CN102601834B - Surface color-fixing dye for mat rush products and color-fixing method - Google Patents
Surface color-fixing dye for mat rush products and color-fixing method Download PDFInfo
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- CN102601834B CN102601834B CN201210057836.6A CN201210057836A CN102601834B CN 102601834 B CN102601834 B CN 102601834B CN 201210057836 A CN201210057836 A CN 201210057836A CN 102601834 B CN102601834 B CN 102601834B
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- 238000000034 method Methods 0.000 title claims abstract description 23
- 244000078283 Scirpus lacustris Species 0.000 title abstract 4
- 239000000654 additive Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 11
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 239000000975 dye Substances 0.000 claims description 26
- 230000000996 additive effect Effects 0.000 claims description 17
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- 238000005507 spraying Methods 0.000 claims description 8
- 238000007590 electrostatic spraying Methods 0.000 claims description 6
- 229930002875 chlorophyll Natural products 0.000 claims description 5
- 235000019804 chlorophyll Nutrition 0.000 claims description 5
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical group C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 claims description 5
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000009941 weaving Methods 0.000 claims description 5
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 claims description 2
- 239000002002 slurry Substances 0.000 abstract description 19
- 239000002932 luster Substances 0.000 abstract description 9
- 238000004043 dyeing Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 244000025254 Cannabis sativa Species 0.000 description 26
- 238000000576 coating method Methods 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000010902 straw Substances 0.000 description 5
- 238000013019 agitation Methods 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000002906 tartaric acid Nutrition 0.000 description 3
- 239000011975 tartaric acid Substances 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- IEBJZLRZRKTGFN-UHFFFAOYSA-N N=NC=NN.N=NC=NN.C1=CC=CC=C1 Chemical compound N=NC=NN.N=NC=NN.C1=CC=CC=C1 IEBJZLRZRKTGFN-UHFFFAOYSA-N 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000001599 direct drying Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000576 food coloring agent Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Floor Finish (AREA)
Abstract
The invention relates to a surface color-fixing dye for mat rush products. The surface color-fixing dye is characterized by comprising the following components in percentage by weight: 12%-18% of polyvinyl acetate, 2%-5% of TiO2, 0.1%-3% of dyeing additives and the balance of water. The invention further discloses a preparation method and a color-fixing method of the color-fixing dye. Compared with the prior art, the invention has the advantages that: the color and luster of the mat rush products after dyeing treatment can be better and fuller, the adjustment of color depth is more convenient, and the retention time of the apparent color of the mat rush products is also more lasting. Furthermore, slurry used by the surface color-fixing dye is of water-based slurry, the surface color-fixing dye has no toxicity and no volatilization of harmful gas, and the used additives are harmless to skin of human bodies, thus the surface color-fixing dye is in line with green and environment-friendly requirements.
Description
Technical field
The present invention relates to a kind of dyestuff of Lin's of being applied to straw-made articles, the invention still further relates to preparation method and the color-fixing method of this fixation dyestuff.
Background technology
Lin's grass (rush) is at China cultivation and the processing history of existing two over thousands of years, be China Jiangsu and Zhejiang Provinces one with traditional economy special product, the long-term cultivated area in Zhejiang Province is about 180,000 mu of left and right at present.Lin's straw-made articles has tatami, upper deposited seat, jacquard mat and other small articles etc., main exit Japanese market.Japan at present tatami year approximately 2,000 ten thousand of demands, upper deposited seat year approximately 9,500,000 pieces of demands, 90% from Chinese import, Ningbo City is as " Chinese Lin Caozhi township ", " Chinese straw plaited base ", " Chinese Lin's grass original producton location ", export share accounts for 90% of the whole nation.The development of producing due to Lin grass and the formation of industry, for agro based economic development, increase farmers' income, solve rural area employment and very important effect has been played in foreign exchange earning.Under normal circumstances, after the direct drying of Lin's grass harvesting is processed, the chlorophyll on Lin's grass surface can be destroyed, makes apparent colour flavescence, can not meet the product quality requirement of export market.Therefore,, in traditional Rush-processing process, before drying, Lin's grass needs through overstain mud fixation treatment, to keep the color and luster of Lin's grass.The color fixing process of generally taking is: a) harvesting, point Lin's grass of having tied are distributed in special waggon, remove the foul on Lin's grass surface through water spray; B) will dye soil (generally dying soil with Japan) and be mixed with