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CN102583927B - Sludge micro oxygen hydrolytic acidizing method - Google Patents

Sludge micro oxygen hydrolytic acidizing method Download PDF

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CN102583927B
CN102583927B CN2012100719400A CN201210071940A CN102583927B CN 102583927 B CN102583927 B CN 102583927B CN 2012100719400 A CN2012100719400 A CN 2012100719400A CN 201210071940 A CN201210071940 A CN 201210071940A CN 102583927 B CN102583927 B CN 102583927B
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stirring
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acidification
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CN102583927A (en
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宋秀兰
李亚新
冀文侃
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Taiyuan University of Technology
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Abstract

本发明涉及一种微氧水解酸化处理污泥方法,是在水解酸化反应器中接种含有产酸菌的污泥,向水解酸化反应器中间歇通入空气进行空气搅拌,并同时辅助间歇式机械搅拌,在保持溶解氧DO为0.4~0.8mg/L的微氧条件下对污水处理厂污泥进行水解酸化,水解酸化处理后的污泥进入沉淀池泥水分离,上清液作为城市污水生物脱氮除磷处理的碳源。本发明的微氧水解酸化处理污泥方法在常温下进行,不需要加酸碱调节pH值,操作简单,运行稳定,可以抑制甲烷菌的生长,提高污泥水解酸化处理系统的稳定性,污泥产酸量提高38%~50%,同时使得污泥最大程度得到减量化和稳定化处理。The invention relates to a sludge treatment method by microaerobic hydrolysis and acidification. The sludge containing acid-producing bacteria is inoculated in the hydrolysis and acidification reactor, air is intermittently introduced into the hydrolysis and acidification reactor for air stirring, and at the same time, the intermittent mechanical Stirring, hydrolyzing and acidifying the sludge of the sewage treatment plant under the micro-aerobic condition of maintaining dissolved oxygen DO of 0.4-0.8mg/L, the sludge after hydrolytic acidizing treatment enters the sedimentation tank for mud-water separation, and the supernatant is used as urban sewage biological decontamination Carbon source for nitrogen and phosphorus removal treatment. The microaerobic hydrolysis and acidification treatment sludge method of the present invention is carried out at normal temperature, does not need to add acid and alkali to adjust the pH value, is simple to operate, runs stably, can inhibit the growth of methane bacteria, and improves the stability of the sludge hydrolysis and acidification treatment system. The amount of acid produced by mud is increased by 38% to 50%, and at the same time, the sludge is reduced and stabilized to the greatest extent.

Description

微氧水解酸化处理污泥方法Micro-aerobic hydrolysis and acidification treatment of sludge

技术领域 technical field

本发明属于污泥处理及资源化利用技术领域,涉及一种污水处理厂污泥的处理方法,特别是涉及一种污水处理厂污泥的微氧水解酸化处理方法。 The invention belongs to the technical field of sludge treatment and resource utilization, and relates to a treatment method for sewage treatment plant sludge, in particular to a microaerobic hydrolysis acidification treatment method for sewage treatment plant sludge.

背景技术 Background technique

污水处理厂污泥在厌氧条件下水解发酵,可以产生乙酸、丙酸、丁酸等短链挥发酸。用污泥酸性发酵产物作为反硝化菌、聚磷菌的碳源,可降低污水处理成本,并可使污水厂污泥减量化和资源化。 Sludge from sewage treatment plants is hydrolyzed and fermented under anaerobic conditions to produce short-chain volatile acids such as acetic acid, propionic acid, and butyric acid. Using the acidic fermentation product of sludge as the carbon source of denitrifying bacteria and phosphorus accumulating bacteria can reduce the cost of sewage treatment, and can reduce and recycle sludge in sewage plants.

20世纪80年代以来,国外针对厌氧消化的水解酸化阶段研究越来越多,其中大多是利用污水处理厂的初沉池污泥水解发酵来产生挥发性脂肪酸(VFA),也有采用初沉污泥和剩余污泥的混合污泥进行研究。而国内对污泥产酸的研究很鲜见。现有一些研究表明:产酸菌最适pH为6.0~7.0,而此范围与甲烷菌的最适pH6.5~7.5有冲突,因而不可避免地在污泥水解酸化反应器中会产生甲烷化现象,使系统运行不稳定,且污泥的产酸量低。 Since the 1980s, there have been more and more studies abroad on the hydrolysis and acidification stage of anaerobic digestion, most of which use the primary sedimentation tank sludge hydrolysis fermentation of sewage treatment plants to produce volatile fatty acids (VFA), and some use primary sedimentation The mixed sludge of sludge and excess sludge was studied. However, domestic research on acid production from sludge is rare. Some existing studies have shown that the optimum pH of acidogenic bacteria is 6.0-7.0, and this range conflicts with the optimum pH of 6.5-7.5 for methanogens, so methanation will inevitably occur in the sludge hydrolysis acidification reactor Phenomenon, make the system run unstable, and the acid production of sludge is low.

ZL 200810054486.1提供了一种处理废水的碳源的制备方法,该专利中,酸性发酵反应器内生化反应在酸性发酵阶段的pH值为5.5~6.5,酸性发酵反应器的控制温度为26℃~38℃。该专利要求有加热装置控制温度,加酸控制pH,生产成本高,污泥产酸量低。 ZL 200810054486.1 provides a method for preparing carbon sources for wastewater treatment. In this patent, the pH value of the biochemical reaction in the acid fermentation reactor during the acid fermentation stage is 5.5 to 6.5, and the temperature of the acid fermentation reactor is controlled at 26°C to 38°C. ℃. This patent requires a heating device to control the temperature, adding acid to control the pH, the production cost is high, and the amount of acid produced by the sludge is low.

