CN102604232A - Antistatic polypropylene material and preparation method thereof - Google Patents
Antistatic polypropylene material and preparation method thereof Download PDFInfo
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- CN102604232A CN102604232A CN2011100226748A CN201110022674A CN102604232A CN 102604232 A CN102604232 A CN 102604232A CN 2011100226748 A CN2011100226748 A CN 2011100226748A CN 201110022674 A CN201110022674 A CN 201110022674A CN 102604232 A CN102604232 A CN 102604232A
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- 239000000463 material Substances 0.000 title claims abstract description 39
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 33
- -1 polypropylene Polymers 0.000 title claims abstract description 33
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 235000006708 antioxidants Nutrition 0.000 claims description 18
- 239000003112 inhibitor Substances 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002367 phosphate rock Substances 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 150000007970 thio esters Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000002131 composite material Substances 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 229920000049 Carbon (fiber) Polymers 0.000 abstract 2
- 239000004917 carbon fiber Substances 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 238000005452 bending Methods 0.000 abstract 1
- 230000003068 static effect Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 229920006576 PP-G Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention relates to an antistatic polypropylene material and a preparation method thereof. The material comprises the following raw materials, by weight, 78-90 parts of polypropylene, 8-15 parts of a carbon fiber, 1-8 parts of a compatilizer and 0.2-0.4 parts of an antioxidant. The addition of the carbon fiber in the invention is small, so the material has a permanent antistatic performance; and the antistatic performance of the prepared polypropylene material can be guaranteed, and simultaneously the tensile strength and the bending strength of the material can be improved. Additionally, the method for improving the antistatic performance of the polypropylene composite material of the invention has the advantages of simple preparation technology and low production cost. When the polypropylene material prepared through the method of the invention is used to produce an antistatic hollow plate, the volume resistivity of the antistatic hollow plate is reduced to 10<3>-10<8>omega.cm, so the antistatic hollow plate can be used to package electrical and electronic products.
Description
Technical field
The invention belongs to polymer modification technical field and processing technique field, relate to a kind of polypropylene material and preparation method thereof.
Background technology
Vestolen PP 7052 (PP) is a kind of thermoplastics, light specific gravity, and finished surface hardness is big, and elasticity is high, and thermotolerance, chemicalstability, insulativity are good, are widely used in the numerous areas of producing, living.Yet its volume specific resistance is 10
16～10
20The scope of Ω cm in use is easy to generate static hazard, thereby has limited its application in fields such as electronics, petrochemical complex, medical treatment.
The PP hollow sheeting is to be main raw material with the Vestolen PP 7052, a kind of thin plate that obtains through the forcing machine melted extrusion modeling.Characteristics such as the PP hollow sheeting is nontoxic because of having, tasteless, moistureproof, corrosion-resistant, in light weight, intensity is high, environmental protection all obtain to use widely at industry-by-industry.But the PP hollow sheeting is not antistatic, has limited its application in the electric equipment products packing greatly.
The method of giving the polypropylene material antistatic property at present mainly contains two kinds:
The one, apply static inhibitor in polypropylene surface, the shortcoming of this method is that the static inhibitor of material surface comes off easily, the antistatic cycle is short;
The 2nd, adopt blending method, with Vestolen PP 7052 and static inhibitor melt blending, the PP composite material that obtains had so both had antistatic property, had and had the good mechanical performance.It is material modified that blending method obtains mainly is to utilize static inhibitor at the material surface adsorption moisture, reduces surface resistivity and reaches anlistatig purpose.Common lower molecular weight static inhibitor poor durability, scrubbing resistance is not big to the dependency of ambient moisture.Polymer permanent antistatic agent antistatic effect is lasting, no inductive phase, do not receive condition influence such as wiping and washing, but price is higher.
Thomel has performances such as good electrical conductivity, erosion resistance, is good anti static additive.
Summary of the invention
The objective of the invention is to the defective of prior art and provide a kind of have excellent antistatic can polypropylene material and preparation method thereof.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is following:
A kind of polypropylene material, this raw material comprises following component and parts by weight thereof:
Vestolen PP 7052: 78～90 parts,
Thomel: 8～15 parts,
Compatilizer: 1～8 part,
Oxidation inhibitor: 0.2～0.4 part.
Described Vestolen PP 7052 is mobile different COPP or one or more the mixture in the HOPP, and under the condition of 230 ℃ * 2.16kg, its melt flow rate(MFR) is 1～100g/10min.
Described thomel is continuity thomel or staple fibre.
Described oxidation inhibitor comprises primary antioxidant and auxiliary anti-oxidant.
Described primary antioxidant can be selected one or several in hindered phenol or the thioesters kind antioxidant for use; Preferred antioxidant 1010; Chemical name: four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, and antioxidant 1076; Chemical name: β-(4 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl) propionic acid stearyl alcohol ester.