certain density slurries; C) Lin's grass is immersed in slurry and keeps certain hour to carry out fixation, after completing, Lin's grass is taken out; D) put into again special oven and utilize hot blast to be dried, about about 20 hours; E) Lin's grass after oven dry packs in black plastic packaging bag, in the time working out, opens and uses.Through dying, mud Lin's grass after treatment is easy to be dried, color and luster is good, have hay-scented, be worth high, but due to the difference between the superficial film structure of Lin grass own and different fixation batch, make Lin's grass after fixation, establishment, Lin's straw-made articles surface there will be the even phenomenon of irregular colour, affects quality and the outlet grade of product.For this reason, some Rush-processing enterprises are also at Lin's straw-made articles surface spraying color-fixing agent, but due to the quality problems of color-fixing agent own, make effect unsatisfactory.Also have Some Enterprises to adopt import color-fixing agent, although effect is pretty good, color-fixing agent is expensive, affects the economic benefit of enterprise.Also have the enterprise that Lin's straw-made articles spraying color-fixing agent is provided although domestic, the multiplex organic pigment allotment of color-fixing agent providing forms, and color and luster is not good, large with the surface color difference of Lin's grass own, affects result of use;
There is the report about Lin's grass mud-dyeing material although domestic, but be all about Lin's grass fixation treatment in early stage mud-dyeing material used, if application number is open " colouring method of seat grass " (publication number is CN1048348A) of 89105742.0 Chinese invention patent applications, this application proposes with the copper sulphate of 1.5%-3%, the composition slurry such as malachite green, alkali blue, the tartaric acid of 0.15%-0.2% and the ammoniacal liquor of 0.4%-0.6% of 0.01%-0.02% of 0.03%-0.05%, Lin's grass to be dyeed.Can also referenced patent number be similarly the Chinese invention patent " colouring method of seat grass " (Granted publication number is CN1212224C) of ZL02136733.7.But because ammoniacal liquor and tartaric acid and alkali blue in above-mentioned slurry can react, thereby reduce the complexing degree of ammoniacal liquor, tartaric acid and copper ion, Lin's straw-made articles is easily faded.
The patent No. is in the Chinese invention patent " colouring method of seat grass " (Granted publication number for CN1212224C) of ZL02136733.7, to have proposed a kind of seat grass colouring method that need not tradition dye mud, and the method adopts the slurries of configuration voluntarily to dye.These slurries are mainly made up of food coloring, ammoniacal liquor, copper sulphate, sheet alkali, EDTA etc.Although the method can be avoided in working environment the generation of a large amount of dust, owing to having adopted copper sulphate, Long Term Contact is harmful, and seat grass after dyeing is more crisp, is unfavorable for braiding, and therefore this technique is not widely applied.
The Zhang Huiling of Dalian Nationality College etc. (Central University for Nationalities's journal (natural science edition) 2003,12(2): 154-157) produce kaolin as base-material taking Bay, Ningde, Fujian Province, added therein respectively khaki iron oxide yellow (Fe
2o
3xH
2o), the organic complex benzene diformazan green grass or young crops (C of blue toner powder containing metal atom
32h
16n
8and black powder shape tri-iron tetroxide (Fe Cu)
3o
4) etc. three kinds of additives.Though the experiment proved that its fixing property approaches Japan and dyes soil, and three kinds of additives experimental results show that through white mouse it is nontoxic, and harmless to skin, it does not reduce and dyes native consumption, reduces dust pollution degree.And the use of organic complex makes its popularization have certain difficulty, have not yet to see this and dye a large amount of reports that use of soil.
In the Chinese invention patent " mud-dyeing material that a kind of black rush fixation is used " (Granted publication number is CN101456202B) of patent No. ZL200810163884.7, propose to dye soil 6%～10%, TiO with Japan
2micro mist 0.02%～0.1%, coloration additive 0.2%～1%, surplus is that the black rush fixation of water (being weight percentage above) is with dying mud, this dyes mud and can significantly reduce tradition and dye native consumption, reduce the dust pollution of the generation of Lin's grass subsequent job process, but can not meet the demand of market to Lin's straw-made articles appearance color quality completely.
Summary of the invention
Technical problem to be solved by this invention is that a kind of Lin's straw-made articles surface fixation dyestuff is provided in addition for the above-mentioned state of the art.
Another technical problem to be solved by this invention is to provide Lin's straw-made articles surface fixation dyestuff that a kind of green is full, guarantor's look time is longer.
Another technical problem to be solved by this invention is to provide the preparation method that a kind of green is full, protect longer Lin's straw-made articles surface fixation dyestuff of look time.
Another technical problem to be solved by this invention is to provide the color-fixing method that a kind of green is full, protect longer Lin's straw-made articles surface fixation dyestuff of look time.