胡颖华等[能源环境保护,2005,19(1):28~31]进行了污水厂剩余污泥微氧消化的中试研究,在其反应器中,一部分污泥处于好氧状态,一部分污泥处于缺氧状态,在有氧状态下,兼性菌利用氧作为电子受体降解有机物,在缺氧条件下则由部分硝酸盐取代氧做为电子供体,通过内源性硝酸盐呼吸达到降解微生物体的目的。该研究的消化时间为20天,但未见有高浓度挥发酸的积累。 Hu Yinghua et al. [Energy and Environmental Protection, 2005, 19(1): 28-31] carried out a pilot study on microaerobic digestion of excess sludge in sewage plants. In their reactor, part of the sludge was in an aerobic state, and part of the sludge In the anoxic state, in the aerobic state, facultative bacteria use oxygen as the electron acceptor to degrade organic matter, and in the anoxic condition, part of the nitrate replaces oxygen as the electron donor, and the degradation is achieved through endogenous nitrate respiration. purpose of microorganisms. The digestion time in this study was 20 days, but no accumulation of high concentrations of volatile acids was seen.

张全等[上海环境科学,1995,14(11):15~16]进行了剩余污泥微氧消解工艺的研究,污泥的减量化效果好,但因只采用空气搅拌,污泥易沉积于底部,也未见有高浓度挥发酸的积累。 [Shanghai Environmental Science, 1995, 14(11): 15-16] carried out research on the micro-aerobic digestion process of excess sludge. The sludge reduction effect is good, but because only air stirring is used, the sludge is easy to digest. It was deposited at the bottom, and there was no accumulation of high-concentration volatile acids.

发明内容 Contents of the invention

本发明的目的是提供一种微氧水解酸化处理污泥方法,以该方法处理污水处理厂污泥,可以提高污泥水解酸化处理系统的稳定性,显著提高污泥产酸量。 The purpose of the present invention is to provide a method for sludge treatment by microaerobic hydrolysis and acidification, which can improve the stability of the sludge hydrolysis and acidification treatment system and significantly increase the amount of acid produced by sludge.

本发明的微氧水解酸化处理污泥方法是在水解酸化反应器中接种含有产酸菌的污泥,向水解酸化反应器中间歇通入空气进行空气搅拌,并同时辅助间歇式机械搅拌,在保持溶解氧DO为0.4~0.8mg/L的微氧条件下对污水处理厂污泥进行水解酸化,水解酸化处理后的污泥进入沉淀池泥水分离,上清液作为城市污水生物脱氮除磷处理的碳源。 The microaerobic hydrolysis and acidification treatment sludge method of the present invention is to inoculate the sludge containing acid-producing bacteria in the hydrolysis and acidification reactor, intermittently feed air into the hydrolysis and acidification reactor for air stirring, and at the same time assist intermittent mechanical stirring. Under the micro-aerobic condition with dissolved oxygen DO of 0.4-0.8 mg/L, the sludge of the sewage treatment plant is hydrolyzed and acidified, and the sludge after hydrolytic acidification is sent to the sedimentation tank for separation of mud and water, and the supernatant is used as urban sewage biological nitrogen and phosphorus removal Treated carbon sources.

本发明中,空气搅拌和机械搅拌是同时进行的,每间隔40~60min搅拌一次,每次搅拌时间5~10min。 In the present invention, air stirring and mechanical stirring are carried out at the same time, stirring once every 40-60 minutes, and each stirring time is 5-10 minutes.

其中,机械搅拌强度优选10~15W/m3;空气搅拌的空气量优选0.06~0.14m3/m3池容·min。 Among them, the mechanical stirring intensity is preferably 10-15 W/m 3 ; the air volume of the air stirring is preferably 0.06-0.14 m 3 /m 3 cell volume·min.

本发明的微氧水解酸化处理污泥方法是在20℃~25℃条件下进行水解酸化的,期间水解酸化反应器内的pH值维持在6.0~7.0。 The microaerobic hydrolysis acidification method of the present invention carries out hydrolysis acidification under the condition of 20 DEG C to 25 DEG C, during which the pH value in the hydrolysis acidification reactor is maintained at 6.0 to 7.0.

本发明优选的水解酸化反应器为序批式反应器。 The preferred hydrolytic acidification reactor of the present invention is a sequencing batch reactor.

本发明微氧水解酸化处理污泥方法具体包括以下工艺步骤: The microaerobic hydrolysis acidification treatment sludge method of the present invention specifically comprises the following process steps:

1、产酸菌的培养驯化 1. Cultivation and domestication of acid-producing bacteria

在水解酸化反应器中接种占反应器容积50%~70%的污水处理厂好氧污泥,并加入碳水化合物类有机废水作为培养基,进行机械搅拌和空气搅拌,二者同时进行,每间隔40~60min搅拌一次,每次搅拌时间5~10min,机械搅拌强度10~15W/m3,空气搅拌空气量0.06~0.14m3/m3池容·min,以保持水解酸化反应器中溶解氧DO为0.4~0.8mg/L的微氧条件;在培养驯化过程中不排泥,只间歇排放上清液,排出上清液后再补入等体积的碳水化合物类有机废水作为培养基,排上清液前停止搅拌,沉淀0.5-1h,循环操作;每天加入碳水化合物类有机废水的COD浓度和体积由有机负荷率和水力停留时间确定,有机负荷率3~4gCOD/L·d,水力停留时间3~4d;待水解酸化反应器内挥发酸浓度达到3000mg/L以上时,完成产酸菌的培养驯化; Inoculate the aerobic sludge from the sewage treatment plant accounting for 50% to 70% of the reactor volume in the hydrolytic acidification reactor, and add carbohydrate organic waste water as the medium, and carry out mechanical stirring and air stirring, both at the same time, every interval Stir once every 40 to 60 minutes, each stirring time is 5 to 10 minutes, the mechanical stirring intensity is 10 to 15 W/m 3 , and the air volume of air stirring is 0.06 to 0.14 m 3 /m 3 pool capacity min to maintain the dissolved oxygen in the hydrolysis acidification reactor. DO is 0.4~0.8mg/L under micro-aerobic conditions; during the cultivation and acclimatization process, no sludge is discharged, only the supernatant is discharged intermittently, after the supernatant is discharged, an equal volume of carbohydrate-based organic wastewater is added as the medium, and the discharge Stop stirring before the supernatant, settle for 0.5-1h, and cycle operation; the COD concentration and volume of carbohydrate organic wastewater added every day are determined by the organic loading rate and hydraulic retention time, the organic loading rate is 3 ~ 4gCOD/L·d, and the hydraulic retention The time is 3 to 4 days; when the concentration of volatile acid in the hydrolytic acidification reactor reaches above 3000 mg/L, the cultivation and acclimation of acid-producing bacteria is completed;