Described auxiliary anti-oxidant is selected from one or several in the phosphorite kind antioxidant, preferred oxidation inhibitor 168, chemical name: three (2, the 4-di-tert-butyl-phenyl) phosphorous acid ester.
Said compatilizer is a maleic anhydride inoculated polypropylene, and density is 0.89～0.91g/cm
3, percentage of grafting is 0.5～3%; The PP-G that preferred Hefei Genius Advanced Materials Co., Ltd. produces.
A kind of preparation method of above-mentioned polypropylene material, this method may further comprise the steps:
(1), puts into high-speed mixer and mixed 3～5 minutes according to the above ratio with Vestolen PP 7052, compatilizer, oxidation inhibitor;
(2) then said mixture is added in the forcing machine, said thomel is added to the twin screw extruder and extrudes from going into fine mouth, the barrel temperature of control twin screw extruder is in 200～250 ℃ of scopes;
(3) extrude bar and be cooled to room temperature, obtain above-mentioned antistatic polypropylene material through getting into the dicing machine granulation after the blower drying through circulating water channel.
Polypropylene material of the present invention, its performance meets the performance requriements of Anti-static PP hollow sheeting material, and therefore, technical scheme of the present invention comprises the purposes of polypropylene material of the present invention as Anti-static PP hollow sheeting material.
Advantage of the present invention is:
1, the thomel addition of the present invention's use is few, has permanent antistatic performance.
2, the prepared polypropylene material of the present invention can also improve the tensile strength and the flexural strength of material when guaranteeing the material antistatic property.
3, the method preparation technology of the antistatic property that improves PP composite material of the present invention's proposition is simple, production cost is low.
4, the polypropylene material that obtains of method of the present invention is used to produce hollow sheeting, can make the volume specific resistance of hollow sheeting drop to 10
3～10
8Ω cm can be used to pack electric equipment products.
Embodiment
Below in conjunction with embodiment the present invention is further described.
In the prescription of embodiment and Comparative Examples matrix material, Vestolen PP 7052 is the block copolymerization polypropylene that Shanghai Yangzi Petrochemical Co., Ltd produces, and commodity are called YPJ-1215C, and its melting index is a 15g/10min (test condition: 230 ℃ * 2.16kg).Described thomel is a macrofiber.Described compatilizer is the PP-G that Hefei Jieshijiexin Materials Co., Ltd produces, and percentage of grafting is 0.6%, and melting index is a 120g/10min (test condition: 230 ℃ * 2.16kg), density is 0.9g/cm
3Described primary antioxidant is 1010 of Ciba company production, and described auxiliary anti-oxidant is 168 of Ciba company production.
Comprehensive mechanical performance is judged through the numerical value of tensile strength, flexural strength and the volume specific resistance of test gained.
Embodiment 1
With 88.8 parts of PP YPJ-1215C, 3 parts of PP-G, 0.1 part of antioxidant 1010; 0.1 part oxidation inhibitor 168 is put into high-speed mixer and was mixed 5 minutes, then mixture is added twin screw extruder; With 8 parts of said thomels from go into fine mouth lead into, be added in the twin screw extruder then and extrude.Each zone temperatures of the barrel of twin screw extruder is set to respectively: 205 ℃ in a district, 205 ℃ in two districts, 215 ℃ in three districts, 215 ℃ in four districts, 215 ℃ in five districts, 220 ℃ in six districts, 225 ℃ of heads.Extrude bar and be cooled to room temperature, through getting into the dicing machine granulation after the blower drying through circulating water channel.
Embodiment 2
With 83.8 parts of PP YPJ-1215C, 5 parts of PP-G, 0.1 part of antioxidant 1010; 0.1 part oxidation inhibitor 168 is put into high-speed mixer and was mixed 3 minutes, then mixture is added twin screw extruder; With 11 parts of said thomels from go into fine mouth lead into, be added in the twin screw extruder then and extrude.Each zone temperatures of the barrel of twin screw extruder is set to respectively: 215 ℃ in a district, 215 ℃ in two districts, 220 ℃ in three districts, 225 ℃ in four districts, 230 ℃ in five districts, 235 ℃ in six districts, 240 ℃ of heads.Extrude bar and be cooled to room temperature, through getting into the dicing machine granulation after the blower drying through circulating water channel.