The present invention solves the problems of the technologies described above adopted technical scheme: a kind of Lin's straw-made articles surface fixation dyestuff, is characterized in that comprising following component and weight proportion thereof:
Polyvinyl acetate: 12%～18%;
TiO
2：2%～5%；
Coloration additive: 0.1%～3%;
Water: surplus.
As preferably, fixation dyestuff comprises following component and weight proportion thereof:
Polyvinyl acetate: 15%～16%;
TiO
2：3%～4%；
Coloration additive: 1%～2%;
Water: surplus.
As preferably, described TiO
2average grain diameter≤1 μ m.
Described coloration additive can be in chlorophyll additive, green direct dyes, green reactive dye, green acid dyes and environment-friendly pigment one of at least.As naphthol green, phthalocyanine green, chlorophyll etc.
As preferably, described coloration additive average grain diameter≤0.5 μ m.
A preparation method for Lin's straw-made articles surface fixation dyestuff, comprises the steps: first polyvinyl acetate to be mixed with water, stirs 5～10 minutes, then adds while stirring TiO
2and coloration additive, stir stand-by after 15～30 minutes.
A color-fixing method for Lin's straw-made articles surface fixation dyestuff, comprises the steps: to adopt the method for compressed air spraying or electrostatic spraying fixation dyestuff to be coated with and to be contained on Lin's straw-made articles, then film-forming at 80～85 DEG C, 4～10 minutes hardening times.
Compared with prior art, the invention has the advantages that: using polyvinyl acetate as film forming agent, with TiO
2micro mist is filler, taking coloration additive as developer, taking water as solvent, make water paint, the color and luster of Lin's straw-made articles after treatment that dyes is better full, the adjustment of color depth is convenient, the retention time of Lin's straw-made articles apparent colour is also more lasting.And slurry therewith is water paste, without toxic and harmful volatilization, additive therefor is also all harmless to human body skin, meets environment protection requirement.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1:
Each constituent content (mass percent) in slurry:
Polyvinyl acetate: 15%;
TiO
2(average grain diameter 0.5 μ m): 4%;
Coloration additive (phthalocyanine green, particle mean size 0.2 μ m): 2%;
Water: surplus.
By above component in proportion successively limit mechanical agitation limit be added to the water, be mixed with 2kg slurry, adopt the method for electrostatic spraying to be coated with and be contained in the rush mat surface of processing through fixation by dyed earth weaving, then enter hot blast drying tunnel, at 80 DEG C curing 6 minutes.In coating process, the slurry in bucket can not stop stirring, to ensure uniformity and the stability of slurry.Before spraying, the green on rush mat surface is more shallow and colour consistency is poor, through spray treatment and after solidifying, and straw mat apparent colour good uniformity, color and luster is full.
Embodiment 2:
Each constituent content (mass percent) in slurry:
Polyvinyl acetate: 16%;
TiO
2: 3% (average grain diameter 0.9 μ is m);
Coloration additive (phthalocyanine green, particle mean size 0.5 μ m): 1%,
Water: surplus.
By above component in proportion successively limit mechanical agitation limit be added to the water, be mixed with 5kg coating, adopt the method for electrostatic spraying to be coated with and be contained in the rush mat surface of processing through fixation by dyed earth weaving, then enter drying tunnel at 85 DEG C curing 5 minutes.In coating process, the coating in bucket can not stop stirring, to ensure the uniformity of coating.Before spraying, the green on tatami rush surface is slightly shallow, glossiness is poor, and through above slurry spray treatment and after solidifying, straw mat apparent colour is even, and color and luster is full, has improved the apparent colour quality of rush mat.
Embodiment 3:
Each constituent content (mass percent) in slurry:
Polyvinyl acetate: 18%;
TiO
2: 2% (average grain diameter 0.6 μ is m);
Coloration additive (chlorophyll): 0.1%,
Water: surplus.
By above component in proportion successively limit mechanical agitation limit be added to the water, be mixed with 5kg coating, adopt the method for electrostatic spraying to be coated with and be contained in the rush mat surface of processing through fixation by dyed earth weaving, then enter drying tunnel at 85 DEG C curing 5 minutes.In coating process, the coating in bucket can not stop stirring, to ensure the uniformity of coating.Before spraying, the green on tatami rush surface is slightly shallow, glossiness is poor, and through above slurry spray treatment and after solidifying, straw mat apparent colour is even, and color and luster is full, has improved the apparent colour quality of rush mat.
Embodiment 4:
Each constituent content (mass percent) in slurry:
Polyvinyl acetate: 12%;
TiO
2: 5% (average grain diameter 0.4 μ is m);
Coloration additive (phthalocyanine green, particle mean size 0.3 μ m): 3%,
Water: surplus.