2、污水处理厂污泥的水解酸化 2. Hydrolysis and acidification of sewage treatment plant sludge

将VS(挥发性固体浓度)为15~25g/L,VS/TS(挥发性固体浓度/总固体浓度)比值大于0.5的污水处理厂污泥作为进入污泥,进入步骤1已经培养驯化好产酸菌的反应器中,进行机械搅拌和空气搅拌,二者同时进行,每间隔40~60min搅拌一次,每次搅拌时间5~10min,机械搅拌强度10~15W/m3,空气搅拌空气量0.06~0.14m3/m3池容·min;进入反应器中污泥满足3~6d的固体停留时间后排出,每天排泥前要搅拌5~10min,排出富含挥发酸的泥水混合液,同时再补入等体积的新污水处理厂污泥,循环操作; Sludge from sewage treatment plants with a VS (volatile solid concentration) of 15-25g/L and a ratio of VS/TS (volatile solid concentration/total solid concentration) greater than 0.5 is used as input sludge, which has been cultivated and domesticated in step 1. In the acid bacteria reactor, mechanical stirring and air stirring are carried out at the same time, stirring once every 40-60 minutes, each stirring time is 5-10 minutes, the mechanical stirring intensity is 10-15W/m 3 , and the air stirring air volume is 0.06 ~0.14m 3 /m 3 pool volume·min; the sludge entering the reactor is discharged after the solid residence time of 3~6d is met, and the sludge should be stirred for 5~10min every day before sludge discharge, and the mud-water mixture rich in volatile acids is discharged, and at the same time Add the same volume of sludge from the new sewage treatment plant, and recycle the operation;

上述反应器在20℃~25℃下进行水解酸化,反应器启动后,反应器内pH值靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.0~7.0,不需要再加酸碱调节; The above-mentioned reactor is hydrolyzed and acidified at 20°C-25°C. After the reactor is started, the pH value in the reactor is naturally maintained at 6.0-7.0 by the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it. Add acid-base adjustment;

3、水解酸化后污泥的泥水分离 3. Sludge-water separation of sludge after hydrolysis and acidification

步骤2排出的富含挥发酸的泥水混合液进入沉淀池进行泥水分离,沉淀池上清液回收作为城市污水生物脱氮除磷工艺的碳源,沉淀的废弃污泥直接排放。 The volatile acid-rich mud-water mixture discharged from step 2 enters the sedimentation tank for mud-water separation, and the supernatant of the sedimentation tank is recycled as a carbon source for the urban sewage biological denitrification and phosphorus removal process, and the settled waste sludge is directly discharged.

其中,泥水混合液进入沉淀池进行泥水分离的水力停留时间为1~2h。 Among them, the hydraulic retention time for the mud-water mixture to enter the sedimentation tank for mud-water separation is 1 to 2 hours.

本发明提供了一种微氧水解酸化处理污泥的方法,以该方法处理污水处理厂污泥,可以抑制甲烷菌的生长,提高污泥水解酸化处理系统的稳定性和污泥产酸量,同时使得污泥最大程度得到减量化和稳定化处理,该方法的优点主要体现在以下几个方面: The invention provides a method for sludge treatment by microaerobic hydrolysis and acidification, which can inhibit the growth of methane bacteria and improve the stability of the sludge hydrolysis and acidification treatment system and the amount of acid produced by the sludge. At the same time, the sludge can be reduced and stabilized to the greatest extent. The advantages of this method are mainly reflected in the following aspects:

1、微氧水解酸化法处理污水处理厂污泥操作简单,在反应器中采用空气搅拌和机械搅拌,两种搅拌方式同时进行,每间隔40~60min搅拌一次,这样的搅拌方式提高了污泥的沉降比,延长了污泥混合反应的时间,更重要的是抑制了甲烷菌的生长,提高了污泥挥发酸的产量,增加了系统运行的稳定性。 1. The microaerobic hydrolysis acidification method is easy to operate for sludge treatment in sewage treatment plants. Air stirring and mechanical stirring are used in the reactor. The two stirring methods are carried out at the same time, stirring once every 40 to 60 minutes. This stirring method improves the sludge The sedimentation ratio prolongs the time of sludge mixing reaction, more importantly, it inhibits the growth of methane bacteria, increases the production of volatile acids in sludge, and increases the stability of system operation.

2、微氧水解酸化法可以在常温下进行操作,不需要加热和密闭,不需要另外加酸碱调节反应器的pH值,操作条件简化。  2. The microaerobic hydrolysis acidification method can be operated at normal temperature, without heating and airtightness, and without adding acid and alkali to adjust the pH value of the reactor, and the operating conditions are simplified. the

3、污水处理厂污泥属于污水处理厂的固体废弃物,微氧水解酸化法处理污水处理厂污泥操作简单,其发酵产物乙酸、丙酸、丁酸可作为污水生物脱氮除磷工艺反硝化菌、聚磷菌的碳源,降低污水处理的成本,同时实现污泥的资源化利用。 3. Sewage treatment plant sludge belongs to the solid waste of sewage treatment plants. The microaerobic hydrolysis acidification method is simple to treat sewage treatment plant sludge. The fermentation products of acetic acid, propionic acid and butyric acid can be used as sewage biological denitrification and phosphorus removal process. The carbon source of nitrifying bacteria and phosphorus accumulating bacteria reduces the cost of sewage treatment and realizes the resource utilization of sludge at the same time.

4、采用微氧水解酸化法处理高浓度悬浮固体污泥,不仅能够取得理想的挥发酸产量,而且可以实现很好的VS去除效果,污泥产酸量0.11~0.19gVFA/gVS,VS去除率35%~44%,系统运行稳定,污泥减量化和稳定化效果好。 4. Using the microaerobic hydrolysis acidification method to treat high-concentration suspended solid sludge can not only obtain the ideal volatile acid production, but also achieve a good VS removal effect. The acid production of sludge is 0.11-0.19gVFA/gVS, and the VS removal rate 35% to 44%, the system runs stably, and the effect of sludge reduction and stabilization is good.

