part, hydrophober or water-resisting agent 0.08-0.20 part; as alkylphenol oxyethane 0.06-0.12 part of air entrapment agent, asbestos wool 0.6-1.2 part.
2. inorganic heat-conserving energy-saving multi temperature adjustment materials for wall according to claim 1, it is characterized in that: polypropylene fibre is polypropylene fibre FC-05.
3. inorganic heat-conserving energy-saving multi temperature adjustment materials for wall according to claim 1, it is characterized in that: redispersable latex powder is redispersable latex powder F2805.
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| CN 201210097827 CN102617094B (en) | 2012-04-06 | 2012-04-06 | Inorganic heat-storage, energy-saving and temperature-regulating wall material |
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| CN 201210097827 CN102617094B (en) | 2012-04-06 | 2012-04-06 | Inorganic heat-storage, energy-saving and temperature-regulating wall material |
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| CN103351132B (en) * | 2013-06-25 | 2015-07-08 | 天长市开林化工有限公司 | Environmentally-friendly interior wall putty powder |
| CN103467034B (en) * | 2013-08-16 | 2015-07-08 | 张自喜 | Inorganic wall heat insulation mortar |
| CN103467028B (en) * | 2013-09-16 | 2016-01-20 | 安方高科电磁安全技术(北京)有限公司 | Thermal insulation mortar |
| CN104844117A (en) * | 2015-05-30 | 2015-08-19 | 佛山市佳密特防水材料有限公司 | Light-weight flexible cohesive-failure ceramic tile adhesive |
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| US8586512B2 (en) * | 2007-05-10 | 2013-11-19 | Halliburton Energy Services, Inc. | Cement compositions and methods utilizing nano-clay |
| CN101575191B (en) * | 2008-05-08 | 2012-09-05 | 四川蜂巢科技有限公司 | Expanded and vitrified microsphere insulating material for construction wall and production process |
| CN101759416A (en) * | 2009-12-25 | 2010-06-30 | 唐山市思远涂料有限公司 | Thermal insulation building mortar and preparation process thereof |
| CN102241907A (en) * | 2011-05-10 | 2011-11-16 | 安徽省建筑科学研究设计院 | Elastic crack-resistant insulation putty for external thermal insulation system of rockwool panel external wall without crack-resistant protective coating |
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Effective date of registration: 20180820 Address after: 130114 Cong Village, Lanjia Town, Kuancheng District, Changchun, Jilin Patentee after: Changchun sunshine inorganic phase change heat insulation sound insulation building material Co.,Ltd. Address before: 110031 No. 30, bu Yunshan Road, Huanggu District, Shenyang, Liaoning. Patentee before: Liu Lirong |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231026 Address after: Room 736, Building 2, Beicheng Yuyuan, Intersection of Haoyue Road and Jianyang Street, Lvyuan District, Changchun City, Jilin Province, 130062 Patentee after: Jilin Yiguan Zhongneng Industrial Co.,Ltd. Address before: 130114 Cong Village, Lanjia Town, Kuancheng District, Changchun, Jilin Patentee before: Changchun sunshine inorganic phase change heat insulation sound insulation building material Co.,Ltd. |