Embodiment 3
With 78.8 parts of PP YPJ-1215C, 6 parts of PP-G, 0.1 part of antioxidant 1010; 0.1 part oxidation inhibitor 168 is put into high-speed mixer and was mixed 3 minutes, then mixture is added twin screw extruder; With 15 parts of said thomels from go into fine mouth lead into, be added in the twin screw extruder then and extrude.Each zone temperatures of the barrel of twin screw extruder is set to respectively: 220 ℃ in a district, 225 ℃ in two districts, 225 ℃ in three districts, 235 ℃ in four districts, 235 ℃ in five districts, 240 ℃ in six districts, 245 ℃ of heads.Extrude bar and be cooled to room temperature, through getting into the dicing machine granulation after the blower drying through circulating water channel.
Comparative Examples 1
With 99.8 parts of PP YPJ-1215C, 0.1 part of antioxidant 1010,0.1 part of oxidation inhibitor 168 is put into high-speed mixer and was mixed 5 minutes, mixture is added in the twin screw extruder extrude then.Each zone temperatures of the barrel of twin screw extruder is set to respectively: 205 ℃ in a district, 205 ℃ in two districts, 215 ℃ in three districts, 215 ℃ in four districts, 215 ℃ in five districts, 220 ℃ in six districts, 225 ℃ of heads.Extrude bar and be cooled to room temperature, through getting into the dicing machine granulation after the blower drying through circulating water channel.
Comparative Examples 2
With 94.8 parts of PP YPJ-1215C, 5 parts of PP-G, 0.1 part of antioxidant 1010,0.1 part of oxidation inhibitor 168 is put into high-speed mixer and was mixed 5 minutes, mixture is added in the twin screw extruder extrude then.Each zone temperatures of the barrel of twin screw extruder is set to respectively: 205 ℃ in a district, 205 ℃ in two districts, 215 ℃ in three districts, 215 ℃ in four districts, 215 ℃ in five districts, 220 ℃ in six districts, 225 ℃ of heads.Extrude bar and be cooled to room temperature, through getting into the dicing machine granulation after the blower drying through circulating water channel.
The test result of each prescription is as shown in table 1.
Table 1 embodiment 1～3 and Comparative Examples 1～2 performance table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative Examples 1 | Comparative Examples 2 | Examination criteria | |
| Melting index (g/10min) | 13 | 12 | 11 | 15 | 18 | GB/T?3682 |
| Density (g/cm 3) | 0.97 | 1.00 | 1.03 | 0.90 | 0.90 | GB/T?1033 |
| Tensile strength (MPa) | 33 | 36 | 43 | 21 | 25 | GB/T?1040 |
| Flexural strength (MPa) | 46 | 50 | 58 | 27 | 30 | GB/T?9341 |
| Modulus in flexure (MPa) | 2108 | 2390 | 2670 | 1020 | 1180 | GB/T?9341 |
| Volume specific resistance (Ω cm) | 6.8×10 8 | 1.5×10 6 | 2.0×10 3 | 1×10 16 | 1×10 16 | GB/T?1410 |
Can find out from the contrast of embodiment 1～3 and Comparative Examples 1～2, add the volume specific resistance that thomel can significantly reduce material.Can find out that from the performance data of embodiment 1～3 material provided by the invention has good static resistance.This material is through being injection molded into hollow sheeting, and its performance can reach the requirement of electronic apparatus wrapping material.
The above-mentioned description to embodiment is can understand and use the present invention for ease of the those of ordinary skill of this technical field.The personnel of skilled obviously can easily make various modifications to these embodiment, and needn't pass through performing creative labour being applied in the General Principle of this explanation among other embodiment.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not breaking away from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.
Claims (8)
1. polypropylene material, it is characterized in that: this material comprises following component and parts by weight thereof:
Vestolen PP 7052: 78～90 parts,
Thomel: 8～15 parts,
Compatilizer: 1～8 part,
Oxidation inhibitor: 0.2～0.4 part.
2. polypropylene material according to claim 1 is characterized in that: described Vestolen PP 7052 is mobile different COPP or one or more the mixture in the HOPP; Under the condition of 230 ℃ * 2.16kg, its melt flow rate(MFR) is 1～100g/10min.
3. polypropylene material according to claim 1 is characterized in that: described thomel is continuity thomel or staple fibre.
4. polypropylene material according to claim 1 is characterized in that: described oxidation inhibitor comprises primary antioxidant and auxiliary anti-oxidant.
5. polypropylene material according to claim 4 is characterized in that: described primary antioxidant is selected from one or several in hindered phenol or the thioesters kind antioxidant; Described auxiliary anti-oxidant is selected from one or several in the phosphorite kind antioxidant.
6. polypropylene material according to claim 5 is characterized in that: described primary antioxidant is selected from antioxidant 1010 or antioxidant 1076; Described auxiliary anti-oxidant is selected from oxidation inhibitor 168.
7. polypropylene material according to claim 1 is characterized in that: said compatilizer is a maleic anhydride inoculated polypropylene, and density is 0.89～0.91g/cm
3, percentage of grafting is 0.5～3%.