5、本发明方法与采用半连续运行反应器的污泥酸性发酵法比较,运行稳定,产酸量可以提高38%~50%,具体比较数据见表1。 5. Compared with the sludge acid fermentation method using a semi-continuous operation reactor, the method of the present invention is stable in operation, and the acid production can be increased by 38% to 50%. The specific comparison data are shown in Table 1.

具体实施方式 Detailed ways

实施例1 Example 1

水解酸化反应器采用序批式反应器,将污水处理厂曝气池回流污泥接种至序批式反应器中,接种污泥量为反应器容积的60%。接种后,加入碳水化合物类有机废水作为培养基,在序批式反应器中常温下进行机械搅拌和空气搅拌,二者同时进行,每间隔60min搅拌一次,每次搅拌时间5min,机械搅拌强度10W/m3,空气搅拌的空气量0.06m3/m3池容·min,以保持反应器中溶解氧DO为0.4mg/L的微氧条件。产酸菌的培养驯化一般需要7~14天,培养过程中不排泥,每天在停止搅拌并静置沉淀1h后排出上清液,同时再补充进入等体积的碳水化合物类有机废水,以上循环操作。每天加入碳水化合物类有机废水的COD浓度和体积由有机负荷率和水力停留时间确定,有机负荷率采用3gCOD/L·d,水力停留时间3d。待水解酸化反应器内挥发酸浓度达到3000mg/L以上,产酸菌的培养驯化结束。 The hydrolytic acidification reactor adopts a sequencing batch reactor, and the return sludge from the aeration tank of the sewage treatment plant is inoculated into the sequencing batch reactor, and the amount of inoculated sludge is 60% of the reactor volume. After inoculation, add carbohydrate organic waste water as the medium, carry out mechanical stirring and air stirring in the sequencing batch reactor at room temperature, both at the same time, stirring once every 60 minutes, each stirring time is 5 minutes, and the mechanical stirring intensity is 10W /m 3 , the amount of air stirred by air is 0.06m 3 /m 3 cell volume·min, so as to maintain the micro-aerobic condition where the DO in the reactor is 0.4mg/L. The cultivation and acclimatization of acid-producing bacteria generally takes 7 to 14 days. No sludge is discharged during the cultivation process. The supernatant is discharged after the stirring is stopped and allowed to settle for 1 hour every day, and at the same time, an equal volume of carbohydrate organic wastewater is added, and the above cycle operate. The COD concentration and volume of carbohydrate organic wastewater added every day are determined by the organic loading rate and hydraulic retention time. The organic loading rate is 3gCOD/L·d, and the hydraulic retention time is 3d. When the volatile acid concentration in the hydrolysis acidification reactor reaches above 3000mg/L, the cultivation and acclimation of acid-producing bacteria is completed.

待产酸菌培养驯化好后,以污水处理厂污泥作为含有上述培养驯化好的产酸菌的序批式反应器的进入污泥,采用半连续运行方式,每天从序批式反应器的中部瞬时排出一定体积的处理后污泥的泥水混合物,并从反应器的上部进入等体积的污水处理厂污泥。每次排泥前要预先搅拌5min。每天瞬时进入反应器的污泥量由固体停留时间控制,固体停留时间用SRT表示,序批式反应器容积为V,单位m3,每天投加的污泥量为V1,单位m3,V=SRT×V1。本实施例控制进入污泥的VS 15g/L,VS/TS=0.51,SRT 6d,污泥水解酸化时的搅拌方式同上述产酸菌培养驯化阶段的搅拌方式,温度20℃,反应器内的pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持在6.5,不需要另外调节控制。 After the acid-producing bacteria have been cultivated and domesticated, the sludge from the sewage treatment plant is used as the input sludge of the sequencing batch reactor containing the above-mentioned cultivated and domesticated acid-producing bacteria. A certain volume of sludge-water mixture of treated sludge is discharged instantaneously, and enters an equal volume of sewage treatment plant sludge from the upper part of the reactor. Pre-stir for 5 minutes before each mud discharge. The amount of sludge entering the reactor instantaneously every day is controlled by the solid residence time, which is expressed by SRT. The volume of the sequencing batch reactor is V, the unit is m 3 , and the amount of sludge added every day is V 1 , the unit is m 3 . V=SRT×V 1 . This example controls the VS 15g/L entering the sludge, VS/TS=0.51, and SRT 6d. The stirring method during the hydrolysis and acidification of the sludge is the same as that of the above-mentioned acid-producing bacteria cultivation and acclimation stage, the temperature is 20°C, and the reactor The pH value is naturally maintained at 6.5 by the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced, without additional adjustment and control.

排出的泥水混合物后进入沉淀池,沉淀1h,沉淀池上清液作为城市污水生物脱氮除磷工艺的碳源循环利用,沉淀下来的废弃污泥排放。 The discharged mud-water mixture enters the sedimentation tank and settles for 1 hour. The supernatant of the sedimentation tank is recycled as the carbon source of the urban sewage biological nitrogen and phosphorus removal process, and the settled waste sludge is discharged.

实施例2 Example 2

搅拌间隔时间60min,搅拌时间7min,SRT 4d,其它同实施例1。 Stirring interval time 60min, stirring time 7min, SRT 4d, other are with embodiment 1.

实施例3 Example 3

搅拌间隔时间40min,搅拌时间5min,进入污泥的VS 20g/L,VS/TS=0.55,SRT 3d,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持在6.0,其它同实施例1。 The stirring interval is 40 minutes, the stirring time is 5 minutes, the VS entering the sludge is 20g/L, VS/TS=0.55, and the SRT is 3 days. The pH value in the reactor depends on the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it. At 6.0, others are the same as in Example 1.

水解酸化处理后的泥水混合液中挥发酸浓度2693mg/L,污泥产酸量0.14gVFA/gVS,VS去除率35%。 The volatile acid concentration in the mud-water mixture after hydrolysis and acidification treatment was 2693mg/L, the acid production of sludge was 0.14gVFA/gVS, and the removal rate of VS was 35%.