By above component in proportion successively limit mechanical agitation limit be added to the water, be mixed with 5kg coating, adopt the method for electrostatic spraying to be coated with and be contained in the rush mat surface of processing through fixation by dyed earth weaving, then enter drying tunnel at 85 DEG C curing 5 minutes.In coating process, the coating in bucket can not stop stirring, to ensure the uniformity of coating.Before spraying, the green on tatami rush surface is more shallow, glossiness is poor, and through above slurry spray treatment and after solidifying, straw mat apparent colour is even, and color and luster is full, has improved the apparent colour quality of rush mat.
Claims (2)
1. Lin's straw-made articles surface fixation dyestuff, is characterized in that its preparation method comprises the steps:
First polyvinyl acetate is mixed with water, stir 5～10 minutes, then add while stirring TiO
2and coloration additive, stir stand-by after 15～30 minutes;
This dyestuff comprises following component and weight proportion thereof:
Polyvinyl acetate: 15%～16%;
TiO
2：3％～4％；
Coloration additive: 1%～2%;
Water: surplus,
Described TiO
2average grain diameter≤1 μ m;
Described coloration additive average grain diameter≤0.5 μ m;
Described coloration additive is chlorophyll, phthalocyanine green or naphthol green.
2. utilize the color-fixing method of a kind of Lin's straw-made articles surface fixation dyestuff described in claim 1, comprise the steps: to adopt the method for compressed air spraying or electrostatic spraying that fixation dyestuff is coated with and is contained on Lin's straw-made articles processed through fixation by dyed earth weaving, then film-forming at 80～85 DEG C, 4～10 minutes hardening times.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210057836.6A CN102601834B (en) | 2012-03-07 | 2012-03-07 | Surface color-fixing dye for mat rush products and color-fixing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210057836.6A CN102601834B (en) | 2012-03-07 | 2012-03-07 | Surface color-fixing dye for mat rush products and color-fixing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102601834A CN102601834A (en) | 2012-07-25 |
| CN102601834B true CN102601834B (en) | 2014-11-05 |
Family
ID=46519796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210057836.6A Expired - Fee Related CN102601834B (en) | 2012-03-07 | 2012-03-07 | Surface color-fixing dye for mat rush products and color-fixing method |
Country Status (1)
| Country | Link |
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| CN (1) | CN102601834B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103158183A (en) * | 2013-03-12 | 2013-06-19 | 包中臣 | Schoenoplectus trigueter (L.) Palla mat dye |
| CN106217558A (en) * | 2016-07-21 | 2016-12-14 | 阜南佳利工艺品有限公司 | A kind of straw willow compiles mildew-resistant fixation treatment liquid and the compound method thereof of straw |
| CN105965647A (en) * | 2016-07-21 | 2016-09-28 | 阜南佳利工艺品有限公司 | Softening and color fixation treatment solution for straw and willow braided salix integra and preparation method thereof |
| CN106217564A (en) * | 2016-08-31 | 2016-12-14 | 安徽阜南县万家和工艺品有限公司 | A kind of inorganic agent being easy to the dyeing of wicker knitting |
| CN107541927A (en) * | 2017-09-19 | 2018-01-05 | 安徽阜南县万家和工艺品有限公司 | A kind of processing method for improving Lin's grass dyefastness |
| CN108748548A (en) * | 2018-06-26 | 2018-11-06 | 阜南县宏达工艺品厂 | A kind of wicker products colouring method |
| CN109015998A (en) * | 2018-08-28 | 2018-12-18 | 北京林业大学 | A kind of wood color regulation method based on metal coordination |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1354205A (en) * | 2000-11-16 | 2002-06-19 | 沈运枔 | Grass dyeing agent |
| JP2004216374A (en) * | 1993-02-04 | 2004-08-05 | Shosuke Nagata | Coating device of tatami facing |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5630468A (en) * | 1979-08-19 | 1981-03-27 | Kazuo Komata | Coloring liquid for "tatami"(straw matting) |
| JPS59126474A (en) * | 1983-01-08 | 1984-07-21 | Shinto Paint Co Ltd | Coating for tatami facing |
-
2012
- 2012-03-07 CN CN201210057836.6A patent/CN102601834B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004216374A (en) * | 1993-02-04 | 2004-08-05 | Shosuke Nagata | Coating device of tatami facing |
| CN1354205A (en) * | 2000-11-16 | 2002-06-19 | 沈运枔 | Grass dyeing agent |
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| Publication number | Publication date |
|---|---|
| CN102601834A (en) | 2012-07-25 |
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