8. the preparation method of arbitrary described polypropylene material among the claim 1-7 is characterized in that: may further comprise the steps:
(1) in the described ratio of claim 1 with Vestolen PP 7052, compatilizer, oxidation inhibitor, put into high-speed mixer and mixed 3～5 minutes;
(2) then said mixture is added in the forcing machine, said thomel is added to the twin screw extruder and extrudes from going into fine mouth, the barrel temperature of control twin screw extruder is in 200～250 ℃ of scopes;
(3) extrude bar and be cooled to room temperature, obtain above-mentioned antistatic polypropylene material through getting into the dicing machine granulation after the blower drying through circulating water channel.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952309A (en) * | 2012-12-12 | 2013-03-06 | 中国科学院长春应用化学研究所 | Improved short carbon fiber reinforced polyolefin composite material and preparation method thereof |
| CN103435904A (en) * | 2013-09-18 | 2013-12-11 | 中国石油化工股份有限公司 | Antistatic high-rigidity rotational-moulded polyethylene composition and preparation method thereof |
| CN103601965A (en) * | 2013-10-23 | 2014-02-26 | 安徽冠泓塑业有限公司 | Composition for preparing plastic barrels |
| CN104151708A (en) * | 2014-08-20 | 2014-11-19 | 苏州德宝凯迪新材料有限公司 | Carbon fiber strengthened polypropylene composite material and preparation method thereof |
| CN104151732A (en) * | 2014-08-18 | 2014-11-19 | 苏州市盛百威包装设备有限公司 | Triallylamine film packaging material and preparation method thereof |
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| CN104961941A (en) * | 2015-06-30 | 2015-10-07 | 苏州洋杰电子有限公司 | Preparation method for antistatic composite material |
| CN105646999A (en) * | 2014-11-10 | 2016-06-08 | 合肥杰事杰新材料股份有限公司 | Polypropylene composition and preparation method thereof |
| CN107531961A (en) * | 2015-05-22 | 2018-01-02 | 博里利斯股份公司 | Polypropylene carbon fibers composite |
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| CN108192207A (en) * | 2017-12-28 | 2018-06-22 | 聚威工程塑料(上海)有限公司 | A kind of high-performance conductive PP composite material and preparation method |
| CN110406128A (en) * | 2019-08-12 | 2019-11-05 | 杭州新明包装有限公司 | A kind of hollow plate on-line continuous laminating adhesive production technology |
| CN113150441A (en) * | 2021-04-14 | 2021-07-23 | 华南理工大学 | Carbon fiber reinforced polypropylene foam composite material and preparation method thereof |
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| CN102952309B (en) * | 2012-12-12 | 2014-11-26 | 中国科学院长春应用化学研究所 | Improved short carbon fiber reinforced polyolefin composite material and preparation method thereof |
| CN102952309A (en) * | 2012-12-12 | 2013-03-06 | 中国科学院长春应用化学研究所 | Improved short carbon fiber reinforced polyolefin composite material and preparation method thereof |
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| CN105646999A (en) * | 2014-11-10 | 2016-06-08 | 合肥杰事杰新材料股份有限公司 | Polypropylene composition and preparation method thereof |
| CN104861283A (en) * | 2015-03-31 | 2015-08-26 | 苏州市鼎立包装有限公司 | Impact-resistant modified plastic hollow plate and preparation method thereof |
| CN107531961A (en) * | 2015-05-22 | 2018-01-02 | 博里利斯股份公司 | Polypropylene carbon fibers composite |
| CN107531965A (en) * | 2015-05-22 | 2018-01-02 | 博里利斯股份公司 | The carbon fiber packing material of low-density |
| US10717832B2 (en) | 2015-05-22 | 2020-07-21 | Borealis Ag | Low density carbon fibers filled materials |
| CN104961941A (en) * | 2015-06-30 | 2015-10-07 | 苏州洋杰电子有限公司 | Preparation method for antistatic composite material |
| CN108192207A (en) * | 2017-12-28 | 2018-06-22 | 聚威工程塑料(上海)有限公司 | A kind of high-performance conductive PP composite material and preparation method |
| CN110406128A (en) * | 2019-08-12 | 2019-11-05 | 杭州新明包装有限公司 | A kind of hollow plate on-line continuous laminating adhesive production technology |
| CN113150441A (en) * | 2021-04-14 | 2021-07-23 | 华南理工大学 | Carbon fiber reinforced polypropylene foam composite material and preparation method thereof |
| CN114262482A (en) * | 2021-12-30 | 2022-04-01 | 江苏松上科技有限公司 | Impact-resistant polypropylene material for automobile ceiling and production method thereof |
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