实施例4 Example 4

搅拌间隔时间40min,搅拌时间10min,进入污泥的VS 20g/L,SRT 4d,其它同实施例3。 Stirring interval 40min, stirring time 10min, the VS 20g/L that enters sludge, SRT 4d, other are with embodiment 3.

水解酸化处理后的泥水混合液中挥发酸浓度2965mg/L,污泥产酸量0.15gVFA/gVS,VS去除率39%。 The volatile acid concentration in the mud-water mixture after hydrolysis and acidification treatment was 2965 mg/L, the acid production of the sludge was 0.15 gVFA/gVS, and the removal rate of VS was 39%.

实施例5 Example 5

搅拌间隔时间50min,搅拌时间10min,进入污泥的VS 25g/L,SRT 3d,温度23℃,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持在6.5,其它同实施例3。 The stirring interval is 50 minutes, the stirring time is 10 minutes, the VS entering the sludge is 25g/L, the SRT is 3 days, the temperature is 23°C, and the pH value in the reactor is naturally maintained at 6.5 depending on the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it. , other with embodiment 3.

实施例6 Example 6

搅拌间隔时间40min,搅拌时间10min,进入污泥的VS 25g/L,SRT 4d,温度25℃,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持在7.0,其它同实施例1。 The stirring interval is 40 minutes, the stirring time is 10 minutes, the VS entering the sludge is 25g/L, the SRT is 4 days, and the temperature is 25°C. The pH value in the reactor is naturally maintained at 7.0 by the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it. , other with embodiment 1.

实施例7 Example 7

水解酸化反应器采用序批式反应器,将污水处理厂的好氧污泥接种至序批式反应器中,接种污泥量为反应器容积的70%。接种后,加入碳水化合物类有机废水作为培养基,在序批式反应器中常温下进行机械搅拌和空气搅拌,二者同时进行,每间隔60min搅拌一次,每次搅拌时间7min,机械搅拌强度12W/m3,空气搅拌的空气量0.11m3/m3池容·min,以保持反应器中溶解氧DO为0.6mg/L的微氧条件。产酸菌的培养驯化一般需要7~14天,培养过程中不排泥,每天在停止搅拌并静置沉淀0.5h后排出上清液,同时再补充进入等体积的碳水化合物类有机废水,以上循环操作。每天加入碳水化合物类有机废水的COD浓度和体积由有机负荷率和水力停留时间确定,有机负荷率采用3gCOD/L·d,水力停留时间4d。待水解酸化反应器内挥发酸浓度达到3000mg/L以上,产酸菌的培养驯化结束。 The hydrolytic acidification reactor adopts a sequencing batch reactor, and the aerobic sludge from the sewage treatment plant is inoculated into the sequencing batch reactor, and the amount of inoculated sludge is 70% of the reactor volume. After inoculation, add carbohydrate organic waste water as the culture medium, carry out mechanical stirring and air stirring in the sequencing batch reactor at room temperature, both at the same time, stirring once every 60 minutes, each stirring time is 7 minutes, and the mechanical stirring intensity is 12W /m 3 , the amount of air stirred by air is 0.11m 3 /m 3 cell volume·min, so as to maintain the micro-aerobic condition of dissolved oxygen DO in the reactor at 0.6mg/L. The cultivation and domestication of acid-producing bacteria generally takes 7 to 14 days. No sludge is discharged during the cultivation process. The supernatant is discharged after stopping stirring and standing for 0.5 hours every day. Loop operation. The COD concentration and volume of carbohydrate organic wastewater added every day are determined by the organic loading rate and hydraulic retention time. The organic loading rate is 3gCOD/L·d, and the hydraulic retention time is 4d. When the volatile acid concentration in the hydrolysis acidification reactor reaches above 3000mg/L, the cultivation and acclimation of acid-producing bacteria is completed.

待产酸菌培养驯化好后,以污水处理厂污泥作为含有上述培养驯化好的产酸菌的序批式反应器的进入污泥,采用半连续运行方式,每天瞬时排出一定体积的处理后污泥的泥水混合物并进入等体积的污水处理厂污泥。每次排泥前要预先搅拌8min。控制进入污泥的VS 15g/L,VS/TS=0.6,SRT 6d,污泥水解酸化时的搅拌方式同上述产酸菌培养驯化阶段的搅拌方式,温度23℃,反应器内的pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持在6.5,不需要另外调节控制。 After the acid-producing bacteria have been cultivated and domesticated, the sewage treatment plant sludge is used as the input sludge of the sequencing batch reactor containing the above-mentioned cultivated and domesticated acid-producing bacteria, and a semi-continuous operation mode is adopted to discharge a certain volume of treated sewage instantaneously every day. The mud-water mixture of mud enters an equal volume of sewage treatment plant sludge. Before each mud discharge, pre-stir for 8 minutes. Control the VS 15g/L entering the sludge, VS/TS=0.6, SRT 6d, the stirring method during the hydrolysis and acidification of the sludge is the same as the above-mentioned stirring method in the cultivation and acclimation stage of acid-producing bacteria, the temperature is 23°C, and the pH value in the reactor depends on The acid-producing bacteria in the reactor and the volatile acid and alkalinity they produce are naturally maintained at 6.5, without additional adjustment and control.

排出的泥水混合物后进入沉淀池,沉淀1.5h,沉淀池上清液作为城市污水生物脱氮除磷工艺的碳源循环利用,沉淀下来的废弃污泥排放。 The discharged mud-water mixture enters the sedimentation tank and settles for 1.5 hours. The supernatant of the sedimentation tank is recycled as the carbon source of the urban sewage biological nitrogen and phosphorus removal process, and the settled waste sludge is discharged.

实施例8 Example 8

搅拌时间5min,SRT 4d,其它同实施例7。 Stirring time 5min, SRT 4d, other are with embodiment 7.

实施例9 Example 9

搅拌间隔时间50min,SRT 3d,温度20℃,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.38,其它同实施例7。 The stirring interval is 50min, the SRT is 3 days, the temperature is 20°C, the pH value in the reactor is naturally maintained at 6.38 depending on the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it, and the others are the same as in Example 7.

水解酸化处理后的泥水混合液中挥发酸浓度2425mg/L,污泥产酸量0.16gVFA/gVS,VS去除率38%。 The volatile acid concentration in the mud-water mixture after hydrolysis and acidification treatment was 2425mg/L, the acid production of the sludge was 0.16gVFA/gVS, and the removal rate of VS was 38%.

实施例10 Example 10

搅拌间隔时间60min,搅拌时间10min,进入污泥的VS 20g/L,SRT 4d,其它同实施例9。 Stirring interval time 60min, stirring time 10min, enter the VS 20g/L of sludge, SRT 4d, other are with embodiment 9.

实施例11 Example 11

搅拌间隔时间40min,搅拌时间5min,SRT 6d,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.42,其它同实施例10。 Stirring interval 40min, stirring time 5min, SRT 6d, the pH value in the reactor depends on the volatile acid and the alkalinity that acid-producing bacteria and its production in the reactor are naturally maintained at 6.42, and others are the same as in Example 10.

水解酸化处理后的泥水混合液中挥发酸浓度3665mg/L,污泥产酸量0.18gVFA/gVS,VS去除率36%。 The volatile acid concentration in the mud-water mixture after hydrolysis and acidification treatment was 3665mg/L, the acid production of the sludge was 0.18gVFA/gVS, and the removal rate of VS was 36%.

实施例12 Example 12

搅拌间隔时间50min,温度25℃,进入污泥的VS 25g/L,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.46,其它同实施例7。 The stirring interval is 50min, the temperature is 25°C, and the VS of the sludge is 25g/L. The pH value in the reactor is naturally maintained at 6.46 depending on the acid-producing bacteria and the volatile acid and alkalinity produced in the reactor. Others are the same as in Example 7.

水解酸化处理后的泥水混合液中挥发酸浓度4618mg/L,污泥产酸量0.19gVFA/gVS,VS去除率36%。 The volatile acid concentration in the mud-water mixture after hydrolytic acidification treatment was 4618mg/L, the acid production of sludge was 0.19gVFA/gVS, and the removal rate of VS was 36%.

实施例13 Example 13

进入污泥的VS 20g/L,SRT 4d,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.91,其它同实施例12。 The VS 20g/L that enters sludge, SRT 4d, the pH value in the reactor depends on the volatile acid and the alkalinity that acid-producing bacteria and its production in the reactor are naturally maintained at 6.91, and others are the same as in Example 12.

水解酸化处理后的泥水混合液中挥发酸浓度3391mg/L,污泥产酸量0.17gVFA/gVS,VS去除率38%。 The volatile acid concentration in the mud-water mixture after hydrolysis and acidification treatment was 3391 mg/L, the acid production of the sludge was 0.17 gVFA/gVS, and the VS removal rate was 38%.

实施例14 Example 14

水解酸化反应器采用序批式反应器,将污水处理厂的好氧污泥置入序批式反应器中接种,接种污泥量为反应器容积的70%。接种后,加入碳水化合物类有机废水作为培养基,在序批式反应器中常温下进行机械搅拌和空气搅拌,二者同时进行,每间隔60min搅拌一次,每次搅拌时间10min,机械搅拌强度15W/m3,空气搅拌的空气量0.14m3/m3池容·min,以保持反应器中溶解氧DO为0.8mg/L的微氧条件。产酸菌的培养驯化一般需要7~14天,培养过程中不排泥,每天在停止搅拌并静置沉淀1h后排出上清液,同时再补充进入等体积的碳水化合物类有机废水,以上循环操作。每天加入碳水化合物类有机废水的COD浓度和体积由有机负荷率和水力停留时间确定,有机负荷率采用4gCOD/L·d,水力停留时间3d。待水解酸化反应器内挥发酸浓度达到3000mg/L以上,产酸菌的培养驯化结束。 The hydrolytic acidification reactor adopts a sequencing batch reactor, and the aerobic sludge from the sewage treatment plant is placed in the sequencing batch reactor for inoculation, and the amount of inoculated sludge is 70% of the reactor volume. After inoculation, add carbohydrate organic waste water as the culture medium, carry out mechanical stirring and air stirring in the sequencing batch reactor at room temperature, both at the same time, stirring once every 60 minutes, each stirring time is 10 minutes, and the mechanical stirring intensity is 15W /m 3 , the amount of air stirred by air is 0.14m 3 /m 3 cell volume·min, so as to maintain the micro-aerobic condition of DO in the reactor at 0.8mg/L. The cultivation and acclimatization of acid-producing bacteria generally takes 7 to 14 days. No sludge is discharged during the cultivation process. The supernatant is discharged after the stirring is stopped and allowed to settle for 1 hour every day, and at the same time, an equal volume of carbohydrate organic wastewater is added, and the above cycle operate. The COD concentration and volume of carbohydrate organic wastewater added every day are determined by the organic loading rate and hydraulic retention time. The organic loading rate is 4gCOD/L·d, and the hydraulic retention time is 3d. When the volatile acid concentration in the hydrolysis acidification reactor reaches above 3000mg/L, the cultivation and acclimation of acid-producing bacteria is completed.

待产酸菌培养驯化好后,以污水处理厂污泥作为含有上述培养驯化好的产酸菌的序批式反应器的进入污泥,采用半连续运行方式,每天瞬时排出一定体积的处理后污泥的泥水混合物并进入等体积的污水处理厂污泥。每次排泥前要预先搅拌10min。控制进入污泥的VS 15g/L,VS/TS=0.7,SRT 6d,污泥水解酸化时的搅拌方式同上述产酸菌培养驯化阶段的搅拌方式,温度20℃,反应器内的pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持在6.0,不需要另外调节控制。 After the acid-producing bacteria have been cultivated and domesticated, the sewage treatment plant sludge is used as the input sludge of the sequencing batch reactor containing the above-mentioned cultivated and domesticated acid-producing bacteria, and a semi-continuous operation mode is adopted to discharge a certain volume of treated sewage instantaneously every day. The mud-water mixture of mud enters an equal volume of sewage treatment plant sludge. Pre-stir for 10 minutes before each sludge discharge. Control the VS 15g/L entering the sludge, VS/TS=0.7, SRT 6d, the stirring method during the hydrolysis and acidification of the sludge is the same as the above-mentioned stirring method in the cultivation and acclimation stage of acid-producing bacteria, the temperature is 20°C, and the pH value in the reactor depends on The acid-producing bacteria in the reactor and the volatile acid and alkalinity they produce are naturally maintained at 6.0, without additional adjustment and control.

排出的泥水混合物后进入沉淀池,沉淀2h,沉淀池上清液作为城市污水生物脱氮除磷工艺的碳源循环利用,沉淀下来的废弃污泥排放。 The discharged mud-water mixture enters the sedimentation tank and settles for 2 hours. The supernatant of the sedimentation tank is recycled as the carbon source of the urban sewage biological nitrogen and phosphorus removal process, and the settled waste sludge is discharged.

实施例15 Example 15

搅拌时间7min,SRT 4d,其它同实施例14。 Stirring time 7min, SRT 4d, other are with embodiment 14.

实施例16 Example 16

搅拌时间5min,SRT 3d,其它同实施例14。 Stirring time 5min, SRT 3d, other are with embodiment 14.

实施例17 Example 17

搅拌间隔时间50min,搅拌时间7min,进入污泥的VS 20g/L,SRT 4d,温度23℃,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.5,其它同实施例14。 The stirring interval time is 50 minutes, the stirring time is 7 minutes, the VS entering the sludge is 20g/L, the SRT is 4 days, and the temperature is 23°C. The pH value in the reactor is naturally maintained at 6.5 by the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it. , other with embodiment 14.

实施例18 Example 18

搅拌间隔时间40min,SRT 3d,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.94,温度25℃,其它同实施例17。 The stirring interval is 40min, the SRT is 3d, the pH value in the reactor is naturally maintained at 6.94 depending on the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it, the temperature is 25°C, and the others are the same as in Example 17.

水解酸化处理后的泥水混合液中挥发酸浓度3861mg/L,污泥产酸量0.19gVFA/gVS,VS去除率35%。 The volatile acid concentration in the mud-water mixture after hydrolysis and acidification treatment was 3861mg/L, the acid production of the sludge was 0.19gVFA/gVS, and the removal rate of VS was 35%.

实施例19 Example 19

搅拌间隔时间50min,搅拌时间5min,进入污泥的VS 25g/L,SRT 4d,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为6.5,其它同实施例18。 The stirring interval time is 50 minutes, the stirring time is 5 minutes, the VS entering the sludge is 25g/L, and the SRT is 4 days. The pH value in the reactor is naturally maintained at 6.5 depending on the acid-producing bacteria in the reactor and the volatile acid and alkalinity produced by it. Others are implemented in the same way. Example 18.

实施例20 Example 20

搅拌间隔时间60min,搅拌时间5min,反应器内pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持为7.0,其它同实施例18。 The stirring interval was 60 minutes, and the stirring time was 5 minutes. The pH value in the reactor was naturally maintained at 7.0 by acid-producing bacteria and the volatile acid and alkalinity produced in the reactor, and the others were the same as in Example 18.

实施例21 Example 21

水解酸化反应器采用序批式反应器,将污水处理厂曝气池回流污泥置入序批式反应器中接种,接种污泥量为反应器容积的50%。接种后,加入碳水化合物类有机废水作为培养基,在序批式反应器中常温下进行机械搅拌和空气搅拌,二者同时进行,每间隔60min搅拌一次,每次搅拌时间5min,机械搅拌强度15W/m3,空气搅拌的空气量0.14m3/m3池容·min,以保持反应器中溶解氧DO为0.8mg/L的微氧条件。产酸菌的培养驯化一般需要7~14天,培养过程中不排泥,每天在停止搅拌并静置沉淀0.5h后排出上清液,同时再补充进入等体积的碳水化合物类有机废水,以上循环操作。每天加入碳水化合物类有机废水的COD浓度和体积由有机负荷率和水力停留时间确定,有机负荷率采用4gCOD/L·d,水力停留时间4d。待水解酸化反应器内挥发酸浓度达到3000mg/L以上,产酸菌的培养驯化结束。 The hydrolytic acidification reactor adopts a sequencing batch reactor, and the return sludge from the aeration tank of the sewage treatment plant is placed in the sequencing batch reactor for inoculation, and the amount of inoculated sludge is 50% of the reactor volume. After inoculation, add carbohydrate organic waste water as the medium, carry out mechanical stirring and air stirring in the sequencing batch reactor at room temperature, both at the same time, stirring once every 60 minutes, each stirring time is 5 minutes, and the mechanical stirring intensity is 15W /m 3 , the amount of air stirred by air is 0.14m 3 /m 3 cell volume·min, so as to maintain the micro-aerobic condition of DO in the reactor at 0.8mg/L. The cultivation and domestication of acid-producing bacteria generally takes 7 to 14 days. No sludge is discharged during the cultivation process. The supernatant is discharged after stopping stirring and standing for 0.5 hours every day. Loop operation. The COD concentration and volume of carbohydrate organic wastewater added every day are determined by the organic loading rate and hydraulic retention time. The organic loading rate is 4gCOD/L·d, and the hydraulic retention time is 4d. When the volatile acid concentration in the hydrolysis acidification reactor reaches above 3000mg/L, the cultivation and acclimation of acid-producing bacteria is completed.

待产酸菌培养驯化好后,以污水处理厂污泥作为含有上述培养驯化好的产酸菌的序批式反应器的进入污泥,采用半连续运行方式,每天瞬时排出一定体积的处理后污泥的泥水混合物并进入等体积的污水处理厂污泥。每次排泥前要预先搅拌10min。控制进入污泥的VS 15g/L,VS/TS=0.65,SRT 6d,污泥水解酸化时的搅拌方式同上述产酸菌培养驯化阶段的搅拌方式,温度20℃,反应器内的pH值依靠反应器内产酸菌及其产生的挥发酸和碱度自然维持在6.5,不需要另外调节控制。 After the acid-producing bacteria have been cultivated and domesticated, the sewage treatment plant sludge is used as the input sludge of the sequencing batch reactor containing the above-mentioned cultivated and domesticated acid-producing bacteria, and a semi-continuous operation mode is adopted to discharge a certain volume of treated sewage instantaneously every day. The mud-water mixture of mud enters an equal volume of sewage treatment plant sludge. Pre-stir for 10 minutes before each sludge discharge. Control the VS 15g/L entering the sludge, VS/TS=0.65, SRT 6d, the stirring method during the hydrolysis and acidification of the sludge is the same as the above-mentioned stirring method in the cultivation and acclimation stage of acid-producing bacteria, the temperature is 20°C, and the pH value in the reactor depends on The acid-producing bacteria in the reactor and the volatile acid and alkalinity they produce are naturally maintained at 6.5, without additional adjustment and control.

排出的泥水混合物后进入沉淀池,沉淀2h,沉淀池上清液作为城市污水生物脱氮除磷工艺的碳源循环利用,沉淀下来的废弃污泥排放。 The discharged mud-water mixture enters the sedimentation tank and settles for 2 hours. The supernatant of the sedimentation tank is recycled as the carbon source of the urban sewage biological nitrogen and phosphorus removal process, and the settled waste sludge is discharged.

Figure 753994DEST_PATH_IMAGE001
Figure 753994DEST_PATH_IMAGE001

Claims (3)

1.一种微氧水解酸化处理污泥方法,包括以下步骤: 1. A microaerobic hydrolysis acidification method for treating sludge, comprising the following steps: a)、在水解酸化反应器中接种占反应器容积50%~70%的污水处理厂好氧污泥,并加入碳水化合物类有机废水作为培养基,进行机械搅拌和空气搅拌,二者同时进行,每间隔40~60min搅拌一次,每次搅拌时间5~10min,机械搅拌强度10~15W/m3,空气搅拌空气量0.06~0.14m3/(m3池容·min),以保持水解酸化反应器中溶解氧DO为0.4~0.8mg/L的微氧条件;在培养驯化过程中不排泥,只间歇排放上清液,排出上清液后再补入等体积的碳水化合物类有机废水,排上清液前停止搅拌,沉淀0.5-1h,循环操作;每天加入碳水化合物类有机废水的COD浓度和体积由有机负荷率和水力停留时间确定,有机负荷率3~4gCOD/(L·d),水力停留时间3~4d;待水解酸化反应器内挥发酸浓度达到3000mg/L以上时,完成产酸菌的培养驯化; a) Inoculate the aerobic sludge from the sewage treatment plant accounting for 50% to 70% of the reactor volume in the hydrolytic acidification reactor, and add carbohydrate organic waste water as the medium, and carry out mechanical stirring and air stirring, both at the same time , stirring once every 40-60 minutes, each stirring time is 5-10 minutes, the mechanical stirring intensity is 10-15W/m 3 , and the air volume of air stirring is 0.06-0.14m 3 /(m 3 pool volume min), so as to maintain hydrolysis and acidification Dissolved oxygen DO in the reactor is under micro-aerobic conditions of 0.4-0.8 mg/L; no sludge is discharged during the cultivation and acclimation process, only the supernatant is discharged intermittently, and after the supernatant is discharged, an equal volume of carbohydrate-based organic wastewater is added , stop stirring before discharging the supernatant, settle for 0.5-1h, and cycle; the COD concentration and volume of carbohydrate organic wastewater added every day are determined by the organic load rate and hydraulic retention time, and the organic load rate is 3-4gCOD/(L·d ), the hydraulic retention time is 3 to 4 days; when the volatile acid concentration in the hydrolytic acidification reactor reaches 3000mg/L or more, the cultivation and acclimation of acid-producing bacteria is completed; b)、将挥发性固体浓度15~25g/L,挥发性固体浓度/总固体浓度比值大于0.5的污水处理厂污泥作为进入污泥,进入步骤a)已经培养驯化好产酸菌的反应器中,进行机械搅拌和空气搅拌,二者同时进行,每间隔40~60min搅拌一次,每次搅拌时间5~10min,机械搅拌强度10~15W/m3,空气搅拌空气量0.06~0.14m3/(m3池容·min);进入反应器中污泥满足3~6d的固体停留时间后排出,每天排泥前要搅拌5~10min,排出富含挥发酸的泥水混合液,同时再补入等体积的新污水处理厂污泥,循环操作; b) Use sewage treatment plant sludge with a volatile solid concentration of 15-25g/L and a volatile solid concentration/total solid concentration ratio greater than 0.5 as incoming sludge, and enter step a) into the reactor in which acid-producing bacteria have been cultivated and domesticated In the process, mechanical stirring and air stirring are carried out at the same time, stirring once every 40-60 minutes, each stirring time is 5-10 minutes, the mechanical stirring intensity is 10-15W/m 3 , and the air stirring air volume is 0.06-0.14m 3 / (m 3 tank capacity min); the sludge entering the reactor is discharged after the solid residence time of 3-6 days is met, and the sludge is stirred for 5-10 minutes before the sludge is discharged every day, and the mud-water mixture rich in volatile acids is discharged, and at the same time, it is added Equal volume of new sewage treatment plant sludge, cycle operation; c)、步骤b)排出的富含挥发酸的泥水混合液进入沉淀池进行泥水分离,沉淀池上清液回收作为城市污水生物脱氮除磷工艺的碳源,沉淀的废弃污泥直接排放。 c), the volatile acid-rich mud-water mixture discharged from step b) enters the sedimentation tank for mud-water separation, the supernatant of the sedimentation tank is recovered as a carbon source for the urban sewage biological denitrification and phosphorus removal process, and the deposited waste sludge is directly discharged. 2.根据权利要求1所述的微氧水解酸化处理污泥方法,其特征是所述水解酸化反应器在20℃~25℃下进行水解酸化。 2. The microaerobic hydrolysis acidification method for sludge treatment according to claim 1, characterized in that the hydrolysis acidification reactor is carried out at 20°C to 25°C for hydrolysis acidification. 3.根据权利要求1所述的微氧水解酸化处理污泥方法,其特征是所述泥水混合液进入沉淀池进行泥水分离的水力停留时间为1~2h。 3. The method for treating sludge with microaerobic hydrolysis and acidification according to claim 1, characterized in that the hydraulic retention time of the mud-water mixture entering the sedimentation tank for mud-water separation is 1 to 2 hours.
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